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1.
The Visual and Infrared Mapping Spectrometer (VIMS) observed the Galilean satellites during the Cassini spacecraft's 2000/2001 flyby of Jupiter, providing compositional and thermal information about their surfaces. The Cassini spacecraft approached the jovian system no closer than about 126 Jupiter radii, about 9 million kilometers, at a phase angle of <90°, resulting in only sub-pixel observations by VIMS of the Galilean satellites. Nevertheless, most of the spectral features discovered by the Near Infrared Mapping Spectrometer (NIMS) aboard the Galileo spacecraft during more than four years of observations have been identified in the VIMS data analyzed so far, including a possible 13C absorption. In addition, VIMS made observations in the visible part of the spectrum and at several new phase angles for all the Galilean satellites and the calculated phase functions are presented. In the process of analyzing these data, the VIMS radiometric and spectral calibrations were better determined in preparation for entry into the Saturn system. Treatment of these data is presented as an example of the VIMS data reduction, calibration and analysis process and a detailed explanation is given of the calibration process applied to the Jupiter data.  相似文献   

2.
We have conducted a search for emissivity features in the thermal infrared spectrum of the icy satellites of Saturn, Phoebe, Iapetus, Enceladus, Tethys, and Hyperion, observed by the Composite Infrared Spectrometer (CIRS) on board the Cassini spacecraft. Despite the heterogeneity of the composition of these bodies depicted by Earth-based and Cassini/VIMS observations, the CIRS spectra of all satellites are undistinguishable from black-body spectra, with no detectable emissivity feature. However, several materials, which have been detected on the surface of the same bodies, present emissivity features in the analyzed spectral range. In particular, water ice presents features with sufficient contrast to be detected by CIRS. Here we study the physical causes of the absence of features by simulating the effects of intimate mixtures using models of directional emissivity for optically thick surfaces for different particle sizes and abundances, and porosities. The simulations include a set of materials detected on the Phoebe's surface, like water ice, hydrated silicates, and organics. We find that featureless spectra can be produced in three scenarios: (1) ice particles with large sizes, (2) mixtures of ices dominated by dark contaminants, and (3) small particles with large porosity. Constraints imposed by the NIR spectra of the satellites favors the latter scenario as the more likely explanation to the absence of emissivity features on the icy satellites of Saturn.  相似文献   

3.
We apply a multivariate statistical method to the Phoebe spectra collected by the VIMS experiment onboard the Cassini spacecraft during the flyby of June 2004. The G-mode clustering method, which permits identification of the most important features in a spectrum, is used on a small subset of data, characterized by medium and high spatial resolution, to perform a raw spectral classification of the surface of Phoebe. The combination of statistics and comparative analysis of the different areas using both the VIMS and ISS data is explored in order to highlight possible correlations with the surface geology. In general, the results by Clark et al. [Clark, R.N., Brown, R.H., Jaumann, R., Cruikshank, D.P., Nelson, R.M., Buratti, B.J., McCord, T.B., Lunine, J., Hoefen, T., Curchin, J.M., Hansen, G., Hibbitts, K., Matz, K.-D., Baines, K.H., Bellucci, G., Bibring, J.-P., Capaccioni, F., Cerroni, P., Coradini, A., Formisano, V., Langevin, Y., Matson, D.L., Mennella, V., Nicholson, P.D., Sicardy, B., Sotin, C., 2005. Nature 435, 66-69] are confirmed; but we also identify new signatures not reported before, such as the aliphatic CH stretch at 3.53 μm and the ∼4.4 μm feature possibly related to cyanide compounds. On the basis of the band strengths computed for several absorption features and for the homogeneous spectral types isolated by the G-mode, a strong correlation of CO2 and aromatic hydrocarbons with exposed water ice, where the uniform layer covering Phoebe has been removed, is established. On the other hand, an anti-correlation of cyanide compounds with CO2 is suggested at a medium resolution scale.  相似文献   

4.
Saturn's icy satellites are among the main scientific objectives of the Cassini-VIMS (Visual and Infrared Mapping Spectrometer) experiment. This paper contains a first systematic and comparative analysis of the full-disk spectral properties of Dione, Enceladus, Epimetheus, Hyperion, Iapetus, Mimas, Phoebe, Rhea and Tethys as observed by VIMS from July 2004 to June 2005. The disk integrated properties (350-5100 nm reflectance spectra and phase curves at 550-2232 nm) and images of satellites are reported and discussed in detail together with the observed geometry. In general, the spectra in the visible spectral range are almost featureless and can be classified according to the spectral slopes: from the bluish Enceladus and Phoebe to the redder Iapetus, Hyperion and Epimetheus. In the 1000-1300 nm range the spectra of Enceladus, Tethys, Mimas and Rhea are characterized by a negative slope, consistent with a surface largely dominated by water ice, while the spectra of Iapetus, Hyperion and Phoebe show a considerable reddening pointing out the relevant role played by darkening materials present on the surface. In between these two classes are Dione and Epimetheus, which have a flat spectrum in this range. The main absorption bands identified in the infrared are the 1520, 2020, 3000 nm H2O/OH bands (for all satellites), although Iapetus dark terrains show mostly a deep 3000 nm band while the 1520 and 2020 nm bands are very faint. In this spectral range, the Iapetus spectrum is characterized by a strong reddening. The CO2 band at 4260 nm and the Fresnel ice peak around 3100 nm are evident only on Hyperion, Phoebe and Iapetus. The phase curves at 550 and at 2232 nm are reported for all the available observations in the 0°-144° range; Rhea shows an opposition surge at visible wavelengths in the 0.5°-1.17° interval. The improvement on the retrieval of the full-disk reflectance spectra can be appreciated by a direct comparison with ground-based telescopic data available from literature. Finally, data processing strategies and recent upgrades introduced in the VIMS-V calibration pipeline (flat-field and destriping-despiking algorithm) are discussed in appendices.  相似文献   

5.
We report the detailed analysis of the spectrophotometric properties of Saturn’s icy satellites as derived by full-disk observations obtained by visual and infrared mapping spectrometer (VIMS) experiment aboard Cassini. In this paper, we have extended the coverage until the end of the Cassini’s nominal mission (June 1st 2008), while a previous paper (Filacchione, G., and 28 colleagues [2007]. Icarus 186, 259-290, hereby referred to as Paper I) reported the preliminary results of this study.During the four years of nominal mission, VIMS has observed the entire population of Saturn’s icy satellites allowing us to make a comparative analysis of the VIS-NIR spectral properties of the major satellites (Mimas, Enceladus, Tethys, Dione, Rhea, Hyperion, Iapetus) and irregular moons (Atlas, Prometheus, Pandora, Janus, Epimetheus, Telesto, Calypso, Phoebe). The results we discuss here are derived from the entire dataset available at June 2008 which consists of 1417 full-disk observations acquired from a variety of distances and inclinations from the equatorial plane, with different phase angles and hemispheric coverage. The most important spectrophotometric indicators (as defined in Paper I: I/F continua at 0.55 μm, 1.822 μm and 3.547 μm, visible spectral slopes, water and carbon dioxide bands depths and positions) are calculated for each observation in order to investigate the disk-integrated composition of the satellites, the distribution of water ice respect to “contaminants” abundances and typical regolith grain properties. These quantities vary from the almost pure water ice surfaces of Enceladus and Calypso to the organic and carbon dioxide rich Hyperion, Iapetus and Phoebe. Janus visible colors are intermediate between these two classes having a slightly positive spectral slope. These results could help to decipher the origins and evolutionary history of the minor moons of the Saturn’s system. We introduce a polar representation of the spectrophotometric parameters as function of the solar phase angle (along radial distance) and of the effective longitude interval illuminated by the Sun and covered by VIMS during the observation (in azimuth) to better investigate the spatial distribution of the spectrophotometric quantities across the regular satellites hemispheres. Finally, we report the observed spectral positions of the 4.26 μm band of the carbon dioxide present in the surface material of three outermost moons Hyperion, Iapetus and Phoebe.  相似文献   

6.
Photometric and spectral analysis of data from the Cassini Visual and Infrared Mapping Spectrometer (VIMS) has yielded significant results regarding the properties and composition of the surface of Saturn's satellite Enceladus. We have obtained spectral cubes of this satellite, containing both spatial and spectral information, with a wavelength distribution in the infrared far more extensive than from any previous observations and at much higher spatial resolution. Using a composite mosaic of the satellite, we map the distribution of crystalline and amorphous ices on the surface of Enceladus according to a “crystallinity factor” and also the depth of the temperature- and structure-dependent 1.65 micron water-ice band. These maps show the surface of Enceladus to be mostly crystalline, with a higher degree of crystallinity at the “tiger-stripe” cracks and a larger amorphous signature between these stripes. These results suggest recent geological activity at the “tiger stripe” cracks and an intriguing atmospheric environment over the south pole where amorphous ice is produced either through intense radiative bombardment, flash-freezing of cryovolcanic liquid, or rapid condensation of water vapor particles on icy microspherules or on the surface of Enceladus.  相似文献   

7.
The Visual Infrared Mapping Spectrometer (VIMS) onboard the CASSINI spacecraft obtained new spectral data of the icy satellites of Saturn after its arrival at Saturn in June 2004. VIMS operates in a spectral range from 0.35 to 5.2 μm, generating image cubes in which each pixel represents a spectrum consisting of 352 contiguous wavebands.As an imaging spectrometer VIMS combines the characteristics of both a spectrometer and an imaging instrument. This makes it possible to analyze the spectrum of each pixel separately and to map the spectral characteristics spatially, which is important to study the relationships between spectral information and geological and geomorphologic surface features.The spatial analysis of the spectral data requires the determination of the exact geographic position of each pixel on the specific surface and that all 352 spectral elements of each pixel show the same region of the target. We developed a method to reproject each pixel geometrically and to convert the spectral data into map projected image cubes. This method can also be applied to mosaic different VIMS observations. Based on these mosaics, maps of the spectral properties for each Saturnian satellite can be derived and attributed to geographic positions as well as to geological and geomorphologic surface features. These map-projected mosaics are the basis for all further investigations.  相似文献   

8.
G.J. Black  D.B. Campbell 《Icarus》2007,191(2):702-711
We have measured the bulk radar reflectance properties of the mid-size saturnian satellites Rhea, Dione, Tethys, and Enceladus with the Arecibo Observatory's 13 cm wavelength radar system during the 2004 through 2007 oppositions of the Saturn system. Comparing to the better studied icy Galilean satellites, we find that the total reflectivities of Rhea and Tethys are most similar to Ganymede while Dione is most similar to Callisto. Enceladus' reflectivity falls between those of Ganymede and Europa. The mean circular polarization ratios of the saturnian satellites range from ∼0.8 to 1.2, and are on average lower than those of the icy Galilean satellites at this wavelength although still larger than expected for single reflections off the surface. The ratio for the trailing hemisphere of Enceladus may be the exception with a value ?0.56. The 13 cm wavelength radar albedos and polarization ratios may be systematically lower than similar results from the Cassini orbiter's RADAR instrument at 2.2 cm wavelength [Ostro, S.J., and 19 colleagues, 2006. Icarus 183, 479-490]. Overall, these reflectivities and polarization properties, together with the shapes of the echo spectra, suggest subsurface multiple scattering to be the dominant reflection mechanism although operating less efficiently than on the large icy moons of Jupiter. All these saturnian moons and icy jovian moons are atmosphere-less, low temperature water ice surfaces, and any differences in radar properties may be indicative of differences in composition or the effects of various processes that modify the regolith structure. The degree of variation in radar properties with wavelength on each satellite may constrain the thickness and efficiency of the scattering layer.  相似文献   

9.
In this paper we will summarize some of the most important results of the Cassini mission concerning the satellites of Saturn. The Cassini Mission was launched in October 1997 on a Titan IV-Centaur rocket from Cape Canaveral. Cassini mission was always at risk of cancelation during its development but was saved many times thanks to the great international involvement. The Cassini mission is in fact a NASA-ESA-ASI project. The main effort was made by NASA, which provided the launch facilities, the integration and several instruments; ESA provided the Huygens probe while ASI some of the key elements of the mission such as the high-gain antenna, most of the radio system and important instruments of the Orbiter, such as the Cassini Radar and the visual channel of the VIMS experiment. ASI contributed also to the development of HASI experiment on Huygens probe. The Cassini mission was the first case in which the Italian planetology community was directly involved, developing state of the art hardware for a NASA mission. Given the long duration of the mission, the complexity of the payload onboard the Cassini Orbiter and the amount of data gathered on the satellites of Saturn, it would be impossible to describe all the new discoveries made, therefore we will describe only some selected, paramount examples showing how Cassini’s data confirmed and extended ground-based observations. In particular we will describe the achievements obtained for the satellites Phoebe, Enceladus and Titan. We will also put these examples in the perspective of the overall evolution of the system, stressing out why the selected satellites are representative of the overall evolution of the Saturn system. Cassini is also an example of how powerful could be the coordination between ground-based and space observations. In fact coordinated ground-based observations of Titan were performed at the time of Huygens atmospheric probe mission at Titan on 14 January 2005, connecting the in situ observations by the probe with the general view provided by ground-based measurements. Different telescopes operating at different wavelengths were used, including radio telescopes (up to 17-tracking of the Huygens signal at 2040 MHz), eight large optical observatories studying the atmosphere and surface of Titan, and high-resolution infrared spectroscopy used to observe radiation emitted during the Huygens Probe entry (Witasse et al. J. Geophys. Res. 111:E07S01, 2006).  相似文献   

10.
Cassini VIMS has obtained spatially resolved imaging spectroscopy data on numerous satellites of Saturn. A very close fly-by of Dione provided key information for solving the riddle of the origin of the dark material in the Saturn system. The Dione VIMS data show a pattern of bombardment of fine, sub-0.5-μm diameter particles impacting the satellite from the trailing side direction. Multiple lines of evidence point to an external origin for the dark material on Dione, including the global spatial pattern of dark material, local patterns including crater and cliff walls shielding implantation on slopes facing away from the trailing side, exposing clean ice, and slopes facing the trailing direction which show higher abundances of dark material. Multiple spectral features of the dark material match those seen on Phoebe, Iapetus, Hyperion, Epimetheus and the F-ring, implying the material has a common composition throughout the Saturn system. However, the exact composition of the dark material remains a mystery, except that bound water and, tentatively, ammonia are detected, and there is evidence both for and against cyanide compounds. Exact identification of composition requires additional laboratory work. A blue scattering peak with a strong UV-visible absorption is observed in spectra of all satellites which contain dark material, and the cause is Rayleigh scattering, again pointing to a common origin. The Rayleigh scattering effect is confirmed with laboratory experiments using ice and 0.2-μm diameter carbon grains when the carbon abundance is less than about 2% by weight. Rayleigh scattering in solids is also confirmed in naturally occurring terrestrial rocks, and in previously published reflectance studies. The spatial pattern, Rayleigh scattering effect, and spectral properties argue that the dark material is only a thin coating on Dione's surface, and by extension is only a thin coating on Phoebe, Hyperion, and Iapetus, although the dark material abundance appears higher on Iapetus, and may be locally thick. As previously concluded for Phoebe, the dark material appears to be external to the Saturn system and may be cometary in origin. We also report a possible detection of material around Dione which may indicate Dione is active and contributes material to the E-ring, but this observation must be confirmed.  相似文献   

11.
Images of the icy Saturnian satellites Mimas, Enceladus, Tethys, Dione, Rhea, Iapetus, and Phoebe, derived by the Voyager and Cassini cameras are used to produce new local high-resolution image mosaics as well as global mosaics [http://ciclops.org, http://photojournal.jpl.nasa.gov]. These global mosaics are valuable both for scientific interpretation and for the planning of future flybys later in the ongoing Cassini orbital tour. Furthermore, these global mosaics can be extended to standard cartographic products.  相似文献   

12.
Three weeks prior to the commencement of Cassini's 4 year tour of the saturnian system, the spacecraft executed a close flyby of the outer satellite Phoebe. The infrared channel of the Visual Infrared Mapping Spectrometer (VIMS) obtained images of reflected light over the 0.83-5.1 μm spectral range with an average spectral resolution of 16.5 nm, spatial resolution up to 2 km, and over a range of solar phase angles not observed before. These images have been analyzed to derive fundamental photometric parameters including the phase curve and phase integral, spectral geometric albedo, bolometric Bond albedo, and the single scattering albedo. Physical properties of the surface, including macroscopic roughness and the single particle phase function, have also been characterized. Maps of normal reflectance show the existence of two major albedo regimes in the infrared, with gradations between the two regimes and much terrain with substantially higher albedos. The phase integral of Phoebe is 0.29±0.03, with no significant wavelength dependence. The bolometric Bond albedo is 0.023±007. We find that the surface of Phoebe is rough, with a mean slope angle of 33°. The satellite's surface has a substantial forward scattering component, suggesting that its surface is dusty, perhaps from a history of outgassing. The spectrum of Phoebe is best matched by a composition including water ice, amorphous carbon, iron-bearing minerals, carbon dioxide, and Triton tholin. The characteristics of Phoebe suggest that it originated outside the saturnian system, perhaps in the Kuiper Belt, and was captured on its journey inward, as suggested by Johnson and Lunine (2005).  相似文献   

13.
The surface composition of Titan is of great importance for understanding both the internal evolution of Titan and its atmosphere. The Visual and Infrared Mapping Spectrometer (VIMS) investigation on Cassini is observing Titan from 0.35 to 5.11 μm with spatial resolution down to a few kilometers during each flyby of the spacecraft as it orbits Saturn. Our search for spectral diversity using seven methane transmission windows in the near infrared suggests that spectrally distinct units exist on the surface of Titan and that most of the surface can be modeled using only a few distinct spectral units: water frost, CO2 frost, atmospheric scattering, and an unknown material bright at 2 μm. A dark, spectrally neutral material is also implied. Use of an atmospheric scattering component with spectral mixing analysis may provide a method for partially removing atmospheric effects. In some locations, atmospheric scattering accounts for the majority of the signal. There are also small regions with unusual spectra that may be due to low signal and high noise and/or may be exotic materials of interest. Further, we searched within the methane windows for spectral features associated with Titan's surface. Only the 5-μm and, to a lesser extent, the 2-μm window provide a reasonable opportunity for this, as the shorter-wavelength windows are too narrow and the 2.8-μm window is cluttered with an unknown atmospheric constituent. We find evidence for only one spectral feature: near 4.92 μm for the 5-μm bright Tui Regio region. CO2 frost with grains smaller than about 10 μm is the best candidate we have found so far to explain this absorption as well as the feature's spectral contrast between the 2.7- and the 2.8-μm atmosphere subwindows. This suggested CO2 identification is supported by the presence of an endmember in the spectral mixture analysis that is consistent with CO2 frost with large grain sizes. We find no other absorption features that are statistically significant, including those reported earlier by others. These results are consistent with but greatly extend our early analysis that treated only the Ta data set [McCord, T.B., et al., 2006a. Planet. Space Sci. 54, 1524-1539]. In the spectral feature search process, we explored in detail the noise characteristics of the VIMS data within the 5-μm window, which has generally very low signal (4-20 DN), due to the measurement conditions and low illumination levels. We find noise of nearly Gaussian statistics except for some erratic darks and noise spikes, and the data set seems generally well behaved. We present examples of our attempt to improve on the standard VIMS pipeline data calibration.  相似文献   

14.
The surface of Enceladus consists almost completely of water ice. As the band depths of water ice absorptions are sensitive to the size of particles, absorptions can be used to map variations of icy particles across the surface. The Visual and Infrared Mapping Spectrometer (VIMS) observed Enceladus with a high spatial resolution during three Cassini flybys in 2005 (orbits EN 003, EN 004 and EN 011). Based on these data we measured the band depths of water ice absorptions at 1.04, 1.25, 1.5, and 2 μm. These band depths were compared to water ice models that represent theoretically calculated reflectance spectra for a range of particle diameters between 2 μm and 1 mm. The agreement between the experimental (VIMS) and model values supports the assumption that pure water ice characterizes the surface of Enceladus and therefore that variations in band depth correspond to variations in water ice particle diameters. Our measurements show that the particle diameter of water ice increases toward younger tectonically altered surface units with the largest particles exposed in relatively “fresh” surface material. The smallest particles were generally found in old densely cratered terrains. The largest particles (∼0.2 mm) are concentrated in the so called “tiger stripes” at the south pole. In general, the particle diameters are strongly correlated with geologic features and surface ages, indicating a stratigraphic evolution of the surface that is caused by cryovolcanic resurfacing and impact gardening.  相似文献   

15.
The results of ground-based spectrophotometry of the icy Galilean satellites of Jupiter—Europa, Ganymede, and Callisto—are discussed. The observations were carried out in the 0.39–0.92 μm range with the use of the CCD spectrometer mounted on the 1.25-m telescope of the Crimean laboratory of the Sternberg Astronomical Institute in March 2004. It is noted that the calculated reflectance spectra of the satellites mainly agree with the analogous data of the earlier ground-based observations and investigations in the Voyager and Galileo space missions. The present study was aimed at identifying new weak absorption bands (with the relative intensity of ～3–5%) in the reflectance spectra of these bodies with laboratory measurements (Landau et al., 1962; Ramaprasad et al., 1978; Burns, 1993; Busarev et al., 2008). It has been ascertained that the spectra of all of the considered objects contain weak absorption bands of molecular oxygen adsorbed into water ice, which is apparently caused by the radiative implantation of O+ ions into the surface material of the satellites in the magnetosphere of Jupiter. At the same time, spectral features of iron of different valence (Fe2+ and Fe3+) values typical of hydrated silicates were detected on Ganymede and Callisto, while probable indications of methane of presumably endogenous origin, adsorbed into water ice, were found on Europa. The reflectance spectra of the icy Galilean satellites were compared to the reflectance spectra of the asteroids 51 Nemausa (C-class) and 92 Undina (X-class).  相似文献   

16.
The photometry of mutual occultations and eclipses of natural planetary satellites can be used to infer very accurate astrometric data. This can be achieved by processing the light curves of the satellites observed during international campaigns of photometric observations of these mutual events.
This work focuses on processing the complete data base of photometric observations of the mutual occultations and eclipses of the Galilean satellites made during the international campaign in 2002–2003. The final goal is to derive new accurate astrometric data.
We propose the most accurate photometric model of mutual events based on all the data available to date about the satellites, and develop the corresponding method for extracting astrometric data. This method is applied to derive astrometric data from photometric observations of mutual occultations and eclipses of the Galilean satellites.
We process the 371 light curves obtained during the international campaign of photometric observations of the Galilean satellites in 2002–2003. As compared with the theory, the rms 'O-C' residuals with respect to theory is equal to 0.055 and 0.064 arcsec in right ascension and declination, respectively, for the 274 best observations. Topocentric or heliocentric angular differences for satellite pairs are obtained for 119 time instants during the time period from 2002 October 10 to 2003 July 17.  相似文献   

17.
Material of low geometric albedo (pV?0.1) is found on many objects in the outer Solar System, but its distribution in the saturnian satellite system is of special interest because of its juxtaposition with high-albedo ice. In the absence of clear, diagnostic spectral features, the composition of this low-albedo (or “dark”) material is generally inferred to be carbon-rich, but the form(s) of the carbon is unknown. Near-infrared spectra of the low-albedo hemisphere of Saturn's satellite Iapetus were obtained with the Visible-Infrared Mapping Spectrometer (VIMS) on the Cassini spacecraft at the fly-by of that satellite of 31 December 2004, yielding a maximum spatial resolution on the satellite's surface of ∼65 km. The spectral region 3-3.6 μm reveals a broad absorption band, centered at 3.29 μm, and concentrated in a region comprising about 15% of the low-albedo surface area. This is identified as the CH stretching mode vibration in polycyclic aromatic hydrocarbon (PAH) molecules. Two weaker bands attributed to CH2 stretching modes in aliphatic hydrocarbons are found in association with the aromatic band. The bands most likely arise from aromatic and aliphatic units in complex macromolecular carbonaceous material with a kerogen- or coal-like structure, similar to that in carbonaceous meteorites. VIMS spectra of Phoebe, encountered by Cassini on 11 June 2004, also show the aromatic hydrocarbon band, although somewhat weaker than on Iapetus. The origin of the PAH molecular material on these two satellites is unknown, but PAHs are found in carbonaceous meteorites, cometary dust particles, circumstellar dust, and interstellar dust.  相似文献   

18.
Several of the icy satellites of Saturn show the spectroscopic signature of the asymmetric stretching mode of C-O in carbon dioxide (CO2) at or near the nominal solid-phase laboratory wavelength of 4.2675 μm (2343.3 cm−1), discovered with the Visible-Infrared Mapping Spectrometer (VIMS) on the Cassini spacecraft. We report here on an analysis of the variation in wavelength and width of the CO2 absorption band in the spectra of Phoebe, Iapetus, Hyperion, and Dione. Comparisons are made to laboratory spectra of pure CO2, CO2 clathrates, ternary mixtures of CO2 with other volatiles, implanted and adsorbed CO2 in non-volatile materials, and ab initio theoretical calculations of CO2 * nH2O. At the wavelength resolution of VIMS, the CO2 on Phoebe is indistinguishable from pure CO2 ice (each molecule’s nearby neighbors are also CO2) or type II clathrate of CO2 in H2O. In contrast, the CO2 band on Iapetus, Hyperion, and Dione is shifted to shorter wavelengths (typically ∼4.255 μm (∼2350.2 cm−1)) and broadened. These wavelengths are characteristic of complexes of CO2 with different near-neighbor molecules that are encountered in other volatile mixtures such as with H2O and CH3OH, and non-volatile host materials like silicates, some clays, and zeolites. We suggest that Phoebe’s CO2 is native to the body as part of the initial inventory of condensates and now exposed on the surface, while CO2 on the other three satellites results at least in part from particle or UV irradiation of native H2O plus a source of C, implantation or accretion from external sources, or redistribution of native CO2 from the interior.The analysis presented here depends on an accurate VIMS wavelength scale. In preparation for this work, the baseline wavelength calibration for the Cassini VIMS was found to be distorted around 4.3 μm, apparently as a consequence of telluric CO2 gas absorption in the pre-launch calibration. The effect can be reproduced by convolving a sequence of model detector response profiles with a deep atmospheric CO2 absorption profile, producing distorted detector profile shapes and shifted central positions. In a laboratory blackbody spectrum used for radiance calibration, close examination of the CO2 absorption profile shows a similar deviation from that expected from a model. These modeled effects appear to be sufficient to explain the distortion in the existing wavelength calibration now in use. A modification to the wavelength calibration for 13 adjacent bands is provided. The affected channels span about 0.2 μm centered on 4.28 μm. The maximum wavelength change is about 10 nm toward longer wavelength. This adjustment has implications for interpretation of some of the spectral features observed in the affected wavelength interval, such as from CO2, as discussed in this paper.  相似文献   

19.
The Cassini Visual and Infrared Mapping Spectrometer (VIMS) is an imaging spectrometer covering the wavelength range 0.3-5.2 μm in 352 spectral channels, with a nominal instantaneous field of view of 0.5 mrad. The Cassini flyby of Jupiter represented a unique opportunity to accomplish two important goals: scientific observations of the jovian system and functional tests of the VIMS instrument under conditions similar to those expected to obtain during Cassini's 4-year tour of the saturnian system. Results acquired over a complete range of visual to near-infrared wavelengths from 0.3 to 5.2 μm are presented. First detections include methane fluorescence on Jupiter, a surprisingly high opposition surge on Europa, the first visual-near-IR spectra of Himalia and Jupiter's optically-thin ring system, and the first near-infrared observations of the rings over an extensive range of phase angles (0-120°). Similarities in the center-to-limb profiles of H+3 and CH4 emissions indicate that the H+3 ionospheric density is solar-controlled outside of the auroral regions. The existence of jovian NH3 absorption at 0.93 μm is confirmed. Himalia has a slightly reddish spectrum, an apparent absorption near 3 μm, and a geometric albedo of 0.06±0.01 at 2.2 μm (assuming an 85-km radius). If the 3-μm feature in Himalia's spectrum is eventually confirmed, it would be suggestive of the presence of water in some form, either free, bound, or incorporated in layer-lattice silicates. Finally, a mean ring-particle radius of 10 μm is found to be consistent with Mie-scattering models fit to VIMS near-infrared observations acquired over 0-120° phase angle.  相似文献   

20.
The nominal tour of the Cassini mission enabled the first spectra and solar phase curves of the small inner satellites of Saturn. We present spectra from the Visual Infrared Mapping Spectrometer (VIMS) and the Imaging Science Subsystem (ISS) that span the 0.25-5.1 μm spectral range. The composition of Atlas, Pandora, Janus, Epimetheus, Calypso, and Telesto is primarily water ice, with a small amount (∼5%) of contaminant, which most likely consists of hydrocarbons. The optical properties of the “shepherd” satellites and the coorbitals are tied to the A-ring, while those of the Tethys Lagrangians are tied to the E-ring of Saturn. The color of the satellites becomes progressively bluer with distance from Saturn, presumably from the increased influence of the E-ring; Telesto is as blue as Enceladus. Janus and Epimetheus have very similar spectra, although the latter appears to have a thicker coating of ring material. For at least four of the satellites, we find evidence for the spectral line at 0.68 μm that Vilas et al. [Vilas, F., Larsen, S.M., Stockstill, K.R., Gaffley, M.J., 1996. Icarus 124, 262-267] attributed to hydrated iron minerals on Iapetus and Hyperion. However, it is difficult to produce a spectral mixing model that includes this component. We find no evidence for CO2 on any of the small satellites. There was a sufficient excursion in solar phase angle to create solar phase curves for Janus and Telesto. They bear a close similarity to the solar phase curves of the medium-sized inner icy satellites. Preliminary spectral modeling suggests that the contaminant on these bodies is not the same as the exogenously placed low-albedo material on Iapetus, but is rather a native material. The lack of CO2 on the small inner satellites also suggests that their low-albedo material is distinct from that on Iapetus, Phoebe, and Hyperion.  相似文献   

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