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1.
在压力为1.0～4.0 GPa、温度为873～1 223 K下采用Sarltron-1260阻抗/增益-相位阻抗谱分析仪测定了叶蜡石的电导率.实验结果表明,电导率与温度间的关系符合Arrenhius关系式;叶蜡石的脱水引起电导率的突然变化,使电导率急剧上升;脱水前,电导率随着压力增大而减小,其导电机制为电子导电;脱水后,电导率随着压力增大而增大,其导电机制为离子导电.  相似文献   

2.
We report the first study of electrical conductivities of silicate melts at very high pressures (up to 10 GPa) and temperatures (up to 2,173 K). Impedance spectroscopy was applied to dry and hydrous albite (NaAlSi3O8) glasses and liquids (with 0.02–5.7 wt% H2O) at 473–1,773 K and 0.9–1.8 GPa in a piston-cylinder apparatus, using a coaxial cylindrical setup. Measurements were also taken at 473–2,173 K and 6–10 GPa in two multianvil presses, using simple plate geometry. The electrical conductivity of albite melts is found to increase with temperature and water content but to decrease with pressure. However, at 6 GPa, conductivity increases rapidly with temperature above 1,773 K, so that at temperatures beyond 2,200 K, conductivity may actually increase with pressure. Moreover, the effect of water in enhancing conductivity appears to be more pronounced at 6 GPa than at 1.8 GPa. These observations suggest that smaller fractions of partial melt than previously assumed may be sufficient to explain anomalously high conductivities, such as in the asthenosphere. For dry melt at 1.8 GPa, the activation energy at T > 1,073 K is higher than that at T < 1,073 K, and the inflection point coincides with the rheological glass transition. Upon heating at 6–10 GPa, dry albite glass often shows a conductivity depression starting from ~1,173 K (due to crystallization), followed by rapid conductivity enhancement when temperature approaches the albite liquidus. For hydrous melts at 0.9–1.8 GPa, the activation energies for conductivity at ≥1,373 K are lower than those at <973 K, with a complex transition pattern in between. Electrical conductivity and previously reported Na diffusivity in albite melt are consistent with the Nernst–Einstein relation, suggesting the dominance of Na transport for electrical conduction in albite melts.  相似文献   

3.
Fast diffusion along mobile grain boundaries in calcite   总被引：1，自引：0，他引：1  
Experimental measurements of grain boundary diffusion are usually conducted on static boundaries, despite the fact that grain boundaries deep in the Earth are frequently mobile. In order to explore the possible effect of boundary mobility on grain boundary diffusion rates we have measured the uptake of 44Ca from a layer of 44Ca-enriched calcite powder during the static recrystallization of a single crystal of calcite at 900°C. A region about 500 μm wide adjacent to the powder layer is heterogeneously enriched in 44Ca, and complex zoning patterns, including sharp steps in composition and continuous increases and decreases in 44Ca content, are developed. In metamorphic rocks, these would normally be interpreted in terms of changes in pressure or temperature, Rayleigh fractionation, or episodic fluid infiltration. These explanations cannot apply to our experiments, and instead the zoning patterns are interpreted as being due to variations in grain boundary migration rate. We have applied an analytical model which allows the product of grain boundary diffusion coefficient and grain boundary width (D GB δ) to be calculated from the grain boundary migration rate and the compositional gradient away from the powder layer. The value of D GB δ in the mobile grain boundaries is at least five orders of magnitude greater than the published value for static boundaries under the same conditions. In order to allow the scale of chemical equilibrium (and hence textural evolution) to be predicted under both experimental and geological conditions, we present quantitative diffusion-regime maps for static and mobile boundaries in calcite, using both published values and our new values for grain boundary diffusion in mobile boundaries. Enhanced diffusion in mobile boundaries has wide implications for the high temperature rheology of Earth materials, for geochronology, and for interpretations of the length- and time-scales of chemical mass-transport. Moreover, zones of anomalously high electrical conductivity in the crust and mantle could be regions undergoing recrystallization such as active shear zones, rather than regions of anomalous mineralogy, water- or melt-content as is generally suggested.  相似文献   

4.
The morphologies of calcite grain boundaries were analyzed to provide insight into the evolution of pore networks in unfractured rock. Two synthetic calcite rocks were fabricated by hot isostatically pressing (HIP-ing) dried analytical-grade powders of pure CaCO3 and CaCO3 plus 5% Al2O3 at 600° C and 200 MPa confining pressure for 3 hours (HIP-1). Some samples were HIPed a second time at different temperatures and pressures to investigate the stability of the structures (HIP-2a-c). SEM and TEM were used to image both grain faces and grain boundary cross-sections. Structures on grain faces vary from open shallow basins with peripheral rims, to labyrinths of irregular ridges and channels, to isolated circular depressions. All of these structures are mirrored across the plane between grain faces. The grain size in both the single and two-phase samples increased markedly during HIP-1. Migrating boundaries either dragged pores along or broke away leaving grain interiors dotted with small voids. The structures present after HIP-1 were not stable but evolved considerably in a way dependent on the conditions of the HIP-2. Confining pressure had the most pronounced effect. With low confining pressure, the grain-boundary porosity evolved into isolated circular depressions but the total pore volume did not noticeably decrease. With high confining pressure, the pore volume virtually disappeared. The structures present after HIP-1 are strikingly similar to those that develop in intragranular cracks during healing. We infer that grain boundaries and intragranular cracks heal by similar processes. Decomposition, localized melting, impurities, and anisotropic surface energies played no evident role in forming the grain-boundary structures. The timing of the formation of the porosity and of the subsequent healing processes is more difficult to ascertain. Some structures appear to have evolved gradually throughout the constant, high temperature stage of HIPing. The most obvious structures, however, appear to have evolved on grain boundary cracks that opened during cooling.  相似文献   

5.
Melting experiments of calcite were performed on the join CaCO3‐H2O at a pressure of 1000 bars. The system evolves to the ternary CaO‐H2O‐CO2 system during melting experiments. Our experiments show that partial melting of calcite begins at a low temperature, below 650 °C. Such a low partial melting temperature for carbonates revives the debate about the presence of carbonate melts in the upper crust. More specifically, the conditions for carbonate partial melting are present in carbonate host rocks undergoing contact metamorphism at high temperatures in the presence of water‐rich fluid. The presence of carbonate melts influences physical parameters such as viscosity and permeability in contact aureoles, and, furthermore, decarbonation reactions release massive amounts of CO2.  相似文献   

6.
高温高压实验作为地球科学研究的重要方向之一,通过模拟地球深部的温度和压力条件,了解地球深部物质的物理化学性质、地球内部结构和动力学演化。角闪石属于双链硅酸盐矿物,为地幔岩石圈的重要组成,广泛分布在海洋地壳、俯冲板块、变质岩和火成岩中。作为俯冲带的重要含水矿物,角闪石的广泛分布和高温高压下的脱水对于理解俯冲带水含量以及水迁移具有重要作用,同时在俯冲带的地震活动、高电导率异常、地震波速异常和岩浆活动中扮演重要角色。在过去的近百年时间里,国内外学者对角闪石高温高压物理化学性质进行了大量的研究。角闪石具有非常复杂的元素组成和结构特征,由此也导致了不同角闪石物理化学性质存在显著不同,包括脱水与脱羟基反应中元素迁移的差异、角闪石形成与分解过程中碱性元素(K+Na)和H2O含量对热稳定的影响、不同空间群结构下的高压结构相变、原位条件下不同结晶方向的电导率异常、不同结晶学优选方位(CPO)下的波速异常等。已有的研究对于角闪石的物理化学性质以及其在俯冲带中发挥的作用有了比较清楚的认识,但仍然有许多问题需要进一步研究,如角闪石的高压脱水动力学、热物性和变形机制等。  相似文献   

7.
Fluid is released by dehydration reactions during prograde metamorphism. If the Claperyron slope for the dehydrating reaction is positive, then there is a net decrease in the total solid volume, which implies an irreversible increase in porosity. If the dilation of the pore space is insufficient to provide storage for all the released fluid, then pore pressure excess is generated, and if it becomes sufficiently high, it may lead to brittle fracturing. The time scale for pressure generation and the pore pressure excess can be maintained over long duration hinge on the interplay of reaction kinetics and fluid drainage. Motivated by experimental and microstructural observations, a hydrological model is developed that incorporates dehydration kinetics and its pressure dependence. Analytic solutions were derived for the undrained development of pore pressure. Whether lithostatic pressure may be exceeded hinges on magnitude of the overstep in temperature and corresponding equilibrium pressure. The time scale for development of pore pressure depends on the trade-off between poroelasticity and the pressure sensitivity of reaction rate. A finite difference model was also developed to simulate the progressive development of pore pressure excess, dehydration and porosity development. The model captures the experimental observation in gypsum of a reaction front that progressively propagates from the drained end toward the undrained end of a laboratory sample. It is also in reasonable agreement with experimental data on fluid drainage and porosity production.  相似文献   

8.
The electrical conductivity of (Mg0.93Fe0.07)SiO3 ilmenite was measured at temperatures of 500–1,200 K and pressures of 25–35 GPa in a Kawai-type multi-anvil apparatus equipped with sintered diamond anvils. In order to verify the reliability of this study, the electrical conductivity of (Mg0.93Fe0.07)SiO3 perovskite was also measured at temperatures of 500–1,400 K and pressures of 30–35 GPa. The pressure calibration was carried out using in situ X-ray diffraction of MgO as pressure marker. The oxidation conditions of the samples were controlled by the Fe disk. The activation energy at zero pressure and activation volume for ilmenite are 0.82(6) eV and −1.5(2) cm3/mol, respectively. Those for perovskite were 0.5(1) eV and −0.4(4) cm3/mol, respectively, which are in agreement with the experimental results reported previously. It is concluded that ilmenite conductivity has a large pressure dependence in the investigated P–T range.  相似文献   

9.
Metasedimentary and sedimentary rocks that represent the allochthonous Bolkardagi Unit crop out in the Central Taurus Belt. Devonian units include mainly slate, metadolomite, metadolomitic limestone, and metasandstone. Slates with slaty cleavage and chlorite-mica stacks are characterized by phyllosilicate, quartz, calcite, dolomite, feldspar, and goethite. Phyllosilicates consist of 2M1 and lesser amounts of 1M muscovite, IIb chlorite, pyrophyllite, paragonite. PM, C-V, C-S. rectorite, and dickite, and reflect conditions of the low epizone-anchizone. In the Carboniferous-Triassic units, limestone, clayey limestone, dolomitic limestone, marl, shale, and sandstone retaining primary textures are composed of calcite, dolomite, quartz,1Md illite, chlorite, and I-S, and locally smaller quantities of 2M1 muscovite, PM, paragonite, pyrophyllite, and rectorite. In contrast, the Triassic formation is made up of calcite, 1Md illite, I-S, kaolinite, smectite, chlorite, C-S, C-V, dolomite, and quartz. Textural and mineralogical data indicate that development of the diagenetic-metamorphic grade in the Central Taurus was related to sedimentary burial and thrusting; moreover, the metasedimentary rocks were metamorphosed in a typical anticlockwise P-T-t pathway in an extensional setting.  相似文献   

10.
Electrical conductivity and partial melting of mafic rocks under pressure   总被引：2，自引：0，他引：2  
We demonstrate the importance of electric conductivity measurements of partially molten mafic rocks by examining of Oman gabbro, Karelia olivinite, Ronda and Spitzbergen peridotites. The electrical conductivities of these rocks were estimated using the impedance spectroscopy at temperatures between 800°C and 1450°C and at pressures between 0.3 and 2 GPa in experiments performed in a piston cylinder apparatus. At temperatures below and above melting, samples were equilibrated during durations on the order of 200 h. Our results show that a jump in electrical conductivity can be correlated with the temperature range slightly above the solidus, due to the delayed formation of an interconnected melt phase. Thin sections of quenched samples were used to estimate volume fractions and chemical compositions of the partial melts. The increase of the electrical conductivity compares well with the connectivity of melt in partially molten samples. Above the solidus, the electrical conductivity increases by ∼1 to 2 orders of magnitude in comparison with the conductivity of non-melted rock below solidus. When a complete melt connectivity is established, the charge transport follows the network of the formed melt films at grain boundaries. Durations of up to ?200 h are required in order to reach a steady state electrical resistance in a partially molten rock sample. The experimental results were compared with the conductivity data obtained from magnetotelluric (MT) and electromagnetic (EM) measurements in the Northern part of the mid-Atlantic ridge where a series of axial magma chambers (AMC) are presumably located. There is good agreement between the measured electric conductivity of gabbroic samples with a melt fraction of 10 to 13 vol.% and the conductivity estimated at AMC, beneath the central part of Reykjanes ridge, as well as between the conductivity of partially molten peridotites and the source zone beneath the mid-Atlantic ridge at ?60 km.  相似文献   

11.
The rates of grain growth of stoichiometric dolomite [CaMg(CO3)2] and magnesite (MgCO3) have been measured at temperatures T of 700–800°C at a confining pressure P c of 300 MPa, and compared with growth rates of calcite (CaCO3). Dry, fine-grained aggregates of the three carbonates were synthesized from high purity powders by hot isostatic pressing (HIP); initial mean grain sizes of HIP-synthesized carbonates were 1.4, 1.1, and 17 μm, respectively, for CaMg(CO3)2, MgCO3, and CaCO3, with porosities of 2, 28, and 0.04% by volume. Grain sizes of all carbonates coarsened during subsequent isostatic annealing, with mean values reaching 3.9, 5.1, and 27 μm for CaMg(CO3)2, MgCO3, and CaCO3, respectively, in 1 week. Grain growth of dolomite is much slower than the growth rates of magnesite or calcite; assuming normal grain growth and n = 3 for all three carbonates, the rate constant K for dolomite (≃5 × 10−5 μm3/s) at T = 800°C is less than that for magnesite by a factor of ~30 and less than that for calcite by three orders of magnitude. Variations in carbonate grain growth may be affected by differences in cation composition and densities of pores at grain boundaries that decrease grain boundary mobility. However, rates of coarsening correlate best with the extent of solid solution; K is the largest for calcite with extensive Mg substitution for Ca, while K is the smallest for dolomite with negligible solid solution. Secondary phases may nucleate at advancing dolomite grain boundaries, with implications for deformation processes, rheology, and reaction kinetics of carbonates.  相似文献   

12.
Grain boundary processes contribute significantly to electronic and ionic transports in materials within Earth’s interior. We report a novel experimental study of grain boundary conductivity in highly strained olivine aggregates that demonstrates the importance of misorientation angle between adjacent grains on aggregate transport properties. We performed electrical conductivity measurements of melt-free polycrystalline olivine (Fo90) samples that had been previously deformed at 1200 °C and 0.3 GPa to shear strains up to γ?=?7.3. The electrical conductivity and anisotropy were measured at 2.8 GPa over the temperature range 700–1400 °C. We observed that (1) the electrical conductivity of samples with a small grain size (3–6 µm) and strong crystallographic preferred orientation produced by dynamic recrystallization during large-strain shear deformation is a factor of 10 or more larger than that measured on coarse-grained samples, (2) the sample deformed to the highest strain is the most conductive even though it does not have the smallest grain size, and (3) conductivity is up to a factor of ~?4 larger in the direction of shear than normal to the shear plane. Based on these results combined with electrical conductivity data for coarse-grained, polycrystalline olivine and for single crystals, we propose that the electrical conductivity of our fine-grained samples is dominated by grain boundary paths. In addition, the electrical anisotropy results from preferential alignment of higher-conductivity grain boundaries associated with the development of a strong crystallographic preferred orientation of the grains.  相似文献   

13.
《Applied Geochemistry》1998,13(2):177-184
Calcium carbonate is one of the most common and important scale-forming minerals in oilfield produced water, but the kinetics of CaCO3 precipitation has been ignored in most scale prediction models because of the lack of reliable precipitation rate model. There are none in the open literature for oilfield conditions (temperature > 100°C, pressure > 200 bar and salinity > 0.5 mol kg− 1). In this work the kinetics of calcite (CaCO3) precipitation from high salinity waters (up to 2 mol kg−1) have been studied by a pH-free-drift method in a closed water system. This method. is much easier to operate than the often used steady-state method. The experimental results indicate that the calcite precipitation rate is not only affected by the solution CaCO3 saturation level, but also by the solution pH, ionic strength and the concentration ratios of Ca to HCO3− ions (CCa2+/CHCO3−). When the concentration ratios of Ca to HCO3− ions are close to their chemical stoichiometric ratio of 0.5, the calcite growth from a supersaturated solution is believed to be surface reaction controlled. However, at higher CCa2+CHCO3− ratios, the transportation of the lattice ions to calcite crystal surface has to be considered.  相似文献   

14.
During the production of hydrocarbons from subterranean reservoirs, scaling with calcium carbonate and barium sulfate causes flux decline and dangerous problems in production facilities. This work is intended to study the effect of calcium ions on the precipitation of barium sulfate (barite); then, the effect of the formed barite on calcium carbonate crystallization. The conductometric and pH methods were used to follow the progress of the precipitation reaction in aqueous medium. The obtained precipitates were characterized by FTIR, RAMAN, SEM, and XRD. It was shown that Ca2+ in the reaction media does not affect the microstructure of barite even for higher calcium–barium molar ratio. It influences the precipitation kinetics and the solubility of barite by the formation of CaSO4° ion pairing as a predominant role of complex formation (CaSO4) and the increase of the ionic strength. In Ca(HCO3)2-BaSO4-NaCl aqueous system, experiments have showed that added or formed barite in the reaction media accelerates calcite precipitation. No effect on the microstructure of heterogeneous formed calcite which remain calcite shape. However the presence of carbonate ions affects slightly the microstructure of barite.  相似文献   

15.
Sun  Meng  Cao  Junnan  Cao  Jingjing  Zhang  Shuai  Chen  Yunmin  Bate  Bate 《Acta Geotechnica》2022,17(7):2633-2649

Bioremediation is widely used to improve ground soil by introducing calcium carbonate (CaCO3). Shear wave velocity (Vs) is usually adopted to evaluate effect but the microscopic mechanism is unclear. The discrete element method (DEM), a promising tool for simulating the behaviors of cohesive and noncohesive materials, was used in this study to simulate Vs evolution and wave propagation path of sand reinforced by calcite precipitates. Two basic calcite precipitate forms are proposed for representing individual calcite precipitation (CaCO3-P) and calcite aggregation (CaCO3-C). Contact cementation between adjacent sand grain pairs was the primary association pattern for calcite precipitates at a low calcite content. At a higher calcite content, the preferential shear wave propagation pathway is the clusters cemented by CaCO3-C. With calcite content increasing from 0 to 9%, the coordination number and average contact force increased. Vs increased from 169.73 to 2132.64 m/s but had high variability due to the spatial distribution. The results suggest that the calibrated DEM model can elucidate the microscopic mechanisms and evaluate the enhancement effect of microorganism-reinforced soil.

  相似文献   

16.
The solid‐state reaction magnesite (MgCO3) + calcite (aragonite) (CaCO3) = dolomite (CaMg(CO3)2) has been identified in metapelites from western Tianshan, China. Petrological studies show that two metamorphic stages are recorded in the metapelites: (1) the peak mineral assemblage of magnesite and calcite pseudomorphs after aragonite which is only preserved as inclusions within dolomite; and (2) the retrograde glaucophane‐chloritoid facies mineral assemblage of glaucophane, chloritoid, dolomite, garnet, paragonite, chlorite and quartz. The peak metamorphic temperatures and pressures are calculated to be 560–600 °C, 4.95–5.07 GPa based on the calcite–dolomite geothermometer and the equilibrium calculation of the reaction dolomite = magnesite + aragonite, respectively. These give direct evidence in UHP metamorphic rocks from Tianshan, China, that carbonate sediments were subducted to greater than 150 km depth. This UHP metamorphism represents a geotherm lower than any previously estimated for subduction metamorphism (< 3.7 °C km?1) and is within what was previously considered a ‘forbidden’ condition within Earth. In terms of the carbon cycle, this demonstrates that carbonate sediments can be subducted to at least 150 km depth without releasing significant CO2 to the overlying mantle wedge.  相似文献   

17.
在三轴条件下,对饱和土（砂土和黏土）进行排水与不排水条件下的冲击试验及冲击后再固结试验,对比研究了不同渗透性土在不同排水条件下的冲击动力响应和冲击后再固结性状。结果表明：饱和黏土不排水冲击时的孔隙水压力随冲击击数增加而升高并逐渐稳定,排水冲击时的孔隙水压力则是先达到峰值然后有所下降;砂土不排水冲击时的冲击能量对孔隙水压力影响最明显;饱和砂土不排水冲击时的轴向应变与冲击击数呈近似线性关系,饱和黏土冲击及饱和砂土排水冲击则呈近二次曲线关系;饱和砂土不排水冲击后再固结阶段的孔隙水压力立即消散为0,同时体变迅速增大到一定值;饱和黏土在冲击后再固结阶段的孔隙水压力在一定时间内逐渐消散完毕,同时体变逐渐增大;饱和黏土排水冲击时,冲击阶段产生的体变占冲击引起总体变的39%～49%,冲击后再固结阶段产生的体变占51%～61%;砂土和黏土的总体变均表现为排水冲击明显大于不排水冲击,改善冲击时的排水条件有利于提高加固效果。  相似文献   

18.
Experimental runs were made in cold-seal pressure vessels using synthetic CaCO8·6H2O, calcite and aragonite as starting materials. The reaction CaCO3·6H2O (ikaite) ? CaCO3 (calcite I) + 6H2O was reversed across its metastable extension into the aragonite stability field and the phase boundary is defined by brackets at 4.14kb, 14.3°C and 2.96 kb, ?3.0°C. An invariant point for CaCO3·6H2O, calcite I, aragonite and water thus occurs at about 3.02 kb and ?2.0°C. No other reaction could be reversed. Calculations based on the equilibrium phase boundary between calcite and ikaite and the available thermochemical data for calcite and water yield the stadard free energy of formation, standard enthalpy of formation and third law entropy of CaCO3·6H2O at 25°C and 1 bar total pressure; ?607.3 kcal/mole, ?705.8 kcal/mole, and 88.4 cal/deg mole, respectively.  相似文献   

19.
Using impedance spectroscopy, we have measured the electrical properties of two dunites and a single crystal olivine sample from 1000 to 1200° C as a function of oxygen fugacity (f o 2). Two conduction mechanisms with resistances that add in series are observed for the dunites corresponding to grain interior and grain boundary conduction mechanisms. The conductivities for each mechanism were determined by analyzing the data using a complex nonlinear least squares fitting routine and the equivalent circuit approach. The grain interiors display a conductivity dependent on f o 2 to the 1/5.5–1/7 power, consistent with other determinations, and interpreted as indicating small polaron transport (Fe Mg · ). The grain boundaries demonstrate a weaker f o 2 dependence that is dependent on temperature and material. Under certain conditions the f o 2 dependence of the grain boundary conductivity is negative. This result indicates that oxygen ion transport is probably not the dominant grain boundary charge transport mechanism; however, an unequivocal determination of the grain boundary mechanism has not been achieved. In some dunites the grain boundaries are more conductive than the grain interiors; in other dunites they are more resistive than grain interiors. The grain boundaries do not enhance the total conductivity of any of the materials of this study but are the controlling mechanism in some instances. Measurement of the complex electrical response at frequencies as low as 10-4 Hz is required to determine the role of grain boundaries on the overall electrical properties of polycrystalline dunite.  相似文献   

20.
About two hydrological years of continuous data of discharge, temperature, electrical conductivity and pH have been recorded at the Glarey spring in the Tsanfleuron glaciated karst area in the Swiss Alps, to understand how glaciated karst aquifer systems respond hydrochemically to diurnal and seasonal recharge variations, and how calcite dissolution by glacial meltwater contributes to the atmospheric CO2 sink. A thermodynamic model was used to link the continuous data to monthly water quality data allowing the calculation of CO2 partial pressures and calcite saturation indexes. The results show diurnal and seasonal hydrochemical variations controlled chiefly by air temperature, the latter influencing karst aquifer recharge by ice and snowmelt. Karst process-related atmospheric CO2 sinks were more than four times higher in the melting season than those in the freezing season. This finding has implication for understanding the atmospheric CO2 sink in glaciated carbonate rock terrains: the carbon sink will increase with increasing runoff caused by global warming, i.e., carbonate weathering provides a negative feedback for anthropogenic CO2 release. However, this is a transient regulation effect that is most efficient when glacial meltwater production is highest, which in turn depends on the future climatic evolution.  相似文献   

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