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1.
辽宁小佟家堡子金矿床成矿流体特征及来源讨论 总被引：1，自引：0，他引：1
小佟家堡子金矿床地处辽宁青城子矿田东南部,为一大型蚀变岩型矿床。矿床产于辽河群大石桥组三段白云石大理岩中,矿体呈层状、似层状产出。矿床由热液叠加改造作用形成,历经石英-黄铁矿、石英-碳酸盐两个阶段。流体包裹体研究表明,该矿床成矿流体属中低温、低盐Na Cl-H2O型体系热液。碳氢氧同位素地球化学的研究表明,石英-黄铁矿阶段成矿流体氧同位素δ18O组成在15.2‰~18.4‰,碳同位素δ13CV-PDB组成在-7.4‰~-13.2‰,氢同位素δD组成为-89.3‰~-92.2‰,反应该阶段成矿流体主要来自岩浆水并伴有少量的大气降水。石英-碳酸盐阶段成矿流体氧同位素δ18O组成在17‰~17.8‰,碳同位素δ13CV-PDB组成在-12.3‰~-13.5‰,氢同位素组成δD为-87.7‰~-90.4‰,表明该阶段成矿流体主要来自大气降水。 相似文献
2.
牟乳成矿带是胶东半岛金矿集区三大金成矿带之一,但带内金矿床的成矿流体来源仍存在着较大分歧。范家庄金矿床是近年在该成矿带内新发现的金矿床,其成矿流体的研究较为薄弱。鉴于此,本文从流体包裹体和H-O同位素研究入手,结合矿床地质特征,对范家庄金矿床的成矿流体和矿床成因进行探讨。金矿体主要产于侏罗纪弱片麻状黑云母二长花岗岩内,呈脉状、透镜状,受断裂构造控制明显。该矿床热液成矿期可分为3个成矿阶段：石英-粗粒黄铁矿阶段（成矿早阶段）、石英-金-多金属硫化物阶段（主成矿阶段）、石英-碳酸盐阶段（成矿晚阶段）。流体包裹体岩相学特征显示,矿床中的原生包裹体以气液两相包裹体和纯液相水溶液包裹体为主,另有少量含CO2三相包裹体。显微测温结果显示,成矿早阶段和主成矿阶段的均一温度分别为167.2~297.5℃和168.4~253.6℃,盐度（w（NaCl））分别为3.55%~22.65%和2.58%~12.05%,密度分别为0.77~1.06 g/cm3和0.84~1.02 g/cm3,具有中低温、中低盐度、低密度的特征,与中温热液成矿系统流体特征相一致。对成矿压力和深度的估算表明,主成矿阶段的成矿压力为45.8~68.7 MPa （平均为52.8 MPa）,成矿深度为5.38~6.71 km （平均为5.93 km）,显示出中浅成成矿的特点。成矿流体H-O同位素示踪显示,成矿早阶段流体的δDH2O-SMOW值介于-96.9‰~-89.0‰之间,δ18OH2O-SMOW值介于-4.3‰~4.5‰之间;主成矿阶段的δDH2O-SMOW值介于-90.7‰~-85.3‰之间,δ18OH2O-SMOW值介于-5.4‰~-0.2‰之间。由此认为,范家庄金矿床的成矿流体来源于岩浆水与大气降水的混合,且随着成矿流体的演化,大气降水的混入比例增加。综合矿床地质特征和成矿流体研究,认为范家庄金矿床应属中温热液脉型金矿床。 相似文献
3.
什根特铁矿赋存于康布铁堡组火山沉积岩系中,矿体呈层状、透镜状、脉状,受地层控制。同时发育矽卡岩及磁铁矿化。矿床形成经历了火山沉积期(主成矿期),岩浆热液期(矽卡岩型矿化)和区域变质期。火山沉积期和岩浆热液期退化蚀变阶段的磁铁矿均具有富Fe,贫Si、Ti、V、Mg、Mn特点;磁铁矿稀土元素配分模式和原始地幔标准化蛛网图具有相似曲线变化特征,指示火山沉积期和退化蚀变阶段的铁矿化具有相同的物质来源,即来自基性火山岩。早期矽卡岩阶段石榴子石中流体包裹体均一温度为160~403℃,集中在180~260℃,盐度集中在5%~9%(质量分数,Na Cleq,下同),δD介于-134‰~-125‰,δ18OH2O值为4.7‰~8.6‰,表明流体为岩浆水。石英碳酸盐阶段流体包裹体均一温度为140~536℃,主要集中在160~340℃,盐度集中在6%~16%,表明流体具有从高温演化到低温、中低盐度和中低密度的特征,石英的δD介于-98‰~-95‰,δ18OH2O值为-0.6‰~2.0‰,表明该阶段流体来自岩浆水混合大气降水。 相似文献
4.
争光浅成低温热液型金矿床位于大兴安岭成矿带北段,是多宝山矿集区内的一个重要矿床。文章通过流体包裹体和C_H_O_He_Ar同位素的系统研究,对该矿床成矿流体和矿床成因进行了深入探讨。矿床成矿作用可划分为4个主要阶段:石英_黄铁矿阶段(成矿前阶段)、石英_多金属硫化物阶段(主成矿阶段)、方解石_(石英)_多金属硫化物阶段(主成矿阶段)和方解石阶段(成矿后阶段)。流体包裹体研究表明,争光金矿床主要发育富液相流体包裹体。石英_黄铁矿阶段、方解石_(石英)_多金属硫化物阶段和方解石阶段流体包裹体的均一温度分别介于116~243℃(集中于150~170℃)、129~294℃(集中于140~160℃)和130~155℃(集中于130~150℃);w(NaCleq)分别介于0.9%~10.1%、1.2%~13.8%和2.7%~8.7%。成矿流体具有低温、低盐度、相对还原的特征,属H_2O_Na Cl体系。石英_黄铁矿阶段成矿流体的δD和δ18O分别为-127‰~-110‰和-5.9‰~0.6‰,蚀变围岩的δD值和δ18O值分别为-118‰~-108‰和6.3‰~7.9‰。方解石_(石英)_多金属硫化物阶段和方解石阶段方解石的δ~(13)C分别为-5.3‰~-2.0‰和-2.9‰~-2.2‰,δ18O分别为7.7‰~9.3‰和9.9‰~13.5‰。黄铁矿流体包裹体的~3He/~4He、~(40)Ar/~(36)Ar和~(40)Ar*/4He比值分别为1.75~3.06 Ra、683~1295和0.30~0.63。综合流体包裹体特征和稳定同位素组成,认为成矿早阶段成矿流体为大气降水与围岩发生水_岩反应后的演化水。随着成矿作用的进行,成矿流体变为大气降水与岩浆水的混合水,但仍以大气降水为主导。成矿流体与贫H_2S的流体混合和硫化物沉淀的共同作用可能是该矿床金沉淀的主要机制。 相似文献
5.
新疆阿尔泰萨尔朔克多金属矿地质特征及成矿作用 总被引：2，自引：0，他引：2
萨尔朔克中型多金属矿主要赋存于潜流纹岩中,少量在阿舍勒组火山岩中。矿石呈致密块状、块状、条纹状、浸染状、细脉、网脉状和脉状构造,围岩蚀变主要是硅化、绢云母化和黄铁矿化,矿床的形成经历了喷流沉积期、潜火山热液期和表生期,金铜铅锌矿化形成于潜火山热液期的早成矿阶段。矿石中石英、方解石和绿帘石中流体包裹体划分为H2O-Na Cl型和H2O-CO2(±CH4/N2)-Na Cl型。主成矿阶段成矿温度集中于130~390℃,在350℃、310℃、190℃和140℃出现明显峰值;流体盐度集中于3.0%~10.0%Na Cleqv,密度0.56~1.03g/cm3。硫化物δ34S集中于-1.52‰~6.18‰,峰值为2.5‰,表明硫来自深源岩浆。石英δD介于-140‰~-103‰,δ18O SMOW值为6.9‰~8.5‰,δ18O H2O值为-4.03~0.94‰,表明主成矿阶段成矿流体是岩浆水混合深循环的海水。成矿时代为中泥盆世(382Ma),成矿作用与流纹斑岩有关。温度和压力的降低导致流体不混溶作用,同时流体成分的改变等在金铜铅锌成矿过程中起着主导作用。 相似文献
6.
内蒙古自治区碾子沟钼矿床地处华北地台北缘西拉木伦钼成矿带西段,为一典型的中型石英脉型钼矿床。该钼矿床矿脉（体）主要产于燕山早期二长花岗岩-钾长花岗岩内NNW、NW向断裂构造体系之中,成矿作用过程经历了黄铁矿±辉钼矿＋石英（Ⅰ）、辉钼矿＋黄铁矿±黄铜矿＋石英（Ⅱ）、黄铜矿＋黄铁矿±闪锌矿＋石英（Ⅲ）及石英±方解石（Ⅳ）4个阶段。系统的流体包裹体岩相学、包裹体组分析、包裹体显微测温研究表明,矿床初始成矿流体为高温、中低盐度（490~550℃,盐度（w（NaC1））2%~10%,50~62 MPa）均匀的NaCl-H2O体系热液,δ18OH2O-SMOW（2.21‰）及δDH2O-SMOW（-68.9‰）表明其主要来源于岩浆热液;成矿流体上升并不断汇聚于容矿断裂空间,伴随温度、压力降低（380~460℃,26~40 MPa→360~420℃,25~30 MPa）而进入两相不混溶区,流体开始发生沸腾→强烈沸腾作用,导致成矿元素Mo大量沉淀富集成矿,成矿晚期残余流体与大气降水混合（δ18OH2O-SMOW为-2.41‰~2.51‰,δDH2O-SMOW为-110.1‰~-105.5‰）,矿床属燕山早期中高温岩浆热液型钼矿床。 相似文献
7.
《矿物岩石》2015,(4)
小西弓金矿床是北山造山带南带重要的中型金矿床,矿体产出受韧性剪切带控制。热液成矿过程由早到晚分为石英-黄铁矿阶段、石英-多金属硫化物阶段和石英-碳酸岩阶段。石英-黄铁矿阶段石英中发育富液二相、富气二相和含CO2三相流体包裹体,均一温度范围为228℃~438℃,盐度为4.03%~17.50%NaCleqv,属中高温、中低盐度流体。石英-多金属硫化物阶段石英中发育富液二相、富气二相、含CO2三相和纯液相流体包裹体,均一温度范围为182℃~376℃,盐度为3.23%~12.21%NaCleqv。流体演化过程中发生了流体沸腾和混合作用,这可能是导致金沉淀富集的主要机制。流体沸腾温度区间约为268℃~347℃。成矿早阶段石英中流体包裹体的δ18 O和δD值分别为8.0‰~8.3‰和-84‰~-107‰。结合矿床地质特征和氢氧同位素研究认为,初始成矿流体来自变质热液,晚阶段有大气降水加入。 相似文献
8.
偃尾山铜银矿床是大兴安岭北段呼中-塔源成矿带内新发现的中小型矿床。矿床围岩蚀变呈面状分布,主要蚀变类型为硅化、碳酸盐化、黄铁矿化、伊利石化、高岭石化和绢云母化。热液成矿期可分为三个阶段:成矿早期石英-黄铁矿阶段(含少量黄铜矿)、主成矿期石英-斑铜矿-黄铜矿-辉铜矿(含铜硫化物)阶段和成矿晚期石英-碳酸盐-萤石阶段(含少量方铅矿和闪锌矿)。该矿床流体包裹体主要为富液相包裹体,也有少量纯气相包裹体,未见含子矿物包裹体。主成矿阶段流体包裹体均一温度为155℃~342℃,峰值集中在160℃~230℃,冰点温度在﹣3.3℃~﹣0.3℃,盐度为0.53%NaC_(leqv)~5.41%Na Cleqv;流体成分以K~+、Na~+、SO_4~(2-)为主,含少量Ca~(2+)和Cl~-,气相成分以H_2O为主,含少量的CO_2;流体δ~(18)O在-11.8‰~-13.72‰之间,δD变化范围在-105‰~-137‰之间。总体上,成矿流体为低温低盐度流体,流体来源主要是大气降水,成矿流体和矿床蚀变-矿化特征显示本矿床可能为高硫型浅成低温热液矿床。流体压力的突然降低可能是成矿物质沉淀的主要机制。偃尾山矿床可能代表了区域上同时代一种新的矿床类型,后续深入研究将有助于认识该区域成矿规律和找矿方向。 相似文献
9.
撒岱沟门钼矿床是华北地台北缘燕辽钼(铜)成矿带上典型的斑岩型钼矿床,位于河北省丰宁县境内,是该区目前发现的最大钼矿床。矿床成矿作用可划分为3期:成矿前(无矿石英脉阶段)、成矿期((1)石英+磁铁矿+辉钼矿+黄铁矿+钾长石阶段,(2)石英+辉钼矿阶段,(3)石英+云母+辉钼矿+黄铁矿阶段,(4)石英+辉钼矿+黄铁矿阶段)、成矿期后(晚期无矿热液阶段)。对矿床流体包裹体的研究表明,撒岱沟门钼矿床主要发育两类包裹体:盐水溶液包裹体和含CO_2三相包裹体。成矿前与成矿期后流体以气液两相的盐水溶液包裹体为主,对应的均一温度、盐度分别为248~296℃和6.0%~10.2%NaCleqv,以及130~197℃和0.2%~5.9%Na Cleqv。成矿期两种类型包裹体均发育,均一温度和盐度主要集中在200~260℃和7.0%~17.5%NaCleqv。成矿流体中气相成分以CO_2、H_2O、N_2为主,离子以Na~+、Ca~(2+)、NO_3~-和Cl~-为主。氢、氧同位素研究表明,撒岱沟门钼矿床中石英的δD值为-88‰~-102‰,δ~(18)OH_2O值为-1.90‰~3.12‰,成矿流体属于以岩浆水为主的中低温中低盐度的CO_2-H_2O-NaCl体系。 相似文献
10.
阿克希克铁金矿床位于准噶尔北缘,矿体呈似层状、脉状、透镜状赋存于南明水组火山岩及凝灰岩的接触带上。围岩蚀变不发育,主要为硅化、绢云母化、绿泥石化、黄铁矿化、碳酸盐化等。矿床的形成经历了火山沉积期和热液期,铁矿化主要形成于火山沉积期,金矿化主要形成于热液期。火山沉积期石英以发育液体包裹体和少量含CO2包裹体为特征,热液期石英以发育含CO2和碳质(CH4和C4H6)包裹体为特征。火山沉积期成矿流体为中温(集中于180~320℃)、低盐度(集中于6~10 wt%Na Cleq)、中-低密度(0.59~0.98 g/cm3)的Na Cl-H2O-CO2体系。热液期成矿流体为中温(集中于220~320℃),低盐度(集中于2~10 wt%Na Cleq),中-低密度(0.55~1.03 g/cm3)的Na Cl-H2O-CO2-CH4型流体。火山沉积期石英的δDSMOW为-129.9‰~-97.9‰,δ18OSMOW值介于7.9‰~12.3‰,δ18OH2O值为-2.6‰~4.4‰,推测成矿流体为海水与岩浆水的混合。热液期石英的δDSMOW介于-129.8‰~-102.6‰,δ18OSMOW值介于11.2‰~16.1‰,δ18OH2O变化于3.1‰~7.4‰,推测成矿流体为变质水混合深循环的大气降水。结合矿床地质特征、流体成分和性质,本文认为热液期金矿化与CO2-CH4流体有关。 相似文献
11.
Emily Keeble David I. Whiteside Michael J. Benton 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(2):99-119
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco. 相似文献
12.
The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts 总被引：4，自引：0，他引：4
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species. 相似文献
13.
Muriel Rocher Stéphane Baize Stéphane Jaillet Edward Marc Cushing Yannick Lozac&#x;h Francis Lemeille 《Comptes Rendus Geoscience》2003,335(8):701-708
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003). 相似文献
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