共查询到19条相似文献，搜索用时 109 毫秒
1.
在1.0、2 .0GPa和873～12 2 3K的温压条件下,借助于12 6 0阻抗增益相位分析仪测定了叶蜡石的电导率,并用阻抗谱原理分析了其微观导电机制。实验结果表明:样品的电导率对频率具有很强的依赖性;电阻率随着温度的升高而减小,电导率随着温度升高而增大,logσ与1/T之间符合Arrenhius线性关系;叶蜡石在1.0GPa和2 .0GPa的压力下脱水温度分别为10 74K和110 1K。根据本次获得的电导率实验结果并结合前人对滑石族所做的工作,得出了与前人不同的结论:滑石族矿物脱水电导率曲线出现了转折点。 相似文献
2.
在俯冲带中,菱镁矿相比于其他碳酸盐矿物会在更高的温度压力环境下稳定存在,常被认为是地球深部碳循环的主要载体,其电学性质的研究对俯冲带及地球深部的电性结构具有重要的意义。本文在YJ-3000t高温高压设备上利用Solartron-1260阻抗/增益-相位分析仪,在1～3 GPa和773～1173 K条件下,对天然菱镁矿的电导率进行了原位测量。实验结果表明,在实验条件下,天然菱镁矿的电导率在10-2～10-7 S/m范围内,菱镁矿的电导率对温度有很强的依赖性,随着温度的升高,电导率增大,电导率与压力的关系呈正相关,随着压力的升高而增强。结合前人的研究成果及样品电导率随温度、压力的效应和活化能,可推断天然菱镁矿导电机制为大极化子导电。 相似文献
3.
4.
高温高压和控制氧逸度条件下透辉石电导率的各向异性实验研究 总被引：2，自引：0，他引：2
在1.0～4.0GPa 和1073～1373K 及控制氧分压条件下,借助于 YJ-3000t 紧装式六面顶固体高压设备和1260阻抗/增益-相位分析仪,就位测定了沿着不同晶轴方向的透辉石的电导率。氧逸度控制是由 Ni+NiO 固体缓冲剂完成的。实验结果表明:(1)在选择的频率范围,无论从复阻抗的模与频率还是从相角与频率关系上,部可以看出复阻抗对频率具有很强的依赖性;(2)随着温度升高,阻抗降低,电导率增大,Logo 与1/T 之间符合 Arrenhius 线性关系式;(3)随着压力升高,[001]方向的透辉石电导率降低,活化焓和指前因子亦随之减小,并首次获得了透辉石中主要载流子的活化能和活化体积分别为1.80±0.04eV 和0.035±0.015cm~3/mol;(4)在2.0GPa 下按照[001]、[100]、[010]的顺序,样品的电导率和指前因子降低,活化焓依次升高,高压下的透辉石电学性质存在各向异性;(5)小极化子导电机制可为透辉石在高温高压下的导电行为提供合理的解释。 相似文献
5.
利用交流阻抗谱实验技术,在0.5~2.0 GPa、573~873 K和10-1~106 Hz条件下,借助YJ-3000t紧装式六面顶高压设备和Solartron-1260阻抗/增益-相位分析仪测定了石英砂岩的电导率。实验结果表明:在测定的频率范围,样品的复阻抗的实部、虚部、模和相角对频率有很强的依赖性。随着温度升高,电导率增大,lgσT与1/T之间符合Arrhenius线性关系。通过拟合计算,获得了表征样品电学性质的指前因子、活化焓、活化能、活化体积等物性参数。杂质离子导电机制对高温高压下石英砂岩的导电行为提供了合理的解释。 相似文献
6.
高温高压下辉长岩的电导率实验研究 总被引：1，自引：1，他引：1
在 1 .0～2 .0GPa和 3 2 0～ 70 0℃下 ,1 2～ 1 0 5Hz的频率范围内 ,进行了辉长岩的电导率就位测量 ,并用阻抗谱分析了其微观电传导机制。结果表明 ;电导率对测量频率具有依赖性。复阻抗平面上只出现了反映颗粒内部传导机制的阻抗弧 ,在高压下这种机制起主导作用 ,该阻抗弧出现在 1 0 5～n×1 0 2 Hz(n为 1～9的正整数 )的频率范围内。以本实验所获得的电导率结果和前人的工作为依据得出辉长岩不能在中下地壳形成高导层的结论。 相似文献
7.
8.
河北汉诺坝新生代玄武岩携带的石榴辉石岩为岩浆底侵于上地幔顶部40～45 km形成的堆晶岩,是壳-幔过渡带的典型样品。本文使用Solartron 1260阻抗分析仪,测量1.2 GPa和380～900 ℃下石榴辉石岩WD958的电阻率。样品电导率(σ)与温度的关系遵守Arrhenius方程: σ=σ0exp(-ΔH/kT),其中T是样品的绝对温度,k是Boltzmann常数,指前因子σ0为97.5 S/m,活化焓ΔH为1.27 eV。使用傅立叶红外光谱仪测定样品中单斜辉石的平均含水量为117×10-6 H2O,橄榄石无水,石榴子石的含水量因蚀变无法测定。使用Hashin-Shtrikman平均方法计算样品WD958的电导率,发现样品可看作由含水单斜辉石、无水石榴子石和无水橄榄石组成的高阻集合体,电导率同时受小极化子导电和质子导电的影响。如果原位的石榴辉石岩的矿物含水量保持平衡,其电导率将提高1个数量级,质子导电成为主控导电机制。石榴辉石岩在高温的壳-幔过渡带(～1 000℃)表现为高导层,而在正常地温梯度下,与尖晶石二辉橄榄岩的电导率近似,为高阻层。因此,在岩浆底侵作用下,电性上的壳-幔边界将随着温度和含水量的变化而改变。 相似文献
9.
10.
高温高压下矿物岩石电导率的实验研究数据,不仅是人们了解地球内部物质组成及其演化过程的重要窗口,而且可以为野外大地电磁测深和地磁测深反演提供重要约束.重点介绍了温度、压力、水含量、铁含量、氧逸度、熔融等矿物岩石电导率的影响因素,深入阐述了存在于矿物岩石的4种主要导电机制,即离子、质子、小极化子和大极化子.回顾近年来地壳主要造岩矿物(长石、石英和辉石)的电导率实验研究取得的新成果,讨论了它们的导电机制和地球物理意义,并对其目前存在的问题及尚需进一步展开的工作进行了探讨. 相似文献
11.
In situ impedance spectroscopy in laboratory experiments at high pressure and temperature can provide crucial quantitative
information on properties of rock materials at depth as well as on physical and chemical processes occurring in the deep Earth.
We developed an experimental setup for in situ electrical impedance measurements in a piston-cylinder apparatus and applied
it to study the kinetics of charge carriers and phase transformations in pyrophyllite and CaCO3 aggregates. From comparison with previous studies, we found that absolute values of electrical conductivity and pressure–temperature
conditions for dehydration reactions in pyrophyllite and phase transformations in CaCO3 can be accurately determined using our setup. Dehydration of pyrophyllite significantly enhances the transport kinetics and
the effect is more pronounced under undrained conditions than under drained conditions. When dehydroxylation and decomposition
temperatures for pyrophyllite under undrained and drained conditions are combined, they appear independent of pressure rather
than increasing with pressure as previously suggested. Electrical conductivity of CaCO3 varies with impurity content and grain size, and is most likely controlled by diffusion of oxygen along wet grain boundaries.
When applied to the Earth, the results on pyrophyllite suggest that the increase in electrical conductivity in rocks that
undergo dehydration should be taken into account in interpreting magnetotelluric surveys of regions with anomalously high
conductivity found above subducting plates. The results on CaCO3 indicate that grain boundary transport controls the electrical conductivity in fine-grained calcite rocks; hence calcite
mylonites may be detected using magnetotelluric methods. Order–disorder transformations, such as occurring in calcite, possibly
affect the physical properties of rocks (e.g., rheology) by changing the kinetics of atomistic transport processes. 相似文献
12.
地球深部物质的某些物性测量方法研究 总被引：8，自引：1，他引：8
文中介绍了地球深部物质实验室近 2 0年来开展高温高压下地球深部物质物性实验研究过程中 ,在测量方法方面的进步和应用情况。这些测量方法包括了高温、高压下弹性的超声测量方法、高温高压下电性的测量方法、高压差热分析法和高压下热学Gr櫣ｎｅｉｓｅｎ参数的测量方法诟呶赂哐瓜卵沂涂笪锏牡猿饬恐?,我们由超声脉冲透射方法改进为超声脉冲透射反射法 ,克服了样品室中压力和温度梯度对样品的影响。在高温高压下岩石和矿物的电学性质测量中 ,我们由直流法发展为阻抗谱法 ,不仅克服了样品极化对测量结果的影响 ,还可以获得离子在溶液中的多种物理化学参数 ,以及监测含水矿物在高温高压下的脱水动力学特征。在固体传压介质中建立的高压热学Gr櫣ｎｅｉｓｅｎ参数的测量方法 ,由于升压速率比较小且叶蜡石在高压下的热导系数增大 ,其测量结果需要进行校正 ,其测量方法有待进一步改进。 相似文献
13.
Dehydration temperatures of serpentine were measured in the pressure range between 1.0GPa and 5.0GPa by using the electrical conductivity metod simultaneously at high temperatures and high pressures.The results show that with increasing pressure th dehydration temperature of antigorite increases slightly below 2.0GPa ,but drops markedly above2.0GPa .This strongly suggests that high pressure would favor the dehydration of serpentine minerals and the water released thereby would be an important source of fluids involved in magmatism in a subduction zone and mantle metasomatism,Meanwhile,the greatly enhanced electric conductivity in the presence of water may be one of the reasons underlying the occurrence of a high-conductivity zone in the lower crust. 相似文献
14.
Electrical conductivity of talc was measured at 0.5 GPa and ~473 to ~1,300 K by using impedance spectroscopy both before and after dehydration. Before dehydration, the electrical conductivity of talc increased with temperature and is ~10?4 S/m at 1,078 K. After dehydration, most of the talc changed to a mixture of enstatite and quartz and the total water content is reduced by a factor 6 or more. Despite this large reduction in the total water content, the electrical conductivity increased. The activation enthalpy of electrical conductivity (~125 kJ/mol) is too large for the conduction by free water but is consistent with conduction by small polaron. Our results show that a majority of hydrogen atoms in talc do not enhance electrical conductivity, implying the low mobility of the hydrogen atoms in talc. The observed small increase in conductivity after dehydration may be attributed to the increase in oxygen fugacity that enhances conductivity due to small polaron. 相似文献
15.
首次报导了秦岭-大别山壳幔岩石高温高压下电导率的测定结果。该区中上地壳主要代表岩石(角闪岩、绢云母石英片岩、千枚岩等)在10-25km的温压条件下,含水矿物出现脱水会引起电导率值升高,认为这是该区出现高导层体的主要原因;中下地壳代表性岩石(片麻岩、麻粒岩、榴辉岩等)由于石英从α相向β相转变,会导致电导率值(σ)下降。在下地壳的温压条件下电导率值一般为10-2到10-3S·m-1;上地幔的代表性岩石由于组成矿物较为基性,电导率值比下地壳高,从0.1到1S·m-1。 相似文献
16.
The electric conductivity of gabbro has been measured at 1.0 - 2.0 GPa and 320-700℃, and the conduction mechanism has been analyzed in terms of the impedance spectra.Experimental results indicated that the electric conductivity depends on the frequency of alternative current. Impedance arcs representing the conduction mechanism of grain interiors are displayed in the complex impedance plane, and the mechanism is dominated at high pressure.These arcs occur over the range of 102 - k× 105 Hz (k is the positive integer from 1 to 9). On the basis of our results and previous work, it is concluded that gabbro cannot form any high conductivity layer (HCL) in the middle-lower crust. 相似文献
17.
徐有生 《矿物岩石地球化学通报》1997,(4)
高温高压下水和氯化钠溶液的物理化学性质研究徐有生（中国科学院地球化学研究所，贵阳５５０００２）关键词高温高压水和ＮａＣｌ溶液物理化学性质水和ＮａＣｌ溶液是地质上最常见的溶液，了解其物理化学性质有助于研究水溶液在地球内部各种地质作用和地质过程中所起的作... 相似文献
18.
DAI Lidong LI Heping LIU Congqiang SHAN Shuangming CUI Tongdi SU Genli Laboratory of the Earth’s Interior Materials Fluid Geochemistry Institute of Geochemistry Chinese Academy of Sciences Guiyang Guizhou Graduate School of Chinese Academy of Sciences Beijing Institute of Geochemistry Chinese Academy of Sciences Guiyang Guizhou University of Guizhou Guiyang Guizhou 《《地质学报》英文版》2005,79(6):803-809
1 Introduction recognized and accepted by more and more experts engaged in experimental research at high temperature and In-situ laboratory measurement of the electricity of high pressure. This method has been regardedgeological materials at high temperature and high pressure internationally as the most advanced one for the in-situis an important approach to revealing the composition, laboratory measurement of the electric properties ofstructure and properties of materials in the deep interior… 相似文献
19.
Haiying Hu Lidong Dai Heping Li Jianjun Jiang Keshi Hui 《Mineralogy and Petrology》2014,108(5):609-618
Electrical conductivity measurements on dry polycrystalline K-feldspar were performed at 1.0 to 3.0 GPa and 873 to 1,173 K with a multi-anvil high-pressure apparatus and the Solartron-1260 Impedance/Gain Phase Analyzer in the frequency range of 10?1 to 106 Hz. At each temperature the complex impedance displays a perfect semi-circular arc that represents the grain-interior conduction. Under the experimental conditions, electrical conductivity exponentially increases with increasing temperature and slightly decreases with increasing pressure; however, the effect of pressure on the conductivity is less pronounced than that of temperature. The activation enthalpy decreases slightly from 0.99 to 1.02 eV with increasing pressure, and the activation energy and activation volume for K-feldspar are 0.98 eV and 1.46?±?0.17 cm3/mol, respectively. According to these Arrhenius parameters, ionic conduction is proposed to be the dominant conduction mechanism in K-feldspar at high temperatures and pressures, and potassium ions are the charge carriers transporting by an interstitial mechanism. The diffusion coefficient of potassium at high temperatures was calculated from our conductivity data on K-feldspar using Nernst–Einstein equation, and the results were compared with the previous experimental results. 相似文献