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1.
在水土耦合的室内原土环境中,通过微型贯入、扫描电镜(SEM)、能谱(EDS)分析、X射线衍射(XRD)、离子含量及pH值测试等多种试验手段,研究滨海相软土场地形成的水泥土强度的分布规律及其衰减过程,并阐明水泥土劣化层和未劣化层的发展规律。结果表明:水泥土劣化深度随养护时间的增长和水泥掺入比的减小不断增大,至360 d时最大劣化深度达到11.9 mm,明显大于同龄期海水环境中养护的水泥土的劣化深度;与未劣化层相比,劣化层的孔径增大,孔隙增多,水泥水化产物减少;经原土养护相同时间,水泥土中pH值及主要离子含量分布规律与室内海水环境中的水泥土相似,其中pH值和Ca~(2+)含量随着试样深度的增大而增大,而Mg~(2+)、SO_4~(2-)、Cl~-含量随试样深度的增大而减小;水泥土中Ca~(2+)含量沿试样深度方向的分布规律与强度变化规律相似。在原土条件下,水泥土中Ca的溶出更加显著,导致后期水泥土强度衰减加剧。原土中水泥土强度衰减过程与海水中相同。 相似文献
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莱州湾东南岸海水入侵区地下水中若干离子的主成分分析 总被引：7，自引：0，他引：7
运用主成分分析方法探讨了海水入侵对莱州湾东南岸地下水地球化学特征的影响。分析结果表明,第一主分量是海水入侵强度的量度,K^ 、Na^ 、Mg^2 、SO4^2-、Cl^-的正向负荷量大,它们的增加意味着海水入侵的加剧,这间接表明可以用以上指标监测地下水的海水入侵。第二主分量是在第一主分量表示的海水入侵强度大致相同的情况下,可逆反应CaCO3 CO2 H2O可逆反应Ca^2 HCO3^-进行情况的量度。Ca^2 、HCO3^-、pH在第二主分量上的负荷量最大,说明水中溶解的CO2显著影响这三者的数值。Ca^2 与HCO3^-负荷量的符号相反,说明两者在含量上是相互消长的。以相关系数为基础作聚类分析,K^ 、Na^ 、Mg^2 、SO4^2-、Cl^-明显地聚为一组,而后三项指标之间的距离较大,并与上述Cl^--K^ 组也保持较远的距离。 相似文献
3.
长期处于腐蚀场地中的水泥土等加固体会发生强度降低、渗透性增大的劣化现象,劣化的发生严重影响加固体的使用寿命。研究水泥土劣化随时间的演化规律及对劣化深度的预测,对于腐蚀地基中水泥土桩的长期承载力预测具有一定的理论和实际工程应用价值。利用室内试验模拟研究了场地环境变化引起的水泥土劣化问题。试验结果表明:水泥土劣化深度随浸泡时间的增加而增大,浸泡前期劣化速度快,后期劣化速度降低;水泥土初始强度越低劣化速度越快,当水泥土超过28 d强度后,劣化速度增加变慢,且趋于稳定。本文基于试验结果,提出了根据28 d劣化深度推测长期劣化深度的预测式,根据试验数据回归得到的待定参数A约在0.2～0.8之间,与腐蚀场地形成的水泥土劣化问题的0.5～0.7不同。 相似文献
4.
以莱州湾东岸为研究区,利用统计分析、相关性分析、Piper图、饱和指数以及离子比例等方法系统研究了该区的浅层地下水化学特征及盐化机理。结果表明,水化学参数Cl-、HCO3-和Ca2+离子浓度较高,而Mg2+、K+离子浓度很低,研究区硝酸盐污染严重,平均离子浓度高达172.88 mg/L,为劣五类水质;Cl-、SO42-、Na+和K+的离子浓度变异系数较大,是随环境变化的敏感因子,是决定地下水盐化的主要变量;该区地下水中Ca2+、Mg2+和Cl-占主要优势,地下水化学类型复杂,按阳离子主要划分为Ca、Ca·Mg(Ca·Mg·Na)、Ca·Na(Ca·Na·Mg)及Na·Ca型水;按阴离子主要有Cl、Cl·HCO3(HCO3·Cl)、HCO·Cl·SO4(Cl·HCO3·SO4)、Cl·SO4、Cl·SO4·HCO3以及HCO3·SO4·Cl(SO4·HCO3·Cl)型水;TDS质量浓度呈现显著的空间结构性特征,表现为从中部向两侧浓度逐渐升高,由海向陆TDS质量浓度逐渐降低,南部TDS质量浓度要显著大于北部;蒸发沉积、溶滤、阳离子交换作用以及人类活动的影响是浅层地下水盐化的主要控制因素;岩盐、白云石、方解石以及石膏等矿物是地下水常规离子的主要物源。 相似文献
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实施了水泥固化粉土和高岭土的室内渗透试验,在分析水泥土灰水比和龄期对渗透性影响的基础上,提出了不含拟合参数的水泥土长期渗透系数预测式。试验结果表明,与原土种类无关,同一龄期水泥土的渗透系数随灰水比的增大线性减小;粉土水泥土的渗透系数大于相同灰水比、相同龄期高岭土水泥土的渗透系数;水泥土渗透系数随灰水比的降低速率与原土的种类及龄期有关,粉土水泥土渗透系数随灰水比的降低速率大于相同龄期高岭土水泥土的渗透系数降低速率;与原土种类无关,水泥土的渗透系数随龄期的增大逐渐降低,在龄期超过28 d后,渗透系数随龄期的降低速率减小。预测式预测的结果基本反映了水泥土渗透系数随龄期的变化规律。 相似文献
7.
麻地沟遗址地处泥河湾盆地东部岑家湾台地古人类活动集中区,是近年来新发现和发掘的早更新世古人类活动遗址之一。对遗址湖滨相沉积物易溶盐类的测试和分析表明,此剖面代表的泥河湾古湖易溶盐为SO_4^(2-)-Na^+-HCO_3^--C^l-型,剖面平均含盐量为11.41‰,属于半咸水湖,处于半干旱区湖泊演化中后期的硫酸盐湖向氯化物湖的过渡阶段。K^+、Na^+、Ca^(2+)、Mg^(2+)、SO_4^(2-)和Cl^-等6类离子的变化曲线表现出较大的相似性,且它们与含盐量的变化大体一致。地层含盐量的变化和沉积物中细颗粒含量变化具有一致性,细颗粒含量较高对应含盐量相对较高时期。根据含盐量和各主要离子比值并结合平均粒径和磁化率的变化将湖泊气候演化划分为5个阶段,古人类在该遗址活动时期对应于湖泊演化的第2—4阶段,处于气候相对较为温湿、动植物资源丰富、湖水含盐量较低时期。该项研究对探讨麻地沟遗址利用者的生存行为与环境的关系具有重要意义。 相似文献
8.
通过对19个观测井2年定期、连续的水位观测,以及水质主要9种离子浓度分析,阐述了辽东湾西部沿岸海水入侵的分布特征。根据海水入侵区地下水中主要离子浓度与地下水的相关关系,总结了随着海水入侵的发展地下水化学类型的变化。地下水化学类型分为5大类型:Na+-Cl-型、Cl-.HCO3-或HCO3-.Cl-型(阳离子为Ca2+.Na+)、HCO3-.Cl-.SO42-或Cl-.HCO3-.SO42-型水(阳离子为Ca2+)、SO42-.HCO3-型(阳离子为Na+.Ca2+)、HCO3-型(阳离子为Ca2+.Na+)。该区地下水水化学类型呈带状分布,类型变化规律明显,反映了海水入侵分布特征。当淡水开采时,水位降深越大,微咸水入侵强度越大。控制淡水开采是防止微咸水入侵的主要措施。 相似文献
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螺旋桩芯劲性复合桩（helix stiffened cement mixing pile,简称HSCM桩）是一种新型复合桩,其成桩工艺会对桩身及其承载性能有较大影响。为验证HSCM桩在软黏土中同步旋进注浆工艺的可行性,并研究其成桩参数对抗压承载性能的影响,设计了2组缩尺模型试验,包括不同叶片数量与钻进速度的HSCM桩与对比螺旋桩。通过在高岭土制备的软黏土中成桩,并进行抗压承载性能及桩身几何尺寸测试,分析HSCM桩的成桩参数与水泥土桩身间的关系。试验结果表明：同步旋进注浆工艺能够在螺旋桩周围形成倒圆台状的水泥土桩身,水泥土桩身的平均黏结直径约为叶片直径的1.17～1.35倍;适当增加叶片数量能够使水泥与土体充分拌和,提高水泥土桩身的完整性与连续性,以改善HSCM桩的成桩质量;钻进速度大幅提高会导致注浆量不足,减小水泥土桩身的黏结直径与刚度;试验条件下HSCM桩的抗压极限承载力是螺旋桩的3.83～3.93倍,桩径扩大提高了侧摩阻力,注浆工艺加固并提高了土体强度,弥补了叶片在旋进过程中扰动土体造成强度降低的问题。 相似文献
11.
Zhang Dingwen Fan Libin Liu Songyu Deng Yongfeng 《Marine Georesources & Geotechnology》2013,31(4):360-374
Soft clay with high sodium chloride salt concentration is a problem encountered by geotechnical and highway engineers. Chemical stabilization using cement is an attractive method to improve the engineering properties of soft soil. However, very limited studies have been conducted to reveal the effect of salt concentration on the engineering properties of cement-stabilized soil and the reported results in literature are not consistent. The impact of sodium chloride salt on the strength and stiffness properties of cement-stabilized Lianyungang marine clay is studied in this study. The clay with various sodium chloride salt concentrations was prepared artificially and stabilized by various contents of Ordinary Portland cement. A series of unconfined compressive strength (UCS) tests of cement stabilized clay specimen after 7, 14, and 28 days curing periods were carried out. The results indicate that a high sodium chloride salt concentration has a detrimental effect on the UCS and stiffness of cement-stabilized clay. The detrimental effect of salt concentration on the strength and stiffness of cement-stabilized clay directly relates to cement content. Soils mixed with high cement content are more resistant to the negative effect of salts than soils mixed with low cement content. The ratio of modulus of elasticity to UCS of cement treated soil does not have an obvious relationship with salt concentration. The findings of this study present a rational basis for the understanding of the impact of salt on the engineering properties of cement-treated soil. 相似文献
12.
Dongxing Wang Mahfoud Benzerzour Hongwei Wang Nor-Edine Abriak 《Marine Georesources & Geotechnology》2020,38(9):1046-1055
AbstractA novel approach to mitigate the environmental concerns associated with cement industry is to replace Portland cement with low carbon alternative materials such as fly ash-based geopolymer cement. Hence, reactive MgO-activated low-calcium Class F fly ash was employed in comparison to Na2SO4-activated fly ash to stabilize a lacustrine soil reused potentially in soft coastal reclamation projects and as reinforced aggregates for anti-corrosion in marine engineering. The microstructural and strength properties were investigated with series of tests including X-ray diffraction (XRD), thermogravimetry/differential thermogravimetry (TG/DTG), mercury intrusion porosimetry (MIP), scanning electron microscopy (SEM), and unconfined compressive strength (UCS). The results demonstrate that the main hydration products in reactive MgO- and Na2SO4-fly ash-solidified soils are, respectively, magnesium silicate hydrate (M-S-H) gel and sodium aluminosilicate hydrate (N-A-S-H) gel. This finding is reconfirmed by the weight loss of solidified samples at 40–200?°C, which is correspondingly attributed to the dehydration of magnesium silicate hydrate (M-S-H) gel and sodium aluminosilicate hydrate (N-A-S-H) gel. The morphology and bonding ability of hydration products affects the microstructure and long-term strength of solidified soils. The microstructural change identified from SEM images coincides well with the quantitative evolution of pore structure. The pores with radius of 0.01–1?µm, i.e., micropore and mesopore, are supposed to be the dominant pores in reactive MgO- and Na2SO4-activated fly ash-solidified soils. The comparison of UCS indicates reactive MgO-activated low-Ca fly ash behaves much superior to Na2SO4-activated fly ash in enhancing the long-term compressive strength of soils. This study provides insight into the promising potential of low-Ca fly ash activated by immerging material – reactive MgO to replace cement in soil improvement. 相似文献
13.
A. Maher W. S. Douglas D. Yang F. Jafari V. R. Schaefer 《Marine Georesources & Geotechnology》2013,31(3-4):221-235
A preliminary study was conducted to determine the potential for cement deep soil mixing (CDSM) technology as a method for in-situ solidification of contaminated river and estuarine sediments. The study was conducted in Newark Bay, near the mouth of the Passaic River, New Jersey. The primary objective of the study was to evaluate the viability of CDSM for the in-situ S/S with a focus on: 1) determining the correct mix of the cement slurry, which provides rapid stabilization of the sediment matrix, 2) potential resuspension of solids during CSDM operations, 3) the effects of high organic content on the solidification process, and 4) the feasibility of using conventional dredging/extraction methods once the sediments have been stabilized and allowed to cure. The results of the study show CDSM slurry mixtures, as low as 7% in cement content, result in significant solidification and strength gain of in-situ sediments under ambient conditions. In sediments with very high organic contents (> 20%), the slurry mix would need to be adjusted to account for retardation effects of organics on cement hydration. Sediment resuspension during application was shown to be minimal at a distance of as little as 75 feet from the mixing head. Strength gains were considerable, effectively consolidating the sediment particles in a secure matrix, but not so high as to preclude extraction of solidified sediments with conventional dredging equipment. Dredged solidified sediment exhibited characteristics of a stiff glacial clay, and as such was easier to handle and transport than untreated dredged sediments. This technique has high potential to be used as an interim remedial measure prior to either extraction and decontamination/disposal or proper capping. 相似文献
14.
Dongxing Wang Xiangyun Gao Ruihong Wang Stefan Larsson Mahfoud Benzerzour 《Marine Georesources & Geotechnology》2020,38(6):659-671
AbstractAlkali-activated industrial by-products (granulated blast furnace slag, Class F fly ash) by traditional alkali activator (such as NaOH and Na2SiO3) serves as a partial replacement for Portland cement in soil stabilization projects and suffers from environmental and technical problems. Reactive MgO – a greener and more practical alternative has recently emerged as a potential activator for slag and fly ash, but its micromechanisms of alkaline activation still need to be deeply investigated for strength improvement of soils. Hence, this study focuses on the strength and hydration properties of reactive MgO-slag and MgO-fly ash solidified soils, especially incorporating the impact of elevated curing temperature. Reactive MgO is proved to be excellent as a novel activator for activation of slag and fly ash, and their activating efficiency increases with elevated curing temperature that helps to remarkably enhance the compressive strength of soils. The major hydration products for reactive MgO-slag solidified soils, detected jointly by X-ray diffraction, scanning electron microscopy and thermogravimetric/differential thermogravimetric tests, are calcium silicate hydrate gels and hydrotalcite-like phases. The primary hydration products for MgO-fly ash solidified soils are magnesium silicate hydrate gels and Mg(OH)2. That is just the intrinsic reason why the microstructure of solidified soils becomes much denser and the mechanical behavior is significantly improved. The minor carbonate phases such as magnesium carbonate and/or calcite are also observed in reactive MgO-slag and MgO-fly ash solidified soils, depending on the period of exposure to air. The curing temperature and binder amount are proved to be the two major factors governing the hydration process of reactive MgO-slag and MgO-fly ash blends. A higher curing temperature and binder amount can generate more hydration products, but their chemical compositions such as accurate element ratios need to be investigated in the future study. 相似文献
15.
Kaiwei Liu Yueming Wang Aiguo Wang Daosheng Sun Xingxing Chen 《Marine Georesources & Geotechnology》2020,38(7):844-853
AbstractDurability of cement-based materials for marine/coastal structures is an increasingly challenging problem. Sulfate ions in seawater can react with aluminate in cement to form erosion products, causing cracks and spalling. When cement is used to stabilize loose erodible sand in coastal areas, the resistance to sulfate attack is questionable. In this study, four cements with different aluminate contents were used to stabilize sand. Cement stabilized sands were immersed in 5% Na2SO4 solution for 300-days to simulate long-term sulfate attack process. The deterioration of engineering performance was evaluated based on expansion ratio, mass change, uniaxial compressive strength, and ultrasonic velocity. The deterioration mechanisms were analyzed through mineralogical and microstructural observations including X-ray diffraction, EDS, scanning electronic microscopy, and nuclear magnetic resonance. The results showed that the development of macro-scale mechanical performances could be divided into two stages (initial stage and erosion stage) when subjected to 300-days immersion in 5% Na2SO4 solution. Sand stabilized by low-aluminate-content cement displayed better engineering performance especially at the erosion stage. Mechanistically, more ettringite was formed in high-aluminate-content cement stabilized sand, leading to swelling and cracking. The formation of ettringite and gypsum were accompanied with the consumption of portlandite, leading to further strength loss. 相似文献
16.
Influence of Salinity on pH and Aluminum Concentration on the Interaction of Acidic Red Soil with Seawater 总被引：1，自引：0，他引：1
Contamination of acidic red soil in the coastal areas of Okinawa Islands is a serious environmental problem. This study was conducted to examine the effects of the salinity on pH and aluminum concentration when the acidic red soil interacts with seawater. Acidic red soil from Gushikawa recreation center was fractionated into bulk soil, coarse sand and silt + clay. Different weights of each fraction were equilibrated with seawater solutions. The pH and concentrations of Al3+, Na+, K+, Ca2+ and Mg2+ were then analyzed in the extracts. The results showed a decreasing trend of pH with increasing soil to solution ratio while the extracted Al3+ revealed an increasing trend. The lowest pH values were 3.85, 4.06, 4.41, 4.66 and their corresponding highest Al3+ concentrations were 2.50, 1.01, 0.062 and 0.036 mmolL−1 in the seawater extracts, one-tenth seawater extracts, one-hundredth seawater extracts and one-thousandth seawater solution extracts, respectively. Mostly, the concentrations of Na+, Ca2+, Mg2+ and especially K+ decreased with increasing soil weight in the high salinities but showed the opposite trend in the low salinity samples. Potassium concentration decreased by 39%, 53% and 40% in the seawater extracts, one-tenth and one-hundredth seawater extracts but increased by 200% in one-thousandth seawater extracts. The coincidence of the increase in Al3+ and H+ concentrations, and the decrease of Na+, K+, Ca2+ and Mg2+ concentrations in the solutions suggests ion exchange/adsorption, while the increased patterns, particularly at low salinity could be attributed to the dissolution of the species from the soils. 相似文献
17.
Bhim Kumar Dahal Rong-Jun Zhang Ding-Bao Song 《Marine Georesources & Geotechnology》2013,31(6):755-764
AbstractThe use of soft clay and dredged marine clays as the construction material is challenging. This is because the high water content, high compressibility and low permeability of the clay causing the instability of ground and structure. This detrimental effect of soft clay can be improved by the cement solidification process, which is relatively cheap and efficient. This paper mainly focuses on the study of improvement on the mechanical behavior of cement mixed marine clay. The soil is reconstituted by using ordinary Portland cement of 5%, 10%, 15% and 20% by its mass. The study reveals that cementation of clay significantly improves the peak and residual strength of soil. Similarly, the primary yield stress of the soil is also improved from 16 to 275?kPa as cement content increases from 5% to 20%, respectively. By using statistical tools, the relationships between various parameters are established, which are very important to define the mechanical behavior of the clay. This study reveals that the yield surface of the solidified marine clay is not a smooth elliptical surface. Rather it is composed of two linear surfaces followed by a log-linear surface which can be modeled by using simple parameters obtained from triaxial tests. 相似文献
18.
波浪作用下埕岛海域海底土液化分区 总被引：1，自引：0，他引：1
根据埕岛海域表层沉积物特征,结合该区的波浪实测资料推算的波浪要素,利用动三轴实验得到研究区土体在循环荷载作用下孔隙水压力的增长与振动次数的关系,计算研究区内海底土层的液化可能性和液化所需的时间,并根据土体在不同水深情况下达到液化所需的时间对研究海域进行了液化分区。结果显示,7-8 m等深线之间的海底土体由于受到波浪破碎作用的影响,最易发生液化,液化影响深度也最深,自该海域向近岸和远海,液化可能性降低;土层埋深为2.5 m以浅时,研究区大部分区域液化可能性为高,而到埋深为4 m时土层液化可能性明显降低。 相似文献
19.
Ayşe Pekrioglu Balkis 《Marine Georesources & Geotechnology》2020,38(1):73-82
AbstractThis study investigated the penetrability of high volume fly ash cement suspensions prepared with and without superplasticizer into sandy soil having different relative densities with 30%, 60%, 73%, and 83% through permeation grouting. Class C fly ash was used due to its pozzolanic activity and fineness. Due to engineering characteristics and cost, cementitious grouts are the most commonly used grout in both waterproofing and ground strengthening. Fly ash-cement grouts have relatively constant and low viscosity values for a reasonable period after preparation, exhibit limited or negligible bleed capacity and set and develop satisfactory strength within a relatively short period. Modeling of grouting of soil was done in laboratory and improvements in physical and mechanical properties of grouted soil were analyzed. Unconfined compressive strength, shear strength and permeability characteristics of grouted soil were studied as a result. Unconfined compressive strength values of grouted sand with high volume fly ash ranged between 410 and 1107?kPa. Morover, cohesion values were comparable to microfine cement grouting ranging from 373 to 511?kPa. Furthermore, permeability values were also approximately equal to the permeability of impervious liners, which is around 1?×?10?7?cm/s. The findings support the applicability of grouting in different applications. 相似文献
20.
Kai Yao Dongliang An Na Li Chen Zhang Aizhao Zhou 《Marine Georesources & Geotechnology》2020,38(2):250-255
AbstractA series of direct shear tests were performed on cement-admixed silty clay to investigate the effect of cement content and nano-magnesia (MgO) on its shear strength properties. For each normal stress, shear strength increased with cement content. However, an obvious increment in shear strength was achieved when the cement content was adjusted from 13% to 17%. Both cohesion and friction angle of cemented soil increased with cement content, and exponential function was adopted to correlate both the factors with cement content. For cement content of 10% investigated in this study, the optimum nano-MgO content was 10‰, wherein the cohesion could reach the peak value. The microstructure of the mixture revealed that the structure of the mixture was compacted for the optimum nano-MgO content. However, micro-cracks were formed when the amount of nano-MgO exceeded its optimum content. 相似文献