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1.
The In Ouzzal terrane (Western Hoggar) is an example of Archaean crust remobilized during a very-high-temperature metamorphism related to the Paleoproterozoic orogeny (2 Ga). Pan-African events (≈0.6 Ga) are localized and generally of low intensity. The In Ouzzal terrane is composed of two Archaean units, a lower crustal unit made up essentially of enderbites and charnockites, and a supracrustal unit of quartzites, banded iron formations, marbles, Al–Mg and Al–Fe granulites commonly associated with mafic (metanorites and garnet pyroxenites) and ultramafic (pyroxenites, lherzolites and harzburgites) lenses. Cordierite-bearing monzogranitic gneisses and anorthosites occur also in this unit. The continental crust represented by the granulitic unit of In Ouzzal was formed during various orogenic reworking events spread between 3200 and 2000 Ma. The formation of a continental crust made up of tonalites and trondhjemites took place between 3200 and 2700 Ma. Towards 2650 Ma, extension-related alkali-granites were emplaced. The deposition of the metasedimentary protoliths between 2700 and 2650 Ma, was coeval with rifting. The metasedimentary rocks such as quartzites and Al–Mg pelites anomalously rich in Cr and Ni, are interpreted as a mixture between an immature component resulting from the erosion and hydrothermal alteration of mafic to ultramafic materials, and a granitic mature component. The youngest Archaean igneous event at 2500 Ma includes calc-alkaline granites resulting from partial melting of a predominantly tonalitic continental crust. These granites were subsequently converted into charnockitic orthogneisses. This indicates crustal thickening or heating, and probably late Archaean high-grade metamorphism coeval with the development of domes and basins. The Paleoproterozoic deformation consists essentially of a re-activation of the pre-existing Archaean structures. The structural features observed at the base of the crust argue in favour of deformation under granulite-facies. These features are compatible with homogeneous horizontal shortening of overall NW–SE trend that accentuated the vertical stretching and flattening of old structures in the form of basins and domes. This shortening was accommodated by horizontal displacements along transpressive shear corridors. Reactional textures and the development of parageneses during the Paleoproterozoic suggest a clockwise P–T path characterized by prograde evolution at high pressures (800–1050 °C at 10–11 kbar), leading to the appearance of exceptional parageneses with corundum–quartz, sapphirine–quartz and sapphirine–spinel–quartz. This was followed by an isothermal decompression (9–5 kbar). Despite the high temperatures attained, the dehydrated continental crust did not undergo any significant partial melting. The P–T path followed by the granulites is compatible with a continental collision, followed by delamination of the lithosphere and uprise of the asthenosphere. During exhumation of this chain, the shear zones controlled the emplacement of carbonatites associated with fenites.  相似文献   

2.
Some granulites from the Amessmessa area (south In Ouzzal unit, Hoggar) contain the peak assemblage gedrite+garnet+sillimanite+quartz that was used to estimate the P–T conditions of metamorphism. The rocks developed symplectites and corona textures by the breakdown of the primary paragenesis to orthopyroxene, cordierite and spinel. The successive parageneses formed in separate microdomains according to a clockwise P–T path. Geothermometry, geobarometry and phase diagram calculations indicate that the textures formed by decompression and cooling from 7–9 kbar and 850–900°C to 3.5–4.5 kbar and 700–800°C. This P–T evolution is consistent with low to medium aH2O, between 0.4 and 0.7, and is similar to the metamorphic conditions deduced in Al–Mg granulites from the north of In Ouzzal.  相似文献   

3.
The In Ouzzal granulitic massif is composed mainly of various meta-igneous rocks which, in spite of Rb, U, Th, Cs and some K and Sr mobility, can be dated and generally classified according to their chemical composition as follows. Basic and ultrabasic granulites interlayered with the metasediments correspond to (1) ultrabasic cumulates from dislocated tholeiitic bodies, (2) ancient komatiitic to high-Mg tholeiitic basalts similar to the suites found in Archaean greenstone belts and (3) calcalkaline protoliths of high-K andesitic composition. No geochronological constraints are available apart from the depositional age of some associated sediments which is younger than 2.70 Ga detrital zircons, and the Nd model age of the andesitic granulites of c. 3.4 Ga. In spite of the high-grade metamorphism, the acidic magmatic precursors of the charnockites can be divided in three groups. (1) The most juvenile acid orthogneisses are trondhjemitic or tonalitic in composition, being similar to the TTG suites which are classically considered to be formed by partial melting of mantle-derived protoliths. The 3.3–3.2 Ga TDM indicates a possible age of separation from the mantle reservoir while the plutons may have been emplaced between 3.3 and 2.7 Ga (U–Pb zircon & Nd ages). (2) A group of alkaline granitic gneisses, similar in composition to rift-related-granites, were emplaced at 2650±10 Ma (U–Pb & Rb–Sr ages) in a thick continental crust. (3) Calcalkaline granodioritic and monzogranitic suites derived from the partial melting of continental precursors (3.5–3.3 Ga), in lower to middle levels of the continental crust. They were emplaced close to 2.5 Ga during crustal thickening. The very high-temperature metamorphism occurred at 2002±7 Ma from the age of synfoliation intrusions and was probably related to major overthrusting. Retrogressive metamorphism is dated at 1.95 Ga from garnet-Nd ages. In spite of the very high-temperature conditions, partial melting during granulite facies metamorphism may be restricted to scarce cordierite-bearing monzogranitic gneisses. The 2.0 Ga VHT metamorphism could be related to overthrusting, extensional or underplating processes.  相似文献   

4.
Osumilite is reported in Palaeoproterozoic Al–Mg‐rich granulites from the Khanfous area (Tekhamalt, In Ouzzal, Hoggar, Algeria). The main peak assemblages are osumilite + sapphirine + biotite + orthopyroxene + sillimanite and osumilite + orthopyroxene + sillimanite + quartz ± biotite (±K‐feldspar) in silica‐deficient and silica‐saturated granulites respectively. Osumilite coexists with F‐rich biotite (XF ≈ 0.6). The observed microstructures, the mass balance of metamorphic reactions and P–T pseudosections modelled for bulk‐rock and reaction‐microdomain compositions indicate a clockwise P–T metamorphic evolution at ultrahigh temperatures, without substantial post‐peak deformation. The peak P–T conditions recorded by the osumilite‐bearing assemblages are 8.5–9.0 kbar and 930–980 °C. During retrogression, osumilite was partially or totally replaced by fine‐grained pseudomorphs of cordierite + orthopyroxene + K‐feldspar + quartz at ~7 kbar and ~850 °C. This study confirms that osumilite can occur only in Mg‐rich metamorphic rocks that experienced ultrahigh‐temperature metamorphism under anhydrous conditions. In the presence of a hydrous fluid, it is replaced, even at high temperatures, by cordierite‐bearing assemblages. This important feature explains the rarity of osumilite in granulite facies rocks and its common replacement by cordierite + orthopyroxene + K‐feldspar + quartz pseudomorphs. The peak conditions suggest that a delamination of the lithospheric mantle underneath the In Ouzzal crust brought the asthenosphere close to the Mohorovi?i? discontinuity.  相似文献   

5.
Paleoarchean granulite-facies metasedimentary rocks (quartzites, garnet quartzites, garnet-pyroxene gneisses, pyroxene-magnetite and magnetite quartzites) attributed to the Dniester-Bug Group of the Ukrainian Shield were studied. On the basis of geochemical data, including REE, the primary composition of these rocks was reconstructed as association of Fe-rich sandstones and sublitharenites, Fe-shales, and BIFs. This sedimentary association is similar to the rocks of other ancient greenstone belts and ascribed to the Algama-type iron formation. The sum of Al2O3, CaO, Na2O, and TiO2, high Zr contents (>100 ppm in quartzites), and the presence of detrital zircon grains of different ages are consistent with the terrigenous nature of sedimentary rocks. The Sm/Nd, Ti/Zr, Sc/Zr, and Ni/Zr ratios indicate the predominance of granitoid rocks in the source areas. The elevated Cr contents suggest that, in addition to granitoids, the source area contained ultramafic rocks. Geochemical characteristics, such as Fe/Mn ratio, low REE contents, and variations of REE versus the sum of Ni, Co, and Cu testify that sedimentation occurred under shallow-water conditions on the continent or its slope, similarly as the formation of ancient (3.5–3.2 Ga) basalt-komatiitic series intercalated with sedimentary rocks in the Pilbara Craton. The age of supracrustal rocks of the Dniester-Bug Group was constrained within the time interval of 3.4–3.2 Ga on the basis of U-Pb zircon dating and determination of Nd isotope composition. The DM model age of quartzites varies from 3.37 to 3.5 Ga. Sedimentary rocks together with volcanic rocks represent the oldest supracrustal association of the East European Platform.  相似文献   

6.
The In Ouzzal granulitic unit (IOGU) consists predominantly of felsic orthogneisses most of which correspond to granitoids emplaced during the Archaean, plus metasediments, including olivine-spinel marbles, of late Archaean age. All units were metamorphosed at granulite facies during the Eburnean (2 Ga). The stable isotope signature of the marbles (δ13C=–0.8 to –4.2‰/PDB; δ18O = 7.9 to 18.9‰/SMOW) does not record a massive streaming of C-bearing fluids during metamorphism. Most of the isotopic variation in the marbles is explained in terms of pregranulitic features. Metasomatic transformation of granulites into layered potassic syenitic rocks and emplacement of carbonate veins and breccias occurred during retrogressive granulite facies conditions. The chemistry of these rocks is comparable with that of fenites and carbonatites with high contents of (L)REEs, Th, U, F, C, Ba and Sr but, with respect to these elements, a relative depletion in Nb, Ta, Hf, Zr and Ti. The isotopic compositions of Nd (?Nd(T)=–6.3 to –9.9), of Sr (87Sr/86Sr(T)= 0.7093–0.7104), and the O isotopic composition of metasomatic clinopyroxene (δ18O = 6.9 to 8‰), all indicate that the fluid had a strong crustal imprint. On the basis of the C isotope ratios (δ13C =–3.5 to –9.7‰), the fluid responsible for the crystallization of carbonates and metasomatic alteration is thought to be derived from the mantle, presumably through degassing of mantle-derived magmas at depth. Intense interaction with the crust during the upward flow of the fluid may explain its chemical and isotopic signatures. The zones of metasomatic alteration in the In Ouzzal granulites may be the deep-seated equivalents of the zones of channelled circulation of carbonated fluids described at shallower levels in the crust.  相似文献   

7.
The properties of ordinary chondrites (OC) reflect both nebular and asteroidal processes. OC are modeled here as having acquired nebular water, probably contained within phyllosilicates, during agglomeration. This component had high Δ17O and acted like an oxidizing agent during thermal metamorphism. The nebular origin of this component is consistent with negative correlations in H, L, and LL chondrites between oxidation state (represented by olivine Fa) and bulk concentration ratios of elements involved in the metal-silicate fractionation (e.g., Ni/Si, Ir/Si, Ir/Mn, Ir/Cr, Ir/Mg, Ni/Mg, As/Mg, Ga/Mg). LL chondrites acquired the greatest abundance of phyllosilicates with high Δ17O among OC (and thus became the most oxidized group and the one with the heaviest O isotopes); H chondrites acquired the lowest abundance, becoming the most reduced OC group with the lightest O isotopes.Chondrule precursors may have grown larger and more ferroan with time in each OC agglomeration zone. Nebular turbulence may have controlled the sizes of chondrule precursors. H-chondrite chondrules (which are the smallest among OC) formed from the smallest precursors. In each OC region, low-FeO chondrules formed before high-FeO chondrules during repeated episodes of chondrule formation.During thermal metamorphism, phyllosilicates were dehydrated; the liberated water oxidized metallic Fe-Ni. This caused correlated changes with petrologic type including decreases in the modal abundance of metal, increases in olivine Fa and low-Ca pyroxene Fs, increases in the olivine/pyroxene ratio, and increases in the kamacite Co and Ni contents. As water (with its heavy O isotopes) was lost during metamorphism, inverse correlations between bulk δ18O and bulk δ17O with petrologic type were produced.The H5 chondrites that were ejected from their parent body ∼7.5 Ma ago during a major impact event probably had been within a few kilometers of each other since they accreted ∼4.5 Ga ago. There are significant differences in the olivine compositional distributions among these rocks; these reflect stochastic nebular sampling of the oxidant (i.e., phyllosilicates with high Δ17O) on a 0.1-1 km scale during agglomeration.  相似文献   

8.
In the W Hoggar (Algeria), the major transcurrent N–S East Ouzzal shear zone (EOSZ) hosts several world-class gold deposits over a 100-km length. The late Pan-African EOSZ separates two contrasting Precambrian domains: the Archaean In Ouzzal block to the west (orthogneisses with subordinate metasediments, reworked and granulitized in the c. 2 Ga Eburnean event) and a Middle Proterozoic block to the east (again orthogneisses and metasediments, involved in the c. 600 Ma Pan-African event). The EOSZ is a mylonite belt, 1–3 km wide, with a 50-m-wide ultramylonite belt hosting numerous quartz veins and lenses (giant hydrothermal quartz system) associated with a quartz-sericite-pyrite-carbonate (beresite) alteration. These hydrothermal events occurred under ductile (evolving towards brittle) conditions, between 500 and 300 MPa, at 500–300°C, with aqueous-carbonic fluids derived both from underlying devolatilized metamorphic rocks and a mantle source, as recorded by stable (C, O) isotope data. No gold mineralization was associated with these typical mesothermal events. Following a pressure drop (to 130 MPa), related to the inception of extensional tectonics, the EOSZ was later percolated by a new set of hydrothermal fluids, evolved from basinal waters that deeply penetrated into the In Ouzzal basement. These fluids were Ca-bearing brines (up to 25% wt. eq. NaCl), characterized by high δD (-9 to + 18‰ range), mobilized by the thermal energy released by the late Pan-African granite magmatism (Taourirt granites). As demonstrated by Pb isotope data, the brines leached Au from the In Ouzzal granulites (which contain 3 ppb Au). Fluid inclusion studies indicate that gold was deposited from these brines in the EOSZ at a depth of c. 5 km, due to mixing and cooling with descending diluted fluids.  相似文献   

9.
The In Ouzzal terrane (IOT) or In Ouzzal granulite unit (IOGU) is an elongated Palaeoproterozoic block within the Neoproterozoic Pan-African belt of north-west Africa. The granulites derive from Archaean protoliths that include a large volume of metasediments which were deposited on a 3.2-Ga gneissic basement. Near-peak granulite facies conditions between 2.17 and 2 Ga were estimated at P=10 kbar and T rising from 800 to 1000°C. Premetamorphic orthogneisses were intruded at 2.5 Ga, and followed by the emplacement of syn- to late-kinematic charnockites, syenites and carbonatites at around 2 Ga. Cooling of the granulites occurred till 1800 Ma. Shortly after its exhumation coeval with crustal extension and related alkaline magmatism in adjacent areas, the IOT was buried beneath late Palaeoproterozoic and Neoproterozoic cover sequences, and then behaved as a rigid block. Both margins are lithospheric faults, as evidenced by the occurrence of shear-zone-related mafic and felsic plutons. Pan-African tectonothermal events were negligible in the north, but granulites in the south were significantly reworked under lower greenschist facies conditions during the northern motion of the block with respect to both the western and the eastern Pan-African terranes. The Cambrian molasse, associated with widespread alkaline volcanism and subvolcanic granites, is horizontal in the north. The IOT, which was part of a larger continental mass including its counterpart in northern Mali, is interpreted as an exotic terrane which may have docked during Pan-African plate convergence and lateral collision. The unchanged pediplain since c. 1.7 Ga in the north suggests that the IOT is underlain by thick Palaeoproterozoic lithospheric mantle, whereas its southern part is probably allochthonous and overlies Pan-African structural units.  相似文献   

10.
We report new data on the major, minor and trace element compositions of metasedimentary quartzcordierite gneisses (QCG), an important member of the Archaean Malene supracrustal suite found throughout the Godthåbsfjord region of West Greenland. The analyzed QCG contain assemblages of quartz+cordierite+biotite±garnet±anthophyllite/gedrite±staurolite±sillimanite±plagioclase (with abundant accessory zircon, and minor rutile, monazite and allanite), and broadly resemble cordierite-orthoamphibole rocks found in a great number of other metamorphic terrains. Chemically, the QCG are characterized by: (1) high but variable SiO2 (59–87 wt%), relative enrichments in MgO, FeO, and Al2O3 (mg～0.35–0.85), and depletions in Na2O, K2O and especially CaO; (2) low concentrations of Sc, Cr, Co, Ni, and Sr; (3) high concentrations of Y, Nb, Zr, Hf, Ta, Th, U, and REE (rare earth elements)-with prominent negative Eu-anomalies in each case; (5) high concentrations of Ga (18–55 ppm), with variable Ga/Al ratios that are significantly higher than average crustal material. Low Cr and Ni, together with enriched and fractionated REE (displaying negative Eu-anomalies), distinguish the Malene QCG from published accounts of most other Archaean sedimentary rocks. Furthermore, all of the above-mentioned trace element characteristics distinguish the QCG from “ordinary” Malene clastic metasediments (quartzites, psammites, and pelites), suggesting a separate origin for the QCG. These data point towards chemically evolved felsic igneous rocks being the source of the QCG. Consequently, we propose that the Malene QCG represent metamorphosed felsic volcaniclastic sediments that underwent hydrothermal alteration by heated seawater prior to metamorphism, which resulted in gain of Mg (and Fe?), loss of alkalis and lime, and possibly Eu and Sr. The overall trace-element characteristics of the QCG (elevated Ga, Zr, Nb, REE, etc.) are features shared by A-type granites and their volcanic equivalents. Such igneous rocks may represent the ultimate source material for the QCG protolith.  相似文献   

11.
Ultrahigh temperature (UHT) granulites in the Eastern Ghats Province (EGP) have a complex P–T–t history. We review the P–T histories of UHT metamorphism in the EGP and use that as a framework for investigating the P–T–t history of Mg–Al‐rich granulites from Anakapalle, with the express purpose of trying to reconcile the down‐pressure‐dominated P–T path with other UHT localities in the EGP. Mafic granulite that is host to Mg–Al‐rich metasedimentary granulites at Anakapalle has a protolith age of c. 1,580 Ma. Mg–Al‐rich metasedimentary granulites within the mafic granulite at Anakapalle were metamorphosed at UHT conditions during tectonism at 960–875 Ma, meaning that the UHT metamorphism was not the result of contact metamorphism from emplacement of the host mafic rock. Reworking occurred during the Pan‐African (c. 600–500 Ma) event, and is interpreted to have produced hydrous assemblages that overprint the post‐peak high‐T retrograde assemblages. In contrast to rocks elsewhere in the EGP that developed post‐peak cordierite, the metasedimentary granulites at Anakapalle developed post‐peak, generation ‘2’ reaction products that are cordierite‐absent and nominally anhydrous. Therefore, rocks at Anakapalle offer the unique opportunity to quantify the pressure drop that occurred during so‐called M2 that affected the EGP. We argue that M2 is either a continuation of M1 and that the overall P–T path shape is a complex counter‐clockwise loop, or that M1 is an up‐temperature counter‐clockwise deviation superimposed on the M2 path. Therefore, rather than the rocks at Anakapalle having a metamorphic history that is apparently anomalous from the rest of the EGP, we interpret that other previously studied localities in the EGP record a different part of the same P–T path history as Anakapalle, but do not preserve a significant record of pressure decrease. This is due either to the inability of refractory rocks to extensively react to produce a rich mineralogical record of pressure decrease, or because the earlier high‐P part of the rocks history was erased by the M1 loop. Irrespective of the specific scenario, models for the tectonic evolution of the EGP must take the substantial pressure decrease during M2 into account, as it is probable the P–T record at Anakapalle is a reflection of tectonics affecting the entire province.  相似文献   

12.
The paper presents data on high-grade silicate–carbonate rocks (calciphyres) from the Irkut block (Sharyzhalgai uplift, southwestern Siberian craton). Their origin and age were determined from the rock characteristics, U–Pb dating, REE content, and Hf isotope composition of zircon. The calciphyres occur both as independent section fragments and as interbeds within Paleoproterozoic garnet-bearing and high-alumina (cordierite- and sillimanite-bearing) gneisses. They were produced by metamorphism of terrigenous-carbonate sediments. The terrigenous sediments range in maturity from arenites and wackes to argillaceous rocks; this is consistent with the reconstruction of the sedimentary protoliths of paragneisses, which are predominant in the metasedimentary rocks. The petrogeochemical features of the calciphyres, their LREE enrichment relative to “pure” carbonate rocks, and a distinct Eu anomaly were inherited from the terrigenous component of calc-silicate sediments. The Nd model age (2.4–2.7 Ga) of the calciphyres and the value THf(DM-2st) = 2.5–3.0 Ga for zircon from these rocks indicate that carbonate accumulation was accompanied by the supply of terrigenous material, which formed during the erosion of Archean and Paleoproterozoic crust. Zircon from the calciphyres is similar to metamorphic zircon in REE patterns and Th/U ratios. It might have been of detrital origin and then recrystallized during high-temperature metamorphism. Terrigenous-silicate rocks were metamorphosed at ca. 1.87 Ga. This is close to the previous age estimates for the terrigenous rocks metamorphism (1.85–1.86 Ga) and the age of baddeleyite from apocarbonate metasomatic rocks (1.86 Ga).  相似文献   

13.
川西同德和沙坝麻粒岩及其退变质岩石之间的元素迁移   总被引：6，自引：0，他引：6  
利用川西麻粒岩的全岩化学组成与岩石中特征矿物的化学性质,研究了麻粒岩退变质作用的元素迁移。对紫苏辉石、普通辉石和普通角闪石的电子探针分析表明,随着麻粒岩退变质作用程度的加深,矿物的化学组成与全岩的元素迁移同步变化。由于矿物组合和岩相的转变以及地壳流体的作用,同德二辉麻粒岩在退变质至黑云角闪斜长片麻岩过程中,K,Rb,Cs,K／Na,Fe^3+和Fe3+／Fe^2+增加,Fe^2+,V,Co,Ba,Sr和Pb降低;在沙坝二辉麻粒岩退变质为含绿帘石角闪斜长片麻岩过程中,Na,Ca,Fe^3+,Zr,Hf,Nb,Ta,Rb,U,Th,REE和Fe^3+／Fe^2+增加,Fe^2+,Mg,K,Co,Zn,Cs,Pb和K／Na降低。麻粒岩退变质过程中制约不同元素迁移的主要矿物相是普通角闪石等退变质新生矿物。同德和沙坝两个麻粒岩块退变质作用中,个别元素迁移性状并不相同,这可能与原岩的性质和变质流体的成分等环境地质条件有关。  相似文献   

14.
In the Hunan-Guizhou-Guangxi area there have developed very thick bedded siliceous rocks of the late Sinian. The rocks have a fairly pure composition, with an average content of siliceous minerals exceeding 95%. They are relatively rich in Fe and Mn, and poor in Al, Ti and Mg. The Fe/Ti, (Fe+Mn)/Ti, Al/(Al+Fe+Mn) and U/Th ratios and the Al-Fe-Mn and Fe-Mn-(Ni+Co+Cu)×10 triangle diagrams all show that they are hydrothermal sedimentary siliceous rocks. In the rocks the total amount of REEs is low, the δCe shows an obvious negative anomaly and the 8Eu a weak anomaly, and LREE>HREE, all indicating that they are products of hydrothermal processes. The δ30Si and δ18O values, as well as the formation temperature of the rocks all clearly show that the silica forming the rocks comes from hot water. Besides, analyses of the depositional environment of the rocks using the MnO/TiO2 ratio and the δCe and δ30Si values yield the same conclusion that they are formed in environments from continental marginal slope  相似文献   

15.
The Houxianyu borate deposit in northeastern China is one of the largest boron sources of China, hosted mainly in the Paleoproterozoic meta-volcanic and sedimentary rocks (known as the Liaohe Group) that are characterized by high boron concentrations. The borate ore-body has intimate spatial relationship with the Mg-rich carbonates/silicates of the Group, with fine-grained gneisses (meta-felsic volcanic rocks) as main country rocks. The presence of abundant tourmalinites and tourmaline-rich quartz veins in the borate orebody provides an opportunity to study the origin of boron, the nature of ore-forming fluids, and possible mineralization mechanism. We report the chemical and boron isotopic compositions of tourmalines from the tourmaline-rich rocks in the borate deposit and from the tourmaline-bearing fine-grained gneisses.Tourmalines from the fine-grained gneisses are chemically homogeneous, showing relatively high Fe and Na and low Mg, with δ11B values in a narrow range from +1.22‰ to +2.63‰. Tourmalines from the tourmaline-rich rocks, however, commonly show compositional zoning, with an irregular detrital core and a euhedral overgrowth, and have significantly higher Mg, REE (and more pronounced positive Eu anomalies), V (229–1852 ppm) and Sr (208–1191 ppm) than those from the fine-grained gneisses. They show varied B isotope values ranging from +4.51‰ to +12.43‰, which plot intermediate between those of the terrigenous sediments and arc rocks with low boron isotope values (as represented by the δ11B = +1.22‰ to +2.63‰ of the fine-grained gneisses of this study) and those of marine carbonates and evaporates with high boron isotope values. In addition, the rim of the zoned tourmaline shows notably higher Mg, Ti, V, Sn, and Pb, and REE (particularly LREEs), but lower Fe, Co, Cr, Ni, Zn, Mn, and lower δ11B values than the core. These data suggest that (1) the sources of boron of the borate ore-body are mainly the Paleoproterozoic meta-volcanic and sedimentary rocks, and (2) the ore-forming fluids should be the high temperature metamorphic fluids related to the amphibolite-facies metamorphism of the Paleoproterozoic foldbelt, which leach boron from the boron-rich meta-volcanic and sedimentary rocks of the Liaohe Group, and the boron-rich metamorphic fluids subsequently interacted with the marine Mg-rich carbonates and evaporates, forming borate deposit, the tourmaline overgrowth in the rim and the tourmaline-rich rocks.  相似文献   

16.
Quartz Al–Mg granulites exposed at In Hihaou, In Ouzzal (NW Hoggar), preserve an unusual high-grade mineral association stable at temperatures up to 1050°C, involving the parageneses orthopyroxene–sillimanite–garnet–quartz, sapphirine–quartz and spinel–quartz. The phase relationships within the FMAS system show that a continuum exists between the earlier prograde reaction textures and those of the later decompressive event. The following mineral reactions involving sillimanite are deduced: (1) Grt+Qtz→Opx+Sil, (2) Opx+Sil→Grt+Spr+Qtz, (3) Grt+Sil+Qtz→Crd, (4) Grt+Sil→Crd+Spr, (5) Grt+Sil+Spr→Crd+Spl, (6) Grt+Sil→Crd+Spl, (7) Grt+Crd+Sil→Spl+Qtz and (8) Grt+Sil→Spl+Qtz. Minerals in quartz Al–Mg granulites display compositional variations consistent with the observed reactions. The Mg/(Mg+Fe2+) range of the main minerals is as follows: cordierite (0.81–0.97), sapphirine (0.77–0.88), orthopyroxene (0.65–0.81), garnet (0.33–0.64) and spinel (0.23–0.56). The reaction textures and the evolution of the mineral assemblages in the quartz Al–Mg granulites indicate a clockwise P–T trajectory characterized by peak conditions of at least 10 kbar and 1050°C, followed by decompression from 10 to 6 kbar at a temperature of at least 900°C.  相似文献   

17.
The upper deck of the East Athabasca mylonite triangle (EAmt), northern Saskatchewan, Canada, contains mafic granulites that have undergone high P–T metamorphism at conditions ranging from 1.3 to 1.9 GPa, 890–960 °C. Coronitic textures in these mafic granulites indicate a near‐isothermal decompression path to 0.9 GPa, 800 °C. The Godfrey granite occurs to the north adjacent to the upper deck high P–T domain. Well‐preserved corona textures in the Godfrey granite constrain igneous crystallization and early metamorphism in the intermediate‐pressure granulite field (Opx + Pl) at 1.0 GPa, 775 °C followed by metamorphism in the high pressure granulite field (Grt + Cpx + Pl) at 1.2 GPa, 860 °C. U–Pb geochronology of zircon in upper deck mafic granulite yields evidence for events at both c. 2.5 Ga and c. 1.9 Ga. The oldest zircon dates are interpreted to constrain a minimum age for crystallization or early metamorphism of the protolith. A population of 1.9 Ga zircon in one mafic granulite is interpreted to constrain the timing of high P–T metamorphism. Titanite from the mafic granulites yields dates ranging from 1900 to 1894 Ma, and is interpreted to have grown along the decompression path, but still above its closure temperature, indicating cooling following the high P–T metamorphism from c. 960–650 °C in 4–10 Myr. Zircon dates from the Godfrey granite indicate a minimum crystallization age of 2.61 Ga, without any evidence for 1.9 Ga overgrowths. The data indicate that an early granulite facies event occurred at c. 2.55–2.52 Ga in the lower crust (c. 1.0 GPa), but at 1.9 Ga the upper deck underwent high P–T metamorphism, then decompressed to 0.9–1.0 GPa. Juxtaposition of the upper deck and Godfrey granite would have occurred after or been related to this decompression. In this model, the high P–T rocks are exhumed quickly following the high pressure metamorphism. This type of metamorphism is typically associated with collisional orogenesis, which has important implications for the Snowbird tectonic zone as a fundamental boundary in the Canadian Shield.  相似文献   

18.
苏鲁超高压变质带胡家林超镁铁质岩成因及构造意义   总被引：1，自引：1，他引：0  
胡家林超镁铁质杂岩体产于苏鲁超高压变质带中部,纯橄岩和(石榴)单斜辉石岩呈不连续透镜体产于蛇纹石化橄榄岩中。纯橄岩遭受了部分蛇纹石化(烧失量=6.6%～13.2%),全岩富集强相容元素(Ni、Cr、Co)和Ir族PGE(IPGE;Ir、Os、Ru)及高IPGE/PPGE值,亏损Al、Ti、V,具高Mg~#橄榄石(Fo=91.7～92.4)和高Cr~#(0.68～0.76)尖晶石。纯橄岩高耐熔地球化学及矿物化学特征和古老的大陆岩石圈地幔相一致,表明其原岩来源于弧前地幔,代表了华北克拉通古老的大陆岩石圈地幔残留。(石榴)单斜辉石岩全岩呈相对低含量的强相容元素(Cr、Ni、Co)和IPGE,高含量的Al、Ti、V和流体迁移元素(Sr、Pb和Ba),球粒陨石标准化REE配分图呈明显"上凸"型,具低Mg~#橄榄石(Fo=76.6～76.8)和低Al_2O_3(2.76%)和高SiO_2(54.56%～56.87%)的单斜辉石。全岩组成和矿物化学表明其原岩为俯冲带内超镁铁质火成堆晶岩,最初岩浆由地幔岩高程度部分熔融的熔体和俯冲带中富H_2O流体和/或熔体构成。(石榴)单斜辉石岩原岩曾被地幔流带入扬子大陆俯冲板片和上覆地幔楔之间的俯冲通道,经历了超高压变质作用和生成大量石榴石。(石榴)单斜辉石岩在折返过程中,与大陆岩石圈地幔楔剥离的蛇纹石化橄榄岩及纯橄岩相结合,形成超镁铁质杂岩体,整体被低密度的俯冲板片(主要由花岗质片麻岩和变质沉积岩组成)裹挟,折返至地壳浅部。  相似文献   

19.
This contribution addresses contact metamorphism and fluid flow in calcareous rocks of the Neoproterozoic Shaler Supergroup on Victoria Island, Arctic Canada. These processes occurred due to intrusion of gabbroic sills and dykes at c. 720 Ma during the Franklin magmatic event, which was associated with the break‐up of Rodinia. The intrusive sheets (sills and dykes) are a few metres to ～50 m thick. Metasedimentary rocks were examined in three locations with very good exposures of vertical dykes feeding horizontal sills, the Northern Feeder Dyke (NFD) complex, the Southern Feeder Dyke (SFD) complex and the Uhuk Massif. In the NFD and SFD complexes, protoliths were limestones and dolostones with minor silicates, and at the Uhuk Massif, the protoliths were silty dolostones. At the time of magma emplacement, these locations were at depths of 1–4 km. The widths of contact aureoles are only several decametres wide, commensurate with thicknesses of the dykes and sills. Splays of tremolite mark incipient metamorphism. Highest grade rocks in the NFD and SFD complexes contain the prograde assemblage diopside + phlogopite whereas at Uhuk they contain the assemblage vesuvianite + garnet + diopside. The assemblages are successfully modelled with T–X(CO2)fluid pseudosections that suggest achievement of CO2‐rich fluid compositions due to early decarbonation reactions, followed by influx of aqueous fluids after peak metamorphism. Rapid heating of host rocks and short near‐peak temperature intervals are demonstrated by the prevalent morphology of diopside as radial splays of acicular crystals that appear to pseudomorph tremolite and by incomplete recrystallization of calcite in marbles. Calcsilicates in the roof of one sill at Uhuk experienced metasomatic influx of Fe that is evidenced by nearly pure andradite rims on grossular garnet. Vesuvianite, which overgrew the grossular portions of garnet, also contains ferric iron. Vesuvianite was partially consumed during retrograde growth of serpentine and andradite. The occurrence of serpentine in high‐grade portions of aureoles is consistent with eventual levelling‐off of temperatures between 350 and 400 °C, an inference that is supported by modelled conductive heat transfer from the cooling magma sheets. Focused fluid flow near intrusion‐wall rock contacts is demonstrated by narrow zones of anomalously low δ13C and δ18O values of carbonate minerals. Although the up to 5‰ decrease of both δ13C and δ18O values from sedimentary values is much smaller than is typical for calcsilicate aureoles around large plutons, it is greater than what could have been achieved by decarbonation alone. The decrease in δ13C is attributed to fluid‐mediated exchange with organic low‐13C carbon that is dispersed through the unmetamorphosed rocks and the decrease in δ18O is attributed to fluid‐mediated isotopic exchange with the gabbroic intrusive sheets. This study shows that when gabbroic sills and dykes intrude a sedimentary basin, (i) contact aureoles are likely to be narrow, only on the scale of several decametres; (ii) short high‐temperature regimes prevent achievement of equilibrium metamorphic textures; and (iii) T–X(CO2)fluid paths in calcareous contact aureoles are likely to be complex, reflecting a transition from prograde decarbonation reactions to influx of aqueous fluids during cooling.  相似文献   

20.
The lower-crustal rocks of the Kohistan complex (northern Pakistan) are mostly composed of metabasic rocks such as pyroxene granulites, garnet granulites and amphibolites. We have investigated P–T trajectories of the relic two-pyroxene granulites, which are the protolith of the amphibolites within the Kamila amphibolite belt. Aluminous pyroxene retains igneous textures such as exsolution lamellae developed in the core. The significant amount of Al in clinopyroxene is buffered by breakdown reactions of plagioclase accompanied by film-like quartz as a product at grain boundaries between plagioclase and clinopyroxene. Distinct Al zoning profiles are preserved in pyroxene with exsolution lamellae in the core and in plagioclase adjacent to clinopyroxene in pyroxene granulites. In the northern part of the Kamila amphibolite belt, Al in clinopyroxene increases towards the rim and abruptly decreases at the outer rim, and anorthite in plagioclase decreases towards the rim and abruptly increases near the grain boundary between plagioclase and clinopyroxene. In the southern part of the Kamila amphibolite belt, Al in clinopyroxene and anorthite in plagioclase simply increase towards the margins of the grains. The anorthite zoning in plagioclase is in agreement with the zoning profiles of Ca-Tschermaks and jadeite components inferred from variations of Al, Na, Ti and Fe3+ in clinopyroxene. Assuming that the growth surface between them was in equilibrium, geothermobarometry based on Al zoning in clinopyroxene coexisting with plagioclase indicates that metamorphic pressures significantly increased with increasing temperature under granulite facies metamorphism. The peak of granulite facies metamorphism occurred at conditions of about 800 °C and 800–1100 MPa. These prograde P–T paths represent a crustal thickening process of the Kohistan arc during the Early to Middle Cretaceous. The crustal thickening of the Kohistan arc was caused by accretion of basaltic magma at mid-crustal depths.  相似文献   

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