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1.
Many of the commonly used analytical techniques for assessing the properties of fluvial suspended particulate matter (SPM) are neither cost effective nor time efficient, making them prohibitive to long‐term high‐resolution monitoring. We present an in‐depth methodology utilizing two types of spectroscopy which, when combined with automatic water samplers, can generate accurate, high‐temporal resolution SPM geochemistry data, inexpensively and semi‐destructively, directly from sediment covered filter papers. A combined X‐ray fluorescence spectroscopy and diffuse reflectance infrared Fourier transform spectroscopy approach is developed to estimate concentrations for a range of elements (Al, Ca, Ce, Fe, K, Mg, Mn, Na, P, Si, Ti) and compounds (organic carbon, Aldithionate, Aloxalate, Fedithionate, and Feoxalate) within SPM trapped on quartz fibre filters at masses as low as 3 mg. Calibration models with small prediction errors are derived, along with mass correction factor models to account for variations in retained SPM mass. Spectral pre‐processing methods are shown to enhance the reproducibility of results for some compounds, and the importance of filter paper selection and homogeneous sample preparation in minimizing spectral interference is emphasized. The geochemical signal from sediment covered filter papers is demonstrated to be time stable enabling samples to be stored for several weeks prior to analysis. Example results obtained during a heavy precipitation event in October 2012 demonstrate the methodology presented here has considerable potential to be utilized for high‐resolution monitoring of SPM geochemistry under a range of in‐stream hydrological conditions. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

2.
Recent advances in sediment fingerprinting research have seen Bayesian mixing models being increasingly employed as an effective method to coherently translate component uncertainties into source apportionment results. Here, we advance earlier work by presenting an extended Bayesian mixing model capable of providing a full Bayes treatment of geochemical uncertainties. The performance of the extended full Bayes model was assessed against the equivalent empirical Bayes model and traditional frequentist optimisation. The performance of models coded in different Bayesian software (JAGS and Stan) was also evaluated, alongside an assessment of model sensitivity to reduced source representativeness and nonconservative fingerprint behaviour. Results revealed comparable accuracy and precision for the full and empirical Bayes models across both synthetic and real sediment geochemistry datasets, demonstrating that the empirical treatment of source data here represents a close approximation of the full Bayes treatment. Contrasts in the performance of models coded in JAGS and Stan revealed that the choice of software employed can impact significantly upon source apportionment results. Bayesian models coded in Stan were the least sensitive to both reduced source representativeness and nonconservative fingerprint behaviour, indicating Stan as the preferred software for future Bayesian sediment fingerprinting studies. Whilst the frequentist optimisation generally yielded comparable accuracy to the Bayesian models, uncertainties around apportionment estimates were substantially greater and the frequentist model was less effective at dealing with nonconservative behaviour. Overall, the effective performance of the extended full Bayes mixing model coded in Stan represents a notable advancement in source apportionment modelling relative to previous approaches. Both the mixing model and the software comparisons presented here should provide useful guidelines for future sediment fingerprinting studies.  相似文献   

3.
Reliable information on catchment scale suspended sediment sources is required to inform the design of management strategies for helping abate the numerous environmental issues associated with enhanced sediment mobilization and off‐site loadings. Since sediment fingerprinting techniques avoid many of the logistical constraints associated with using more traditional indirect measurement methods at catchment scale, such approaches have been increasingly reported in the international literature and typically use data sets collected specifically for sediment source apportionment purposes. There remains scope for investigating the potential for using geochemical data sets assembled by routine monitoring programmes to fingerprint sediment provenance. In the United States, routine water quality samples are collected as part of the US Geological Survey's revised National Stream Quality Accounting Network programme. Accordingly, the geochemistry data generated from these samples over a 10‐year period (1996–2006) were used as the basis for a fingerprinting exercise to assess the key tributary sub‐catchment spatial sources of contemporary suspended sediment transported by the Ohio River. Uncertainty associated with the spatial source estimates was quantified using a Monte Carlo approach in conjunction with mass balance modelling. Relative frequency weighted means were used as an alternative way of summarizing the spatial source contributions, thereby avoiding the need to use confidence limits. The results should be interpreted in the context of the routine, but infrequent nature, of the suspended sediment samples used to assemble geochemistry as a basis for the sourcing exercise. Nonetheless, the study demonstrates how routine monitoring samples can be used to provide some preliminary information on sediment provenance in large drainage basins. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

4.
The dynamics of suspended sediment transport were monitored continuously in a large agricultural catchment in southwest France from January 2007 to March 2009. The objective of this paper is to analyse the temporal variability in suspended sediment transport and yield in that catchment. Analyses were also undertaken to assess the relationships between precipitation, discharge and suspended sediment transport, and to interpret sediment delivery processes using suspended sediment‐discharge hysteresis patterns. During the study period, we analysed 17 flood events, with high resolution suspended sediment data derived from continuous turbidity and automatic sampling. The results revealed strong seasonal, annual and inter‐annual variability in suspended sediment transport. Sediment was strongly transported during spring, when frequent flood events of high magnitude and intensity occurred. Annual sediment transport in 2007 yielded 16 614 tonnes, representing 15 t km?2 (85% of annual load transport during floods for 16% of annual duration), while the 2008 sediment yield was 77 960 tonnes, representing 70 t km?2 (95% of annual load transport during floods for 20% of annual duration). Analysis of the relationships between precipitation, discharge and suspended sediment transport showed that there were significant correlations between total precipitation, peak discharge, total water yield, flood intensity and sediment variables during the flood events, but no relationship with antecedent conditions. Flood events were classified in relation to suspended sediment concentration (SSC)–discharge hysteretic loops, complemented with temporal dynamics of SSC–discharge ranges during rising and falling flow. The hysteretic shapes obtained for all flood events reflected the distribution of probable sediment sources throughout the catchment. Regarding the sediment transport during all flood events, clockwise hysteretic loops represented 68% from river deposited sediments and nearby source areas, anticlockwise 29% from distant source areas, and simultaneity of SSC and discharge 3%. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

5.
The composition and amount of colloidal and suspended participate matter transported during a small flood event in Magela Creek in tropical northern Australia was investigated. The flood studied constituted approximately 3 % of the total annual flow, most (90%) of which occurred between mid-January and mid-February of the study year. Three fractions were separated from water samples using a sequential method involving a continuous flow centrifuge to separate suspended particulate matter (SPM; nominally > 1 μm) followed by hollow fibre filtration, first using a 0.1 μm filter to separate course colloidal matter (CCM; nominal size 1–0.1 μm) and then a 0–015 μm filter to separate fine colloidal matter (FCM; nominal size 0.1–0.015 μm). The SPM was predominantly inorganic (organic matter 21 %), whereas the colloidal fractions were dominantly organic matter (CCM 60%; FCM 83%). Analysis of individual particles using electron microprobe and automated image analysis indicated that the mineral fractions in both the SPM and CCM were dominated by iron-enriched aluminosilicates (including kaolinite) (72–82%) and quartz (9–10%), indicative of a highly weathered and extensively laterized catchment. Surprisingly there was very little difference in the composition of the SPM or CCM fractions during the flood event studied, which may indicate either that sediment availability was restricted following the major run-off events in January and February, or that all the sediment sources within the catchment are geochemically similar. Approximately the same amounts of particulate (20 tonne), colloidal (21 tonne) and dissolved material (17 tonne) were transported during the 25 hour period of the main flood peak; over 90% of the colloidal matter was 0.1–1.0 μm in size. These data suggest that previous estimates of the amounts of particulate (and colloidal) matter transported by Magela Creek, which were based on suspended solids measurements, may have underestimated the particulate matter load by as much as 50%. It is possible that the relatively high proportion of colloidal matter is unique to Magela Creek because coagulation and aggregation of colloidal matter to particulate matter is slow due to the very low concentations of calcium and magnesium in these waters. However, if the result is more widespread, there are important implications for the global estimates of fluvially transported particulate and dissolved materials as many of the previous studies may have underestimated the particulate load and overestimated the dissolved load.  相似文献   

6.
The identification of sediment sources is fundamental to the management of increasingly scarce water resources. Tracing the origin of sediment with elemental geochemistry is a well‐established approach to determining sediment provenance. Fundamental to the confident apportionment of sediment to their lithogenic sources is the modelling process. Recent approaches have incorporated distributions throughout the modelling process including source contribution terms for two end‐member sources. The shift from modelling source samples to modelling samples drawn from distributions has removed relationships, including potential correlations between elemental concentrations, from the modelling process. Here, we present a novel modelling approach that re‐incorporates correlations between elemental concentrations and models distributions for source contribution terms for multiple source end members. Artificial mixtures, based on catchment sources samples, were created to test the accuracy of this correlated distribution model and also examine modelling approaches used in the literature. The most accurate model incorporates correlations between elements, uses the absolute mixing model difference and does not use any weighting. This model was then applied to identify the sources of sediment in three South East Queensland catchments and demonstrated that Quaternary Alluvium is the most dominant source of sediment in these catchments (μ 44%, σ 12%). This study demonstrates that it is important to understand how different weightings may impact modelling results. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

7.
This paper investigates temporal variations in fluxes of peat and other sediment in the catchment of March Haigh Reservoir, West Yorkshire. Long‐term estimates of sediment yield were derived from a study of reservoir sediments. Magnetic properties were used to correlate ten cores to a master profile dated using 210Pb and 137Cs. A 14C date suggests that most of the organic component of the sediment is allochthonous and derived from peat eroded from the catchment. Organic sediment yields suggest low catchment erosion rates between 1838 and 1963. Blanket peat erosion increased significantly after 1963, and peaked between 1976 and 1984. Estimates of total sediment yield range between 2 and 28 t km?2 a?1. These yields are significantly lower than those from some previous studies examining reservoir sedimentation in other blanket peat‐covered catchments. The low yield estimates may be due to relatively low rates of erosion in the basin, but may also be partly explained by maintenance of silt traps during the early life of the reservoir and removal of sediment by scouring. Sedimentation within the reservoir is spatially variable, and bathymetry and sediment source appear to be the dominant controls on sedimentation patterns within the reservoir. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

8.
Sediment fingerprinting has been widely used to distinguish discrete sediment sources; however, application to intra-storm sediment source variability has received relatively little focus despite the benefit being long recognized. In this investigation, sediment fingerprinting was applied to a 53-hr storm event sampled hourly to determine sediment source dynamics throughout the event. Sediment sources were differentiated using 16 variables, and source contribution determined using Bayesian and Frequentist mixing models for comparison. Both models provided comparable source predictions for the dominant source estimates and the general temporal pattern. The Frequentist model appeared to exhibit some unreliable values coinciding with low GOF and attributed to inherent model structure. The Bayesian model showed higher uncertainty, likely due to the “process error” utilized associated with single sample mixtures. High variability in sediment source contribution was observed between hourly time steps; however, local smoothing reveals temporal trends during the event. A higher average proportion of mudstone is found in the falling limb (0.544) compared with the rising limb (0.464), and the reverse is observed for mountain range (0.218 vs. 0.283) and unconsolidated (0.073 vs. 0.055). In the initial hours of the storm, mudstone source contribution significantly drops, whereas mountain range and unconsolidated contributions peak. The SSC-Q clockwise hysteresis indicates proximal sediment sources, suggesting the mudstone sediment is stored channel sediment and easily entrained. This sediment flushes through, coinciding with a drop as the distal mountain range and unconsolidated sources arrive to peak contribution. The wider Manawatū discharge and sediment load then arrive, delivering increasing levels of mudstone throughout the remainder of the event while mountain range sediment diminishes. Spatial representation of the sediment source contribution was derived from distributing sediment source loads to the spatial extent of the source material according to sub-catchment sediment loads and was weighted according to slope. This provided an effective means to visualize the origin of the sediment and a better spatial interpretation of sediment fingerprinting results, which is typically limited by poor spatial resolution.  相似文献   

9.
Aeolian sediment fingerprinting using a Bayesian mixing model   总被引：1，自引：0，他引：1       下载免费PDF全文
Identifying sand provenance in depositional aeolian environments (e.g. dunefields) can elucidate sediment pathways and fluxes, and inform potential land management strategies where windblown sand and dust is a hazard to health and infrastructure. However, the complexity of these pathways typically makes this a challenging proposition, and uncertainties on the composition of mixed‐source sediments are often not reported. This study demonstrates that a quantitative fingerprinting method within the Bayesian Markov Chain Monte Carlo (MCMC) framework offers great potential for exploring the provenance and uncertainties associated with aeolian sands. Eight samples were taken from dunes of the small (~58 km2) Ashkzar erg, central Iran, and 49 from three distinct potential sediment sources in the surrounding area. These were analyzed for 61 tracers including 53 geochemical elements (trace, major and rare earth elements (REE)) and eight REE ratios. Kruskal–Wallis H‐tests and stepwise discriminant function analysis (DFA) allowed the identification of an optimum composite fingerprint based on six tracers (Rb, Sr, 87Sr, (La/Yb)n, Ga and δCe), and a Bayesian mixing model was applied to derive the source apportionment estimates within an uncertainty framework. There is substantial variation in the uncertainties in the fingerprinting results, with some samples yielding clear discrimination of components, and some with less clear fingerprints. Quaternary terraces and fans contribute the largest component to the dunes, but they are also the most extensive surrounding unit; clay flats and marls, however, contribute out of proportion to their small outcrop extent. The successful application of these methods to aeolian sediment deposits demonstrates their potential for providing quantitative estimates of aeolian sediment provenances in other mixed‐source arid settings, and may prove especially beneficial where sediment is derived from multiple sources, or where other methods of provenance (e.g. detrital zircon U–Pb dating) are not possible due to mineralogical constraints. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

10.
Plant source water identification using stable isotopes is now a common practice in ecohydrological process investigations. Notwithstanding, little critical evaluation of the approaches for source apportionment have been conducted. Here, we present a critical evaluation of the main methods used for source apportionment between vadose and saturated zone water: simple mass balance and Bayesian mixing models. We leverage new isotope stem water samples from a diverse set of tree species in a strikingly uniform terrain and soil conditions at the Christchurch Botanic Garden, New Zealand. Our results show that using δ2H alone in a simple, two‐source mass balance approach leads to erroneous results, particularly an apparent overestimation of groundwater contribution to xylem. Alternatively, using both δ2H and δ18O in a Bayesian inference framework improves the source water estimates and is more useful than the simple mass balance approach, particularly when soil and groundwater contributions are relatively disproportionate. We suggest that plant source water quantification methods should take into consideration the possible effects of 2H/1H fractionation. The Bayesian inference approach used here may be less sensitive to 2H/1H fractionation effects than simple mass balance methods.  相似文献   

11.
The coupling relationships between hillslope and channel network are fundamental for the understanding of mountainous landscapes' evolution. Here, we applied dendrogeomorphic methods to identify the hillslope–channel relationship and the sediment transfer dynamics within an alpine catchment, at the highest possible resolution. The Schimbrig catchment is located in the central Swiss Alps and can be divided into two distinct geomorphic sectors. To the east, the Schimbrig earth flow is the largest sediment source of the basin, while to the west, the Rossloch channel network is affected by numerous shallow landslides responsible for the supply of sediment from hillslopes to channels. To understand the connectivity between hillslopes and channels and between sources and sink, trees were sampled along the main Rossloch stream, on the Schimbrig earth flow and on the Rossloch depositional area. Geomorphic observations and dendrogeomophic results indicate different mechanisms of sediment production, transfer and deposition between upper and lower segments of the channel network. In the source areas (upper part of the Rossloch channel system), sediment is delivered to the channel network through slow movements of the ground, typical of earth flow, shallow landslides and soil creep. Contrariwise, in the depositional area (lower part of the channel network), the mechanisms of sediment transfer are mainly due to torrential activity, floods and debris flows. Tree analysis allowed the reconstruction of periods of high activity during the last century for the entire catchment. The collected dataset presents a very high temporal resolution but we encountered some limitations in establishing the source‐to‐sink connectivity at the catchment‐wide scale. Despite these uncertainties, for decennial timescales the results suggest a direct coupling between hillslopes and neighbouring channels in the Rossloch channel network, and a de‐coupling between sediment sources and sink farther downstream, with connections possible only during extraordinary events. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

12.
A. Pistocchi 《水文研究》2008,22(13):2292-2314
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13.
Riverbank erosion is a major contributor to catchment sediment budgets. At large spatial scales data is often restricted to planform channel change, with little information on process distributions and their sediment contribution. This study demonstrates how multi‐temporal LiDAR and high resolution aerial imagery can be used to determine processes and volumes of riverbank erosion at a catchment scale. Remotely sensed data captured before and after an extreme flood event, enabled a digital elevation model of difference (DoD) to be constructed for the channel and floodplain. This meant that: the spatial area that could be assessed was extensive; three‐dimensional forms of bank failures could be mapped at a resolution that enabled process inference; and the volume and rates of different bank erosion processes over time could be assessed. A classification of riverbank mass failures, integrating form and process, identified a total of 437 mass failure polygons throughout the study area. These were interpreted as wet flow mass failures based on the presence of a well defined scarp wall and the absence of failed blocks on the failure floor. The failures appeared to be the result of: bank exfiltration, antecedent moisture conditions preceding the event, and the historic development of the channel. Using one‐dimensional hydraulic modelling to delineate geomorphic features within the main boundary of the macrochannel, an estimated 1 466 322 m2 of erosion was interpreted as fluvial entrainment, occurring across catchment areas from 30 to 1668 km2. Only 8% of the whole riverbank planform area was occupied by mass failures, whilst fluvial entrainment covered 33%. A third of the volume of material eroded came from mass failures, even though they occupied 19% of the eroded bank area. The availability of repeat LiDAR surveys, combined with high‐resolution aerial photography, was very effective in erosion process determination and quantification at a large spatial scale. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

14.
In order to understand the differences in the suspended sediment and total dissolved solid (TDS) yield patterns between the glacial and non‐glacial catchments at the headwaters of Urumqi River, northwestern China, water samples were collected from a glacier catchment and an empty cirque catchment within the region, during three melting seasons from 2006 to 2008. These samples were analyzed to estimate suspended sediment and TDS concentrations, fluxes and erosion rates in the two adjoining catchments. There were remarked differences in suspended sediment and TDS yield patterns between the two catchments. Suspended sediment concentrations were controlled mainly by the sediment source, whereas TDS concentrations were primarily related to the hydrologic interaction with soil minerals. Generally, the glacial catchment had much higher suspended sediment and TDS yields, together with higher denudation rates, than the non‐glacial catchment. Overall, glacial catchment was mainly dominated by physical denudation process, whereas the non‐glacial catchment was jointly influenced by physical and chemical denudation processes. The observed differences in material delivery patterns were mainly controlled by the runoff source and the glacial processes. The melting periods of glacier and snow were typically the most important time for the suspended sediment and TDS yields. Meanwhile, episodic precipitation events could generate disproportionately large yields. Subglacial hydrology dynamics, glaciers pluck and grind processes could affect erodibility, and the large quantities of dust stored on the glacier surface provided additional sources for suspended sediment transport in the glacial catchment. These mechanisms imply that, in response to climate change, the catchment behaviour will be modified significantly in this region, in terms of material flux. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

15.
Continuous monitoring of dissolved organic matter (DOM) character and concentration at hourly resolution is rare, despite the importance of analysing organic matter variability at high‐temporal resolution to evaluate river carbon budgeting, river water health by detecting episodic pollution and to determine short‐term variations in chemical and ecological function. The authors report a 2‐week experiment performed on DOM sampled from Bournbrook, Birmingham, UK, an urban river for which spectrophotometric (fluorescence, absorbance), physiochemical (dissolved organic carbon [DOC], electrical conductivity, pH) and isotopic (D/H) parameters have been measured at hourly frequency. Our results show that the river had sub‐daily variations in both organic matter concentration and characteristics. In particular, after relatively high‐magnitude precipitation events, organic carbon concentration increased, with an associated increase in intensity of both humic‐like and tryptophan‐like fluorescence. D/H isotopic ratio demonstrates different hydrological responses to different rainfall events, and organic matter character reflects this difference. Events with precipitation < 2 mm typically yielded isotopically heavy water with relatively hydrophilic DOM and relatively low specific absorbance. Events with precipitation > 2 mm had isotopically lighter water with higher specific absorbance and a decrease in the proportion of microbially derived to humic‐like fluorescence. In our heavily urbanized catchment, we interpret these signals as one where riverine DOM is dominated by storm sewer‐derived ‘old’ organic matter at low‐rainfall amounts and a mixed signal at high‐precipitation amounts where ‘event’ surface runoff‐derived organic matter dominate during storm sewer and combined sewer overflow routed DOM. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

16.
Fine sediment is a dynamic component of the fluvial system, contributing to the physical form, chemistry and ecological health of a river. It is important to understand rates and patterns of sediment delivery, transport and deposition. Sediment fingerprinting is a means of directly determining sediment sources via their geochemical properties, but it faces challenges in discriminating sources within larger catchments. In this research, sediment fingerprinting was applied to major river confluences in the Manawatu catchment as a broad‐scale application to characterizing sub‐catchment sediment contributions for a sedimentary catchment dominated by agriculture. Stepwise discriminant function analysis and principal component analysis of bulk geochemical concentrations and geochemical indicators were used to investigate sub‐catchment geochemical signatures. Each confluence displayed a unique array of geochemical variables suited for discrimination. Geochemical variation in upstream sediment samples was likely a result of the varying geological source compositions. The Tiraumea sub‐catchment provided the dominant signature at the major confluence with the Upper Manawatu and Mangatainoka sub‐catchments. Subsequent downstream confluences are dominated by the upstream geochemical signatures from the main stem of Manawatu River. Variability in the downstream geochemical signature is likely due to incomplete mixing caused in part by channel configuration. Results from this exploratory investigation indicate that numerous geochemical elements have the ability to differentiate fine sediment sources using a broad‐scale confluence‐based approach and suggest there is enough geochemical variation throughout a large sedimentary catchment for a full sediment fingerprint model. Combining powerful statistical procedures with other geochemical analyses is critical to understanding the processes or spatial patterns responsible for sediment signature variation within this type of catchment. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

17.
The fate of mud in an estuary over an entire year was unravelled using complementary, independent, spatially explicit techniques. Sequential ERS-2 SAR and Envisat MERIS-FR data were used to derive synoptic changes in intertidal bottom mud and suspended particulate matter (SPM) in the top of the water column, respectively. These satellite data were combined with in situ measurements and with a high resolution three-dimensional cohesive sediment model, simulating mud transport, resuspension, settling and deposition under the influence of tides, wind, waves and freshwater discharge. The spatial distribution of both bottom mud and SPM as observed by in situ and satellite techniques was largely explained by modelled estuarine circulation, tidal and wind-induced variations in vertical mixing and horizontal advection. The three data sources also showed similar spring-neap and seasonal variations in SPM (all factor 1.5 to 2), but semi-diurnal tidal variations were underestimated by the model. Satellite data revealed that changes in intertidal bottom mud were spatially heterogeneous, but on average mud content doubled during summer, which was confirmed by in situ data. The model did not show such seasonal variation in bed sediment, suggesting that seasonal dynamics are not well explained by the physical factors presently implemented in the model, but may be largely attributed to other (internal) factors, including increased floc size in summer, temporal stabilisation of the sediment by microphytobenthos and a substantially lower roughness of the intertidal bed in summer as observed by the satellite. The effects of such factors on estuarine mud dynamics were evaluated.  相似文献   

18.
The sediment budget of the small research catchment of Cal Parisa (Vallcebre, Eastern Pyrenees) was studied by hydrological monitoring and assessment of the erosion rates in the major sediment sources. This area is characterized by clayey mudrock prone to landsliding and badland erosion, but the catchment was selected in an area free of major badland features, as a representative of middle mountain regions where a system of terraces and drainage ditches had been built for agricultural use but is now abandoned. Streamwater chemistry is dominated by Ca2+ and HCO3− at concentrations close to calcite saturation. Total dissolved solids show dilution during runoff peaks and positive hysteresis loops that support a slow contribution of subsurface water. Relative dissolved ion concentrations are different for each event analysed. Particulate sediment yield is very low and represents only about 1 per cent of gross erosion in the catchment. Mineralogical analysis of suspended sediments shows an enrichment in calcite because of precipitation. Chemical analysis of suspended sediments, using common one-litre water samples, shows higher contents of Ca, P and Mn in transported sediment than in sediment source areas, attributed to the precipitation of calcite, and enrichment in organic particulate matter during events respectively for the two first elements, whereas enrichment in Mn remains uncertain. Solid matter yield is therefore clearly dominated by dissolved transport as a result of both high calcium bicarbonate concentrations in runoff waters and strong suspended sediment conveyance discontinuities. Land conservation structures are very effective because they are in good condition whereas the soil is covered by dense permanent vegetation. Nevertheless, this state is unstable because the network of drainage ditches needs maintenance; its spontaneous breakdown after abandonment may result in the rearrangement of the elementary stream network and gullying of old fields in hollows. © 1997 John Wiley & Sons, Ltd.  相似文献   

19.
Use of isotopes to quantify the temporal dynamics of the transformation of precipitation into run‐off has revealed fundamental new insights into catchment flow paths and mixing processes that influence biogeochemical transport. However, catchments underlain by permafrost have received little attention in isotope‐based studies, despite their global importance in terms of rapid environmental change. These high‐latitude regions offer limited access for data collection during critical periods (e.g., early phases of snowmelt). Additionally, spatio‐temporal variable freeze–thaw cycles, together with the development of an active layer, have a time variant influence on catchment hydrology. All of these characteristics make the application of traditional transit time estimation approaches challenging. We describe an isotope‐based study undertaken to provide a preliminary assessment of travel times at Siksik Creek in the western Canadian Arctic. We adopted a model–data fusion approach to estimate the volumes and isotopic characteristics of snowpack and meltwater. Using samples collected in the spring/summer, we characterize the isotopic composition of summer rainfall, melt from snow, soil water, and stream water. In addition, soil moisture dynamics and the temporal evolution of the active layer profile were monitored. First approximations of transit times were estimated for soil and streamwater compositions using lumped convolution integral models and temporally variable inputs including snowmelt, ice thaw, and summer rainfall. Comparing transit time estimates using a variety of inputs revealed that transit time was best estimated using all available inflows (i.e., snowmelt, soil ice thaw, and rainfall). Early spring transit times were short, dominated by snowmelt and soil ice thaw and limited catchment storage when soils are predominantly frozen. However, significant and increasing mixing with water in the active layer during the summer resulted in more damped steam water variation and longer mean travel times (~1.5 years). The study has also highlighted key data needs to better constrain travel time estimates in permafrost catchments.  相似文献   

20.
Recent emphasis on sediment connectivity in the literature highlights the need for quantitative baseline studies on the patterns and distribution of sediment stores to facilitate understanding of how sediment moves through the landscape at various temporal and spatial scales. This study evaluates the distribution and make‐up of sediment stores within the dramatically incised landscapes of the upper Yellow River, where basin fill deposits up to 1200 m in depth have been extensively reworked following incision by the Yellow River. Field and GIS analyses highlight the discontinuous distribution of sediment stores in Garang catchment, a 236 km2 tributary of the upper Yellow River. Volumetric estimates of sediment storage were obtained through a combination of field mapping, GPR transects, and GIS analyses. Sediment stores cover 20% of the Garang catchment, with an estimated volume of 474.0 × 106 m3, and inferred residence times from OSL and 14C dating of 103–104 years. Fans and terraces reworked from basin fill deposits, and associated cut and fill terrace features, are the dominant forms of sediment storage (~90% of total). A space‐for‐time argument is used to assess stages of basin infilling and subsequent landscape responses to incision, outlining a dramatic example of changes to sediment dynamics and connectivity relationships within the upper Yellow River. Sediments within the upper catchment lie above the regional basin fill level, offering a glimpse of pre‐incisional conditions. This contrasts markedly with the enduring influence of basin incisional history seen within the middle catchment, and the contemporary landscapes of the lower catchment where nearly all available sediment has been excavated from the basin and the landscape effectively operates under post‐incisional conditions. The need to contextualise catchment‐scale studies in terms of landscape history is emphasised. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

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