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1.
Effect of water quality on the leaching of potassium from sandy soil   总被引:1,自引:0,他引:1  
When potassium (K+) fertilizers are applied to soil, K+ is subject to displacement through the soil profile. More generally, the application of K+ fertilizers to sandy soils with low clay content and small buffer capacity, in which K+ does not interact strongly with the soil matrix, results in localized increases in K+ concentration in the soil solution. Losses of K+ depend on the concentration of calcium (Ca2+) as a competing ion in the leaching water and the amount of water that passes through the soil. In this study, we examined the adsorption and movement of applied K+ in columns of sandy soil. Glass tubes, 4.8 cm in diameter and 40 cm in length, were packed with either native soil or Ca2+-saturated soil. The resulting 10-cm-long column of soil had a bulk density of 1.65 g cm−3. Native soil was leached with distilled water and CaCl2 solutions of various concentrations. In the Ca2+-saturated soil, a pulse of K+ was leached with CaCl2 solutions of various concentrations or distilled water. Increasing the CaCl2 concentration from 3 to 15 mm resulted in earlier breakthrough, a higher peak concentration of K+, and greater amounts of leached K+. The breakthrough curve for K+, when leached with distilled water, showed very low concentrations and was more delayed than the other treatments. In Ca2+-saturated soil, the amount of K+ leached increased as Ca2+ concentration increased, with up to 54% of the added pulse K+ being removed from 10 pore volumes (Pv) (387 mm) of 15 mm CaCl2. The presence of Ca2+ in irrigation water and soil minerals able to release Ca2+ is important in determining the amount of K+ leached from soils. Large amounts of K+ are leached from soils in areas where crops are irrigated with water that contains significant concentrations of Ca2+ and other cations.  相似文献   

2.
In arid and semi-arid areas biological soil crusts are main contributors to C and N-cycles and the origin of organic matter. Nevertheless systematic studies on the spatial distribution of total organic carbon (TOC) and nitrogen (N) and a characterization of crust organic matter composition are missing. To describe the spatial distribution of TOC and N we examined three soil depths and three relief positions along a steep rainfall gradient. In addition the molecular composition of organic matter was characterized by Pyrolysis-field ionization mass spectrometry.TOC and N concentrations decreased with increasing depth, the effects of the relief followed no clear trend. Surprisingly the amount of TOC and N decreased with increasing rainfall. Stable organic matter compounds were reduced with increasing rainfall. Topcrusts (0–2 mm) showed a relative enrichment in bacteria, as indicated by proportionally larger contents in N-acetylmuramic acid (m/z 167 + 276) than the subcrusts (2–40 mm). These were enrichment in cyanobacteria, as indicated by proportionally larger contents of hexadecadienoic acid (m/z 252).We conclude that the spatial distribution of TOC and N is related to sampling depth and annual precipitation. Organic matter composition and the main biomass contributors in crusts are successfully identified by pyrolysis-field ionization mass spectrometry.  相似文献   

3.
This paper describes and compares the hydrological responses of runoff, soil moisture and groundwater levels to rainfall events for two small semi-arid catchments over a 2-year period. Romwe received 1430 and 756 mm of rainfall in the 19999/00 and 2000/01 season, respectively. Mutangi received 756 and 615 mm of rainfall in the same years. Romwe generated 520 and 102 mm of runoff in the 19999/00 and 2000/01 seasons, respectively, while Mutangi generated 82 and 69 mm of runoff in the same years. The runoff response of the catchments was dominated by a relatively quick response to rainfall and with little or no significant contribution from regional groundwater or ‘old water’ sources. Total soil moisture storage to a depth of 120 cm was higher at Romwe than Mutangi for the entire study period reflecting the differences in the soil types. The groundwater level was closer to the surface and responded more quickly to rainfall at Romwe compared to Mutangi where water levels were between 12 and 16 m below the surface. There was a significant relationship between profile soil moisture and water table level at Romwe and none was observed at all in Mutangi. Significant (p<0.05) monthly rainfall runoff relationships were observed at both Romwe and Mutangi. At Romwe and Mutangi 91% and 76% of the runoff variation was accounted for by rainfall in the 1999/00 season, respectively. The rainfall–runoff relationship were different at Romwe for the two seasons, it was higher in the 1999/00 season than the 2000/01 season when 91% and 49% of the runoff variation was due to rainfall, respectively. The relationships were almost similar at Mutangi during the two seasons.  相似文献   

4.
We compared seed banks between two contrasting anthropogenic surface disturbances (compacted, trenched) and adjacent undisturbed controls to determine whether site condition influences viable seed densities of perennial and annual Mojave Desert species. Viable seeds of perennials were rare in undisturbed areas (3–4 seeds/m2) and declined to <1 seed/m2 within disturbed sites. Annual seed densities were an order of magnitude greater than those of perennials, were one-third the undisturbed seed densities on compacted sites, but doubled on trenched sites relative to controls. On trenched sites, greater litter cover comprising the infructescences of the dominant spring annuals, and low gravel content, enhanced seed densities of both annuals and perennials. Litter cover and surface ruggedness were the best explanations for viable perennial seed densities on compacted sites, but litter cover and the presence of a common harvester ant explained annual seed densities better than any other surface characteristics that were examined. Surface disturbances can have a varied impact on the condition of the soil surface in arid lands. Nevertheless, the consistently positive relationship between ground cover of litter and viable seed density emphasizes the importance of litter as an indicator of site degradation and recovery potential in arid lands.  相似文献   

5.
Soil salinity is a major abiotic stress influencing plant productivity worldwide. Schinopsis quebracho colorado is one of the most important woody species in the Gran Chaco, an arid and salt-prone subtropical biome of South America. To gain a better understanding of the physiological mechanisms that allow plant establishment under salt conditions, germination and seedling growth of S. quebracho colorado were examined under treatment with a range of NaCl solutions (germination: 0–300 mmol l−1 NaCl; seedling growth: 0–200 mmol l−1 NaCl). The aim was to test the hypothesis that S. quebracho colorado is a glycophite that shows different salt tolerance responses with development stage. Proline content, total soluble carbohydrates and Na+, K+ and Cl concentrations in leaves and roots of seedlings, and the chlorophyll concentration and relative water content of leaves were measured. Germination was not affected by 100 mmol l−1 NaCl, but decreased at a concentration of 200 mmol l−1. At 300 mmol l−1 NaCl, germination did not occur. Seedling growth decreased drastically with increasing salinity. An increase in NaCl from 0 to 100 mmol l−1 also significantly reduced the leaf relative water content by 22% and increased the proline concentration by 60% in roots. In contrast, total soluble carbohydrates were not significantly affected by salinity. Seedlings showed a sodium exclusion capacity, and there was an inverse correlation between Cl concentration and the total chlorophyll concentration. S. quebracho colorado was more tolerant to salinity during germination than in the seedling phase. The results suggest that this increased tolerance during germination might, in part, be the result of lower sensitivity to high tissue Na+ concentrations. The significant increment of proline in the roots suggests the positive role of this amino acid as a compatible solute in balancing the accumulation of Na+ and Cl as a result of salinity. These results help clarify the physiological mechanisms that allow establishment of S. quebracho colorado on salt-affected soils in arid and semi-arid Gran Chaco.  相似文献   

6.
Representative rainfall thresholds for landslides in the Nepal Himalaya   总被引:14,自引:0,他引:14  
Measuring some 2400 km in length, the Himalaya accommodate millions of people in northern India and Pakistan, Nepal, Bhutan, and parts of other Asian nations. Every year, especially during monsoon rains, landslides and related natural events in these mountains cause tremendous damage to lives, property, infrastructure, and environment. In the context of the Himalaya, however, the rainfall thresholds for landslide initiation are not well understood. This paper describes regional aspects of rainfall thresholds for landslides in the Himalaya. Some 677 landslides occurring from 1951 to 2006 were studied to analyze rainfall thresholds. Out of the 677 landslides, however, only 193 associated with rainfall data were analyzed to yield a threshold relationship between rainfall intensity, rainfall duration, and landslide initiation. The threshold relationship fitted to the lower boundary of the field defined by landslide-triggering rainfall events is = 73.90D− 0.79 (I = rainfall intensity in mm h− 1 and = duration in hours), revealing that when the daily precipitation exceeds 144 mm, the risk of landslides on Himalayan mountain slopes is high. Normalized rainfall intensity–duration relationships and landslide initiation thresholds were established from the data after normalizing rainfall-intensity data with respect to mean annual precipitation (MAP) as an index in which NI = 1.10D− 0.59 (NI = normalized intensity in h− 1). Finally, the role of antecedent rainfall in causing landslides was also investigated by considering daily rainfall during failure and the cumulative rainfall to discover at what point antecedent rainfall plays an important role in Himalayan landslide processes. Rainfall thresholds presented in this paper are generalized so they can be used in landslide warning systems in the Nepal Himalaya.  相似文献   

7.
Many arid basins in western North America are likely to experience future changes in precipitation timing and amount. Where shallow water tables occur, plant acquisition of groundwater and soil water may be influenced by growing season precipitation. We conducted a rainfall manipulation experiment to investigate responses of four common native plant species to ambient, increased, and decreased summer monsoon rainfall. We measured plant xylem pressure potentials (Ψ) and stable oxygen isotope signatures (δ18O) to assess effects of altered precipitation on plant water relations and water acquisition patterns. Reduced rainfall decreased Ψ more in the grasses Sporobolus airoides and Distichlis spicata than the more deeply rooted shrubs Sarcobatus vermiculatus and Ericameria nauseosa. E. nauseosa had little response to natural or experimental differences in available soil water. Plant xylem water δ18O indicated that S. airoides and D. spicata are almost entirely dependent on rain-recharged soil water, while E. nauseosa is almost entirely groundwater-dependent. Sarcobatus vermiculatus used groundwater during dry periods, but utilized precipitation from soil layers after large rainfall events. Persistent changes in precipitation patterns could cause shifts in plant community composition that may alter basin-scale groundwater consumption by native plants, affecting water availability for human and ecosystem uses.  相似文献   

8.
Forage availability for mule deer (Odocoileus hemionus) in the Sonoran Desert depends on plant biomass, which is influenced by rainfall. We determined how rainfall, temperature and plant characteristics affected biomass of deer forage. We measured forage biomass, rainfall and temperature every 3 months from April 2000 to December 2002. Quarterly rainfall ranged from <1 to 57 mm, and forage biomass in desert washes fluctuated between 6 and 34 g m−2. There was a positive relationship between forage biomass and rainfall the previous six months (p<0.001), and a negative relationship between biomass and average temperature the previous 3 months (p<0.001). Quarterly forage growth was positively influenced by rainfall (p<0.001) and negatively influenced by forage biomass (p<0.001). The relationships between deer forage and environmental factors established here will be useful in understanding population ecology of mule deer as part of an interactive model of plant–herbivore dynamics in arid environments.  相似文献   

9.
Interrelated, biotic (flora and fauna) and abiotic (pedogenesis and hydrology) processes were examined at four sites (30, and approximately 1000–3000, 7000–12 000, and 125 000 years before present) in the northern Mojave Desert. Data collected at each included floral and faunal surveys; soil texture, structure, and morphology; and soil hydraulic properties. Separate measurements were made in shrub undercanopy and intercanopy microsites. At all sites, shrubs made up greater than 86 percent of total perennial cover, being least on the youngest site (4 percent) and most on the 7000–12 000-year-old site (31 percent). In the intercanopy, winter annual density was highest on the 1000- to 3000-year-old site (249 plants/m2) and lowest on the oldest site (4 plants/m2). Faunal activity, measured by burrow density, was highest on the 1000–3000- and 7000–12 000-year-old sites (0.21 burrows/m2) and density was twice as high in the undercanopy versus the intercanopy. Burrow density was lower at the two oldest sites, although density was not statistically greater in the undercanopy than intercanopy. At the older sites, the soil water balance was increasingly controlled by Av horizons in intercanopy soils in which saturated hydraulic conductivity (Ksat) decreased 95 percent from the youngest to the oldest site. No significant reduction in Ksat in undercanopy soils was observed. Decreases in the intercanopy sites correlated with decreases in annual plant density and bioturbation, suggesting these processes are interrelated with surface age.  相似文献   

10.
Liu  Muxing  Wang  Qiuyue  Guo  Li  Yi  Jun  Lin  Henry  Zhu  Qing  Fan  Bihang  Zhang  Hailin 《地理学报(英文版)》2020,30(6):949-968
Rainfall provides essential water resource for vegetation growth and acts as driving force for hydrologic process, bedrock weathering and nutrient cycle in the steep hilly catchment. But the effects of rainfall features, vegetation types, topography, and also their interactions on soil water movement and soil moisture dynamics are inadequately quantified. During the coupled wet and dry periods of the year 2018 to 2019, time-series soil moisture was monitored with 5-min interval resolution in a hilly catchment of the Three Gorges Reservoir Area in China. Three hillslopes covered with evergreen forest(EG), secondary deciduous forest mixed with shrubs(SDFS) and deforested pasture(DP) were selected, and two monitoring sites with five detected depths were established at upslope and downslope position, respectively. Several parameters expressing soil moisture response to rainfall event were evaluated, including wetting depth, cumulative rainfall amount and lag time before initial response, maximum increase of soil water storage, and transform ratio of rainwater to soil water. The results indicated that rainfall amount is the dominant rainfall variable controlling soil moisture response to rainfall event. No soil moisture response occurred when rainfall amounts was 8 mm, and all the deepest monitoring sensors detected soil moisture increase when total rainfall amounts was 30 mm. In the wet period, the cumulative rainfall amount to trigger surface soil moisture response in EG-up site was significantly higher than in other five sites. However, no significant difference in cumulative rainfall amount to trigger soil moisture response was observed among all study sites in dry period. Vegetation canopy interception reduced the transform ratio of rainwater to soil water, with a higher reduction in vegetation growth period than in other period. Also, interception of vegetation canopy resulted in a largeraccumulated rainfall amount and a longer lag time for initiating soil moisture response to rainfall. Generally, average cumulative rainfall amount for initiating soil moisture response during dry period of all sites(3.5–5.6 mm) were less than during wet period(5.7–19.7 mm). Forests captured more infiltration water compared with deforested pasture, showing the larger increments of both soil water storage for the whole soil profile and volumetric soil water content at 10 cm depth on two forest slopes. Topography dominated soil subsurface flow, proven by the evidences that less rainfall amount and less time was needed to trigger soil moisture response and also larger accumulated soil water storage increment in downslope site than in corresponding upslope site during heavy rainfall events.  相似文献   

11.
This is the first of two papers that describe the surface hydrology of the Lake Eyre Basin (LEB) (1,140,000 km2) in central Australia and compares some key characteristics with those observed from arid regions globally. This paper concentrates on annual rainfall, whereas the second paper is devoted to streamflow. The first part describes the LEB's climate (arid to semi-arid), which is dominated by a subtropical high pressure ridge stretching latitudinally across central Australia. Then follow major analyses that include the characteristics of rainfall, wet and dry spell lengths and cumulative surpluses and deficiencies, rainfall trends and intra- and inter-decadal fluctuations, and the relationship between rainfall and El Niño-Southern Oscillation (ENSO). The paper concludes with six conclusions, the key ones being: the variability of the annual rainfall (based on the coefficient of variation) in the LEB is approximately 60% greater than that found for stations located in arid regions in the rest of the world; there is a bias towards longer lengths of dry years than observed in the rest of Australia; and, there is a significant lag correlation between rainfall and ENSO, particularly in the east and in the latter part of a year.  相似文献   

12.
Vegetation within some parts of Western Australia has been degraded by resource extraction, and ecological restoration is necessary to prevent erosion and reinstate plant biodiversity. Two restoration approaches, seed broadcasting and planting of seedlings, were tested with plant species (Acacia tetragonophylla F. Muell., Atriplex bunburyana F. Muell. and Solanum orbiculatum Poir.) known to have been dominant prior to mining activities in the World Heritage Area at Shark Bay. For broadcast seeding, soil raking and/or ripping increased seedling emergence, but only after sufficient rainfall. Survival of A. bunburyana seedlings (≤92%) was higher than A. tetragonophylla (≤13%) almost two years after planting and soil ripping partly alleviated soil impedance and resulted in increased seedling survival. Shoot pruning, fertiliser and moisture retaining gel had a reduced or detrimental effect on survival. Seedling survival differed between the three experimental sites, with electrical conductivity being the most noted soil difference between the sites. Restoration in the arid environs of the World Heritage Area at Shark Bay in Western Australia is challenging, but this study shows that seedling establishment is technically feasible and provides methodology useful to other arid restoration projects.  相似文献   

13.
 通常认为极干旱区土壤水分来源于降水、大气或凝结水,深埋区不存在潜水蒸发。然而通过使用拱棚法初步证明在极干旱深埋区存在潜水蒸发,而潜水是土壤水分的重要来源。为了进一步求证土壤水分来源,开挖200 cm×200 cm×200 cm的土坑,完全隔绝与下层土壤及四周的水分联系,回填后监测土壤10、30、50、100、150 cm的空气温湿度;同时设置与四周隔绝但底面联通的对照坑。27 d后都模拟25 mm降雨。监测发现模拟降雨前联通土壤的水分含量、空气相对湿度、绝对湿度都明显高于隔绝土壤。1 a后远离降雨时土壤水分的检测发现隔绝土壤水分含量低于联通对照,但因隔绝土壤处于潜水蒸发漫溢的相同气象环境,其湿度不会无限下降。隔绝对比实验反演证明深埋极干旱区存在潜水蒸发。  相似文献   

14.
In arid and semiarid rangelands, soil erosion has been widely considered an important soil degradation process and one of the main factors responsible for declining soil fertility. In this study, we determined the sediment production and the enrichment ratios of clay, organic C, and total N by using rainfall simulations on runoff plots (0.60 × 1.67 m) in three plant communities of northeastern Patagonia: grass (GS), degraded grass with scattered shrubs (DGS), and degraded shrub steppes (DSS). Our results clearly indicate that spatial variability in soil loss rate and enrichment process exists as a result of the local differences in both plant composition and soil surface characteristics. Sediment production was significantly lower in the GS (14.2 g m−2) compared with the DGS and DSS (38.2 and 51.5 g m−2, respectively). In the GS, the enrichment ratio of clay was significantly greater (3.9) and enrichment ratio of organic C was lower (3.1) than in the DGS and the DSS, though differences in enrichment ratios of total N were not significant. The high rate of soil loss and nutrients through overland-flow may limit the opportunities that promote the pathway from DGS back to GS community, favoring the dominance of shrubs.  相似文献   

15.
Regions with Mediterranean climates are seasonally arid and provide a niche for ephemeral species which germinate following discrete and variable rainfall during summer. These species must be able to detect when conditions are suitable for completion of their life cycle. Common heliotrope (Heliotropium europaeum) is one such species. It is considered a weed in its naturalised habitat in southern Australia as it uses resources that could be used by ensuing crops, and is toxic to livestock.We examined common heliotrope's germination responses to temperature and water potential, the effect of simulated rainfall on seedling emergence and plant growth in lysimeters.Fresh seeds of common heliotrope have relatively high optimum temperatures and water potentials for germination (around 35 °C and 0 MPa). Germination percentage of seeds extracted from the soil seed bank varies seasonally. In the soil types and climate of the study area, 24.2 mm is the minimum amount of rainfall resulting in emergence. Evapotranspiration required to reach minimal reproductive output was 19.4 mm.Common heliotrope's germination requirements have been selected to ensure that it will only germinate after sufficient rainfall to allow reproductive output. This is the mechanism through which common heliotrope detects its temporal niche.  相似文献   

16.
Aboveground biomass in Tibetan grasslands   总被引:2,自引:0,他引:2  
This study investigated spatial patterns and environmental controls of aboveground biomass (AGB) in alpine grasslands on the Tibetan Plateau by integrating AGB data collected from 135 sites during 2001–2004 and concurrent enhanced vegetation index derived from MODIS data sets. The AGB was estimated at 68.8 g m?2, with a larger value (90.8 g m?2) in alpine meadow than in alpine steppe (50.1 g m?2). It increased with growing season precipitation (GSP), but did not show a significant overall trend with growing season temperature (GST) although it was negatively correlated with GST at dry environments (<200 mm of GSP). Soil texture also influenced AGB, but the effect was coupled with precipitation; increased silt content caused a decrease of AGB at small GSP, and generated a meaningful increase under humid conditions. The correlation between AGB and sand content indicated an opposite trend with that between AGB and silt content. An analysis of general linear model depicted that precipitation, temperature, and soil texture together explained 54.2% of total variance in AGB. Our results suggest that moisture availability is a critical control of plant production, but temperature and soil texture also affect vegetation growth in high-altitude regions.  相似文献   

17.
中国沙漠(地)深层渗漏量及动态特征   总被引:1,自引:1,他引:0  
土壤水分深层渗漏是沙区水循环的重要环节,深层渗漏的定量测定对沙区水资源评估及水量平衡研究具有重要意义。本文采用YWB-01型土壤深层水量渗漏测试记录仪对中国毛乌素沙地等六大沙漠(地)降雨入渗到深层土壤的渗漏水量进行实时动态监测。结果表明:流动沙丘降雨渗漏补给量存在明显的时空差异,与降雨时空变化特征具有相对一致性,降雨格局是影响深层渗漏过程的主要因素,随降雨增大渗漏补给量增加,半干旱区降雨量与渗漏量显著正相关(p<0.05),干旱区相关性不显著(p>0.05);观测期内正镶白旗、伊金霍洛旗、阜康流动沙丘土壤200 cm以下渗漏量为48.5、146.8、1.0 mm,分别占同期降雨的21.4%、33.3%、1.3%;乌审旗、磴口150 cm以下渗漏量为1009.6、52.6mm,分别占同期降雨的55.7%、12.7%。不同气候区固定沙丘渗漏量基本没有差异,降雨格局不是影响水分深层渗漏的主导因素,而植被覆盖的影响占主要作用,且沙丘植被盖度>45%时深层渗漏量不超过同期降雨的2.0%。中国沙区深层土壤水分补给主要来自于强降雨或高频次小降雨事件,特别是干旱区降水少、频次低,其深层土壤水分补给更加依赖于强降水。  相似文献   

18.
Salinization and alkalinization are increasing problems in the world. Some land has been degraded to bare saline-alkaline soil where vegetation restoration is difficult because high toxic ionic content and pH are harmful to the survival of introduced plants. We grew Leymus chinensis with and without arbuscular mycorrhizal fungi (Glomus mosseae and G. geosporum) in either pots filled with soil from bare saline-alkaline land, or transplanted seedlings into field plots, to determine the influence of AM fungi on the reestablishment of this dominant grass species in bare degraded land. Association with AM fungi increased the absorption of N, P, K+, Ca2+, but decreased Mg2+, Na+ and Cl uptake under saline-alkaline stress. Therefore, higher K/Na, Ca/Na, P/Na, and P/Cl ratios were found in the inoculated plants. Plants inoculated with AM fungi accumulated significantly higher biomass, root/shoot ratio and tiller number than non-inoculated plants. AM fungi also significantly increased the survival of seedlings when they were transplanted into a bare saline-alkaline land in the field. The improvement of survival, growth and asexual reproduction of inoculated plants indicated that the plant-AM fungi mutualism could improve the reestablishment of vegetation in bare saline-alkaline soil, drive the vegetation restoration to a community dominated by original species.  相似文献   

19.
A hypothesis for understanding the stability of northern Chihuahuan Desert landscapes is that the distribution of soil resources changes from spatially homogeneous in arid grasslands to spatially heterogeneous in invading shrublands. Since radioactive fallout 137Cesium (137Cs) was deposited uniformly across the landscape during the 1950s and 1960s and was quickly adsorbed to soil particles, any redistribution of 137Cs across the landscape would be due to soil redistribution or instability at either plant-interspaces or on a landscape scale. The concentration of 137Cs in soils collected from different vegetation communities (black grama grass, tarbush, tobosa grass, and mesquite) at the USDA-ARS Jornada Experimental Range in the Northern Chihuahuan Desert in New Mexico was determined. At the black grama grass and tobosa grass sites, 137Cs was uniformly distributed at the plant interspace scale. At the mesquite sites, 137Cs was concentrated in the dune area under mesquite shrubs with little to no 137Cs in the interdune areas. 137Cs data support the hypothesis that significant soil redistribution has occurred at dune sites created by invading mesquite. In the arid grassland-shrub sites with black grama grass, tobosa grass, and tarbush the 137Cs data support the hypothesis of spatially homogeneous distribution of soil resources. High concentrations of 137Cs in the biological soil crusts (0–5 mm) at the tarbush sites indicate that biological soil crusts can contribute to the stability of these sites.  相似文献   

20.
Salinity and sodicity of groundwater are the principal water quality concerns in irrigated areas of arid and semi-arid regions. The hydrochemical characteristics and sodicity of groundwater in the Shirin Sou area, western Iran were investigated in this study by chemical analyses of groundwater samples from 49 wells. Chemical analysis of the groundwater showed that the mean concentration of the cations was in the order: Na+ > Ca2+ > Mg2+ > K+, while that for anions was SO3 2− > Cl > HCO3  > NO3 . The most prevalent water type is Na–SO4 followed by water types Na–Cl and Ca–SO4. The chemical evolution of groundwater is primarily controlled by water–rock interactions: mainly weathering of aluminosilicates, dissolution of sulfate minerals, and cation exchange reactions. Sulfate dissolution and pyrite weathering may both contribute to the SO4 2− load of the groundwater. High Na+ concentrations in groundwater participate in ion-exchange processes, resulting in the displacement of base cations into solution and raised concentrations in groundwater. The principal component analysis (PCA) performed on groundwater identified three principal components controlling variability of groundwater chemistry. Electrical conductivity, Ca2+, Mg2+, Na+, SO4 2−, and Cl content were associated in the same component (PC1) (salinity), most likely linked to anthropogenic activities.  相似文献   

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