The evolution of charged particles in a model of contracting cloud     

M. S. El-Nawawy  M. Y. Amin 《Earth, Moon, and Planets》1996,75(1):41-51

The evolution of the charged particles are followed during contraction of a model of an interstellar cloud, with initial density number of n = 10 cm^–3. The contraction is followed up to density increase by five orders of magnitude. Special care is given to the details of the negative ions. In addition, we have tested the ambipolar diffusion according to the results of the ion density.The results predict the importance of atomic ions in the diffuse regions. H⁺ and C⁺ are distinctly enhanced in the beginning of contraction but decrease as contraction proceeds. Molecular ions enhance as contraction proceeds and becomes important in dense regions. The most enhanced molecular ions are HCO⁺, O₂ ⁺, C₂H₃ ⁺, H₃O⁺ and SO⁺, H₃ ⁺ is less abundant. The atomic ions (except metalic ions) decrease noticeably as density increases. In general the negative ions are of negligible fractional abundances. It has also been found that the time of ambipolar diffusion is shorter than the dynamical time, hence the magnetic field should be weakened in the central core as the central density increases to n = 10⁴ cm^–3.  相似文献   

Time dependent chemical study of contracting interstellar clouds. II. abundances of oxygen- and sulphur-bearing molecules     

M. Y. Amin  M. S. El Nawawy  B. G. Ateya  A. Aiad 《Earth, Moon, and Planets》1995,69(2):113-125

Abstract. We have constructed a chemical reaction system in a contracting interstellar cloud. In paper (I) we have presented the details of the physical and chemical scheme and the method of solution. The results of our chemical model produce fractional abundances of H₂CO, CO, OH, H₂O, SO and OCS which are in good agreement with the results of observations. On the other hand, the results of chlorine-bearing species are not in agreement with those of the observations. The calculated abundances of H₂CO, CO, OH, H₂O, SO, OCS and Cl⁺ are in agreement with the results of previous theoretical studies.  相似文献   

Time dependent chemical study of contracting interstellar clouds. I. Abundances of nitrogen- and carbon-bearing molecules     

M. Y. Amin  M. S. El Nawawy  B. G. Ateya  A. Aiad 《Earth, Moon, and Planets》1995,69(2):95-112

We have constructed a reaction system containing the chemical families of H, C, O, N, S, Si, Cl, metals (Me) and grains. A total of 104 species have been included and a network of 557 reactions has been studied. The chemical kinetic equations were integrated as a function of time by using gear program. The chemical reaction system was followed at low, intermediate and high cloud densities i.e. from 10–10⁷ particles cm^-3. The calculated fractional abundances of N₂, CN, HCN, and CH which are in good agreement with the results of observations and with those of previous theoretical studies.  相似文献   

Deuterium enrichment of the interstellar medium     

《New Astronomy》2015

Despite the low elemental abundance of atomic deuterium in the interstellar medium (ISM), observational evidence suggests that several species, both in the gas phase and in ices, could be heavily fractionated. We explore various aspects of deuterium enrichment by constructing a chemical evolution model in both gaseous and granular phases. Depending on various physical parameters, gases and grains are allowed to interact with each other through the exchange of their chemical species. It is known that HCO⁺ and N₂H⁺ are two abundant gas phase ions in the ISM and, their deuterium fractionation is generally used to predict the degree of ionization in the various regions of a molecular cloud. For a more accurate estimation, we consider the density profile of a collapsing cloud. The radial distributions of important interstellar molecules, along with their deuterated isotopomers, are presented. Quantum chemical simulations are computed to study the effects of isotopic substitution on the spectral properties of these interstellar species. We calculate the vibrational (harmonic) frequencies of the most important deuterated species (neutral and ions). The rotational and distortional constants of these molecules are also computed in order to predict the rotational transitions of these species. We compare vibrational (harmonic) and rotational transitions as computed by us with existing experimental and theoretical results. It is hope that our results will assist observers in detecting several hitherto unobserved deuterated species.  相似文献   

Shock waves and the chemical structure of interstellar clouds     

M. Y. Amin  M. S. El-Nawawy  M. A. El-Shalaby 《Astrophysics and Space Science》1991,185(2):277-294

In this paper we study the effect of shock waves on the chemical structure of the interstellar clouds. A model of molecular cloud has been assumed. The chemistry is investigated in a time dependent model. Our chemical network contains 56 species in 251 reactions to including molecules of the elements H, O, C, N, S, and Si.The results indicate that the calculated fractional abundance of the molecules NS, H₂O, CN, NH, CO, and SO agrees well with the observations. The molecules OH, H₂S, CS, H₂CS, HS, NO, SiO, CH, CH₂, CH₃, HCO, C₂, and HCN reach high post-shock abundances.  相似文献   

The chemical evolution in a model of contracting cloud     

M. Y. Amin  M. S. El-Nawawy 《Earth, Moon, and Planets》1996,75(1):25-39

The evolution of the different chemical species are followed in a model of contracting interstellar cloud. The central density increases from n = 10 cm^–3 diffuse initial cloud model to a dense cloud with central density number of n >- 10⁵ cm^–3 after a time of 1.2 × 10⁷ yr. A network of 622 reactions has been involved. The chemistry of the cloud is integrated simultaneously with the hydrodynamic equations of contraction.The results predict that the different molecular species increase in abundance as the contraction proceeds. The species which enhance significantly are CO, HCO, CS and NO. The fractional abundances of many of the other molecular species increase distinctly with contraction, e.g. CH, C₂H, CN, SO₂, CO₂, H₂O, C₂, NH₃, HCN, SO, OCS and SN. The transformation of the initial diffuse cloud model with small abundances of molecular species to a dense molecular cloud with enhancement of the different molecular species is confirmed. The results predict good agreements of our results with both the observations and other theoretical studies.  相似文献   

Multifluid models of shocks in magnetized interstellar molecular clouds     

T. W. Hartquist 《Astrophysics and Space Science》1995,233(1-2):97-109

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Chemical diagnostics of magnetized boundary layers     

L. A. M. Nejad  T. W. Hartquist 《Astrophysics and Space Science》1994,220(2):253-260

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The C+, C,CO network in interstellar clouds     

J. B. Pickles  D. A. Williams 《Astrophysics and Space Science》1981,80(2):337-347

A chemical network determining the formation and destruction of C⁺, C, and CO and other species is set up and applied to spherical clouds in the normal interstellar radiation field. The spherical geometry adopted gives results which are different from those for slab models. The sensitivity of chemical species to chemical and astronomical parameters is explored. The relevance of this work to the observations is discussed.  相似文献   

Gravitational instability of interstellar magnetic clouds     

K. K. Ghosh  J. C. Bhattacharyya 《Astrophysics and Space Science》1985,117(1):89-94

The gravitational instability of a nonrotating isothermal gaseous disk permeated by a uniform frozen-in magnetic field is investigated using a fourth-order perturbation technique. From the results it is found that the disk is stable whenn/B ₀ < (4/3³ G)^–1/2, wheren andB are the column density of the disk and unperturbed magnetic field, respectively, andG is the gravitational constant. The disk is gravitationally unstable only whenn/B ₀ > (4/3³ G)^–1/2.  相似文献   

Molecules in the early universe     

B. Novosyadlyj  O. Sergijenko  V. M. Shulga 《Kinematics and Physics of Celestial Bodies》2017,33(6):255-264

The formation of first molecules, negative Hydrogen ions, and molecular ions in a model of the Universe with cosmological constant and cold dark matter is studied. The cosmological recombination is described in the framework of modified model of the effective 3-level atom, while the kinetics of chemical reactions is described in the framework of the minimal model for Hydrogen, Deuterium, and Helium. It is found that the uncertainties of molecular abundances caused by the inaccuracies of computation of cosmological recombination are approximately 2–3%. The uncertainties of values of cosmological parameters affect the abundances of molecules, negative Hydrogen ions, and molecular ions at the level of up to 2%. In the absence of cosmological reionization at redshift z = 10, the ratios of abundances to the Hydrogen one are 3.08 × 10^–13 for H^–, 2.37 × 10^–6 for H₂, 1.26 × 10^–13 for H₂⁺, 1.12 × 10^–9 for HD, and 8.54 × 10^–14 for HeH⁺.  相似文献   

Identification of some diffuse interstellar features     

W. W. Duley 《Astrophysics and Space Science》1982,88(2):501-505

Twenty-eight of the thirty-nine diffuse interstellar bands identified by Herbig (1975) are shown to constitute three vibronic systems with origins at 14 321, 15 153, and 15 343 cm^–1 (vac). Structure within these three systems arises from the excitation of vibrational modes withv ₁=275 cm^–1,v ₂=445.5 cm^–1, andv ₃=793 cm^–1. The electronic origins at 14 321 and 15 343 cm^–1 correspond to narrow lines observed in the spectrum of Cr³⁺ ions at cubic sites in MgO solids while the 15 153 cm^–1 origin arises in Mn⁴⁺ : MgO. Hence, many of the diffuse bands in the visible likely are due to small MgO particles containing these ions. This observation is compatible with recent experimental data showing broad bands at 160 nm and 220 nm from finely divided MgO solids that match features in the interstellar extinction curve.  相似文献   

Gas-Phase Chemistry of the Star Forming Region W3 IRS4     

Magdy Y. Amin 《Astrophysics and Space Science》1998,260(3):405-420

We have followed the chemistry of W3 IRS4, as one of the most famous regions with a chemistry similar to that found in quiescent molecular clouds. Here the time scale, since star formation, has probably been long enough for the gas-phase ion-molecule chemistry to become dominant again. We have constructed a reaction system containing the chemical families of H, C, O, N, S and metals (Me:Fe, Mg, Na and Si). A total of 282 species have been included and a network of 1270 reactions has been used. The chemical kinetic equations were integrated as a function of pseudo-time-dependent approach. The evolution of the different chemical species are followed in models of density n equal to 10⁶ cm^-3 and temperature T equal to 55 K. Different initial abundances have been assumed. Our results are in reasonable agreement with the observation, especially in Model 6. The resulting molecular abundances are compared with those obtained in the intermediate mass star NGC 2264 IRS1, as well as the low mass IRAS 16293-2422. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Evidence for a large population of shocked interstellar clouds     

V. Radhakrishnan  G. Srinivasan 《Journal of Astrophysics and Astronomy》1980,1(1):47-66

A 21 cm absorption measurement over a long path length free of the effects of differential galactic rotation indicates the existence of two distinct cloud populations in the plane. One of them consisting of cold, dense clouds has been well studied before. The newly found hot clouds appear to be at least five times more numerous. They have a spin temperature of ~ 300 K, an rms velocity of ~ 35 km s^-1, twice the total mass, and hundred times the kinetic energy of the cold clouds. Over long path lengths, the hot clouds haveN _H/kpc ~ 2 X 10²¹ cm^-2 Kpc^-1, and are estimated to have individual column densities ≤ 10²⁰ cm^-2. We propose that they are shocked clouds found only within supernova bubbles and that the cold clouds are found in the regions in-between old remnants, immersed in an intercloud medium. We conclude that the solar neighbourhood must be located between old supernova remnants rather than within one.  相似文献   

Radial distribution of production rates, loss rates and densities corresponding to ion masses ?40 amu in the inner coma of Comet Halley: Composition and chemistry     

S.A. Haider 《Icarus》2005,177(1):196-216

In this paper we have studied the chemistry of C, H, N, O, and S compounds corresponding to ions of masses ?40 amu in the inner coma of the Comet 1P/Halley. The production rates, loss rates, and ion mass densities are calculated using the Analytical Yield Spectrum approach and solving coupled continuity equation controlled by the steady state photochemical equilibrium condition. The primary ionization sources in the model are solar EUV photons, photoelectrons, and auroral electrons of the solar wind origin. The chemical model couples ion-neutral, electron-neutral, photon-neutral and electron-ion reactions among ions, neutrals, electrons, and photons through over 600 chemical reactions. Of the 46 ions considered in the model the chemistry of 24 important ions (viz., CH₃OH⁺₂, H₃CO⁺, NH⁺₄, H₃S⁺, H₂CN⁺, H₂O⁺, NH⁺₃, CO⁺, C₃H⁺₃, OH⁺, H₃O⁺, CH₃OH⁺, C₃H⁺₄, C₂H⁺₂, C₂H⁺, HCO⁺, S⁺, CH⁺₃, H₂S⁺, O⁺, C⁺, CH⁺₄, C⁺₂, and O⁺₂) are discussed in this paper. At radial distances <1000 km, the electron density is mainly controlled by 6 ions, viz., NH⁺₄, H₃O⁺, CH₃OH⁺₂, H₃S⁺, H₂CN⁺, and H₂O⁺, in the decreasing order of their relative contribution. However, at distances >1000 km, the 6 major ions are H₃O⁺, CH₃OH⁺₂, H₂O⁺, H₃CO⁺, C₂H⁺₂, and NH⁺₄; along with ions CO⁺, OH⁺, and HCO⁺, whose importance increases with further increase in the radial distance. It is found that at radial distances greater than ∼1000 km (±500 km) the major chemical processes that govern the production and loss of several of the important ions in the inner coma are different from those that dominate at distances below this value. The importance of photoelectron impact ionization, and the relative contributions of solar EUV, and auroral and photoelectron ionization sources in the inner coma are clearly revealed by the present study. The calculated ion mass densities are compared with the Giotto Ion Mass Spectrometer (IMS) and Neutral Mass Spectrometer (NMS) data at radial distances 1500, 3500, and 6000 km. There is a reasonable agreement between the model calculation and the Giotto measurements. The nine major peaks in the IMS spectra between masses 10 and 40 amu are reproduced fairly well by the model within a factor of two inside the ionopause. We have presented simple formulae for calculating densities of the nine major ions, which contribute to the nine major peaks in the IMS spectra, throughout the inner coma that will be useful in estimating their densities without running the complex chemical models.  相似文献   

Deep high spectral resolution spectroscopy and chemical composition of ionized nebulae     

C. Esteban  J. García‐Rojas  A. Mesa‐Delgado  L. Toribio San Cipriano 《Astronomische Nachrichten》2014,335(1):73-78

High spectral resolution spectroscopy has proved to be very useful for the advancement of chemical abundances studies in photoionized nebulae, such as H II regions and planetary nebulae (PNe). Classical analyses make use of the intensity of bright collisionally excited lines (CELs), which have a strong dependence on the electron temperature and density. By using high resolution spectrophotometric data, our group has led the determination of chemical abundances of some heavy element ions, mainly O⁺⁺, O⁺, and C⁺⁺ from faint recombination lines (RLs), allowing us to deblend them from other nearby emission lines or sky features. The importance of these lines is that their emissivity depends weakly on the temperature and density structure of the gas. The unresolved issue in this field is that recombination lines of heavy element ions give abundances that are about 2–3 times higher than those derived from CELs – in H II regions – for the same ion, and can even be a factor of 70 times higher in some PNe. This uncertainty puts into doubt the validity of face values of metallicity that we use as representative not only for ionized nebulae in the Local Universe, but also for star‐forming dwarf and spiral galaxies at different redshifts. Additionally, high‐resolution data can allow us to detect and deblend faint lines of neutron capture element ions in PNe. This information would introduce further restrictions to evolution models of AGBs and would help to quantify the chemical enrichment in s‐elements produced by low and intermediate mass stars. The availability of an échelle spectrograph at the E‐ELT will be of paramount interest to: (a) extend the studies of heavyelement recombination lines to low metallicity objects, (b) to extend abundance determinations of s‐elements to planetary nebulae in the extragalactic domain and to bright Galactic and extragalactic H II regions. (© 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

Ion composition and chemistry in the coma of Comet 1P/Halley—A comparison between Giotto's Ion Mass Spectrometer and our ion-chemical network     

Martin Rubin  Kenneth C. Hansen  Michael R. Combi  Hans Balsiger 《Icarus》2009,199(2):505-519

In order to understand the cometary plasma environment it is important to track the closely linked chemical reactions that dominate ion evolution. We used a coupled MHD ion-chemistry model to analyze previously unpublished Giotto High Intensity Ion Mass Spectrometer (HIS-IMS) data. In this way we study the major species, but we also try to match some minor species like the CH_x and the NH_x groups. Crucial for this match is the model used for the electrons since they are important for ion-electron recombination. To further improve our results we included an enhanced density of supersonic electrons in the ion pile-up region which increases the local electron impact ionization. In this paper we discuss the results for the following important ions: C⁺, CH⁺, CH⁺₂, CH⁺₃, N⁺, NH⁺, NH⁺₂, NH⁺₃, NH⁺₄, O⁺, OH⁺, H₂O⁺, H₃O⁺, CO⁺, HCO⁺, H₃CO⁺, and CH₃OH⁺₂. We also address the inner shock which is very distinctive in our MHD model as well as in the IMS data. It is located just inside the contact surface at approximately 4550 km. Comparisons of the ion bulk flow directions and velocities from our MHD model with the data measured by the HIS-IMS give indication for a solar wind magnetic field direction different from the standard Parker angle at Halley's position. Our ion-chemical network model results are in a good agreement with the experimental data. In order to achieve the presented results we included an additional short lived inner source for the C⁺, CH⁺, and CH⁺₂ ions. Furthermore we performed our simulations with two different production rates to better match the measurements which is an indication for a change and/or an asymmetric pattern (e.g. jets) in the production rate during Giotto's fly-by at Halley's comet.  相似文献   

Silicon ion chemistry in the ionosphere     

E.E. Ferguson  D.W. Fahey  F.C. Fehsenfeld  D.L. Albritton 《Planetary and Space Science》1981,29(3):307-312

Loss processes which remove Si⁺ ions selectively relative to other meteor-derived atomic ions in the E- and D-regions of the ionosphere have been identified and measured in the laboratory. The major Si⁺ loss in the E-region is the reaction Si⁺ + H₂O → HSiO⁺ + H (1) with a rate constant 2.3 ± 0.9 × 10^?10 cm³s^?1 at 300 K. The corresponding reactions with Fe⁺, Mg⁺ and other metallic meteor ions are endothermic. Presumably (1) is followed by a fast dissociative-recombination with electrons to produce neutral SiO or Si. At lower altitudes Si⁺ ions associate in a three-body reaction with O₂ with a much larger rate constant than the corresponding associations of Fe⁺ and Mg⁺ with O₂.  相似文献   

Quantitative Analysis of H₂OComa Images Using a Multiscale MHD Model with Detailed Ion Chemistry     

Roman M. Häberli  Michael R. Combi  Tamas I. Gombosi  Darren L. De Zeeuw  Kenneth G. Powell 《Icarus》1997,130(2):373-386

The observation of ions created by ionization of cometary gas, either by ground-based observations or byin situmeasurements can give us useful information about the gas production and composition of comets. However, due to the interaction of ions with the magnetized solar wind and their high chemical reactivity, it is not possible to relate measured ion densities (or column densities) directly to the parent gas densities. In order to quantitatively analyze measured ion abundances in cometary comae it is necessary to understand their dynamics and chemistry. We have developed a detailed ion–chemical network of cometary atmospheres. We include production of ions by photo- and electron impact-ionization of a background neutral atmosphere, charge exchange of solar wind ions with cometary atoms/molecules, reactions between ions and molecules, and dissociative recombination of molecular ions with thermal electrons. By combining the ion–chemical network with the three-dimensional plasma flow as computed by a new fully three-dimensional MHD model of cometary plasma environments (Gombosiet al.1996) we are able to compute the density of the major cometary ions everywhere in the coma. The input parameters for our model are the solar wind conditions (density, speed, temperature, magnetic field) and the composition and production rate of the gas. We applied our model to Comet P/Halley in early March 1986, for which the input parameters are reasonably well known. We compare the resulting column density of H₂O⁺with ground-based observations of H₂O⁺from DiSantiet al.(1990). The results of our model are in good agreement with both the spatial distribution and the absolute abundance of H₂O⁺and with their variations with the changing overall water production rate between two days. The results are encouraging that it will be possible to obtain production rates of neutral cometary constituents from observations of their ion products.  相似文献   

Models of the cometary coma in which abundances are calculated for various heliocentric distances     

Michael B. Swift  George F. Mitchell 《Icarus》1981,47(3):412-430

One-dimensional radial models of the chemistry in cometary comae have been constructed for heliocentric distances ranging from 2 to 0.125 AU. The coma's opacity to solar radiation is included and photolytic reaction rates are calculated. A parent volatile mixture similar to that found in interstellar molecular clouds is assumed. Profiles through the coma of number density and column density are presented for H₂O, OH, O, CN, C₂, C₃, CH, and NH₂. Whole-coma abundances are presented for NH₂, CH, C₂, C₃, CN, OH, CO⁺, H₂O⁺, CH⁺, N₂⁺, and CO₂⁺.  相似文献