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1.
《地学前缘(英文版)》2020,11(6):2221-2242
We present the first evidence of Archean oceanic crust submitted to Proterozoic high-pressure (HP) metamorphism in the South American Platform. Sm–Nd and Lu–Hf isotopic data combined with U–Pb geochronological data from the Campo Grande area, Rio Grande do Norte domain, in the Northern Borborema Province, reflect a complex Archean (2.9 ​Ga and 2.6 ​Ga) and Paleoproterozoic (2.0 ​Ga) evolution, culminating in the Neoproterozoic Brasiliano/Pan-African orogeny (ca. 600 Ma). The preserved mafic rocks contain massive poikiloblastic garnet and granoblastic amphibole with variable proportions of plagioclase ​+ ​diopside in symplectitic texture, typical of high-pressure rocks. These clinopyroxene-garnet amphibolites and the more common garnet amphibolites from the Campo Grande area are exposed as rare lenses within an Archean migmatite complex. The amphibolite lenses represent 2.65 ​Ga juvenile tholeiitic magmatism derived from depleted mantle sources (positive εHf(t) values of +3.81 to +30.66) later enriched by mantle metasomatism (negative εNd(t) values of –7.97). Chondrite and Primitive Mantle-normalized REE of analyzed samples and discriminant diagrams define two different oceanic affinities, with E-MORB and OIB signature. Negative Eu anomalies (Eu/Eu1 ​= ​0.75–0.95) indicate depletion of plagioclase in the source. Inherited zircon cores of 3.0–2.9 ​Ga in analyzed samples indicate that the Neoarchean tholeiitic magmatism was emplaced into 2923 ​± ​14 ​Ma old Mesoarchean crust (εNd(t) ​= ​–2.58 and Nd TDM ​= ​3.2 ​Ga) of the Rio Grande do Norte domain. The age of retro-eclogite facies metamorphism is not yet completely understood. We suggest that two high-grade metamorphic events are recognized in the mafic rocks: the first at 2.0 ​Ga, recorded in some samples, and the second, at ca. 600 Ma, stronger and more pervasive and recorded in several of the mafic rock samples. The Neoproterozoic zircon grains are found in symplectite texture as inclusions in the garnet grains and represent the age of HP conditions in the area. These zircon grains show a younger cluster of concordant analyses between 623 ​± ​3 ​Ma and 592 ​± ​5 ​Ma with εHf(t) values of +0.74 to –65.88. Thus, the Campo Grande rock assemblage is composed of Archean units that were amalgamated to West Gondwana during Neoproterozoic Brasiliano orogeny continent-continent collision and crustal reworking.  相似文献   

2.
《地学前缘(英文版)》2020,11(5):1581-1592
The newly-discovered supergiant Huayangchuan uranium(U)-polymetallic(Sr,Se,REEs,Ba,Nb and Pb) deposit is located in the Qinling Orogen,central China.The deposit underwent multistage mineralization,with the main carbonatite ore stage being the most important for the U,Nb,REE,Sr and Ba endowments.According to the mineral assemblages,the main carbonatite ore stage can be divided into three substages,i.e.,sulfate(Ba-Sr),alkali-rich U and REE-U mineralization.Main-stage titanite from the Huayangchuan igneous carbonatite are rich in high field strength elements(HFSEs,e.g.,Zr,Nb and REEs),and show clear elemental substitutions(e.g.,Ti vs.Nb+Fe+Al and Ca+Ti vs.Fe+Al+REE).High-precision LA-ICP-MS titanite dating yielded a U-Pb age of 209.0 ± 2.9 Ma,which represents the mainstage mineralization age at Huayangchuan,and is coeval with the local carbonatite dyke intrusion.This mineralization age is further constrained by the Re-Os dating of molybdenite from the Huayangchuan carbonatite,which yielded a weighted mean age of 196.8 ± 2.4 Ma.Molybdenite Re contents(337.55-392.75 ppm) and C-OSr-Nd-Pb isotopic evidence of the Huayangchuan carbonatite both suggest a mantle origin for the carbonatite.Our study supports that the Late Triassic carbonatite magmatism was responsible for the world-class U-Mo-REE mineralization in the Qinling Orogen,and that the regional magmatism and ore formation was likely caused by the closure of the Mianlue ocean and the subsequent North China-South China continent-continent collision.  相似文献   

3.
《地学前缘(英文版)》2020,11(6):2103-2125
The investigated mantle bodies from the External Ligurians (Groppo di Gorro and Mt. Rocchetta) show evidences of a complex evolution determined by an early high temperature metasomatism, due to percolating melts of asthenospheric origin, and a later metasomatism at relatively high temperature by hydrothermal fluids, with formation of rodingites. At Groppo di Gorro, the serpentinization and chloritization processes obliterated totally the pyroxenite protolith, whereas at Mt. Rocchetta relics of peridotite and pyroxenite protoliths were preserved from serpentinization. The rodingite parageneses consist of diopside ​+ ​vesuvianite ​+ ​garnet ​+ ​calcite ​+ ​chlorite at Groppo di Gorro and garnet ​+ ​diopside ​+ ​serpentine ​± ​vesuvianite ​± ​prehnite ​± ​chlorite ​± ​pumpellyite at Mt. Rocchetta. Fluid inclusion measurements show that rodingitization occurred at relatively high temperatures (264–334 ​°C at 500 ​bar and 300–380 ​°C at 1 ​kbar). Garnet, the first phase of rodingite to form, consists of abundant hydrogarnet component at Groppo di Gorro, whereas it is mainly composed of grossular and andradite at Mt. Rocchetta. The last stage of rodingitization is characterized by the vesuvianite formation. Hydrogarnet nucleation requires high Ca and low silica fluids, whereas the formation of vesuvianite does not need CO2-poor fluids. The formation of calcite at Groppo di Gorro points to mildly oxidizing conditions compatible with hydrothermal fluids; the presence of andradite associated with serpentine and magnetite at Mt. Rocchetta suggests Fe3+-bearing fluids with fO2 slightly higher than iron-magnetite buffer. We propose that the formation of the studied rodingite could be related to different pulses of hydrothermal fluids mainly occurring in an ocean-continent transitional setting and, locally, in an accretionary prism associated with intra-oceanic subduction.  相似文献   

4.
大量来自于华北陆块的高压变质岩被发现发育于苏鲁构造杂岩带中,给俯冲带上盘物质如何卷入陆-陆俯冲碰撞作用的研究带来新的契机.通过对乳山地区（含榴）斜长角闪岩进行岩石学、矿物化学及相平衡模拟的研究,发现其保留有3个不同变质演化阶段的矿物组合,峰前矿物组合为粗粒石榴子石+斜长石+角闪石+石英+钛铁矿;峰期矿物组合由石榴子石+单斜辉石+斜长石+角闪石+石英+钛铁矿组成,为典型高角闪岩相矿物组合;峰后退变质阶段矿物组合为角闪石+斜长石+石英+石榴子石+钛铁矿,发育有典型的“白眼圈”结构.相平衡模拟与温压计算表明,乳山午极石榴斜长角闪岩峰前变质阶段的P-T条件分别为P=6.4~7.0 kbar、T=610~640℃,表明其俯冲至30 km左右的地壳深度;峰期变质阶段P-T条件分别为P=9.3~10.0 kbar、T=700~730℃,表明其已俯冲至36~40 km的地壳深度,峰后退变质阶段P-T条件分别为P=5.2~5.8 kbar、T=680~710℃.锆石U-Pb定年结果表明乳山午极石榴斜长角闪岩原岩时代为1 734±24 Ma,龙角山水库斜长角闪岩变质时代为1 849±28 Ma,研究表明二者均来源于华北构造岩片.结合前人研究资料,推测乳山地区石榴斜长角闪岩原岩可能经历三叠纪俯冲作用并发生变质;其与杂岩带中来自华南的构造岩片发生混杂,共同构成华北-华南板块间宽约80~100 km的构造杂岩带.   相似文献   

5.
Eclogite boudins occur within an orthogneiss sheet enclosed in a Barrovian metapelite‐dominated volcano‐sedimentary sequence within the Velké Vrbno unit, NE Bohemian Massif. A metamorphic and lithological break defines the base of the eclogite‐bearing orthogneiss nappe, with a structurally lower sequence without eclogite exposed in a tectonic window. The typical assemblage of the structurally upper metapelites is garnet–staurolite–kyanite–biotite–plagioclase–muscovite–quartz–ilmenite ± rutile ± silli‐manite and prograde‐zoned garnet includes chloritoid–chlorite–paragonite–margarite, staurolite–chlorite–paragonite–margarite and kyanite–chlorite–rutile. In pseudosection modelling in the system Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O (NCKFMASH) using THERMOCALC, the prograde path crosses the discontinuous reaction chloritoid + margarite = chlorite + garnet + staurolite + paragonite (with muscovite + quartz + H2O) at 9.5 kbar and 570 °C and the metamorphic peak is reached at 11 kbar and 640 °C. Decompression through about 7 kbar is indicated by sillimanite and biotite growing at the expense of garnet. In the tectonic window, the structurally lower metapelites (garnet–staurolite–biotite–muscovite–quartz ± plagioclase ± sillimanite ± kyanite) and amphibolites (garnet–amphibole–plagioclase ± epidote) indicate a metamorphic peak of 10 kbar at 620 °C and 11 kbar and 610–660 °C, respectively, that is consistent with the other metapelites. The eclogites are composed of garnet, omphacite relicts (jadeite = 33%) within plagioclase–clinopyroxene symplectites, epidote and late amphibole–plagioclase domains. Garnet commonly includes rutile–quartz–epidote ± clinopyroxene (jadeite = 43%) ± magnetite ± amphibole and its growth zoning is compatible in the pseudosection with burial under H2O‐undersaturated conditions to 18 kbar and 680 °C. Plagioclase + amphibole replaces garnet within foliated boudin margins and results in the assemblage epidote–amphibole–plagioclase indicating that decompression occurred under decreasing temperature into garnet‐free epidote–amphibolite facies conditions. The prograde path of eclogites and metapelites up to the metamorphic peak cannot be shared, being along different geothermal gradients, of about 11 and 17 °C km?1, respectively, to metamorphic pressure peaks that are 6–7 kbar apart. The eclogite–orthogneiss sheet docked with metapelites at about 11 kbar and 650 °C, and from this depth the exhumation of the pile is shared.  相似文献   

6.
Numerous lenses of eclogite occur in a belt of augen orthogneisses in the Gubaoquan area in the southern Beishan orogen, an eastern extension of the Tianshan orogen. With detailed petrological data and phase relations, modelled in the system NCFMASHTO with thermocalc , a quantitative P–T path was estimated and defined a clockwise P–T path that showed a near isothermal decompression from eclogite facies (>15.5 kbar, 700–800 °C, omphacite + garnet) to high‐pressure granulite facies (12–14 kbar, 700–750 °C, clinopyroxene + sodic plagioclase symplectitic intergrowths around omphacite), low‐pressure granulite facies (8–9.5 kbar, ～700 °C, orthopyroxene + clinopyroxene + plagioclase symplectites and coronas surrounding garnet) and amphibolite facies (5–7 kbar, 600–700 °C, hornblende + plagioclase symplectites). The major and trace elements and Sm–Nd isotopic data suggest that most of the Beishan eclogite samples had a protolith of oceanic crust with geochemical characteristics of an enriched or normal mid‐ocean ridge basalt. The U–Pb dating of the Beishan eclogites indicates an Ordovician age of c. 467 Ma for the eclogite facies metamorphism. An 39Ar/40Ar age of c. 430 Ma for biotite from the augen gneiss corresponds to the time of retrograde metamorphism. The combined data from geological setting, bulk composition, clockwise P–T path and geochronology support a model in which the Beishan eclogites started as oceanic crust in the Palaeoasian Ocean, which was subducted to eclogite depths in the Ordovician and exhumed in the Silurian. The eclogite‐bearing gneiss belt marks the position of a high‐pressure Ordovician suture zone, and the calculated clockwise P–T path defines the progression from subduction to exhumation.  相似文献   

7.
The Huai’an Complex in the north-western Trans-North China Orogen, North China Craton is recognized to have undergone high-pressure metamorphism with controversial ages. Two mafic granulite samples (17HT13 and 16HT22) from Huangtuyao of the Huai’an Complex are documented for metamorphism based on petrography, mineral chemistry, phase equilibria modelling and zircon dating. The rocks comprise garnet, clinopyroxene, orthopyroxene, amphibole, plagioclase and ilmenite. They show clockwise P-T paths involving the pre-Tmax decompressional heating, the Tmax and the post-Tmax cooling stages. The pre-Tmax decompressional heating is revealed by the core-rim/mantle anorthite-ascending zoning in coarse-grained plagioclase. The Tmax stage is constrained to 8.5–10.5 kbar/980–1010 °C (17HT13) and 7.5–9.5 kbar/1000–1030 °C (16HT22) by the high Ti content of amphibole, and the anorthite content of coarse-grained plagioclase rims/mantles and fine-grained plagioclase cores. These temperatures are slightly higher than the results of amphibole thermometers (∼940–980 °C). The post-Tmax cooling is defined by the later growth of amphibole and some conventional geothermobarometers. Because it is dominated by temperature with ilmenite present, the Ti content of amphibole is proposed as a reliable thermometer, and the Ti-rich amphibole with Ti > 0.28 p.f.u. or TiO2 > 2.4–2.6 wt% is indicative of ultrahigh-temperature (>900 °C, UHT) conditions. The anorthite content of plagioclase is also significant in confining peak temperatures for UHT granulite but requires defining proper water content. Zircon dating for 17HT13 yields an upper intercept age of 1910 ± 35 Ma, representing the cooling of UHT granulite. We conclude that the Huai’an Complex may have at least locally undergone UHT metamorphism at ∼1.92–1.91 Ga after high-pressure granulite metamorphism at ∼1.95 Ga, similar to the Jining Complex. Therefore, the Huai’an and Jining Complexes share the same tectonic evolution involving ∼1.95 Ga crustal thickening, ∼1.92–1.91 Ga extension with regional or local UHT metamorphism, and subsequent cooling and uplifting.  相似文献   

8.
 The beginning of dehydration melting in the tonalite system (biotite-plagioclase-quartz) is investigated in the pressure range of 2–12 kbar. A special method consisting of surrounding a crystal of natural plagioclase (An45) with a biotite-quartz mixture, and observing reactions at the plagioclase margin was employed for precise determination of the solidus for dehydration melting. The beginning of dehydration melting was worked out at 5 kbar for a range of compositions of biotite varying from iron-free phlogopite to iron-rich Ann70, with and without titanium, fluorine and extra aluminium in the biotite. The dehydration melting of phlogopite + plagioclase (An45) + quartz begins between 750 and 770°C at pressures of 2 and 5 kbar, at approximately 740°C at 8 kbar and between 700 and 730°C at 10 kbar. At 12 kbar, the first melts are observed at temperatures as low as 700°C. The data indicate an almost vertical dehydration melting solidus curve at low pressures which bends backward to lower temperatures at higher pressures (> 5 kbar). The new phases observed at pressures ≤ 10 kbar are melt + enstatite + clinopyroxene + potassium feldspar ± amphibole. In addition to these, zoisite was also observed at 12 kbar. With increasing temperature, phlogopite becomes enriched in aluminium and deficient in potassium. Substitution of octahedral magnesium by aluminium and titanium in the phlogopite, as well as substitution of hydroxyl by fluorine, have little effect on the beginning of dehydration melting temperatures in this system. The dehydration melting of biotite (Ann50) + plagioclase (An45) + quartz begins 50°C below that of phlogopite bearing starting composition. Solid reaction products are orthopyroxene + clinopyroxene + potassium feldspar ± amphibole. Epidote was also observed above 8 kbar, and garnet at 12 kbar (750°C). The experiments on the iron-bearing system performed at ≤ 5 kbar were buffered with NiNiO. The f O 2 in high pressure runs lies close to CoCoO. With the substitution of octahedral magnesium and iron by aluminium and titanium, and replacement of hydroxyl by fluorine in biotite, the beginning of dehydration melting temperatures in this system increase up to 780°C at 5 kbar, which is 70°C above the beginning of dehydration melting of the assemblage containing biotite (Ann50) of ideal composition. The dehydration melting at 5 kbar in the more iron-rich Ann70-bearing starting composition begins at 730°C, and in the Ann25-bearing assemblage at 710°C. This indicates that quartz-biotite-plagioclase assemblages with intermediate compositions of biotite (Ann25 and Ann50) melt at lower temperatures as compared to those containing Fe-richer or Mg-richer biotites. This study shows that the dehydration melting of tonalites may begin at considerably lower temperatures than previously thought, especially at high pressures (>5 kbar). Received: 27 December 1995 / Accepted: 7 May 1996  相似文献   

9.
《地学前缘(英文版)》2020,11(6):2271-2286
In this study we present new mineral chemistry, whole-rock geochemical and zircon U–Pb geochronological data for 12 metamafic dykes in the mantle sequence of the Sangsang ophiolite in South Tibet (China). Modal analyses of these dykes gave averages of ~40%–65% plagioclase and ~35%–60% amphibole and small amounts of (igneous) clinopyroxene, epidote and opaque minerals. This mineral assemblage resembles that of typical orthoamphibolites. Nevertheless, due to the absence of foliation the investigated rocks are described as metamafic lithologies. These rocks have primitive mantle (PM)-normalized multi-element patterns with negative Nb and Ta anomalies as well as weak, negative Ti anomalies. In addition, they have initial 87Sr/86Sr ratios [(87Sr/86Sr)i] of 0.702844–0.703581, initial 143Nd/144Nd ratios [(143Nd/144Nd)i] of 0.512891–0.512959 and high εNd(t) values (+7.9 to +9.3). Uranium-Pb ages of magmatic zircons separated from the investigated metamafic dykes indicate that the parental melts of their protoliths intruded the Sangsang mantle at ~119.0–118.5 ​Ma.The metamorphic mineral assemblages recognized in the investigated dykes are suggestive of a retrograde metamorphic process, from (epidote-)amphibolite facies (~470–610 ​°C, ~1.9–4.3 ​kbar) and to prehnite-pumpellyite facies (≤280 ​°C, ≤ 3 ​kbar), active within a rift-produced oceanic lithosphere. Microtextural and geochemical data suggest that the protoliths of the dykes were most likely massive gabbros. Compositional data show that the parental magmas of the gabbroic protoliths were generated by melting of a depleted mantle (DM) source that had been weakly modified by fluids emanating from a subducted oceanic lithospheric slab. The age of the gabbroic protoliths is slightly younger than the existing ages for ophiolites from the central Yarlung-Zangbo Suture Zone (YZSZ) in the literature (~129–123 ​Ma). We, therefore, suggest that the gabbroic protoliths of the Sangsang metamafic dykes were formed in an incipient forearc setting during Neo-Tethyan subduction re-initiation (Aptian). Our tectonomagmatic model provides insights into the igneous accretion and post-solidification evolution of the oceanic lithosphere in South Tibet.  相似文献   

10.
The Xilingol Complex comprises biotite gneisses and amphibolite interlayers with extensive migmatization. Four representative samples were documented and found to record either two or three metamorphic stages. Phase modelling using thermocalc suggests that the observed assemblages represent the final stages that underwent cooling from temperature peaks, and are consistent with a fluid‐absent solidus in P–T pseudosections. Their P–T conditions are further constrained to be 5–6 kbar/680–725°C and 4–5 kbar/650–680°C for two garnet‐bearing gneiss samples, 4–5 kbar/660–730°C for a cordierite‐bearing gneiss sample, and 4–5 kbar/680–710°C for an amphibolite sample based on mineral composition isopleths, involving measured Mg content in biotite, anorthite in plagioclase, grossular and pyrope in garnet and Ti content in amphibole. The peak temperature conditions recovered are 760–790°C or >760°C at 5–6 kbar based on the composition isopleths of plagioclase, biotite, garnet and especially the comparison of melt contents between the calculated and observed. A pre‐peak heating process with slight decompression can be suggested for some samples on the basis of the core–rim increase in the plagioclase anorthite, and the stability of ilmenite. Zircon U–Pb dating using the LA‐ICP‐MS method provides systemic constraints on the metamorphic ages of the Xilingol Complex to be 348–305 Ma, interpreted to represent the post‐peak cooling stages. Moreover, metagabbroic dykes that intruded into the Xilingol Complex yield 317 ± 3 Ma from magmatic zircon, and are considered to have played a significant role for heat advection triggering the high‐T and low‐P metamorphism. Thus, the clockwise P–T paths involving pre‐peak heating, peak and post‐peak cooling recovered for the Xilingol Complex are consistent with an extensional setting in the Carboniferous that developed on a previous orogen in response to addition of mantle‐derived materials probably together with upwelling of the asthenospheric mantle.  相似文献   

11.
The basement of the central Qilian fold belt exposed along the Minhe-Ledu highway consists of psammitic schists, metabasitic rocks, and crystalline limestone. Migmatitic rocks occur sporadically among psammitic schist and metabasitic rocks. The mineral assemblage of psammitic schist is muscovite + biotite + feldspar + quartz ± tourmaline ± titanite ± sillimanite and that of metabasitic rocks is amphibole + plagioclase + biotite ± apatite ± magnetite ± pyroxene ± garnet ± quartz. The migmatitic rock consists of leucosome and restite of various volume proportions; the former consists of muscovite + alkaline feldspar + quartz ± garnet ± plagioclase while the latter is either fragments of psammitic schist or those of metabasitic rock. The crystalline limestone consists of calcite that has been partly replaced by olivine. The olivine was subsequently altered to serpentine. Weak deformations as indicated by cleavages and fractures were imposed prominently on the psammitic schists, occasionally on me  相似文献   

12.
ABSTRACT The high-grade rocks (metapelite, quartzite, metagabbro) of the Hisøy-Torungen area represent the south-westernmost exposures of granulites in the Proterozoic Bamble sector, south Norway. The area is isoclinally folded and a metamorphic P–T–t path through four successive stages (M1-M4) is recognized. Petrological evidence for a prograde metamorphic event (M1) is obtained from relict staurolite + chlorite + albite, staurolite + hercynite + ilmenite, cordierite + sillimanite, fine-grained felsic material + quartz and hercynite + biotite ± sillimanite within metapelitic garnet. The phase relations are consistent with a pressure of 3.6 ± 0.5 kbar and temperatures up to 750–850°C. M1 is connected to the thermal effect of the gabbroic intrusions prior to the main (M2) Sveconorwegian granulite facies metamorphism. The main M2 granulite facies mineral assemblages (quartz+ plagioclase + K-feldspar + garnet + biotite ± sillimanite) are best preserved in the several-metre-wide Al-rich metapelites, which represent conditions of 5.9–9.1 kbar and 790–884°C. These P–T conditions are consistent with a temperature increase of 80–100°C relative to the adjacent amphibolite facies terranes. No accompanying pressure variations are recorded. Up to 1-mm-wide fine-grained felsic veinlets appear in several units and represent remnants of a former melt formed by the reaction: Bt + Sil + Qtz→Grt + lq. This dehydration reaction, together with the absence of large-scale migmatites in the area, suggests a very reduced water activity in the rocks and XH2O = 0.25 in the C–O–H fluid system was calculated for a metapelitic unit. A low but variable water activity can best explain the presence or absence of fine-grained felsic material representing a former melt in the different granulitic metapelites. The strongly peraluminous composition of the felsic veinlets is due to the reaction: Grt +former melt ± Sil→Crd + Bt ± Qtz + H2O, which has given poorly crystalline cordierite aggregates intergrown with well-crystalline biotite. The cordierite- and biotite-producing reaction constrains a steep first-stage retrograde (relative to M2) uplift path. Decimetre- to metre-wide, strongly banded metapelites (quartz + plagioclase + biotite + garnet ± sillimanite) inter-layered with quartzites are retrograded to (M3) amphibolite facies assemblages. A P–T estimate of 1.7–5.6 kbar, 516–581°C is obtained from geothermobarometry based on rim-rim analyses of garnet–biotite–plagioclase–sillimanite–quartz assemblages, and can be related to the isoclinal folding of the rocks. M4 greenschist facies conditions are most extensively developed in millimetre-wide chlorite-rich, calcite-bearing veins cutting the foliation.  相似文献   

13.
在拉萨地块林芝杂岩体中新发现的石榴角闪岩矿物组合为石榴子石、角闪石、十字石、绿泥石、斜长石、钠云母以及少量的钛铁矿和磷灰石。石榴角闪岩中石榴石核部富锰(Xsps=0.12~0.15)贫铁(Xalm=0.45~0.50)而石榴子石边部相对贫锰(Xsps=0.01~0.03)富铁(Xalm=0.60~0.65),表明石榴子石的核部和边部分别形成于变质作用两个不同阶段。从核部到边部,镁铝榴石升高而钙铝榴石降低,表现为进变质环带特征,这表明石榴子石核部形成于进变质过程。生长在不同的变质阶段的角闪石具有不同的成分特征,作为变质基性岩中罕见的富铝矿物,十字石的结构特征记录了不同变质阶段的信息,结合石榴石的成分和结构特征,为相平衡模拟研究其P-T演化过程提供了可能。我们利用Perplex相图模拟软件在Mn-NCKMASHO体系中模拟出该石榴角闪岩的视剖面图,利用石榴子石边部镁铝榴石和钙铝榴石含量等值线确定出石榴角闪岩峰期温压为:610~630oC,12×105~13×105k Pa,对应峰期矿物组合为石榴子石,角闪石,十字石和白云母。同时结合十字石保存的退变信息得到该石榴角闪岩经历了一个顺时针的变质演化轨迹。  相似文献   

14.
Abstract Blueschists occurring as layers in calcite marbles of the Meliata unit occur along the so-called Roznava tectonic line situated in the southern part of the Gemericum, Slovakia. Mineral assemblages and compositions from seven blueschists localities and one occurrence of amphibolite facies rocks overprinted by blueschist metamorphism were investigated. The most common minerals in the blueschists are blue amphibole, epidote and albite. Some Fe2+- and Al-rich rocks also contain garnet and chloritoid, respectively. Na-pyroxene with a maximum 50% jadeite component was also found. The blue amphiboles correspond mostly to crossite and also to glaucophane and ferroglaucophane in some samples. Almandine- and spessartine-rich garnet has very low MgO content (<3 wt%). The Si content in phengite ranges between 3.3 and 3.5 pfu calculated on the basis of 11 oxygens. The zoning patterns of blue amphibole, garnet and chloritoid suggest their formation during a prograde stage of metamorphism. The P-T conditions of metamorphism are estimated to be about 380–460° C and 10–13 kbar. Pressures of 7.5–8.5 kbar and temperatures of 350–370° C were obtained for some actinolite- and aegirine-rich rocks. Apart from chlorite, other mafic minerals formed during retrograde metamorphism are biotite and occasionally also actinolite.  相似文献   

15.
Eclogites and related high‐P metamorphic rocks occur in the Zaili Range of the Northern Kyrgyz Tien‐Shan (Tianshan) Mountains, which are located in the south‐western segment of the Central Asian Orogenic Belt. Eclogites are preserved in the cores of garnet amphibolites and amphibolites that occur in the Aktyuz area as boudins and layers (up to 2000 m in length) within country rock gneisses. The textures and mineral chemistry of the Aktyuz eclogites, garnet amphibolites and country rock gneisses record three distinct metamorphic events (M1–M3). In the eclogites, the first MP–HT metamorphic event (M1) of amphibolite/epidote‐amphibolite facies conditions (560–650 °C, 4–10 kbar) is established from relict mineral assemblages of polyphase inclusions in the cores and mantles of garnet, i.e. Mg‐taramite + Fe‐staurolite + paragonite ± oligoclase (An<16) ± hematite. The eclogites also record the second HP‐LT metamorphism (M2) with a prograde stage passing through epidote‐blueschist facies conditions (330–570 °C, 8–16 kbar) to peak metamorphism in the eclogite facies (550–660 °C, 21–23 kbar) and subsequent retrograde metamorphism to epidote‐amphibolite facies conditions (545–565 °C and 10–11 kbar) that defines a clockwise P–T path. thermocalc (average P–T mode) calculations and other geothermobarometers have been applied for the estimation of P–T conditions. M3 is inferred from the garnet amphibolites and country rock gneisses. Garnet amphibolites that underwent this pervasive HP–HT metamorphism after the eclogite facies equilibrium have a peak metamorphic assemblage of garnet and pargasite. The prograde and peak metamorphic conditions of the garnet amphibolites are estimated to be 600–640 °C; 11–12 kbar and 675–735 °C and 14–15 kbar, respectively. Inclusion phases in porphyroblastic plagioclase in the country rock gneisses suggest a prograde stage of the epidote‐amphibolite facies (477 °C and 10 kbar). The peak mineral assemblage of the country rock gneisses of garnet, plagioclase (An11–16), phengite, biotite, quartz and rutile indicate 635–745 °C and 13–15 kbar. The P–T conditions estimated for the prograde, peak and retrograde stages in garnet amphibolite and country rock are similar, implying that the third metamorphic event in the garnet amphibolites was correlated with the metamorphism in the country rock gneisses. The eclogites also show evidence of the third metamorphic event with development of the prograde mineral assemblage pargasite, oligoclase and biotite after the retrograde epidote‐amphibolite facies metamorphism. The three metamorphic events occurred in distinct tectonic settings: (i) metamorphism along the hot hangingwall at the inception of subduction, (ii) subsequent subduction zone metamorphism of the oceanic plate and exhumation, and (iii) continent–continent collision and exhumation of the entire metamorphic sequences. These tectonic processes document the initial stage of closure of a palaeo‐ocean subduction to its completion by continent–continent collision.  相似文献   

16.
《地学前缘(英文版)》2020,11(5):1593-1608
The Gejiu-Bozushan-Laojunshan W-Sn polymetallic metallogenic belt(GBLB) in southeast Yunnan Province is an important part of the southwestern Yangtze Block in South China.Tin polymetallic mineralization in this belt includes the Niusipo,Malage,Songshujiao,Laochang and Kafang ore fields in the Gejiu area which are spatially and temporally associated with the Kafang-Laochang and Songshujiao granite plutons.These granites are characterized by variable A/CNK values(mostly 1.1,except for two samples with 1.09),high contents of SiO_2(74.38-76.84 wt.%) and Al_2 O_3(12.46-14.05 wt.%) and variable CaO/Na_2 O ratios(0.2-0.65) as well as high zircon δ~(18)O values(7.74‰-9.86‰),indicative of S-type affinities.These rocks are depleted in Rb,Th,U,Ti,LREE[(La/Yb)N=1.4-20.51],Ba,Nb,Sr,and Ti and display strong negative Eu and Ba anomalies.The rocks possess high Rb/Sr and Rb/Ba ratios,relatively low initial ~(87)Sr/~(86)Sr ratios(0.6917-0.7101),and less radiogenic εNd(t)values(-8.0 to-9.1).The zircon grains from these rocks show negative ε_(Hf)(t) values in the range of-3.7 to-9.9 with mean T_(DM2)(Nd) and T_(DM2)(Hf) values of 1.57 Ga and 1.55 Ga.They show initial ~(207)Pb/~(204)Pb ranging from15.69 to 15.71 and ~(206)Pb/~(204)Pb from 18.36 to 18.70.Monazite from Songshujiao granites exhibits higher U and lower Th/U ratios,lower δ~(18)O values and higher ε_(Hf)(t) values than those of the zircon grains in the KafangLaochang granites.The geochemical and isotopic features indicate that the Laochang-Kafang granites originated by partial melting of Mesoproterozoic crustal components including biotite-rich metapelite and metagraywacke,whereas the Songshujiao granites were derived from Mesoproterozoic muscovite-rich metapelite crustal source.Most zircon grains from the Songshujiao,Laochang and Kafang granites have high-U concentrations and their SIMS U-Pb ages show age scatter from 81.6 Ma to 88.6 Ma,80.7 Ma to 86.1 Ma and 82.3 Ma to 87.0 Ma,suggesting formation earlier than the monazite and cassiterite.Monazite SIMS U-Pb ages and Th-Pb ages of three same granite samples are consistent and show yielded 206 Pb/~(238)U ages of 83.7 ± 0.6 Ma,83.7±0.6 Ma,and 83.4±0.6 Ma,and ~(208)Pb/~(232)Th ages of 83.2 ± 0.5 Ma,83.8 ± 0.4 Ma,and 83.5±0.9 Ma,which are within the range of the SIMS zircon U-Pb ages from these rocks.The data constrain the crystallization of the granites at ca.83 Ma.In situ U-Pb dating of two cassiterite samples from the cassiterite-sulfide ore in the Songshujiao ore field and Kafang ore field,and two from the cassiterite-oxide+cassiterite bearing dolomite in the Laochang ore field yielded weighted mean 206 Pb/~(238)U ages of 83.5±0.4 Ma(MSWD=0.6),83.5 ± 0.4 Ma(MSWD=0.5),83.6 ±0.4 Ma(MSWD=0.6) and 83.2 ±0.7 Ma(MSWD=0.6),respectively.Combined with geological characteristics,the new geochronological data indicate that the formation of the granites and Sn polymetallic deposits are coeval.We correlate the magmatic and metallogenic event with lithospheric thinning and asthenosphere upwelling in continental extension setting in relation to the eastward subduction of the Neo-Tethys beneath the Sanjiang tectonic domain during Late Cretaceous.  相似文献   

17.
Abstract The prograde metamorphism of eclogites is typically obscured by chemical equilibration at peak conditions and by partial requilibration during retrograde metamorphism. Eclogites from the Eastern Blue Ridge of North Carolina retain evidence of their prograde path in the form of inclusions preserved in garnet. These eclogites, from the vicinity of Bakersville, North Carolina, USA are primarily comprised of garnet–clinopyroxene–rutile–hornblende–plagioclase–quartz. Quartz, clinopyroxene, hornblende, rutile, epidote, titanite and biotite are found as inclusions in garnet cores. Included hornblende and clinopyroxene are chemically distinct from their matrix counterparts. Thermobarometry of inclusion sets from different garnets record different conditions. Inclusions of clinozoisite, titanite, rutile and quartz (clinozoisite + titanite = grossular + rutile + quartz + H2O) yield pressures (6–10 kbar, 400–600 °C and 8–12 kbar 450–680 °C) at or below the minimum peak conditions from matrix phases (10–13 kbar at 600–800 °C). Inclusions of hornblende, biotite and quartz give higher pressures (13–16 kbar and 630–660 °C). Early matrix pyroxene is partially or fully broken down to a diopside–plagioclase symplectite, and both garnet and pyroxene are rimmed with plagioclase and hornblende. Hypersthene is found as a minor phase in some diopside + plagioclase symplectites, which suggests retrogression through the granulite facies. Two‐pyroxene thermometry of this assemblage gives a temperature of c. 750 °C. Pairing the most Mg‐rich garnet composition with the assemblage plagioclase–diopside–hypersthene–quartz gives pressures of 14–16 kbar at this temperature. The hornblende–plagioclase–garnet rim–quartz assemblage yields 9–12 kbar and 500–550 °C. The combined P–T data show a clockwise loop from the amphibolite to eclogite to granulite facies, all of which are overprinted by a texturally late amphibolite facies assemblage. This loop provides an unusually complete P–T history of an eclogite, recording events during and following subduction and continental collision in the early Palaeozoic.  相似文献   

18.
东昆仑造山带近年来被厘定为早古生代高压-超高压变质带。带内广泛出露早古生代的中-高级变质基性岩,这些岩石记录了不同的变质温压和多期的变质年龄,是反演和制约东昆仑早古生代变质演化的重要样品。本文选取东昆仑浪木日地区的石榴斜长角闪岩为研究对象,开展了变质岩石学及锆石年代学研究。石榴斜长角闪岩呈团块状出露在黑云二长片麻岩中,主要组成矿物为石榴子石、角闪石、斜长石、透辉石和石英,含少量黑云母、绿泥石、金红石、钛铁矿和榍石。石榴子石变斑晶的核部含有绿帘石、角闪石、斜长石、金红石和石英包裹体,其成分从核部到边部,锰铝榴石逐渐降低、钙铝榴石和Mg/(Mg+Fe;)比值逐渐升高,为进变质作用形成的环带。岩石中的矿物结构关系和成分特征显示其经历了进变质、峰期变质和退变质三个阶段的变质演化,变质温压分别为:T≈610℃和P≈6.5kbar、T≈700℃和P≈10.5kbar以及T≈650℃和P≈4.5kbar。这三阶段的变质作用构成顺时针的变质P-T轨迹,指示岩石经历进变质升温升压至峰期阶段,随后经历近等温降压的退变质阶段。同时该P-T轨迹特征表明岩石形成于俯冲-碰撞的构造背景。对石榴斜长角闪岩中的锆石进行SIMS U-Pb定年,得到492.8±5.1Ma的谐和年龄。锆石的形态特征与典型的变质锆石一致,其内包裹的石榴子石、角闪石和斜长石组合与岩石的峰期矿物组合一致。因此,锆石在峰期变质阶段结晶,所测年龄~493Ma为角闪岩相峰期变质年龄。本文研究的石榴斜长角闪岩与该区高压-超高压榴辉岩在野外产状、P-T轨迹和变质年龄等方面密切相关,暗示ca.490Ma是该区高压-超高压变质作用的一个重要时间节点。石榴斜长角闪岩和榴辉岩之间的变质差异,表明东昆仑早古生代经历了多阶段的变质作用,不同岩石记录了原特提斯洋俯冲-碰撞过程的不同阶段。本文获得的变质P-T轨迹和变质年龄可为进一步探究东昆仑早古生代高压-超高压变质作用提供限定。  相似文献   

19.
New field observations and petrological data from Early Cretaceous metamorphic rocks in the Central Cordillera of the Colombian Andes allowed the recognition of thermally overprinted high-pressure rocks derived from oceanic crust protoliths. The obtained metamorphic path suggests that the rocks evolved from blueschist to eclogite facies towards upper amphibolite to high-pressure granulite facies transitional conditions. Eclogite facies conditions, better recorded in mafic protoliths, are revealed by relic lawsonite and phengite, bleb- to worm-like diopside-albite symplectites, as well as garnet core composition. Upper amphibolite to high pressure granulite facies overprinting is supported by coarse-grained brown-colored Ti-rich amphibole, augite, and oligoclase recrystallization, as well as the record of partial melting leucosomes.Phase equilibria and pressure-temperature (P-T) path modeling suggest initial high-pressure metamorphic conditions M1 yielding 18.2–24.5 kbar and 465–580 °C, followed by upper amphibolite to high pressure granulite facies overprinting stage M2 yielding 6.5–14.2 kbar and 580–720 °C. Retrograde conditions M3 obtained through chlorite thermometry yield temperatures ranging around 286–400 °C at pressures below 6.5–11 kbar. The obtained clockwise P-T path, the garnet zonation pattern revealing a decrease in Xgrs/Xprp related to Mg# increment from core to rim, the presence of partial melting veins, as well as regional constraints, document the modification of the thermal structure of the active subduction zone in Northern Andes during the Early Cretaceous. Such increment of the metamorphic gradient within the subduction interface is associated with slab roll-back geodynamics where hot mantle inflow was triggered. This scenario is also argued by the reported trench-ward magmatic arc migration and multiple extensional basin formation during this period. The presented example constitutes the first report of Cretaceous roll-back-related metamorphism in the Caribbean and Andean realms, representing an additional piece of evidence for a margin-scale extensional event that modified the northwestern border of South America during the Early Cretaceous.  相似文献   

20.
《地学前缘(英文版)》2020,11(4):1305-1321
The Western Qinling Orogen(WQO) is characterized by voluminous distribution of Indosinian granitoids,the formation of which provides an important window to unravel the geochemical and geodynamic evolution and associated metallogeny.Here we investigate a group of intrusions termed "Five Golden Flowers" based on petrological,geochemical,zircon U-Pb geochronological and Lu-Hf isotopic studies on the granitoids and their mafic microgranular enclaves(MMEs).Our results show that these intrusions are genetically divided into two types,namely,magma-mixing and highly fractionated.The Jiaochangba,Lujing,Zhongchuan,and Luchuba granitoids are biotite monzogranites(220±0.8 Ma to 217±2.6 Ma) with abundant coeval MMEs(220±.1 Ma to 217±2.7 Ma).The rocks contain moderate to high SiO_2,high MgO,Rb,Sr,Ba,and Th contents,but low TiO_2,P_2 O_5,and Sc values,A/CNK of 1.1,and a range of ε_(Hf)(t) values of-11.7 to +2.23 with corresponding T_(DM2)values of 1967-1228 Ma.The MMEs possess K-feldspar megacrysts,abundant acicular apatites,and show lopsided textures.They have lower SiO_2,Al_2 O_3,and Th contents,but higher MgO,TiO_2,and Sc,with ε_(Hf)(t) values of-18.0 to +3.18 and T_(DM1) of 849-720 Ma.The data indicate that the MMEs were derived from a magma sourced from the enriched lithospheric mantle.We suggest that these host granitoids were produced by partial melting of latePaleoproterozoic to early-Mesoproterozoic lower crust with the involvement of Neoproterozoic SCLM-derived mafic magmas.The Baijiazhuang pluton is dominantly composed of leucogranite(muscovite granite and twomica monzogranite,216±1.5 Ma) without MMEs.The rocks are peraluminous with high A/CNK(1.06-1.27).Compared with the other four granitoids,the Baijiazhuang leucogranite shows higher SiO_2 content,markedly lower concentrations of TiO_2,MgO,Al_2 O_3,CaO,and Fe_2 O_3~T,and lower LREE/HREE and(La/Yb)N values.These leucogranites are also rich in Rb,Th,and U,and display marked depletions in Ba,Sr,Ti,and Eu,indicating that they experienced significant fractionation.Zircon ε_(Hf)(t) values(-10.2 to-3.27) and T_(DM2)(1868-1424 Ma),as well as the Nb/Ta and K_2 O/Na_2 O values are similar to the other four granitoids,indicating that they are likely to have been derived from a similar source;with sediments playing only a minor role in the magma generation.The low contents of Yb and Y suggest that their partial melting was controlled by garnets and micrographic texture of K-feldspar reflects high-temperature melting through undercooling.Based on the above features,we infer that the Baijiazhuang leucogranite likely represents the product of high degree fractionation of the I-type biotite monzogranite magma which generated the other four granitoids at relatively high temperatures,within magma chambers at mid-crust depths.We propose that the granitoid suite was formed in the transitional setting from synto post-collision during the collisional orogeny between the SCB and NCB,following break-off of the subducted South China Block lithosphere during 220-216 Ma.  相似文献   

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