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1.
唐元骏  谭大芳 《地球科学》1994,19(3):329-336
章介绍了热动力学方法的研究历史,研究原理以及在研究地球化学机制中的应用,如石膏的脱水反应机制可分二步进行,CaSo4.2H2O→CaSO4.1/2H2O→CSO4活化能E=118.7KJ/mol,脱水温度T=380.60,呱应速率K1=4.41×10^-4S^-1方解石的溶解反应机制,在0-5000S期间以溶解反应为主,嗣后,发生周期性的溶解反应,热谱图上表现为化学振荡。  相似文献   

2.
花岗岩-KBF_4-Na_2MoO_4体系的实验结果朱永峰(北京大学地质学系,100871)常压下花岗岩-KBF_4-Na_2MoO_4体系在1250℃条件下呈均匀熔体状态,成矿元素Mo及其它元素(如F,Cl,H_2O及变网离子Ca,Na,K,Mg等...  相似文献   

3.
巩乃斯河流域积雪阴、阳离子的空间变化以K++Na+、Ca2+与SO2-4和HCO-3等离子最明显;K++Na+与SO2-4、Ca2+与HCO-3变化基本同步.从新降雪阴、阳离子的时间变化上看,隆冬季节积雪深厚范围广,相应离子含量低.调查区积雪对局地人类活动所造成的污染有较明显的记录.  相似文献   

4.
李兆麟  翟伟 《岩石学报》2000,16(4):513-520
河台韧性切带金矿床产于震旦系-志留为质岩系深大断裂糜棱岩带中,本研究首次在矿床含矿石英脉及糜棱岩中发现熔融包裹体,流体-熔融包裹体及有机包裹体。不同类型包裹体均一温度,有机包裹体为160℃,成矿流体属K^+-Ca^2+-Mg^2+-Na^+-SO4^2-HCO^2-4-HCO3^-4-Cl^-体系,具中偏碱性,微量气体特征:H2O〉CO2〉CH4〉(或〈)H2〉CO〉C2H2〉C2H6〉O2〉HJ  相似文献   

5.
胶东台上金矿成矿机制模拟实验研究   总被引:2,自引:0,他引:2  
周凤英  李兆麟 《地质论评》1994,40(5):456-465
模拟实验研究表明,台上金矿床的成矿机制为:胶东群地层重熔形成滦家河花岗岩岩浆时,初始浆为几乎均匀的熔体相;随着结晶成岩作用的进行,由于局部岩浆结晶分异作用,产生富K^+,Na^2^+,Ca^2^+,Mg^2^+,F^-,Cl^-,S^2^-,CO3^2^-及挥发份CO2,CO,H2O等的流体相,并不断从已结晶矿物及残熔体中,以[Au(HS)2]^-,[Au(HS)S]^2^-,AuCl4]^-等络  相似文献   

6.
由酸雨对包气带土样的淋滤试验和浸泡试验资料表明,在岩-水相互作用的初期,硬度主要来自土中易溶盐的溶解和H^+,Na^+对土颗粒表面Ca^2+,Mg^2+,Fe^2+等的交换;在后期,硬度主要来自土中碳酸盐,铝硅酸盐的风化水解。酸雨中的酸度与土壤溶液中的碱度的中和过程,即是水中硬度的形成过程,酸雨的pH值越低,在相同作用时内形成的硬度值越高。SO4^2-,HCO3^-是硬度组分自土中迁出的主要载体;  相似文献   

7.
闵茂中  王湘 《矿物岩石》1994,14(2):22-25
在我国贵州某低中温热卤水改造层控铀-汞矿床和湖南某古岩溶热造铀矿床中几乎同时发现了新矿物─—硒锑矿(Sb_2Se_3).该矿物的单晶呈细板条状、针状,集合体呈放射状、禾束状。确定硒锑矿形成于130─160℃富含Ca ̄(2+),Na ̄+,Mg ̄(2+),SO_4 ̄2-,HCO_3 ̄-的弱酸性─弱碱性热液,伴生一套典型的低中温热液矿物组合和围岩蚀变。硒锑矿是低中温热液标型矿物  相似文献   

8.
盆地卤水化学成分的一级控制因素   总被引:1,自引:0,他引:1  
世界范围内许多沉积盆地地下卤水的矿化度变化范围超过4个数量级,主要受大气水,海水和地表蒸发卤水与来自地下蒸发岩脱水和溶解的流体相混合的物理作用所控制,尽管在任意给定矿化度下地下卤水中的主要离子含量相关10倍以上,但随着矿化度的增加,水中的Na^+,K^+,Mg^2+和Ca^2+普遍系统地增加而PH值和HCO^-3系统地减小却支持了这样的假设,即接近由硅酸盐-碳酸盐士(卤化物)矿物组合控制的热力学缓  相似文献   

9.
分析了娘子关泉域岩溶地下水SO2-4,Ca2+,Mg2+等组分含量增多的原因,并定量地探讨了SO2-4,Ca2+,Mg2+的各种来源比例。研究表明,含水层中石膏溶解及硫化物氧化是造成SO2-4,Ca2+,Mg2+高含量的主要原因,控制硫化物氧化水进入含水层,对水质改良有显著效果。  相似文献   

10.
浙西石炭纪层状硅质岩地球化学特征及其意义   总被引:7,自引:0,他引:7  
在浙西石炭纪地层中存在与地层整合产出的层状硅质岩。硅质岩中FeO、MnO、TiO2、Al2O3、MgO、CaO、Na2O、K2O等含量相对较高,富集As、Sb、Bi、Au、Ag、Ga,Fe2O3/FeO、SiO2/Al2O3、SiO2/(Na2O+K2O)、SiO2/MgO比值较小,稀土元素总量低,Ce弱负异常,重稀土相对富集,包裹体富含气相组份CH4、CO2、N2、CO、H2,具热水沉积硅质岩的地球化学特征。在Fe—Mn—(Ni+Co+Cu)三角图及SiO2—Al2O3、SiO2—Fe2O3图上均属于热水沉积硅质岩。硅质岩中硅、氧同位素也显示其热水成因之特点。硅质岩的硅同位素和稀土元素Ce/Ce※值表明本区层状硅质岩主要是在浅海环境下沉积的。硅质岩的形成温度较高,为98℃~152℃  相似文献   

11.
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.  相似文献   

12.
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.  相似文献   

13.
Robert L. Linnen   《Lithos》2005,80(1-4):267-280
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.  相似文献   

14.
15.
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).  相似文献   

16.
正20141520 Bo Ying(Key Laboratory of Metallogeny and Mineral Assessment,MLR,Beijing 100037,China);Liu Chenglin Saline Spring Hydrochemical Characteristics and Indicators for Potassium Exploration in Southwestern and Northern Tarim Basin,Xinjiang(Acta Geoscientica Sinica,ISSN1006-3021,CN11-3474/P,34(5),2013,p.594-602,5 illus.,3 tables,28 refs.)  相似文献   

17.
正20141243Chen Ge(Hangzhou Research Institute of Petroleum Geology,PetroChina,Hangzhou 310023,China);Si Chunsong Study on Sedimentary Numerical Simulation Method of Fan Delta Sand Body(Journal of Geology,  相似文献   

18.
正20142599Chen Sanming(Guangxi Key Laboratory of Concealed Deposits Exploration,Guilin University of Technology,Guilin541004,China);He Yuzhou Block Model and Reserves Estimation of Panzhihua Iron Deposit Based on 3D Geological Modeling(Journal of Guilin University of Technology,ISSN1674-9057,CN45-1375/N,33(4),2013,p.610-615,9illus.,1table,15refs.)  相似文献   

19.
正20140594 Bai Daoyuan(Hunan Institute of Geology Survey,Changsha 410016,China);Zhong Xiang Faults in the Jingzhou Basin and Their Tectonic Settings(Geotectonica et Metallogenia,ISSN1001-1552,CN44-1595/P,37(2),2013,p.173-183,6illus.,59refs.)Key words:basin evolution,tectonic setting,South China In the Upper Paleozoic and Jurassic se-  相似文献   

20.
正20141912Cao Hui(State Key Laboratory for Continental Tectonics and Dynamics,Institute of Geology,Chinese Academy of Geological Sciences,Beijing 100037,China)Gravitational Collapse and Folding during Orogenesis:A Comparative Study of FIA Trends and Fold Axial Plane Traces(Geology in China,ISSN1000-3657,CN11-1167/P,40(6),2013,p.1818-1828,9illus.,35refs.,with  相似文献   

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