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1.
Noble gases were extracted in steps from grain size fractions of microdiamonds ( < 100 μm) from the Kokchetav Massif, Northern Kazakhstan, by pyrolysis and combustion. The concentration of 4He in the diamonds proper (liberated by combustion) shows a 1/r dependence on grain size. For grain diameters > 15 μm the concentration also decreases with the combustion step. Both results are clear evidence that 4He has been implanted into the diamonds from -decaying elements in the surrounding matrix. The saturation concentration of 4He(5.6 × 10−4 cm3 STP/g) is among the very highest observed in any terrestrial diamonds. Fission xenon from the spontaneous fission of 238U accompanies the radiogenic 4He; the 136Xef/4He ratio of (2.5 ± 0.3) × 10−9 agrees well with the production ratio of 2.3 × 10−9 expected in a reservoir where Th/U 3.3. Radiogenic 40Ar is predominantly ( > 90%) set free upon combustion; it also resides in the diamonds and appears to have been incorporated into the diamonds upon their formation.

3He, on the other hand is mainly released during pyrolysis and hence is apparently carried by ‘contaminants’. The concentration in the diamonds proper is of the order of 4 × 10−12 cm3 STP/g, with a 3He/4He ratio of 1 × 10−8. Excess 21Ne, similarly, appears to be present in contaminants as well as in diamonds proper. These two nuclides in the contaminants must have a nucleogenic origin, but it is difficult to explain their high concentrations.  相似文献   


2.
Uranium and thorium diffusion in diopside   总被引：2，自引：0，他引：2  
This paper presents new experimental data on the tracer diffusion rates of U and Th in diopside at 1 atm and 1150–1300°C. Diffusion couples were prepared by depositing a thin layer of U–Th oxide onto the polished surface of a natural diopside single crystal, and diffusion profiles were measured by ion microprobe depth profiling. For diffusion parallel to [001] the following Arrhenius relations were obtained: log10DU=(−5.75±0.98)−(418±28 kJ/mol)/2.303RT log10DTh=(−7.77±0.92)−(356±26 kJ/mol)/2.303RT. The diffusion data are used to assess the extent to which equilibrium is obtained during near fractional melting of a high-Ca pyroxene bearing mantle peridotite. We find that the diffusion rates for both elements are slow and that disequilibrium between solid and melt will occur under certain melting conditions. For near-fractional adiabatic decompression melting at ascent rates >3 cm/yr, high-Ca pyroxene will exhibit disequilibrium effects. High-Ca pyroxene will become zoned in U and Th and the melts extracted will be depleted in these incompatible elements relative to melts produced by equilibrium fractional melting. U and Th diffusivities in high-Ca pyroxene are similar, and diffusive fractionation of these elements will be limited. Numerical solutions to a dynamic melting model with diffusion-controlled chemical equilibration indicate that the activity ratio [230Th/238U] in a partial melt of spinel peridotite will be slightly less than 1 for a broad range of melting parameters. This result reinforces the already widely accepted conclusion that melting of spinel peridotite cannot account for 230Th excesses in mid-ocean ridge and ocean island basalts, and that garnet must therefore be present over part of the melting column.  相似文献   

3.
The impact of domestic sewage effluent (SE) on the dynamics of phytoplankton assemblages from Bedford Basin was evaluated in the laboratory. Phytoplankton production and chlorophyll a increased proportionally with SE enrichment. Phytoplankton species composition also changed. The potentially harmful diatoms, Pseudonitzschia spp., present initially in small numbers (600 cells 1−1) in Bedford Basin seawater, and became dominant (3–5×106 cells 1−1) when the seawater was enriched with 0.5–5% untreated SE. With higher proportions of SE, other harmful species such as Fragilaria spp. and Euglena spp. became dominant (7−15×106 and 2.2×104 cells 1−1, respectively). Treatment of SE with UV light or activated charcoal seems to favour growth of benign species, such as Chaetoceros socialis, Skeletonema costatum and Thalassiosira spp., but not harmful species such as Pseudonitzschia spp. Further research on UV treatment of domestic sewage is recommended.  相似文献   

4.
We have analyzed helium ages of apatites from several boreholes in the Otway basin, Australia, to evaluate whether laboratory helium diffusivity can be accurately extrapolated to conditions relevant in nature. Downhole apatite helium ages define a broad swath of values from 78–71 Ma at the surface (15°C) to nearly zero at depths corresponding to ambient temperatures of 80°C. The width of the swath results from uncertainties in corrected borehole temperatures, differences in the thermal history experienced by the various boreholes, and possibly from slightly different helium diffusivities among the detrital apatite grains studied. In the eastern Otway basin, the shape and position of the helium age profile is in good agreement with predictions based on the extrapolation of laboratory diffusivity data for Durango apatite coupled with published thermal histories for this part of the basin. In contrast, helium ages are much younger than predicted in the western Otway basin. Based on measured ages from Otway sediments, which have been essentially isothermal over the last few million years, an empirical diffusivity (D/a2) of 2×10−15 s−1 can be assigned to apatites residing at downhole temperatures of 67–97°C. This empirical diffusivity is consistent with laboratory diffusion measurements, demonstrating that such measurements are reasonably accurate and can be applied with confidence to natural geologic settings. Given this confirmation of the laboratory diffusivity data, the discrepancy between the observed and modeled helium age profiles in the western Otway basin suggests that these sediments recently experienced higher temperatures than presently supposed.  相似文献   

5.
We have developed techniques to determine238U,234U and232Th concentrations in seawater by isotope dilution mass spectrometry. U measurements are made using a233U236U double spike to correct for instrumental fractionation. Measurements on uranium standards demonstrate that234U/238U ratios can be measured accurately and reproducibly.234U/238U can be measured routinely to ± 5‰ (2σ) for a sample of 5 × 109 atoms of234U (3 × 10−8 g of total U, 10 ml of seawater). Data acquisition time is 1 hour. The small sample size, high precision and short data acquisition time are superior to-counting techniques.238U is measured to ± 2‰ (2σ) for a sample of 8 × 1012 atoms of238U ( 3 × 10−9 g of U, 1 ml of seawater).232Th is measured to ± 20‰ with 3 × 1011232Th atoms (10−10 g232Th, 1 1 of seawater). This small sample size will greatly facilitate investigation of the232Th concentration in the oceans. Using these techniques, we have measured238U,234U and232Th in vertical profiles of unfiltered, acidified seawater from the Atlantic and238U and234U in vertical profiles from the Pacific. Determinations of234U/238U at depths ranging from 0 to 4900 m in the Atlantic (7°44′N, 40°43′W) and the Pacific (14°41′N, 160°01′W) Oceans are the same within experimental error (± 5‰,2σ). The average of these234U/238U measurements is 144 ± 2‰ (2σ) higher than the equilibrium ratio of 5.472 × 10−5. U concentrations, normalized to 35‰ salinity, range from 3.162 to 3.281 ng/g, a range of 3.8%. The average concentration of the Pacific samples (31°4′N, 159°1′W) is 1% higher than that of the Atlantic (7°44′N, 40°43′W and 31°49′N, 64°6′W).232Th concentrations from an Atlantic profile range from 0.092 to 0.145 pg/g. The observed constancy of the234U/238U ratio is consistent with the predicted range of234U/238U using a simple two-☐ model and the residence time of deep water in the ocean determined from14C. The variation in salinity-normalized U concentrations suggests that U may be much more reactive in the marine environment than previously thought.  相似文献   

6.
In 1989, in a hydrological research programme within a deacidification project in the Gårdsjön area in southwest Sweden, flow paths and residence times of soil water and groundwater in microcatchments were examined to support the interpretation of the hydrochemical changes. Saturated hydraulic conductivity and soil water retention were analysed on more than 100 cylinder samples. The catchments have shallow sandy-silty till soil with a mean depth in the main catchment of 43 cm. Porosity of the mineral soil in the main catchment was high and ranged from 38 to 85%. The samples from the B-horizon had generally higher porosity. Porosity and the content of organic matter were correlated. The soil water retention was relatively high at all tensions, likely owing to the high content of organic matter. Dissolved organic substances were most probably transported from the shallow soil on the steep sides of the catchment down to the valley where it precipitated. The high porosities could be a consequence of long-term weathering, provided that the organic substances present have increased the leaching of the weathering products. Measured values of saturated hydraulic conductivity were close to log-normally distributed with a mean for all samples of 3 × 10−5 m s−1. There was a significant increase in conductivity toward the ground surface with the mean conductivity of the samples in the uppermost 10 cm of the mineral soil of 4 × 10−5 m s−1, which was about 13 times higher than the conductivity of 3 × 10−6 m s−1 at 1 m depth. From the relationship between runoff at the catchment outlet and groundwater levels, the conductivity was estimated to be 15–200 times higher in the upper soil layer than in the deeper ones. In one profile, 44–64% of the yearly lateral flow was estimated to occur above 30 cm depth. The conductivity was correlated with the content of drainable water, which indicated the importance of the largest pores for the saturated hydraulic conductivity.  相似文献   

7.
This study aimed to determine whether the δ13C levels in the foliage and twigs of four Eucalyptus grandis clones were related to their water use efficiency (WUE). This relationship has previously been demonstrated in a number of herbaceous species but not in mature trees. The study involved accurate measurements of tree trunk growth and water use over a period of 4 months, with subsequent isotopic analysis of mature foliage from the north and south side of the canopy, and young leaves from the top of the canopy.

The water use efficiencies were found to vary from 5.97 × 10−3 to 12.3 × 10−3 m3 m−3. Significant differences were observed between clonal-mean water use efficiencies averaged over six sampling periods. The average δ13C of the mature and young foliage was found to be significantly correlated with WUE. However, the correlation was weak, suggesting that the relationship between δ13C and WUE is more complex in trees than suggested in the literature on crop plants. It is suggested that differences between sample trees in carbon allocation and leaf-to-air vapour pressure deficits may account for the poor correlation between δ13C and WUE in the four E. grandis clones studied.  相似文献   


8.
We carried out an integrated paleomagnetic, rock-magnetic and paleointensity study of Miocene volcanic succession from the trans-Mexican volcanic belt (TMVB) north of Guadalajara. A total of 37 consecutive basaltic lava flows (326 oriented standard paleomagnetic cores) were collected at Lazo locality. Continuous susceptibility measurements with temperature and hysteresis experiments yield in most cases reasonably reversible curves with Curie points close to that of pseudo-single-domain magnetite. Two geomagnetic reversals were observed in the 300 m thick composite section. Paleosecular variation was lower than the one observed in general during Miocene. It appears that the volcanic units have been emplaced during a relatively short time span of about 1 Ma. The mean paleomagnetic directions obtained from this study do not differ significantly from that expected for the middle Miocene. The mean paleomagnetic direction calculated from all data is I=31.1°, D=354.6°, k=124 and 95=2.1°, N=37. Seventy-two samples with apparently preserved primary magnetic mineralogy and without secondary magnetization, mostly belonging to reverse polarity chron were pre-selected for Thellier paleointensity determination. The flow-mean paleointensity values are ranging from 22.4±3.4 to 53.8±6.0 μT and the corresponding virtual dipole moments (VDMs) are ranging from (5.4±0.8) to (12.0±1.4)×1022 A m2. This corresponds to mean value of (7.7±2.2)×1022 A m2, which is close to present day geomagnetic field strength. Altogether, our data suggest the existence of relatively high geomagnetic field strength undergoing low fluctuations.  相似文献   

9.
We report the first measurements of hydrodynamic dispersion in a microfractured granite using a combination of novel techniques. A fracture network was induced in a cylindrical plug of Ailsa Craig micro-granite by thermal stressing, to produce an isotropic network of fractures with an average aperture of  0.3 μm, a density of approximately 4 × 104 fractures/mm3 and a permeability of 5.5 × 10− 17 m2. After saturating the cores with 0.01 M NaCl solution a step in the concentration profile to 1 M was advected into the plug at flow rates of 0.07 to 2.13 cm3 h− 1. The longitudinal electrical impedance of the plug was measured continuously as the solute front advected through its length until the plug was saturated with the concentrated electrolyte. Analysis of the impedance versus time relationships allows the derivation of the longitudinal dispersion coefficient, DL, and hydrodynamic retardation, RH. The Peclet number–dispersion relationship for the micro-fracture network is very similar to that predicted for other, radically different, fracture networks. Thus dispersion may be more dependent on fracture connectivity and length than fracture density and display a relationship similar to that shown by particle beds and clastic sandstones. The high retardation values observed (2.2–4.9) reflect flow behaviour within a fracture network with a proportion of ‘blind’ sections, and demonstrates how such networks can slow the advance of conservative solute components.  相似文献   

10.
Argon, krypton, chlorine, bromine, and iodine were measured in a homogeneous population of high-salinity hydrothermal fluid inclusions from the Tertiary-age Mississippi Valley-type (MVT) lead-fluorite-barite deposits at Hansonburg, New Mexico to establish new types of evidence for the history of both the fluid and the major dissolved salts. Noble gases and halogens in fluid inclusions containing 10−10–10−9 L of brine (Cl= 3 molal) were analyzed by laser microprobe noble-gas mass spectrometry (lmngms) on neutron-irradiated samples.

The concentrations of36Ar (4.7 × 10−8 molal) and84Kr1.8 × 10−9 molal) in the fluid inclusions are equal to those of fresh surface waters in equilibrium with air at approximately20 ± 5°. The mole ratios ofBr/Cl (1.2 × 10−4) andI/Cl (1–2 × 10−6) are among the lowest measured in any natural waters, similar to those of modern brines formed by dissolution of Permian NaCl-bearing evaporites in southeast New Mexico.40Ar/36Ar ratios (600) are twice that of air, and indicate that the fluid inclusions had excess radiogenic40Ar (1.4 × 10−5 molal) when trapped. The amount of excess40Ar appears to be too large to have been acquired with Cl by congruent dissolution of halite-bearing evaporites, and possibly too small to have been acquired with Pb by congruent dissolution of granitic basement rocks with Proterozoic KAr ages.

From thelmngms data, combined with published Pb and S isotope data, we infer the following sequence of events in the history of the Hansonburg MVT hydrothermal brine: (1) the brine originated as relatively dilute meteoric water, and it did not gain or lose atmospheric Ar or Kr after recharge; (2) the originally dilute fluid acquired the bulk of its Cl and sulfate in the subsurface after recharge by dissolving halite-bearing Permian? marine evaporites; (3) the high salinity brine then acquired most of its Pb and excess radiogenic40Ar from interactions with aquifer rocks other than evaporites, possibly clastic sedimentary rocks or basement rocks with Phanerozoic KAr “ages”; and (4) the brine deposited fluorite without having boiled or degassed.  相似文献   


11.
Isotope and hydrochemical data of the thermal water system in Cieplice laskie Zdrój (Spa) indicate the existence of two subsystems that greatly differ in volume and which meet at the fault zones of a granitic horst, where they discharge at an altitude of about 340m. One of the subsystems is very small (about 4 × 103 m3) as indicated by the tritium age of the order of 10 years and a low outflow rate. Its recharge area found from the δ18O and δD values, is about 200m above the springs, most probably on the slopes of the foothills of the Karkonosze Mountains south-southwest of the spa. The large subsystem contains water which is free of tritium and whose 14C content is from 1 to 8 pmc with δ13C = −8.0 to −9.2‰. The isotopic composition of this water reflects either the climatic effect (low-altitude recharge during a cooler pre-Holocene climate) or the altitude effect (recharge in the early Holocene period at about 1000m at the heights of the Karkonosze assuming that the 14C concentration is strongly reduced by exchange with calcite in veins). For the former hypothesis, the recharge area of this water is probably either at the foot of the southeastern slopes of the Kaczawa Mountains or/and at the foot of the Rudawy Janowickie Mountains, to the east of Cieplice. The noble gas temperatures are more consistent with the pre-Holocene recharge. Similarly, the 4He excess and 40Ar/36Ar ratio support the hypothesis of a pre-Holecene age. The constant 3He/4He ratio of 26 × 10−8 for highly different helium contents indicates crustal origin of helium. For the pre-Holocene age of water its volume is calculated at >- 109m3 (stagnant water in micropores and mobile water in fractures) and the hydraulic conductivity of the host granite massif is estimated at about 7 × 10−8 ms−1. Two outflows from this subsystem have different and variable fractions of a modern water component (bomb age), most probably originating from the bank infiltration of a nearby stream.  相似文献   

12.
The models suggested for the oceanic lithosphere which best predict oceanic heat flow and depth profiles are the constant thickness model and a model in which the lithosphere thickens away from the ridge with a heat source at its base. The latter is considered to be more physically realistic. Such a model, constrained by the observed oceanic heat flow and depth profiles and a temperature at the ridge crest of between 1100°C and 1300°C, requires a heat source at the base of the lithosphere of between 0.5 and 0.9 h.f.u., thermal conductivities for the mantle between 0.005 and 0.0095 cal cm−1 °C−1 s−1 and a coefficient of thermal expansion at 840°C between 4.1 × 10−5 and 5.1 × 10−5 °C−1. Plate creation and subduction are calculated to dissipate about 45% of the total earth heat loss for this model. The efficiency of this mechanism of heat loss is shown to be strongly dependent on the magnitude of the basal heat source. A relation is derived for total earth heat loss as a function of the rate of plate creation and the amount of heat transported to the base of plates. The estimated heat transport to the base of the oceanic lithosphere is similar to estimates of mantle heat flow into the base of the continental lithosphere. If this relation existed in the past and if metamorphic conditions in late Archaean high-grade terrains can be used to provide a maximum constraint on equilibrium Archaean continental thermal gradients, heat flow into the base of the lithosphere in the late Archaean must have been less than about 1.2–1.5 h.f.u. The relation between earth heat loss, the rate of plate creation and the rate of heat transport to the base of the lithosphere suggests that a significant proportion of the heat loss in the Archaean must have taken place by the processes of plate creation and subduction. The Archaean plate processes may have involved much more rapid production of plates only slightly thinner than at present.  相似文献   

13.
A new method is described for estimating: (a) the meridional electric current density, jθ, (b) the vertical growth rate of the zonal magnetic field, ∂Bφ/∂r, or its scale-height, Bφ/∂Bφ/∂r) and (c) the vertical growth rate of the vertical current density, ∂jr/∂r, at a few isolated points on the top surface of the Earth's core from observations of the internal geomagnetic field at the Earth's surface. The theoretical technique rests on combining unaccelerated, gravitationally-driven Boussinesq fluid dynamics of the core with frozen-flux electromagnetism, the mantle being treated as a spherically symmetric insulator.

Insertion into this theory of main field models for epochs 1965, 1975 leads to preliminary values for these quantities of magnitude: (a) jθ 1 A/m2, (b) ∂Bφ/∂r 10−6 T/m or Bφ/(∂Bφ/∂r) 10 m, (c) ∂jr/∂r 10−6 A/m3. Some geophysical implications of these estimates are discussed.  相似文献   


14.
He diffusion in olivine   总被引：1，自引：0，他引：1  
Helium diffusion in olivine (dunite xenolith) has been measured in the temperature range 1180–1460°C; a linear Arrhenius function was obtained with an activation energy of 120−27+32 kcal/mole, and a pre-exponential factor (D0) = 2.2 × 108 cm2/s.

Diffusion mechanisms are not a viable means of degassing He from the mantle. Olivine phenocrysts can be expected to retain previously trapped He, during cooling in extrusive basalts, provided the flow units are thinner than 50 m; xenoliths will retain mantle He signatures only if magma transport times are less than 50 years, or if the He fugacity in the magma is high enough to prevent xenolith degassing. The lower oceanic crust is probably substantially degassed of He. Trapped He will be qualitatively retained in quenched submarine basalt glass only if the cooling rate is faster than 5 × 1014°C/m.y.; glass at several centimeters depth in a basalt flow (near the spherulite zone) will have cooling rates lower than this, so He loss may be significant in many basalt glass samples.  相似文献   


15.
Measurements of transpiration from individual trees of Eucalyptus from plantations at four different sites in Karnataka, Southern India, are presented. These show large (as much as tenfold) differences in the transpiration between premonsoon and postmonsoon periods, a reflection of the effects of soil-moisture stress in the premonsoon periods. For trees with diameters at breast height (DBH) less than 10 cm the transpiration rate of individual trees is proportional to the square of the DBH. For trees which are not experiencing soil-water stress the daily transpiration rate of individual trees, q, is well represented by the relation: q = (6.6 ± 0.3)g (m3 day−1 where g (m2) is the tree basal area. On a unit ground area basis the transpiration rate, expressed as a depth per day is given by the relation: Et = (0.66 ± 0.03)G (mm day−1 where g(m2ha−1) is the total basal area per hectare. For all the sites studied, although there is evidence for the ‘mining’ of soil water as roots penetrate deeper depths in the soil each year, there is no evidence for direct abstraction from the water table.  相似文献   

16.
The formation and development of a salt plume (salinity up to 800 mg Cl 1−1) in the inner part of the Coastal Plain aquifer of Israel is analyzed. Massive groundwater exploitation during the 1950s caused a large drop in the water level and formation of a hydrologic depression in the Be'er Toviyya-Kefar Warburg area. The depression reached a maximal depth during the late 1960s; thereafter a reduction in the rate of pumpage led to restoration of water levels and shallowing of the depression, until its complete disappearance towards the end of the 1980s. A spot of high salinity first appeared in 1956, following a deep drawdown in the water levels. This saline plume has been continuously expanding with increasing salinity concentrations (200–800 mg Cl 1−1) in its center. The average rate of radial expansion was about 50 m year−1. The expansion and salinization did not cease as the depression disappeared. Rather, equalization of water levels in wells situated within the plume area with those of situated along its margins resulted in the salinization of the latter within a period of 1 year.

Mass balances for water and chloride contents were made for the period 1967–1990. Taking into consideration the storage change, pumpage, natural replenishment and artificial recharge, the lateral inflow to the depression is estimated as 60 × 106 m3. Upon addition of the chloride balance, and taking into consideration the chloride concentrations of the surrounding fresh water and the apparent possible end-member of the saline source (based on geochemical considerations), the saline inflow is estimated as (40–60) × 106 m3. These estimates indicate that a large amount of saline water penetrated into the aquifer, of about half of the natural replenishment of the study area, with an estimated salinity of 1900–2700 mg Cl 1−1.

It is suggested that the salt plume was formed as a result of a drop in water level combined with a flow of underlying saline water bodies from deeper strata. The chemical composition of the groundwater points to the existence of two saline water bodies of Ca-chloride composition and a marine Br/Cl ratio: (1) saline water with low Na/Cl (0.6), So4/Cl, and B/Cl ratio; (2) saline water with higher Na/Cl (> 0.6), So4/Cl, and B/Cl ratios. These chemical compositions resemble Ca-chloride saline waters found in other locations in the Coastal Plain aquifer and in underlying formations. The saline water bodies may occur in either pockets at the bottom of the aquifer or lumachelle and sandstone layers of high hydraulic conductivity in underlying sediments.  相似文献   


17.
Zheng TL  Su JQ  Maskaoui K  Yu ZM  Hu Z  Xu JS  Hong HS 《Marine pollution bulletin》2005,51(8-12):1018-1025
The effect of S10, a strain of marine bacteria isolated from sediment in the Western Xiamen Sea, on the growth and paralytic shellfish poison (PSP) production in the alga Alexandrium tamarense (A. tamarense) was studied under controlled experimental conditions. The results of these experiments have shown that the growth of A. tamarense is obviously inhibited by S10 at high concentrations, however no evident effect on its growth was observed at low concentrations. Its PSP production was also inhibited by S10 at different concentrations, especially at low concentrations. The toxicity of this strain of A. tamarense is about (0.95–12.14) × 10−6 MU/cell, a peak toxicity value of 12.14 × 10−6 MU/cell appeared on the 14th day, after which levels decreased gradually. The alga grew well in conditions of pH 6–8 and salinities of 20–34‰. The toxicity of the alga varied markedly at different pH and salinity levels. Toxicity decreased as pH increased, while it increased with salinity and reached a peak value at a salinity of 30‰, after which it declined gradually. S10 at a concentration of 1.02 × 109 cells/ml inhibited growth and the PSP production of A. tamarense at different pH and salinity levels. S10 had the strongest inhibitory function on the growth of A. tamarense under conditions of pH 7 and a salinity of 34‰. The best inhibitory effect on PSP production by A. tamarense was at pH 7, this inhibitory effect on PSP production did not relate to salinity. Interactions between marine bacteria and A. tamarense were also investigated using the flow cytometer technique (FCM) as well as direct microscope counting. S10 was identified as being a member of the genus Bacillus, the difference in 16S rDNA between S10 and Bacillus halmapalus was only 2%. The mechanism involved in the inhibition of growth and PSP production of A. tamarense by this strain of marine bacteria, and the prospect of using it and other marine bacteria in the bio-control of red-tides was discussed.  相似文献   

18.
In the present work, we built a mathematical model of polychlorinated biphenyl (PCB) bioaccumulation in Perna viridis, namely, a one-compartment model with a time dependent incorporation rate R (μg g−1 lipid per ppb water per day), with positive substrate cooperativity as the underlying physical mechanism. The temporal change of the PCB concentration Q (μg g−1 lipid) in the soft tissues of the mussel depends on the competition of the input rate RW and the output rate kQ, where W is the concentration of PCB in water (ppb water) and k is the elimination rate (per day). From our experimental data, k=0.181±0.017 d−1. The critical concentration in water Wc for positive substrate cooperativity was found to be 2.4 ppb. Below Wc, R is a constant. For a water concentration of 0.5 ppb Aroclor 1254, R=24.0±2.4 μg g−1 lipid ppb−1 d−1. Above Wc, positive substrate cooperativity comes into effect and R becomes a function of time and dependent on the concentration Q in a form R=γQ/(Q+δ). This is the case for a water concentration of 5 ppb Aroclor 1254, where γ=15.1 μg g−1 lipid ppb−1 d1 and δ≈200 μg g−1 lipid. From this model, the uptake is exponentially increasing when the PCB concentration in the mussel is small compared to 200 μg g−1 lipid, and hyperbolically increasing when the concentration is large compared to 200 μg g−1 lipid, which are consistent with the experimental data. The model is useful for understanding the true processes taking place during the bioaccumulation and for risk assessment with higher confidence. Future experimental data which challenge the present model are anticipated and in fact desirable for improvement and perfection of the model.  相似文献   

19.
Deformation of synthetic calcite–anhydrite aggregates to large shear strains (up to γ = 12.4 at 600 °C, 300 MPa confining pressure and a constant angular displacement rate corresponding to a shear strain rate of 10− 3 s− 1) resulted in the first experimental observation of strain localisation from initially homogeneous rocks. In contrast to experiments on pure calcite and anhydrite, which deformed homogeneously to large strains (γ ≥ 5), all experiments on calcite–anhydrite mixtures resulted in heterogeneous deformation at γ > 1 and the formation of narrow localised bands in the microstructures at γ > 4. In these bands, the amount of strain is at least twice as large as in the rest of the sample and individual grains of the same phase cluster and align, thereby forming microstructural layering similar to planar fabrics in natural mylonites. A switch in deformation mechanism in anhydrite from dislocation creep to diffusion creep and/or grain boundary sliding occurs simultaneously with strain localisation. It is concluded that deformation-induced heterogeneous phase distributions cause local strength differences initiating strain localisation in the calcite–anhydrite mixtures. The study suggests that the presence of two phases in combination with a change in deformation mechanism may be responsible for strain localisation in natural poly-mineralic mylonites.  相似文献   

20.
Noble gas elemental and isotopic abundances have been analysed in eight samples of youthful basaltic glass dredged from three different locations within the Lau Backarc Basin: (1) the King's Triple Junction, (2) the Central Lau Spreading Centre at 18°S and (3) the Eastern Lau Spreading Centre at 19°S. Samples from the Lau central and eastern spreading centres have MORB-like helium isotopic ratios of approximately 1.2 × 10−5 (8.5 R/RA). In contrast, the samples from the King's Triple Junction yield helium isotopic ratios averaging 9.4 (±0.8) × 10−6 (6.7 ± 0.6 R/RA), systematically lower than the MORB-like value, which may be reflecting the addition of radiogenic 4He released from the descending slab. Neon isotopic ratios are enriched in 20Ne and 21Ne with respect to atmospheric ratios by as much as 23% and 62% respectively. These observations further confirm that non-atmospheric neon is a common characteristic of samples derived from the mantle. The helium and neon isotopic signatures in the samples can be explained by mixing of a primordial solar component, radiogenic and nucleogenic components produced by radioactive processes inside the Earth, and an atmospheric component. This reconnaissance survey of noble gases in a backarc basin indicates that current volcanism is dominated by magmas from the mantle wedge, a source similar to that from which MORBs are derived. The heavier noble gases (argon, krypton and xenon), however, show more atmosphere-like compositions, either indicating strong interaction of the magmas with the atmosphere or the presence of a recycled component derived from the underlying subducting slab.  相似文献   

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