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1.
To identify the causes of salinization and arsenic contamination of surface water on an embanked island (i.e., polder) in the tidal delta plain of SW Bangladesh we collected and analyzed water samples in the dry (May) and wet (October) seasons in 2012–2013. Samples were collected from rice paddies (wet season), saltwater ponds used for brine shrimp aquaculture (dry season), freshwater ponds and tidal channels (both wet and dry season), and rainwater collectors. Continuous measurements of salinity from March 2012 to February 2013 show that tidal channel water increases from ~0.15 ppt in the wet season up to ~20 ppt in the dry season. On the polder, surface water exceeds the World Health Organization drinking water guideline of 10 μg As/L in 78% of shrimp ponds and 27% of rice paddies, raising concerns that produced shrimp and rice could have unsafe levels of As. Drinking water sources also often have unsafe As levels, with 83% of tubewell and 43% of freshwater pond samples having >10 μg As/L. Water compositions and field observations are consistent with shrimp pond water being sourced from tidal channels during the dry season, rather than the locally saline groundwater from tubewells. Irrigation water for rice paddies is also obtained from the tidal channels, but during the wet season when surface waters are fresh. Salts become concentrated in irrigation water through evaporation, with average salinity increasing from 0.43 ppt in the tidal channel source to 0.91 ppt in the rice paddies. Our observations suggest that the practice of seasonally alternating rice and shrimp farming in a field has a negligible effect on rice paddy water salinity. Also, shrimp ponds do not significantly affect the salinity of adjacent surface water bodies or subjacent groundwater because impermeable shallow surface deposits of silt and clay mostly isolate surface water bodies from each other and from the shallow groundwater aquifer. Bivariate plots of conservative element concentrations show that all surface water types lie on mixing lines between dry season tidal channel water and rainwater, i.e., all are related by varying degrees of salinization. High As concentrations in dry season tidal channel water and shrimp ponds likely result from groundwater exfiltration and upstream irrigation in the dry season. Arsenic is transferred from tidal channels to rice paddies through irrigation. Including groundwater samples from the same area (Ayers et al. in Geochem Trans 17:1–22, 2016), principal components analysis and correlation analysis reveal that salinization explains most variation in surface water compositions, whereas progressive reduction of buried surface water by dissolved organic carbon is responsible for the nonconservative behavior of S, Fe, and As and changes in Eh and alkalinity of groundwater.  相似文献   

2.
长江口及邻近海域表层沉积物pH、Eh分布及制约因素   总被引：8，自引：1，他引：7  
使用精密酸度计和新型全自动氧化还原电位仪测定了长江口及其临近海域表层沉积物中的pH、Eh值,分析了它们的分布特征,并从水团性质、层化特征、底质类型、生物扰动等方面深入探讨了pH、Eh的影响因素和影响机理。研究表明:研究区内表层沉积物属于中性—弱碱性环境,pH值变化于7.1～7.8之间,空间分布上具有分带性和不均一性特征;为还原环境,Eh变化于-100～-300 mV之间,大部分在-250 mV左右,其空间分布也具有弱分带和不均一的特点。该区沉积物酸碱性主要受水团性质的制约,同时底质类型、生物扰动对沉积物酸碱性也有一定影响,而氧化还原电位则主要受水团性质、水层层化和生物扰动等的影响。  相似文献   

3.
Monitoring wells are often installed in aquitards to verify effectiveness for preventing migration of surface contaminants to underlying aquifers. However, water sampling of aquitard wells presents a challenge due to the slow recovery times for water recharging the wells, which can take as long as weeks, months or years to recharge depending on the sample volume needed. In this study, downhole profiling and sampling of aquitard wells was used to assess geochemical changes that occur in aquitard wells during water level recovery. Wells were sampled on three occasions spanning 11 years, 1 year and 1 week after they were purged and casing water showed substantial water chemistry variations. Temperature decreased with depth, whereas pH and specific conductance increased with depth in the water column after 11 years of water level recovery. Less stable parameters such as dissolved O2 (DO) and Eh showed strong zonation in the well column, with DO stratification occurring as the groundwater slowly entered the well. Oxidation of reduced till groundwater along with degassing of CO2 from till pore water affects mineral solubility and dissolved solid concentrations. Recommendations for sampling slowly recovering aquitard wells include identifying the zone of DO and Eh stratification in the well column and collecting water samples from below the boundary to better measure unstable geochemical parameters.  相似文献   

4.
512铀矿床不同氧化还原环境水岩体系Eh和pH值的研究结果表明：同一氧化还原环境的水岩体系Eh平均值极为接近；不同氧化还原环境的水岩体系Eh值差异明显，即从氧化带到还原带，水岩体系Eh值明显下降；不同氧化还原环境，其水岩体系pH值也有所不同，氧化带和还原带处于弱碱性介质环境，过渡带（矿化地段）处于中性介质环境；水岩体系Eh和pH值可以作为划分含矿层氧化还原环境分带及圈定铀矿体位置的依据。  相似文献   

5.
Quantitative evaluations of the impact of groundwater abstraction on recharge are rare. Over a period (1975??007) during which groundwater abstraction increased dramatically in the Bengal Basin, changes in net groundwater recharge in Bangladesh are assessed using the water-table fluctuation method. Mean annual groundwater recharge is shown to be higher (300??00?mm) in northwestern and southwestern areas of Bangladesh than in southeastern and northeastern regions (<100?mm) where rainfall and potential recharge are greater. Net recharge in many parts of Bangladesh has increased substantially (5??5?mm/year between 1985 and 2007) in response to increased groundwater abstraction for irrigation and urban water supplies. In contrast, net recharge has slightly decreased (??.5 to ???mm/year) in areas where groundwater-fed irrigation is low (<30% of total irrigation) and where abstraction has either decreased or remained unchanged over the period of 1985??007. The spatio-temporal dynamics of recharge in Bangladesh illustrate the fundamental flaw in definitions of “safe yield??based on recharge estimated under static (non-pumping) conditions and reveal the areas where (1) further groundwater abstraction may increase actual recharge to the shallow aquifer, and (2) current groundwater abstraction for irrigation and urban water supplies is unsustainable.  相似文献   

6.
在我国东部高潜水位地区,长期的地下煤炭开采造成地表形成大面积的沉陷水域,受周围人类活动的影响,沉陷水域水环境污染风险逐渐增大。以淮南潘集采煤沉陷水域为研究对象,根据韦伯-费希纳定律,选取与沉陷水域水环境关系密切的水质评价指标,分析不同时间段沉陷水域的水环境状况,通过图层叠加融合定量反映沉陷水域水环境质量时空变化及潜在水环境风险的发生时间和区域。研究结果显示,沉陷水域水质不容乐观,存在水质恶化的风险。从5月到11月,随着时间的变化,沉陷水域都呈现出中警以上的警情,在不同月份沉陷水域出现的警情区域也有所不同,其中沉陷水域的西部和中部警情出现的概率较大。在今后的水环境管理中需针对不同时间不同区域采取针对性的治理措施,避免水环境污染风险的发生。   相似文献   

7.
底泥原地稳定化过程中药剂对上覆水体的影响   总被引：2，自引：0，他引：2       下载免费PDF全文
采用底泥原地稳定化处理技术中的药剂投加方法,对苏州河底泥中投加零价铁(Fe0)、硝酸钙的上覆水体进行为期80 d研究比较.结果表明:投加Fe0后上覆水体的溶解氧(DO)被迅速消耗,体系易形成厌氧环境,而硝酸钙则减缓了上覆水体DO的消耗;投加零价铁或硝酸钙后都会使上覆水体的pH升高,Eh下降;投加Fe0后对上覆水体CODCr或TOC的影响较硝酸钙小;此外,两者上覆水体DO、pH和Eh与CODCr和TOC之间均具有一定的相关性.  相似文献   

8.
Natural arsenic(As)contamination of groundwater which provides drinking water and/or irrigation supplies remains a major public health issue,particularly in South and Southeast Asia.A number of studies have evaluated various aspects of the biogeochemical controls on As mobilization in aquifers typical to this region,however many are predicated on the assumption that key biogeochemical processes may be deduced by sampled water chemistry.The validity of this assumption has not been clearly established even though the role of sorption/desorption of As and other heavy metals onto Fe/Mn(hydr)oxides is an important control in As mobilization.Here,selective chemical extractions of sand-rich and clay-rich sediments from an As-affected aquifer in Kandal Province,Cambodia,were undertaken to explore the potential role of partial re-equilibrium through sorption/desorption reactions of As and related solutes(Fe,Mn and P)between groundwater and the associated solid aquifer matrix.In general,groundwater As is strongly affected by both pH and Eh throughout the study area.However,contrasting sorption behaviour is observed in two distinct sand-dominated(T-Sand)and clay dominated(T-Clay)transects,and plausibly attributed to differing dominant lithologies,biogeochemical and/or hydrogeological conditions.Sorption/desorption processes appear to be re-setting groundwater As concentrations in both transects,but to varying extents and in different ways.In T-Sand,which is typically highly reducing,correlations suggest that dissolved As may be sequestered by sorption/re-adsorption to Fe-bearing mineral phases and/or sedimentary organic matter;in T-Clay Eh is a major control on As mobilization although binding/occlusion of Fe-bearing minerals to sedimentary organic matter may also occur.Multiple linear regression analysis was conducted with groups categorised by transect and by Eh,and the output correlations support the contrasting sorption behaviours encountered in this study area.Irrespective of transect,however,the key biogeochemical processes which initially control As mobilization in such aquifers,may be "masked" by the re-setting of As concentrations through in-aquifer sorption/desorption processes.  相似文献   

9.
Irrigation in low-lying coastal plains may enhance the formation of fresh groundwater lenses, which counteract salinization of groundwater and soil. This study presents seasonal dynamics of such a freshwater lens and discusses its influence on the salinity distribution of the unconfined aquifer in the coastal plain of Ravenna, Italy, combining field observations with numerical modeling (SEAWAT). The lens originates from an irrigation ditch used as a water reservoir for spray irrigation. The geometry of the freshwater lens shows seasonal differences because of freshwater infiltration during the irrigation season and upconing of deeper saltwater for the remainder of the year. The extent of the freshwater lens is controlled by the presence of nearby drainage ditches. Irrigation also results in a temperature anomaly in the aquifer because of the infiltration of warm water during the irrigation season. The surficial zone in the vicinity of the irrigation ditch is increased considerably in thickness. Finally, different irrigation alternatives and the influence of sea-level rise are simulated. This shows that it is necessary to integrate irrigation planning into the water management strategy of the coastal zone to have maximum benefits for freshening of the aquifer and to make optimal use of the existing infrastructure.  相似文献   

10.
气候变化下长江中下游水稻灌溉需水量时空变化特征   总被引：12，自引：0，他引：12       下载免费PDF全文
选择长江中下游单季中稻为研究对象,结合45个气象站1961~2010年逐日气象资料,基于统计降尺度模型(SDSM),生成HadCM3气候模式A2和B2两种情景下各站点参考作物腾发量和降水数据。基于联合国粮食及农业组织(FAO)推荐的作物系数法,并考虑有效性降雨和不同地区深层渗漏量,分析历史和未来的水稻灌溉需水时空变化特征。结果表明:过去50年,除了太湖流域以外的长江中下游大部分区域的参考作物腾发量和水稻需水量都呈显著下降趋势,而显著下降的水稻灌溉需水量主要位于鄱阳湖流域;未来两种情景下,参考作物腾发量、水稻需水量和水稻灌溉需水量均值都呈下降趋势,但水稻灌溉需水量降幅最小;水稻需水量和水稻灌溉需水量在长江中下游地区的变化趋势具有明显的空间异质性,水稻需水量大幅减少的区域由太湖流域向汉江和洞庭湖流域扩展。未来水稻灌溉需水量减少的区域主要分布在太湖流域、汉江流域东部和洞庭湖流域北部,并随时间推移呈扩大趋势。  相似文献   

11.
The results of thermodynamic calculations demonstrate that the pH and Eh values for bottom sea water enriched in organic matter tend to decrease drastically as a result of bacterial reduction of sulfates in sea water. Syngenetic sulfide ore beds associated with the Jiashengpan strata-bound Pb-Zn-S ore deposit are believed to have been precipitated under the conditions of pH varying from 7.08 to 7.17 and Eh from −0.232 to −0.418V. It is established that in the reducing system in sea water where reduction of sulfates by anaerobic bacteria took place, paleosalinity is an important factor affecting pH and Eh changes and controlling the formation of sulfide ore beds. The present study shows that the quantitative evaluation of physicochemical conditions can be effected from thermodynamic calculations on the basis of geochemical data.  相似文献   

12.
污灌土壤中有机氮的矿化速率及其影响因素   总被引：1，自引：0，他引：1  
蒋景诚  陈金秀 《地球科学》1989,14(6):627-633
  相似文献   

13.
Irrigated agriculture allows for the increase of agrarian yields and stability in food supply and raw materials, being, at the same time, responsible for the reduction of water resources availability and for the pollution by salts and nitrate. This work aims to analyze the impact of changes in irrigation management (establishment of an on-demand flood irrigated system, assignment of irrigation allowances and water payment for surface and irrigation water consumption) in a traditional irrigated land on drainage flow, electrical conductivity and nitrate concentration in irrigation return flows between the year 2001 and the period 2005–2008. Changes in water management significantly modified quantity (lower drainage) and quality (electrical conductivity and nitrate) of irrigation return flows, keeping similar evolution paths during the year with water ameliorants in summer due to the use of good irrigation water quality. Salinity in irrigation return flows is not a current problem in the area as electrical conductivity values in water did not exceed the limit established for water used in irrigation or intended for human consumption. Despite the fact that changes in irrigation management and crop distribution have reduced nitrate concentrations in irrigation return flows by 43 %, the water still presents nitrate values exceeding the 50 mg NO3 ?/l. Thus, nitrate remains as the main agro-environmental problem in this irrigation area. However, the nitrate concentration trends detected in this work mark the possibility of reaching nitrate values below 50 mg NO3 ?/l in the case of maintenance of the conditions in this agricultural system.  相似文献   

14.
Data on spatiotemporal variations in groundwater levels are crucial for understanding arsenic (As) behavior and dynamics in groundwater systems. Little is known about the influences of groundwater extraction on the transport and mobilization of As in the Hetao Basin, Inner Mongolia (China), so groundwater levels were recorded in five monitoring wells from 2011 to 2016 and in 57 irrigation wells and two multilevel wells in 2016. Results showed that groundwater level in the groundwater irrigation area had two troughs each year, induced by extensive groundwater extraction, while groundwater levels in the river-diverted (Yellow River) water irrigation area had two peaks each year, resulting from surface-water irrigation. From 2011 to 2016, groundwater levels in the groundwater irrigation area presented a decreasing trend due to the overextraction. Groundwater samples were taken for geochemical analysis each year in July from 2011 to 2016. Increasing trends were observed in groundwater total dissolved solids (TDS) and As. Owing to the reverse groundwater flow direction, the Shahai Lake acts as a new groundwater recharge source. Lake water had flushed the near-surface sediments, which contain abundant soluble components, and increased groundwater salinity. In addition, groundwater extraction induced strong downward hydraulic gradients, which led to leakage recharge from shallow high-TDS groundwater to the deep semiconfined aquifer. The most plausible explanation for similar variations among As, Fe(II) and total organic carbon (TOC) concentrations is the expected dissimilatory reduction of Fe(III) oxyhydroxides.  相似文献   

15.
在淮南矿区,常年大规模地下煤炭的开采造成地表塌陷,形成了大面积的沉陷水域。选取潘集和顾桥2个不同类型沉陷水域为研究对象,结合同步的地面实测数据和环境卫星数据,利用综合营养指数法对不同时段沉陷水域水质富营养化进行了综合评价。结果表明:沉陷水域水体都已呈现出富营养化状态,不同类型沉陷水域在时间上和空间上存在着明显的差异。从时间上看,沉陷水域5月份的富营养化程度要明显高于11月份。从空间上看,顾桥沉陷水域富营养化程度要明显高于潘集沉陷水域。   相似文献   

16.
The purpose of this work is to characterize the hydrochemical behavior of acid mine drainages (AMD) and superficial waters from the Adoria mine area (Northern Portugal). Samples of superficial and mine drainage water were collected for one year, bi-monthly, with pH, temperature, Eh, conductivity and HCO3 determined in situ with chemical analyses of SO4, Ca, K, Mg, Na, Cl, Ag, As, Bi, Co, Cu, Fe, Mn, Ni, Pb, Zn and Cd. In the mine, there are acidic waters, with low pH and significant concentrations of SO4, and metals (Fe, Mn, Zn, Cu, Pb, Cd and Ni), while in the superficial natural stream waters outside the mine, the pH is close to neutral, with low conductivity and lower metal concentrations. The stream waters inside the mine influence are intermediate in composition between AMD and natural stream waters outside the mine influence. Principal Component Analysis (PCA) shows a clear separation between AMD galleries and AMD tailings, with tailings having a greater level of contamination.  相似文献   

17.
万能  孙科  范伟国  田欢  严森  谢淑云  向武  鲍征宇 《地球科学》2020,45(3):1041-1050
江汉平原是中国四大粮仓之一,拥有约69万公顷富硒土壤,大部分为冷浸田,如何利用富硒冷浸田种植富硒水稻是当前亟需研究解决的重大实际问题.以排水整改、强化施硒肥和排水整改后施硒肥3种模式开展了江汉平原富硒冷浸田的大田种植实验.结果表明,在排水整改模式下,排水降低了冷浸田地下水位,提升了土壤的通气性和氧化还原电位,加快了土壤中有机结合态硒向可利用态硒转化,使得土壤可利用态硒比整改前提高25.0%;促进了水稻对硒的吸收,使得水稻根系和籽实中硒含量比整改前分别增加20.6%和8.3%,仅茎干中硒含量无明显变化.在强化施硒肥模式下,每亩施加80 kg硒肥后土壤可利用态硒比施肥前提高41.7%;极大地促进了水稻对硒的吸收,使得水稻根系、茎秆、籽实中硒含量比施肥前分别提升79.4%、37.1%、25.0%.在冷浸田排水整改后每亩施加80 kg硒肥模式下,土壤可利用态硒含量和水稻根系、茎干、籽实中硒含量分别增加50.0%和41.8%、46.1%、47.9%.总之,上述3种利用模式均可提高土壤可利用态硒含量,有利于水稻对土壤硒的吸收,能够显著提高水稻籽实中硒含量;冷浸田排水整改后强化施硒肥利用模式效果最佳.   相似文献   

18.
在深入分析石羊河流域中下游＂水-生态环境-社会经济＂复合系统的基础上,运用系统动力学方法,建立了包括8个一级系统、27个状态变量、27个速率变量、65个辅助变量、31个表函数、41条反馈回路及191个SD（System Dynamics）方程的水资源承载力系统动力学模型.选取水浇地灌溉面积增长率、水浇地灌溉定额、水浇地灌溉水利用系数、菜田灌溉定额、菜田灌溉水利用系数等5个参数作为方案设计的决策变量,设计了四种方案,在对各方案水量供需关系模拟分析的基础上,以加大农业节水力度、平水年可供水量为约束条件,通过SD模型模拟计算了各规划年研究区可承载的水浇地灌溉面积及社会经济与生态规模.  相似文献   

19.
Résumé Nous discutons la signification du potentiel d'oxydo-réduction dans les eaux naturelles aérées ou sulfurées, au point de vue de leur application dans les diagrammes Eh/pH. — Dans le cas des eaux aérées, nous proposons de reporter sur ces diagrammes non pas le potentiel mesuré mais le potentiel thermodynamique. Pour les eaux sulfurées, nous proposons de remplacer les diagrammes Eh/pH par des diagrammes log S/pH (où log S est la concentration totale de S (-II)).
The meaning of oxidation potentials measured in aerated natural waters and in sulfurated waters is discussed in relation with application in Eh/pH diagrams. In the case of aerated waters, we propose to plot in these diagrams not the measured, but the thermodynamical Eh. For sulfurated waters, we should replace Eh/pH diagrams by log S/pH diagrams (S being the total S (-II) amount).
  相似文献   

20.
《Applied Geochemistry》2006,21(1):83-97
Groundwater in the Gwelup groundwater management area in Perth, Western Australia has been enriched in As due to the exposure of pyritic sediments caused by reduced rainfall, increased groundwater abstraction for irrigation and water supply, and prolonged dewatering carried out during urban construction activities. Groundwater near the watertable in a 25–60 m thick unconfined sandy aquifer has become acidic and has affected shallow wells used for garden irrigation. Arsenic concentrations up to 7000 μg/L were measured in shallow groundwater, triggering concerns about possible health effects if residents were to use water from household wells as a drinking water source. Deep production wells used for public water supply are not affected by acidity, but trends of progressively increasing concentrations of Fe, SO4 and Ca over a 30-a period indicate that pyrite oxidation products extend to the base of the unconfined aquifer. Falling Eh values are triggering the release of As from the reduction of Fe(III) oxyhydroxide minerals near the base of the unconfined aquifer, increasing the risk that groundwater used as a drinking water source will also become contaminated with high concentrations of As.  相似文献   

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