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1.
This study analyzed 267 landslide landforms (LLs) in the Kumamoto area of Japan from the database of about 0.4 million LLs for the whole of Japan identified from aerial photos by the National Research Institute for Earth Science and Disaster Resilience of Japan (NIED). Each LL in the inventory is composed of a scarp and a moving mass. Since landslides are prone to reactivation, it is important to evaluate the sliding-recurrence susceptibility of LLs. One possible approach to evaluate the susceptibility of LLs is slope stability analysis. A previous study found a good correlation (R 2 = 0.99) between the safety factor (F s ) and slope angle (α) of F s  = 17.3α ?0.843. We applied the equation to the analysis of F s for 267 LLs in the area affected by the 2016 Kumamoto earthquake (M j  = 7.3). The F s was calculated for the following three cases of failure: scarps only, moving mass only, and scarps and moving mass together. Verification with the 2016 Kumamoto earthquake event shows that the most appropriate method for the evaluation of LLs is to consider the failure of scarps and moving mass together. In addition, by analyzing the relationship between the factors of slope of entire landslide and slope of scarp for LLs and comparing the results with the Aso-ohashi landslide, the largest landslide caused by the 2016 Kumamoto earthquake, we also found that morphometric analysis of LLs is useful for forecasting the travel distance of future landslides.  相似文献   

2.
Global climate change has increased the frequency of abnormally high rainfall; such high rainfall events in recent years have occurred in the mountainous areas of Taiwan. This study identifies historical earthquake- and typhoon-induced landslide dam formations in Taiwan along with the geomorphic characteristics of the landslides. Two separate groups of landslides are examined which are classified as those that were dammed by river water and those that were not. Our methodology applies spatial analysis using geographic information system (GIS) and models the geomorphic features with 20?×?20 m digital terrain mapping. The Spot 6 satellite images after Typhoon Morakot were used for an interpretation of the landslide areas. The multivariate statistical analysis is also used to find which major factors contribute to the formation of a landslide dam. The objective is to identify the possible locations of landslide dams by the geomorphic features of landslide-prone slopes. The selected nine geomorphic features include landslide area, slope, aspect, length, width, elevation change, runout distance, average landslide elevation, and river width. Our four geomorphic indexes include stream power, form factor, topographic wetness, and elevation–relief ratio. The features of the 28 river-damming landslides and of the 59 non-damming landslides are used for multivariate statistical analysis by Fisher discriminant analysis and logistic regression analysis. The principal component analysis screened out eleven major geomorphic features for landslide area, slope, aspect, elevation change, length, width, runout distance, average elevation, form factor, river width, stream power, and topography wetness. Results show that the correctness by Fisher discriminant analysis was 68.0 % and was 70.8 % by logistic regression analysis. This study suggests that using logistic regression analysis as the assessment model for identifying the potential location of a landslide dam is beneficial. Landslide threshold equations applying the geomorphic features of slope angle, angle of landslide elevation change, and river width (H L/W R) to identify the potential formation of natural dams are proposed for analysis. Disaster prevention and mitigation measures are enhanced when the locations of potential landslide dams are identified; further, in order to benefit such measures, dam volume estimates responsible for breaches are key.  相似文献   

3.
Amending landslides inventories is immensely important to policy and decision makers alike. Sliding creates geometric shapes on the Earth’s surface. This study presents the utilization of LiDAR high-resolution digital elevation model (DEM) in the Alborz Mountains, Iran to refurbish the existing landslide inventory dataset by implementing the proposed algorithm. The method consists of the automated derivation of landslide geometry (length, width, and area) followed by classification of landslide types considering length, width and flow direction. This study has used the trapezoidal rule for numerical integration to develop the proposed algorithm. The landslides were then classified into four types (very long, long, very wide, and wide) based on slope, length, and width. This geometric classification of landslides is based on the geographical coordinates, slope angle (θ), length (L), and width (W), and further failure flow direction. A total of 95 landslides were updated from the existing inventory database. The proposed method was verified and evaluated by field observations; and 14 samples were tested to determine the relative error. The results demonstrated that the mean percentage relative error is 0.496% in length and width and 0.008% in area, related to the GIS analysis. The accuracy performance of determining the landslide’s type is 92%. The purposefulness of this algorithm is to increase the accuracy performance of landslides geometry analysis and automated measurements associated with the usual GIS platforms such as ArcGIS.  相似文献   

4.
This research represents a novel soft computing approach that combines the fuzzy k-nearest neighbor algorithm (fuzzy k-NN) and the differential evolution (DE) optimization for spatial prediction of rainfall-induced shallow landslides at a tropical hilly area of Quy Hop, Vietnam. According to current literature, the fuzzy k-NN and the DE optimization are current state-of-the-art techniques in data mining that have not been used for prediction of landslide. First, a spatial database was constructed, including 129 landslide locations and 12 influencing factors, i.e., slope, slope length, aspect, curvature, valley depth, stream power index (SPI), sediment transport index (STI), topographic ruggedness index (TRI), topographic wetness index (TWI), Normalized Difference Vegetation Index (NDVI), lithology, and soil type. Second, 70 % landslide locations were randomly generated for building the landslide model whereas the remaining 30 % landslide locations was for validating the model. Third, to construct the landslide model, the DE optimization was used to search the optimal values for fuzzy strength (fs) and number of nearest neighbors (k) that are the two required parameters for the fuzzy k-NN. Then, the training process was performed to obtain the fuzzy k-NN model. Value of membership degree of the landslide class for each pixel was extracted to be used as landslide susceptibility index. Finally, the performance and prediction capability of the landslide model were assessed using classification accuracy, the area under the ROC curve (AUC), kappa statistics, and other evaluation metrics. The result shows that the fuzzy k-NN model has high performance in the training dataset (AUC?=?0.944) and validation dataset (AUC?=?0.841). The result was compared with those obtained from benchmark methods, support vector machines and J48 decision trees. Overall, the fuzzy k-NN model performs better than the support vector machines and the J48 decision trees models. Therefore, we conclude that the fuzzy k-NN model is a promising prediction tool that should be used for susceptibility mapping in landslide-prone areas.  相似文献   

5.
The Kualiangzi landslide was triggered by heavy rainfalls in the “red beds” area of Sichuan Basin in southwestern China. Differing from other bedrock landslides, the movement of the Kualiangzi landslide was controlled by the subvertical cracks and a subhorizontal bedding plane (dip angle < 10°). The ingress of rainwater in the cracks formed a unique groundwater environment in the slope. Field measurement for rainfall, groundwater movement, and slope displacement has been made for the Kualiangzi landslide since 2013. The field monitoring system consists of two rainfall gauges, seven piezometers, five water-level gauges, and two GPS data loggers. The equipments are embedded near a longitudinal section of the landslide, where severe deformation has been observed in the past 3 years. The groundwater responses to four heavy rainfall events were analyzed between June 16 and July 24 in 2013 coincided with the flood season in Sichuan. Results showed that both of the water level and the pore-water pressure increased after each rainfall event with delay in the response time with respect to the precipitation. The maximum time lag reached 35 h occurred in a heavy rainfall event with cumulative precipitation of 127 mm; such lag effect was significantly weakened in the subsequent heavy rainfall events. In each presented rainfall event, longer infiltration period in the bedrock in the upper slope increased the response time of groundwater, compared to that of in the gravels in the lower slope. A translational landslide conceptual model was built for the Kualiangzi landslide, and the time lag was attributed to the gradual formation of the uplift pressure on the slip surface and the softening of soils at the slip surface. Another important observation is the effect on the slope movement which was caused by the water level (H w) in the transverse tension trough developed at the rear edge of the landslide. Significant negative correlation was found for H w and the slope stability factor (F s), in particular for the last two heavy rainfall events, of which the drastic increase of water level caused significant deterioration in the slope stability. The rapid drop (Δ?=?22.5 kPa) of pore-water pressure in the deep bedrock within 1 h and the large increase (Δ?=?87.3 mm) of surficial displacement were both monitored in the same period. In the end, a four-level early warning system is established through utilizing H w and the displacement rate D r as the warning indicators. When the large deformation occurred in flood season, the habitants at the leading edge of the landslide can be evacuated in time.  相似文献   

6.
The b-value of the Gutenberg–Richter’s frequency–magnitude relation and the p-value of the modified Omori law, which describes the decay rate of aftershock activity, were investigated for more than 500 aftershocks in the Aksehir-Afyon graben (AAG) following the 15 December 2000 Sultandagi–Aksehir and the 3 February 2002 Çay–Eber and Çobanlar earthquakes. We used the Kandilli Observatory’s catalog, which contains records of aftershocks with magnitudes ≥2.5. For the Çobanlar earthquake, the estimated b-values for three aftershock sequences are in the range 0.34 ≤  b ≤ 2.85, with the exception of the one that occurred during the first hour (4.77), while the obtained p-values are in the range 0.44 ≤ p ≤ 1.77. The aftershocks of the Sultandagi earthquake have a high p-value, indicating fast decay of the aftershock activity. A regular increase of b can be observed, with b < 1.0 after 0.208 days for the Çay–Eber earthquake. A systematic and similar increase and decrease pattern exists for the b- and p-values of the Çobanlar earthquakes during the first 5 days.  相似文献   

7.
The South Jingyang Plateau, with a total area of 70 km2, is located in Shaanxi Province, China. Since 1976, more than 50 landslides of different types have occurred repeatedly on the edge slopes of the plateau due to the start of diversion irrigation on the plateau, resulting in great loss of lives and property. To better understand the initiation and movement mechanisms of these loess landslides, we surveyed them and carried out a detailed investigation of a large landslide in the Xihetan area. Our field survey results revealed that although most of these landslides had a long runout with high mobility, most of the landslide materials originating from the edge slopes may have been in an unsaturated state when the landslide occurred. This suggests that the materials at the toe of the edge slope as well as on the travel path along the river terrace might have played a key role in landslide movement. To examine how the materials on the travel path were involved in the landsliding, we used a multichannel surface wave technique and surveyed shear wave velocity (V s ) profiles of the landslide deposits. We also examined the internal geometry of the deposits that outcropped on the right-side slope of the landslide foot. The longitudinal profile of V s along the direction of movement showed that terrace deposits near the toe of the edge slope may have been sheared upward, indicating that at the toe, the surface of rupture might be located inside the terrace deposits. The V s contours showed an A-shaped fold within the landslide deposits in the middle part of the travel path and became greater in the most distal toe part. The V s profile across the deposits showed a U-shaped belt, in which the soil layers have smaller V s . This belt may be the boundary between the sliding landslide debris and terrace deposits. The observed internal geometry of the landslide deposits indicates that a sliding surface developed within the sandy layer underlying the gravel layer. Therefore, we inferred that after failure, the displaced landslide materials overrode and sheared the terrace deposits along its main sliding direction, resulting in the formation of thrust folds within the terrace deposits, and greater V s on the distal toe part of the landslide.  相似文献   

8.
This paper presents a new region-based preparatory factor, total flux (TF), for landslide susceptibility models (LSMs). TF takes into account the topography and hydrology conditions upstream of each gridded data cell and represents the total flux of water in the stream. The results show that TF is strongly associated with the occurrence of landslides and is a good preparatory factor for LSM. Using TF instead of a drainage distance factor in I-Lan region in Taiwan shows an improvement in the accuracy of the cumulative percentage of landslide occurrence of 44 and 14 % for the top 1 and 10 % susceptible areas, respectively. This significant improvement in accuracy in these high-risk areas is critical for preventing and mitigating the economic and human losses due to landslides.  相似文献   

9.
The high-pressure behavior of a vanadinite (Pb10(VO4)6Cl2, a = b = 10.3254(5), = 7.3450(4) Å, space group P63/m), a natural microporous mineral, has been investigated using in-situ HP-synchrotron X-ray powder diffraction up to 7.67 GPa with a diamond anvil cell under hydrostatic conditions. No phase transition has been observed within the pressure range investigated. Axial and volume isothermal Equations of State (EoS) of vanadinite were determined. Fitting the PV data with a third-order Birch-Murnaghan (BM) EoS, using the data weighted by the uncertainties in P and V, we obtained: V 0 = 681(1) Å3, K 0 = 41(5) GPa, and K′ = 12.5(2.5). The evolution of the lattice constants with P shows a strong anisotropic compression pattern. The axial bulk moduli were calculated with a third-order “linearized” BM-EoS. The EoS parameters are: a 0 = 10.3302(2) Å, K 0(a) = 35(2) GPa and K′(a) = 10(1) for the a-axis; c 0 = 7.3520(3) Å, K 0(c) = 98(4) GPa, and K′(c) = 9(2) for the c-axis (K 0(a):K 0(c) = 1:2.80). Axial and volume Eulerian-finite strain (fe) at different normalized stress (Fe) were calculated. The weighted linear regression through the data points yields the following intercept values: Fe a (0) = 35(2) GPa for the a-axis, Fe c (0) = 98(4) GPa for the c-axis and Fe V (0) = 45(2) GPa for the unit-cell volume. The slope of the regression lines gives rise to K′ values of 10(1) for the a-axis, 9(2) for the c-axis and 11(1) for the unit cell-volume. A comparison between the HP-elastic response of vanadinite and the iso-structural apatite is carried out. The possible reasons of the elastic anisotropy are discussed.  相似文献   

10.
The results of hydrodynamical calculations of radially pulsating helium stars with masses 0.5MM≤0.9M, bolometric luminosities 600L≤5×103L, and effective temperatures 1.5×104 K≤Teff≤3.5×104 K are presented. The pulsation instability of these stars is due to the effects of ionization of iron-group elements in layers with temperatures T~2×105 K. The calculations were carried out using opacities for the relative mass abundances of hydrogen and heavy elements X=0 and Z=0.01, 0.015, and 0.02. Approximate formulas for the pulsation constant Q over the entire range of pulsation instability of the hot helium stars in terms of the mass M, radius R, effective temperature Teff, and heavy-element abundance Z are derived. The instability of BX Cir to radial pulsations with the observed period Π=0.1066 d occurs only for a mass M≥0.55M, effective temperature Teff≥23000 K, and heavy-element abundance Z≥0.015. The allowed mass of BX Cir is in the range 0.55MM≤0.8M, which corresponds to luminosities 800LM≤1400L and mean radii 1.7R?R?2.1R.  相似文献   

11.
The elastic and structural behaviour of the synthetic zeolite CsAlSi5O12 (= 16.753(4), = 13.797(3) and = 5.0235(17) Å, space group Ama2, Z = 2) were investigated up to 8.5 GPa by in situ single-crystal X-ray diffraction with a diamond anvil cell under hydrostatic conditions. No phase-transition occurs within the P-range investigated. Fitting the volume data with a third-order Birch–Murnaghan equation-of-state gives: V 0 = 1,155(4) Å3, K T0 = 20(1) GPa and K′ = 6.5(7). The “axial moduli” were calculated with a third-order “linearized” BM-EoS, substituting the cube of the individual lattice parameter (a 3, b 3, c 3) for the volume. The refined axial-EoS parameters are: a 0 = 16.701(44) Å, K T0a = 14(2) GPa (βa = 0.024(3) GPa?1), K′ a = 6.2(8) for the a-axis; b 0 = 13.778(20) Å, K T0b = 21(3) GPa (βb = 0.016(2) GPa?1), K′ b = 10(2) for the b-axis; c 0 = 5.018(7) Å, K T0c = 33(3) GPa (βc = 0.010(1) GPa?1), K′ c = 3.2(8) for the c-axis (K T0a:K T0b:K T0c = 1:1.50:2.36). The HP-crystal structure evolution was studied on the basis of several structural refinements at different pressures: 0.0001 GPa (with crystal in DAC without any pressure medium), 1.58(3), 1.75(4), 1.94(6), 3.25(4), 4.69(5), 7.36(6), 8.45(5) and 0.0001 GPa (after decompression). The main deformation mechanisms at high-pressure are basically driven by tetrahedral tilting, the tetrahedra behaving as rigid-units. A change in the compressional mechanisms was observed at ≤ 2 GPa. The P-induced structural rearrangement up to 8.5 GPa is completely reversible. The high thermo-elastic stability of CsAlSi5O12, the immobility of Cs at HT/HP-conditions, the preservation of crystallinity at least up to 8.5 GPa and 1,000°C in elastic regime and the extremely low leaching rate of Cs from CsAlSi5O12 allow to consider this open-framework silicate as functional material potentially usable for fixation and deposition of Cs radioisotopes.  相似文献   

12.
On 8th August 2017, a magnitude Ms 7.0 earthquake struck the County of Jiuzhaigou, in Sichuan Province, China. It was the third Ms ≥?7.0 earthquake in the Longmenshan area in the last decade, after the 2008 Ms 8.0 Wenchuan earthquake and the 2013 Ms 7.0 Lushan earthquake. The event did not produce any evident surface rupture but triggered significant mass wasting. Based on a large set of pre- and post-earthquake high-resolution satellite images (SPOT-5, Gaofen-1 and Gaofen-2) as well as on 0.2-m-resolution UAV photographs, a polygon-based interpretation of the coseismic landslides was carried out. In total, 1883 landslides were identified, covering an area of 8.11 km2, with an estimated total volume in the order of 25–30?×?106 m3. The total landslide area was lower than that produced by other earthquakes of similar magnitude with strike-slip motion, possibly because of the limited surface rupture. The spatial distribution of the landslides was correlated statistically to a number of seismic, terrain and geological factors, to evaluate the landslide susceptibility at regional scale and to identify the most typical characteristics of the coseismic failures. The landslides, mainly small-scale rockfalls and rock/debris slides, occurred mostly along two NE-SW-oriented valleys near the epicentre. Comparatively, high landslide density was found at locations where the landform evolves from upper, broad valleys to lower, deep-cut gorges. The spatial distribution of the coseismic landslides did not seem correlated to the location of any known active faults. On the contrary, it revealed that a previously-unknown blind fault segment—which is possibly the north-western extension of the Huya fault—is the plausible seismogenic fault. This finding is consistent with what hypothesised on the basis of field observations and ground displacements.  相似文献   

13.
The area of investigation was subject to multifactor analysis of the relationship between the maximum amount of mudflow solid sediments (W) and parameters such as the mudflow basin area (S), average channel slope (α), and mudflow channel length (L). They were used to obtain analytical expressions in order to approximate the W(S, L, α) relation based on the mudflow genesis and source height. Statistical data on mudflow manifestations in different basins in the North Caucasus covering more than fifty years were used to obtain the analytical expressions in order to assess the maximum volume of mudflow solid sediments.  相似文献   

14.
The Junipers phoenicea, which covers 70 % of the Jabal Al Akhdar (Green Mountain) in Cyrene on the northeast coast of Libya, has deteriorated over large scales. To deal with this problem, the images of the Landsat 7 Enhanced Thematic Mapper Plus (ETM+) and Landsat 8 Operational Land Imager (OLI) in conjunction with the Shuttle Radar Topography Mission (SRTM) digital elevation model (DEM) were used to map factors controlling the J. phoenicea mortality using a set of automated algorithms and tools. These factors include altitude, slope, aspect, curvature, drainage pattern, seawater intrusion, and land cover. As a first step, changes of J. phoenicea and land cover during the period from the year 2000 to 2015 were mapped. The results showed a sharp decline in J. phoenicea covering an area of 396 km2 (22 %) of the total area. The result also showed that areas at a lower elevation with steep slope and faced to the south and southeast directions have a higher probability of J. phoenicea distribution. The spatial analysis showed a positive correlation between wetness and the intensity of J. phoenicea mortality. The results also show that altitude and slope have the most influencing power on the J. phoenicea morality. This study is of great help for decision makers and agriculture engineers and permits a better understanding of ecological and biomass changes in the Jabal Al Akhdar, Libya, over a regional scale.  相似文献   

15.
The specific energy (SE) is the most important parameter to estimate the energy consumption in tunnel boring machines (TBMs). It is defined as the amount of required energy to excavate a unit volume of rock mass which used to predict the performance of TBMs. Several models are used to estimate the SE based on different parameters such as the rock mass properties, disc cutter dimensions and cutting geometry. The aim of this work is to propose new relations between the SE and the strain energy of rock mass (W) using the geological mappings of rock mass and TBM operational parameters from Amir-Kabir Water Transferring Tunnel of Iran. W is an appropriate criterion to estimate SE because it is a function of different parameters such as rock mass behavior, pre and post failure properties and peak and residual strains. In this study, to increase the correlation coefficient of relation between the mentioned parameters, the rock mass is classified in two methods, in the first method according to the geological strength index (GSI) all data is classified in three classes such as weak, fair and good and in the second method using the drop to deformation modulus ratio (η) the classification of data is performed in three classes such as η < 0.05, 0.05 ≤ η < 10 and η ≥ 10. The results show that there are direct relations between both parameters. It is suggested to estimate SE in all rock mass classes using the proposed relations based on GSI classification.  相似文献   

16.
The M w 7.8 2015 Gorkha earthquake and its aftershocks significantly impacted the lives and economy of Nepal. The consequences of landslides included fatalities, property losses, blockades of river flow, and damage to infrastructural systems. Co-seismic landslides triggered by this earthquake were significantly widespread and pose a major geodisaster. There were tens of thousands of landslides triggered by the earthquake, majority of which were distributed in between the epicenter of the main shock and the M w 7.3 aftershock. Although 14,670 landslides triggered by this earthquake were identified, only approximately 23% of them were of moderate to large scale with areas greater than 100 m2. Of the moderate- to large-scale landslides identified, just over 90% were triggered by the main shock and smaller aftershocks prior to the major (M w 7.3) aftershock, while nearly 10% were triggered by the ground shaking induced by the major aftershock. Moreover, the number of landslides triggered by the 2015 Gorkha earthquake, specifically by the main shock, was slightly more than the expected number of landslides for the recorded maximum peak ground acceleration (PGA) in comparison to the co-seismic landslides triggered by 26 earthquakes. Over 90% of those moderate- to large-scale landslides were concentrated within the estimated fault rupture surface. Majority of these moderate- to large-scale landslides were disrupted failures with over 96% of which were classified as earth falls. However, the majority of small-scale landslides were rock or boulder falls. The most number of moderate- to large-scale landslides were triggered in the slate, shale, siltstone, phyllite, and schist of the Lesser Himalayan formation followed by an equally significant number in both schist, gneiss, etc. of the Higher Himalayan formation and the phyllite, metasandstone, schist, etc. of the Lesser Himalayan formation. The sizes (i.e., areas) of the landslides were lognormally distributed, with a mode area of 322.0 m2. Slope inclinations of the moderate- to large-scale landslides followed a normal distribution with a mean slope inclination of 32.6° and standard deviation of 13.5°. There exists a strong correlation between the number of landslides and the peak ground acceleration within the study area, specific for different geological formations.  相似文献   

17.
Fine sediment inputs can alter estuarine ecosystem structure and function. However, natural variations in the processes that regulate sediment transport make it difficult to predict their fate. In this study, sediments were sampled at different times (2011–2012) from 45 points across intertidal sandflat transects in three New Zealand estuaries (Whitford, Whangamata, and Kawhia) encompassing a wide range in mud (≤63 μm) content (0–56 %) and macrofaunal community structure. Using a core-based erosion measurement device (EROMES), we calculated three distinct measures of sediment erosion potential: erosion threshold (? c ; N m?2), erosion rate (ER; g m?2 s?1), and change in erosion rate with increasing bed shear stress (m e ; g N?1 s?1). Collectively, these measures characterized surface (? c and ER) and sub-surface (m e ) erosion. Benthic macrofauna were grouped by functional traits (size and motility) and data pooled across estuaries to determine relationships between abiotic (mud content, mean grain size) and biotic (benthic macrofauna, microbial biomass) variables and erosion measures. Results indicated that small bioturbating macrofauna (predominantly freely motile species <5 mm in size) destabilized surface sediments, explaining 23 % of the variation in ? c (p ≤ 0.01) and 59 % of the variation in ER (p ≤ 0.01). Alternatively, mud content and mean grain size cumulatively explained 61 % of the variation in m e (p ≤ 0.01), where increasing mud and grain size stabilized sub-surface sediments. These results highlight that the importance of biotic and abiotic predictors vary with erosion stage and that functional group classifications are a useful way to determine the impact of benthic macrofauna on sediment erodibility across communities with different species composition.  相似文献   

18.
A Cs-bearing polyphase aggregate with composition (in wt%): 76(1)CsAlSi5O12 + 7(1)CsAlSi2O6 + 17(1)amorphous, was obtained from a clinoptilolite-rich epiclastic rock after a beneficiation process of the starting material (aimed to increase the fraction of zeolite to 90 wt%), cation exchange and then thermal treatment. CsAlSi5O12 is an open-framework compound with CAS topology; CsAlSi2O6 is a pollucite-like material with ANA topology. The thermal stability of this polyphase material was investigated by in situ high-T X-ray powder diffraction, the combined PT effects by a series of runs with a single-stage piston cylinder apparatus, and its chemical stability following the “availability test” (“AVA test”) protocol. A series of additional investigations were performed by WDS–electron microprobe analysis in order to describe the PT-induced modification of the material texture, and to chemically characterize the starting material and the run products. The “AVA tests” of the polyphase aggregate show an extremely modest release of Cs+: 0.05 mg/g. In response to applied temperature and at room P, CsAlSi5O12 experiences an unquenchable and displacive Ama2-to-Amam phase transition at about 770 K, and the Amam polymorph is stable in its crystalline form up to 1600 K; a crystalline-to-amorphous phase transition occurs between 1600 and 1650 K. In response to the applied P = 0.5 GPa, the crystalline-to-amorphous transition of CsAlSi5O12 occurs between 1670 and 1770 K. This leads to a positive Clapeyron slope (i.e., dP/dT > 0) of the crystalline-to-amorphous transition. When the polyphase aggregate is subjected at P = 0.5 GPa and T > 1770 K, CsAlSi5O12 melts and only CsAlSi2O6 (pollucite-like; dominant) and Cs-rich glass (subordinate) are observed in the quenched sample. Based on its thermo-elastic behavior, PT phase stability fields, and Cs+ retention capacity, CsAlSi5O12 is a possible candidate for use in the immobilization of radioactive isotopes of Cs, or as potential solid hosts for 137Cs γ-radiation source in sterilization applications. More in general, even the CsAlSi5O12-rich aggregate obtained by a clinoptilolite-rich epiclastic rock appears to be suitable for this type of utilizations.  相似文献   

19.
Rainfall-induced landslides (RILs) have been a source of social and economic disruption in the mountainous Baguio area in northern Philippines. Prolonged heavy rainfall usually happens during tropical cyclone and southwest monsoon activity. A pragmatic approach to RIL mitigation is to develop rainfall-based early warning. We implemented a modified regression method to derive the empirical minimum intensity (I)–duration (D) threshold I = 6.46 D ?0.28 and a normalized ID threshold NI = 0.002 D ?0.28 for rainfall duration ranging between 24 and 264 h. Using a separate data set to evaluate the applicability of the threshold, 93% of the landslide-triggering rainfall events fell above the derived threshold. RILs also occurred when 24-h rainfall was 0.02–28% of the mean annual precipitation or after accumulating at least 500 mm of rainfall from the onset of the rainy season. The thresholds may be further refined as more landslide data become available in the future.  相似文献   

20.
A pyroxene with composition LiNiSi2O6 was synthesized at T = 1,473 K and P = 2.0 GPa; the cell parameters at T = 298 K are a = 9.4169(6) Å, b = 8.4465(7) Å, c = 5.2464(3) Å, β = 110.534(6)°, V = 390.78(3) Å3. TEM examination of the LiNiSi2O6 pyroxene showed the presence of h + k odd reflections indicative of a primitive lattice, and of antiphase domains obtained by dark field imaging of the h + k odd reflections. A HT in situ investigation was performed by examining TEM selected area diffraction patterns collected at high temperature and synchrotron radiation powder diffraction. In HTTEM the LiNiSi2O6 was examined together with LiCrSi2O6 pyroxene. In LiCrSi2O6 the h + k odd critical reflections disappear at about 340 K; they are sharp up to the transition temperature and do not change their shape until they disappear. In LiNiSi2O6 the h + k odd reflections are present up to sample deterioration at 650 K. A high temperature synchrotron radiation powder diffraction investigation was performed on LiNiSi2O6 between 298 and 773 K. The analysis of critical reflections and of changes in cell parameters shows that the space group is P-centred up to the highest temperature. The comparative analysis of the thermal and spontaneous strain contributions in P21/c and C2/c pyroxenes indicates that the high temperature strain in P-LiNiSi2O6 is very similar to that due to thermal strain only in C2/c spodumene and that a spontaneous strain contribution related to pre-transition features is not apparent in LiNiSi2O6. A different high-temperature behaviour in LiNiSi2O6 with respect to other pyroxenes is suggested, possibly in relation with the presence of Jahn–Teller distortion of the M1 polyhedron centred by low-spin Ni3+.  相似文献   

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