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1.
North-seeking bacteria (NSB) with 1 μm diameters migrate to the S pole only. They were applied to identify the S pole determination on a polished surface of magnetite-rich pyroxenite whose natural remanent magnetization (NRM) intensity was 5.64 × 10 −3 Am 2 kg −1. The microscopic observations were performed under dark-field illumination in a controlled magnetic field to 10 μT. The NSB formed clusters on limited areas of magnetite grains and scattered over the whole magnetite grains. The NRM decreased to 1.02 × 10−5 Am2 kg−1 by alternating field (AF) demagnetization to 60 mT but no clusters appeared, while small populations of the NSB scattered on each grain. These scattered bacteria may gather toward the S pole resulting from magnetic domain walls. When the sample acquired saturation isothermal remanent magnetization (SIRM) to 1 T, the NSB formed dense clusters at the opposite side to the applied field direction on the many grains as expected. This evidence indicated that the NSB can be useful micro-organisms for the determination of fine magnetic structures. Some grains also had NSB clusters at the edge of the grains toward the field direction or did not exhibit any clusters. The complicated distribution of the clusters (the S poles) may be explained by shape anisotropy of the magnetic grains. 相似文献
2.
Noble gases were extracted in steps from grain size fractions of microdiamonds ( < 100 μm) from the Kokchetav Massif, Northern Kazakhstan, by pyrolysis and combustion. The concentration of 4He in the diamonds proper (liberated by combustion) shows a 1/ r dependence on grain size. For grain diameters > 15 μm the concentration also decreases with the combustion step. Both results are clear evidence that 4He has been implanted into the diamonds from -decaying elements in the surrounding matrix. The saturation concentration of 4He(5.6 × 10 −4 cm 3 STP/g) is among the very highest observed in any terrestrial diamonds. Fission xenon from the spontaneous fission of 238U accompanies the radiogenic 4He; the 136Xe f/ 4He ratio of (2.5 ± 0.3) × 10 −9 agrees well with the production ratio of 2.3 × 10 −9 expected in a reservoir where Th/U 3.3. Radiogenic 40Ar is predominantly ( > 90%) set free upon combustion; it also resides in the diamonds and appears to have been incorporated into the diamonds upon their formation. 3He, on the other hand is mainly released during pyrolysis and hence is apparently carried by ‘contaminants’. The concentration in the diamonds proper is of the order of 4 × 10−12 cm3 STP/g, with a 3He/4He ratio of 1 × 10−8. Excess 21Ne, similarly, appears to be present in contaminants as well as in diamonds proper. These two nuclides in the contaminants must have a nucleogenic origin, but it is difficult to explain their high concentrations. 相似文献
3.
Chemical diffusion of four rare-earth elements (La, Nd, Dy and Yb) has been measured in natural calcite under anhydrous conditions, using rare-earth carbonate powders as the source of diffusants. Experiments were run in sealed silica capsules along with finely ground calcite to ensure stability of the single-crystal samples during diffusion anneals. Rutherford backscattering spectroscopy (RBS) was used to measure diffusion profiles. The following Arrhenius relations were obtained over the temperature range 600–850°C: DLa =2.6×10 −14 exp(−147±14 kJ mol −1/ RT) m 2 s −1, DNd =2.4×10 −14 exp(−150±13 kJ mol −1/ RT) m 2 s −1, DDy =2.9×10 −14 exp(−145±25 kJ mol −1/ RT) m 2 s −1, DYb =3.9×10 −12 exp(−186±23 kJ mol −1/ RT) m 2 s −1. In contrast to previous findings for refractory silicates (e.g. zircon), differences in transport rates among the REE are not pronounced over the range of temperature conditions investigated in this study. Diffusion of the REE is significantly slower than diffusion of the divalent cations Sr and Pb and slower than transport of Ca and C at temperatures above 650°C. Fine-scale zoning and isotopic and REE chemical signatures may be retained in calcites under many conditions if diffusion is the dominant process affecting alteration. 相似文献
4.
238U, 232Th, 230Th and 226Ra abundances have been measured in six samples of recent Hawaiian basalt by high precision mass spectrometry, in an attempt to compare the melting process in plumes and at spreading ridges. The data reveal a very small range in ( 230Th/ 238U) activity ratio up to a maximum value of 1.02 ± 0.01, and ( 226Ra/ 230Th) activity ratios which lie between 1.10 ± 0.015 and 1.19 ± 0.02. UTh and RaTh abundances are linearly correlated demonstrating that the disequilibria predate crystallisation and differentiation. Using recently published estimates for the bulk partition coefficients of U and Th, the results are consistent with melting rates > 10 −3 kg m −3 a −1 at porosities < 10 −3 for dynamic fractional melting in the garnet stability field. 相似文献
5.
Analytical procedures in the determination of iodine-129 (half-life: 1.6×10 7 y) have been studied using accelerator mass spectrometry (AMS), with special references to the separation procedures of iodine from soil samples for the AMS measurement. Iodine was successfully volatilized from soil samples by pyrohydrolysis at 1000 °C and collected in a trap solution. Iodine was purified from the matrix by solvent extraction. Finally, it was precipitated as silver iodide to make a target for AMS. In order to obtain information on the 129I/ 127I ratio in a chemical blank (or iodine carrier), we have determined the ratios in several iodine reagents and found that the ratios fell in a narrow range around 1.7×10 −13. The detection limit for soil sample (1 g material) by the present method was about 0.01 mBq/kg or 4×10 −11 as the ratio of stable iodine ( 129I/ 127I ratio), i.e. these values were much better than that by neutron activation analysis (NAA) used in our previous studies. We have applied this method in the analysis of soil samples collected from different places in Japan. We could successfully determine 129I in soil samples with low 129I concentrations, which could not be detected by NAA. Sample size necessary for the soil analysis by AMS was only about 0.5 g or less, whereas about 100 g of the sample were required for NAA [Muramatsu, Y., Ohmomo, Y., 1986. Iodine-129 and iodine-127 in environmental samples collected from Tokaimura/ Ibaraki, Japan. Sci. Total Environ. 48, 33-43]. Using this method, new data were obtained for the 129I levels in 20 soil samples collected from background areas far from nuclear facilities, and the ranges were 1.4×10 −5−4.5×10 −3 Bq/kg as 129I concentrations and 3.9×10 −11−2.2×10 −8 as 129I/ 127I ratios. These values are useful in understanding the 129I levels in Japanese environments. Higher 129I concentrations were observed in forest soils than those in field and rice paddy soils should be related to the interception effect of atmospheric 129I due to tree canopies. Relatively high 129I/ 127I ratios found in rice paddy soils could be explained by their low stable iodine concentrations which were caused by the desorption of stable iodine from the rice paddies during the cultivation. 相似文献
6.
The source of the lunar magnetic anomaly associated with the Rima Sirsalis linear rille has been modelled using the vector field intensities due to arbitrary uniform magnetization in a rectangular prism. It is shown that in order to match the Apollo 16 subsatellite data, the lunar surface near the rille must have a vertical magnetization of 6–9 × 10 −3 G if the anomaly is due to flux leakage from a gap in the crust with the dimensions of the rille. This is more than one order of magnitude larger than the magnetization of any lunar sample, but is comparable with the high magnetization recently deduced for the Reiner γ formation in Oceanus Procellarum. An alternative explanation is that Rima Sirsalis and its surroundings are the site of a vertical magnetization contrast of 10 −5 – 10 −4 G which is at least as wide as the rille and extends to a depth of tens of kilometers in the crust. A wider magnetic source reduces the required magnetization (or depth) proportionately, since to first order the field at high altitude is proportional to the magnetic dipole moment per unit length. 相似文献
7.
This research ( 1) characterized the effects of sublethal cupric ion activities on the grazing behavior of two estuarine copepods ( Acartia tonsa, Acartia hudsonica) and one nearshore, neritic copepod ( Temora longicornis) and ( 2) compared the sensitivity of short-term sublethal behavioral assays with that of longer-term acute toxicity tests. A nitrilotriacetate-trace-metal-ion buffer system at 27‰. S was used to quantify and control the free cupric ion activity. Acute toxicity tests were used to determine the mortality of A. tonsa and T. longicornis over 72 h within the approximate cupric ion activity range of 10 −13 to 10 −9.5 M. 24 h survival was not affected within the approximate cupric ion activity range of 10 −13 to 10 −9.7 M, the range used for subsequent grazing activity experiments after 24 h exposure to Cu. Grazing activity was significantly diminished at cupric ion activities of ≈ 10 −10 M for A. tonsa and T. longicornis, and at ≈ 10 −11 M for A. hudsonica. A hormetic pattern of response in feeding activity was observed with A. tonsa and T. longicornis. Grazing activity was found to be a sensitive measure of sublethal Cu stress compared with the acute toxicity tests. Grazing activity was affected at environmentally relevant cupric ion activities. 相似文献
8.
The impact of domestic sewage effluent (SE) on the dynamics of phytoplankton assemblages from Bedford Basin was evaluated in the laboratory. Phytoplankton production and chlorophyll a increased proportionally with SE enrichment. Phytoplankton species composition also changed. The potentially harmful diatoms, Pseudonitzschia spp., present initially in small numbers (600 cells 1 −1) in Bedford Basin seawater, and became dominant (3–5×10 6 cells 1 −1) when the seawater was enriched with 0.5–5% untreated SE. With higher proportions of SE, other harmful species such as Fragilaria spp. and Euglena spp. became dominant (7−15×10 6 and 2.2×10 4 cells 1 −1, respectively). Treatment of SE with UV light or activated charcoal seems to favour growth of benign species, such as Chaetoceros socialis, Skeletonema costatum and Thalassiosira spp., but not harmful species such as Pseudonitzschia spp. Further research on UV treatment of domestic sewage is recommended. 相似文献
9.
A soil-water flux sensor was developed, which determines the flux value from the difference between downstream and upstream temperatures at some distances from an artificial heat source. It can detect flux values ranging from several mm hr. −1 to as small as 0.01 mm hr. −1. Design and calibration of the sensor are described. The sensor was applied to the field studies of transfer processes in a surface soil, including rainwater infiltration, upward soil-water flow during evapotranspiration, and their effects on the water table level. Cl− accumulation in the surface soil is discussed on the basis of upward water flux and Cl− content observed. 相似文献
10.
Soret diffusion rise times were observed and resolved for Fe–Ni–S–P melts at 10 kbar in thermal gradients between 1300 and 1450°C. A steady-state separation of S-rich components to the hot end of the 2 mm long liquid charges is achieved in about 20 minutes. Chemical diffusivities of about 10 −5 cm 2/s are consistent with these observations and those of the compaction velocity of aggregates of crystalline Fe metal against the cold end of our experiments. These rapid diffusivities are not rapid enough for diffusion to be an important agent of bulk mass transfer in the addition or extraction of light elements in the Earth's core. 相似文献
11.
In 1989, in a hydrological research programme within a deacidification project in the Gårdsjön area in southwest Sweden, flow paths and residence times of soil water and groundwater in microcatchments were examined to support the interpretation of the hydrochemical changes. Saturated hydraulic conductivity and soil water retention were analysed on more than 100 cylinder samples. The catchments have shallow sandy-silty till soil with a mean depth in the main catchment of 43 cm. Porosity of the mineral soil in the main catchment was high and ranged from 38 to 85%. The samples from the B-horizon had generally higher porosity. Porosity and the content of organic matter were correlated. The soil water retention was relatively high at all tensions, likely owing to the high content of organic matter. Dissolved organic substances were most probably transported from the shallow soil on the steep sides of the catchment down to the valley where it precipitated. The high porosities could be a consequence of long-term weathering, provided that the organic substances present have increased the leaching of the weathering products. Measured values of saturated hydraulic conductivity were close to log-normally distributed with a mean for all samples of 3 × 10 −5 m s −1. There was a significant increase in conductivity toward the ground surface with the mean conductivity of the samples in the uppermost 10 cm of the mineral soil of 4 × 10 −5 m s −1, which was about 13 times higher than the conductivity of 3 × 10 −6 m s −1 at 1 m depth. From the relationship between runoff at the catchment outlet and groundwater levels, the conductivity was estimated to be 15–200 times higher in the upper soil layer than in the deeper ones. In one profile, 44–64% of the yearly lateral flow was estimated to occur above 30 cm depth. The conductivity was correlated with the content of drainable water, which indicated the importance of the largest pores for the saturated hydraulic conductivity. 相似文献
12.
We have developed techniques to determine 238U, 234U and 232Th concentrations in seawater by isotope dilution mass spectrometry. U measurements are made using a 233U 236U double spike to correct for instrumental fractionation. Measurements on uranium standards demonstrate that 234U/ 238U ratios can be measured accurately and reproducibly. 234U/ 238U can be measured routinely to ± 5‰ (2σ) for a sample of 5 × 10 9 atoms of 234U (3 × 10 −8 g of total U, 10 ml of seawater). Data acquisition time is 1 hour. The small sample size, high precision and short data acquisition time are superior to-counting techniques. 238U is measured to ± 2‰ (2σ) for a sample of 8 × 10 12 atoms of 238U ( 3 × 10 −9 g of U, 1 ml of seawater). 232Th is measured to ± 20‰ with 3 × 10 11232Th atoms (10 −10 g 232Th, 1 1 of seawater). This small sample size will greatly facilitate investigation of the 232Th concentration in the oceans. Using these techniques, we have measured 238U, 234U and 232Th in vertical profiles of unfiltered, acidified seawater from the Atlantic and 238U and 234U in vertical profiles from the Pacific. Determinations of 234U/ 238U at depths ranging from 0 to 4900 m in the Atlantic (7°44′N, 40°43′W) and the Pacific (14°41′N, 160°01′W) Oceans are the same within experimental error (± 5‰,2σ). The average of these 234U/ 238U measurements is 144 ± 2‰ (2σ) higher than the equilibrium ratio of 5.472 × 10 −5. U concentrations, normalized to 35‰ salinity, range from 3.162 to 3.281 ng/g, a range of 3.8%. The average concentration of the Pacific samples (31°4′N, 159°1′W) is 1% higher than that of the Atlantic (7°44′N, 40°43′W and 31°49′N, 64°6′W). 232Th concentrations from an Atlantic profile range from 0.092 to 0.145 pg/g. The observed constancy of the 234U/ 238U ratio is consistent with the predicted range of 234U/ 238U using a simple two-☐ model and the residence time of deep water in the ocean determined from 14C. The variation in salinity-normalized U concentrations suggests that U may be much more reactive in the marine environment than previously thought. 相似文献
13.
A microflow of free ascending gas has been observed in 26 out of 30 tested boreholes at three different sites. The flow rates vary between 60 × 10 −4 and 4 cm 3/min m 2 horizontally projected borehole area. Sampling has been made in ground boreholes as well as in holes drilled downwards from the lowest levels in two mines. The composition of the gas varies considerably. The main components of the gas are nitrogen, argon, oxygen and methane. Traces of heavier hydrocarbons are observed. At the site of the ground holes, only traces of methane are observed. In all sampled holes the existence of free oxygen is observed. The nitrogen/argon quotient is close to the atmospheric quotient in all sampled holes, indicating a partly atmospheric origin of the gas. The existence of methane and traces of heavier hydrocarbons indicates the existence of a second source. 相似文献
14.
A new method is described for estimating: (a) the meridional electric current density, jθ, (b) the vertical growth rate of the zonal magnetic field, ∂ Bφ/∂ r, or its scale-height, Bφ/∂ Bφ/∂ r) and (c) the vertical growth rate of the vertical current density, ∂ jr/∂ r, at a few isolated points on the top surface of the Earth's core from observations of the internal geomagnetic field at the Earth's surface. The theoretical technique rests on combining unaccelerated, gravitationally-driven Boussinesq fluid dynamics of the core with frozen-flux electromagnetism, the mantle being treated as a spherically symmetric insulator. Insertion into this theory of main field models for epochs 1965, 1975 leads to preliminary values for these quantities of magnitude: (a) jθ 1 A/m2, (b) ∂Bφ/∂r 10−6 T/m or Bφ/(∂Bφ/∂r) 10 m, (c) ∂jr/∂r 10−6 A/m3. Some geophysical implications of these estimates are discussed. 相似文献
15.
The diffusion of the dynamo-generated magnetic field into the electrically conducting inner core of the Earth may provide an explanation for several problematic aspects of long-term geomagnetic field behavior. We present a simple model which illustrates how an induced magnetization in the inner core which changes on diffusive timescales can provide a biasing field which could produce the observed anomalies in the time-averaged field and polarity reversals. The Earth's inner core exhibits an anisotropy in seismic velocities which can be explained by a preferred orientation of a polycrystalline aggregate of hexagonal close-packed (hcp) iron, an elastically anisotropic phase. Room temperature analogs of hcp iron also exhibit a strong anisotropy of magnetic susceptibility, ranging from 15 to 40% anisotropy. At inner core conditions the magnetic susceptibility of hcp iron is estimated to be between 10 −4 and 10 −3 SI. We speculate here that the anisotropy in magnetic susceptibility in the inner core could produce the observed anomalies in the time-averaged paleomagnetic field, polarity asymmetry, and recurring transitional virtual geomagnetic pole (VGP) positions. 相似文献
16.
This study aimed to determine whether the δ 13C levels in the foliage and twigs of four Eucalyptus grandis clones were related to their water use efficiency (WUE). This relationship has previously been demonstrated in a number of herbaceous species but not in mature trees. The study involved accurate measurements of tree trunk growth and water use over a period of 4 months, with subsequent isotopic analysis of mature foliage from the north and south side of the canopy, and young leaves from the top of the canopy. The water use efficiencies were found to vary from 5.97 × 10−3 to 12.3 × 10−3 m3 m−3. Significant differences were observed between clonal-mean water use efficiencies averaged over six sampling periods. The average δ13C of the mature and young foliage was found to be significantly correlated with WUE. However, the correlation was weak, suggesting that the relationship between δ13C and WUE is more complex in trees than suggested in the literature on crop plants. It is suggested that differences between sample trees in carbon allocation and leaf-to-air vapour pressure deficits may account for the poor correlation between δ13C and WUE in the four E. grandis clones studied. 相似文献
18.
Argon, krypton, chlorine, bromine, and iodine were measured in a homogeneous population of high-salinity hydrothermal fluid inclusions from the Tertiary-age Mississippi Valley-type (MVT) lead-fluorite-barite deposits at Hansonburg, New Mexico to establish new types of evidence for the history of both the fluid and the major dissolved salts. Noble gases and halogens in fluid inclusions containing 10 −10–10 −9 L of brine ( Cl= 3 molal) were analyzed by laser microprobe noble-gas mass spectrometry (lmngms) on neutron-irradiated samples. The concentrations of36Ar (4.7 × 10−8 molal) and84Kr1.8 × 10−9 molal) in the fluid inclusions are equal to those of fresh surface waters in equilibrium with air at approximately20 ± 5°. The mole ratios ofBr/Cl (1.2 × 10−4) andI/Cl (1–2 × 10−6) are among the lowest measured in any natural waters, similar to those of modern brines formed by dissolution of Permian NaCl-bearing evaporites in southeast New Mexico.40Ar/36Ar ratios (600) are twice that of air, and indicate that the fluid inclusions had excess radiogenic40Ar (1.4 × 10−5 molal) when trapped. The amount of excess40Ar appears to be too large to have been acquired with Cl by congruent dissolution of halite-bearing evaporites, and possibly too small to have been acquired with Pb by congruent dissolution of granitic basement rocks with Proterozoic KAr ages. From thelmngms data, combined with published Pb and S isotope data, we infer the following sequence of events in the history of the Hansonburg MVT hydrothermal brine: (1) the brine originated as relatively dilute meteoric water, and it did not gain or lose atmospheric Ar or Kr after recharge; (2) the originally dilute fluid acquired the bulk of its Cl and sulfate in the subsurface after recharge by dissolving halite-bearing Permian? marine evaporites; (3) the high salinity brine then acquired most of its Pb and excess radiogenic40Ar from interactions with aquifer rocks other than evaporites, possibly clastic sedimentary rocks or basement rocks with Phanerozoic KAr “ages”; and (4) the brine deposited fluorite without having boiled or degassed. 相似文献
19.
Properties of lunar crustal magnetization thus far deduced from Apollo subsatellite magnetometer data are reviewed using two of the most accurate presently available magnetic anomaly maps — one covering a portion of the lunar near side and the other a part of the far side. The largest single anomaly found within the region of coverage on the near-side map correlates exactly with a conspicuous, light-colored marking in western Oceanus Procellarum called Reiner Gamma. This feature is interpreted as an unusual deposit of ejecta from secondary craters of the large nearby primary impact crater Cavalerius. An age for Cavalerius (and, by implication, for Reiner Gamma) of 3.2 ± 0.2 × 109 y is estimated. The main (30 × 60 km) Reiner Gamma deposit is nearly uniformly magnetized in a single direction, with a minimum mean magnetization intensity of 7 × 10−2 G cm3/g (assuming a density of 3 g/cm3), or about 700 times the stable magnetization component of the most magnetic returned samples. Additional medium-amplitude anomalies exist over the Fra Mauro Formation (Imbrium basin ejecta emplaced 3.9 × 109 y ago) where it has not been flooded by mare basalt flows, but are nearly absent over the maria and over the craters Copernicus, Kepler, and Reiner and their encircling ejecta mantles. The mean altitude of the far-side anomaly gap is much higher than that of the near-side map and the surface geology is more complex, so individual anomaly sources have not yet been identified. However, it is clear that a concentration of especially strong sources exists in the vicinity of the craters Van de Graaff and Aitken. Numerical modeling of the associated fields reveals that the source locations do not correspond with the larger primary impact craters of the region and, by analogy with Reiner Gamma, may be less conspicuous secondary crater ejecta deposits. The reason for a special concentration of strong sources in the Van de Graaff-Aitken region is unknown, but may be indirectly related to the existence of strongly modified crustal terrain which also occurs in the same region. The inferred directions of magnetization for the several sources of the largest anomalies are highly inclined with respect to one another, but are generally depleted in the north-south direction. The north-south depletion of magnetization intensity appears to continue across the far-side within the region of coverage. The mechanism of magnetization and the origin of the magnetizing field remain unresolved, but the uniformity with which the Reiner Gamma deposit is apparently magnetized, and the north-south depletion of magnetization intensity across a substantial portion of the far side, seem to require the existence of an ambient field, perhaps of global or larger extent. The very different inferred directions of magnetization possessed by nearly adjacent sources of the Van de Graaff-Aitken anomalies, and the depletion in their north-south component of magnetization, do not favor an internally generated dipolar field oriented parallel to the present spin axis. A variably oriented interplanetary magnetizing field that was intrinsically strong or locally amplified by unknown surface processes is least inconsistent with the data. 相似文献
20.
We report the first measurements of hydrodynamic dispersion in a microfractured granite using a combination of novel techniques. A fracture network was induced in a cylindrical plug of Ailsa Craig micro-granite by thermal stressing, to produce an isotropic network of fractures with an average aperture of 0.3 μm, a density of approximately 4 × 10 4 fractures/mm 3 and a permeability of 5.5 × 10 − 17 m 2. After saturating the cores with 0.01 M NaCl solution a step in the concentration profile to 1 M was advected into the plug at flow rates of 0.07 to 2.13 cm 3 h − 1. The longitudinal electrical impedance of the plug was measured continuously as the solute front advected through its length until the plug was saturated with the concentrated electrolyte. Analysis of the impedance versus time relationships allows the derivation of the longitudinal dispersion coefficient, DL, and hydrodynamic retardation, RH. The Peclet number–dispersion relationship for the micro-fracture network is very similar to that predicted for other, radically different, fracture networks. Thus dispersion may be more dependent on fracture connectivity and length than fracture density and display a relationship similar to that shown by particle beds and clastic sandstones. The high retardation values observed (2.2–4.9) reflect flow behaviour within a fracture network with a proportion of ‘blind’ sections, and demonstrates how such networks can slow the advance of conservative solute components. 相似文献
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