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1.
Major element, Rb, Sr, Ba, Cr and V analyses as well as 13 new rare earth element (REE) analyses are presented for the greywacke basement surrounding the Taupo Volcanic Zone (TVZ). On this basis the basement rocks are divided into a Western Basement of approximately andesitic composition ( 62% SiO2) and an Eastern Basement of approximately granodiorite composition ( 75% SiO2). These analyses, 5 new REE analyses for the rhyolites, and published data for the volcanic rocks of TVZ are used to investigate the petrogenesis of rhyolitic rocks in the area.Least-squares mixing calculations for major elements show that 88% fractional crystallisation of high-alumina basalt produces a liquid of rhyolitic bulk composition, but Rayleigh fractionation models show that the trace element concentrations of the rhyolites are inconsistent with basalt fractionation. 57% fractionation of the assemblage plagioclase (35.6%), orthopyroxene (9.7%), clinopyroxene (7.8%), ilmenite (0.6%) and magnetite (3.4%) from a plagioclase-pyroxene andesite can produce liquids of rhyolitic bulk composition. REE concentrations produced by this model are consistent with those observed in the rhyolites but predicted Ba and Rb values are lower and V concentrations are higher than those in the rhyolites. Andesite fractionation also produces an unrealistic fractionation of the Cr/V ratio.A non-modal melting model involving 35% melting of a granulitic assemblage (plagioclase + quartz + clinopyroxene + orthopyroxene + biotite + magnetite + cordierite) with a bulk composition equivalent to the Western Basement can reproduce the REE pattern of the rhyolites as well as the concentrations of Rb and Ba. Sr values remain anomalously high, but the Cr/V ratio does not indicate fractionation. Absolute values of Cr and V are within the uncertainties of published crystal—liquid partition coefficients. The rhyolites have relatively flat REE patterns (La/Yb 7.5), as do the greywackes (La/Yb 8.2), so it is therefore unlikely that the rhyolites equilibrated with a garnet or amphibole-bearing assemblage.  相似文献   

2.
Deeply subducted carbonate rocks from the Kokchetav massif (Northern Kazakhstan) recrystallised within the diamond stability field (P = 4.5–6.0 GPa; T  1000 °C) and preserve evidence for ultra high-pressure carbonate and silicate melts. The carbonate rocks consist of garnet and K-bearing clinopyroxene embedded in a dolomite or magnesian calcite matrix. Polycrystalline magnesian calcite and polyphase carbonate–silicate inclusions occurring in garnet and clinopyroxene show textural features of former melt inclusions. The trace element composition of such carbonate inclusions is enriched in Ba and light rare earth elements and depleted in heavy rare earth elements with respect to the matrix carbonates providing further evidence that the inclusions represent trapped carbonate melt. Polyphase inclusions in garnet and clinopyroxene within a magnesian calcite marble, consisting mainly of a tight intergrowth of biotite + K-feldspar and biotite + zoisite + titanite, are interpreted to represent two different types of K-rich silicate melts. Both melt types show high contents of large ion lithophile elements but contrasting contents of rare earth elements. The Ca-rich inclusions display high REE contents similar to the carbonate inclusions and show a general trace element characteristic compatible with a hydrous granitic origin. Low SiO2 content in the silicate melts indicates that they represent residual melts after extensive interaction with carbonates. These observations suggest that hydrous granitic melts derived from the adjacent metapelites reacted with dolomite at ultra high-pressure conditions to form garnet, clinopyroxene – a hydrous carbonate melt – and residual silicate melts. Silicate and carbonate melt inclusions contain diamond, providing evidence that such an interaction promotes diamond growth. The finding of carbonate melts in deeply subducted crust might have important consequences for recycling of trace elements and especially C from the slab to the mantle wedge.  相似文献   

3.
Crystallization paths of basaltic (1763 eruption) and hawaiitic (1865 and 1329 eruptions) scoria from Etna were deduced from mineralogy and melt inclusion chemistry. The volatile behaviour was investigated through the study of melt inclusions trapped in the phenocrysts and those of the whole rocks and the matrix glasses. The results from the 1763 eruption point to the early crystallization of olivine Fo 81.7 from a water-rich alkaline basalt, with high Cl (1750–2000 ppm) and S (2100–2400 ppm) concentrations. The hawaiitic melt inclusions trapped in olivine Fo 74, salite and plagioclase are characterized by a decrease in Cl/K2O and S/K2O ratios. In each investigated system there is good correlation between K2O and P2O5. In the whole rocks, Cl ranges from 980 to 1680 ppm, from basaltic to hawaiitic lavas, whereas S (110–136 ppm) remains low. Cl and S behaviour in the 1763 magma suggests an early degassing stage of Cl and S, with CO2 and a water-rich gaseous phase for a pressure close to 100 MPa, consistent with a permanent outgassing at the summit craters of Etna. During the eruption, the sulphur remaining in the hawaiitic liquid is lost, and the degassing of chlorine is limited. Such a degassing model can be extended to the 1865 and 1329a.d. eruptions.  相似文献   

4.
Major-element, Cl, S, F analyses have been performed on a wide selection of melt inclusions trapped in olivine (Fo81–87) from scoria and crystal-rich lapilli samples of Piton de la Fournaise volcano. As a whole, they display a transitional basaltic composition. The melt inclusions (8–9 wt.% MgO, 0.62–0.73 wt.% K2O) are in equilibrium with olivines (Fo81–85) in the samples from the Central Feeding Zone and the South-East Feeding Zone and show a slight alkaline affinity. The melt inclusions in olivines (Fo85–87) from the North-West Rift (NWR) contain 9.3–9.7 wt.% MgO and 0.54–0.58 wt.% K2O, with a more tholeiitic tendency. In oceanitic lavas and crystal-rich lapilli, the olivine xenocrysts are recognisable by the presence of one or more secondary shear plane fracture(s) filled up with CO2 and alkali-rich basaltic melt inclusions. In dunite nodules, olivines present also contain several secondary shear plane fracture(s) filled up with CO2 and high-SiO2 melt inclusions. Secondary CO2-rich fluid inclusions in olivine (Fo85–87) from the NWR samples indicate PCO2 up to 500 MPa whereas, PCO2 ranges from 95 MPa to few tenths of bars in the other samples. Both the primary melt inclusions and the secondary fluid inclusions strongly suggest that the olivine crystallises and accumulates over a wide depth range (15 km). It is envisioned that cumulative pockets with low residual porosity are repeatedly percolated with a CO2-rich fluid phase, possibly associated with basaltic to SiO2-rich melts, and are finally disrupted and entrained to the surface when vigorous magma transfer occurs. The SiO2-rich residual melts in early-formed dunitic or gabbroic bodies may have acted as contaminant agents for the more alkali character of magmas vented through the central feeding system, where a well-developed cumulative system is thought to exist. Finally, the existence of secondary fluid and melt inclusions in olivines implies that the dunitic bodies are weakened on the micrometric scale.  相似文献   

5.
We present new analyses of volatile, major, and trace elements for a suite of glasses and melt inclusions from the 85°E segment of the ultra-slow spreading Gakkel Ridge. Samples from this segment include limu o pele and glass shards, proposed to result from CO2-driven explosive activity. The major element and volatile compositions of the melt inclusions are more variable and consistently more primitive than the glass data. CO2 contents in the melt inclusions extend to higher values (167–1596 ppm) than in the co-existing glasses (187–227 ppm), indicating that the melt inclusions were trapped at greater depths. These melt inclusions record the highest CO2 melt concentrations observed for a ridge environment. Based on a vapor saturation model, we estimate that the melt inclusions were trapped between seafloor depths (~ 4 km) and ~ 9 km below the seafloor. However, the glasses are all in equilibrium with their eruption depths, which is inconsistent with the rapid magma ascent rates expected for explosive activity. Melting conditions inferred from thermobarometry suggest relatively deep (25–40 km) and cold (1240°–1325 °C) melting conditions, consistent with a thermal structure calculated for the Gakkel Ridge. The water contents and trace element compositions of the melt inclusions and glasses are remarkably homogeneous; this is an unexpected result for ultra-slow spreading ridges, where magma mixing is generally thought to be less efficient based on the assumption that steady-state crustal magma chambers are absent in these environments. All melts can be described by a single liquid line of descent originating from a pooled melt composition that is consistent with the aggregate melt calculated from a geodynamic model for the Gakkel Ridge. These data suggest a model in which deep, low degree melts are efficiently pooled in the upper mantle (9–20 km depth), after which crystallization commences and continues during ascent and eruption. Based on our melting model and the assumption that CO2 is perfectly incompatible, we show that the highest CO2 concentrations of the melt inclusions (~ 1600 ppm) are consistent with the calculated CO2 concentrations of primary undegassed melts. The highest measured CO2/Nb ratio (443) of Gakkel Ridge melt inclusions predicts a mantle CO2 content of 134 ppm and would result in a global ridge flux of 2.0 × 1012 mol CO2/yr.  相似文献   

6.
Abundant fluid inclusions in olivine of dunite xenoliths (~1–3 cm) in basalt dredged from the young Loihi Seamount, 30 km southeast of Hawaii, are evidence for three coexisting immiscible fluid phases—silicate melt (now glass), sulfide melt (now solid), and dense supercritical CO2 (now liquid + gas)—during growth and later fracturing of some of these olivine crystals. Some olivine xenocrysts, probably from disaggregation of xenoliths, contain similar inclusions.Most of the inclusions (2–10 μm) are on secondary planes, trapped during healing of fractures after the original crystal growth. Some such planes end abruptly within single crystals and are termed pseudosecondary, because they formed during the growth of the host olivine crystals. The “vapor” bubble in a few large (20–60 μm), isolated, and hence primary, silicate melt inclusions is too large to be the result of simple differential shrinkage. Under correct viewing conditions, these bubbles are seen to consist of CO2 liquid and gas, with an aggregate ? = ~ 0.5–0.75 g cm?3, and represent trapped globules of dense supercritical CO2 (i.e., incipient “vesiculation” at depth). Some spinel crystals enclosed within olivine have attached CO2 blebs. Spherical sulfide blebs having widely variable volume ratios to CO2 and silicate glass are found in both primary and pseudosecondary inclusions, demonstrating that an immiscible sulfide melt was also present.Assuming olivine growth at ~ 1200°C and hydrostatic pressure from a liquid lava column, extrapolation of CO2P-V-T data indicates that the primary inclusions were trapped at ~ 220–470 MPa (2200–4700 bars), or ~ 8–17 km depth in basalt magma of ? = 2.7 g cm?3. Because the temperature cannot change much during the rise to eruption, the range of CO2 densities reveals the change in pressure from that during original olivine growth to later deformation and rise to eruption on the sea floor. The presence of numerous decrepitated inclusions indicates that the inclusion sample studied is biased by the loss of higher-density inclusions and suggests that some part of these olivine xenoliths formed at greater depths.  相似文献   

7.
A new version of COMAGMAT-3.5 model designed for computer simulations of equilibrium and fractional crystallization of basaltic magmas at low to high pressures is presented. The most important modifications of COMAGMAT include an ability to calculate more accurately the crystallization of magnetite and ilmenite, allowing the user to study numerically the effect of oxygen fugacity on basalt magma fractionation trends. Methodological principles of the use of COMAGMAT were discussed based on its thermodynamical and empirical basis, including specific details of the model calibration. Using COMAGMAT-3.5 a set of phase equilibria calculations (called Geochemical Thermometry) has been conducted for six cumulative rocks from the Marginal Border Series of the Skaergaard intrusion. As a result, initial magma temperature (1165±10°C) and trapped melt composition proposed to be parental magma to the Skaergaard intrusion were determined. Computer simulations of perfect fractionation of this composition as well as another proposed parent produced petrochemical trends opposite to those followed from natural observations. This is interpreted as evidence for an initial Skaergaard magma containing a large amount of olivine and plagioclase crystals (about 40–45%), so that the proposed and calculated parents are related through the melt trapped in the crystal–liquid mixture. This promotes the conclusion that the Skaergaard magma fractionation process was intermediate between equilibrium and fractional crystallization. In this case the classic Wager's trend should be considered an exception rather than a rule for the differentiation of ferro-basaltic magmas. A polybaric version of COMAGMAT has been applied for the genetic interpretation of a volcanic suite from the Klyuchevskoi volcano, Kamchatka, Russia. To identify petrological processes responsible for the observed suite ranging from high-magnesia to high-alumina basalts, we used the model to simulate the Klyuchevskoi suite assuming isobaric crystallization of a parental HMB magma at a variety of pressures and a separate set of simulations assuming fractionation during continuous magma ascent from a depth of 60 km. These results indicate that the Klyuchevskoi trend can be produced by 40% fractionation of Ol–Aug–Sp±Opx assemblages during ascent of the parental HMB magma over the pressure range 19–7 kbar with the rate of decompression being 0.33 kbar/% crystallized (at 1350–1110°C), with 2 wt.% of H2O in the initial melt and 3 wt.% of H2O in the resultant high-Al basalt.  相似文献   

8.
The November 2002 eruption of Piton de la Fournaise in the Indian Ocean was typical of the activity of the volcano from 1999 to 2006 in terms of duration and volume of magma ejected. The first magma erupted was a basaltic liquid with a small proportion of olivine phenocrysts (Fo81) that contain small numbers of melt inclusions. In subsequent flows, olivine crystals were more abundant and richer in Mg (Fo83–84). These crystals contain numerous melt and fluid inclusions, healed fractures, and dislocation features such as kink bands. The major element composition of melt inclusions in this later olivine (Fo83–84) is out of equilibrium with that of its host as a result of extensive post-entrapment crystallization and Fe2+ loss by diffusion during cooling. Melt inclusions in Fo81 olivine are also chemically out of equilibrium with their hosts but to a lesser degree. Using olivine–melt geothermometry, we determined that melt inclusions in Fo81 olivine were trapped at lower temperature (1,182 ± 1°C) than inclusions in Fo83–84 olivine (1,199–1,227°C). This methodology was also used to estimate eruption temperatures. The November 2002 melt inclusion compositions suggest that they were at temperatures between 1,070°C and 1,133°C immediately before eruption and quenching. This relatively wide temperature range may reflect the fact that most of the melt inclusions were from olivine in lava samples and therefore likely underwent minor but variable amounts of post-eruptive crystallization and Fe2+ loss by diffusion due to their relatively slow cooling on the surface. In contrast, melt inclusions in tephra samples from past major eruptions yielded a narrower range of higher eruption temperatures (1,163–1,181°C). The melt inclusion data presented here and in earlier publications are consistent with a model of magma recharge from depth during major eruptions, followed by storage, cooling, and crystallization at shallow levels prior to expulsion during events similar in magnitude to the relatively small November 2002 eruption.  相似文献   

9.
Among the series of eruptions at Miyakejima volcano in 2000, the largest summit explosion occurred on 18 August 2000. During this explosion, vesiculated bombs and lapilli having cauliflower-like shapes were ejected as essential products. Petrological observation and chemical analyses of the essential ejecta and melt inclusions were carried out in order to investigate magma ascent and eruption processes. SEM images indicate that the essential bombs and lapilli have similar textures, which have many tiny bubbles, crystal-rich and glass-poor groundmass and microphenocrysts of plagioclase, augite and olivine. Black ash particles, which compose 40% of the air-fall ash from the explosion, also have similar textures to the essential bombs. Whole-rock analyses show that the chemical composition of all essential ejecta is basaltic (SiO2=51–52 wt%). Chemical analyses of melt inclusions in plagioclase and olivine phenocrysts indicate that melt in the magma had 0.9–1.9 wt% H2O, <0.011 wt% CO2, 0.04–0.17 wt% S and 0.06–0.1 wt% Cl. The variation in volatile content suggests degassing of the magma during ascent up to a depth of about 1 km. The ratio of H2O and S content of melt inclusions is similar to that of volcanic gas, which has been intensely and continuously emitted from the summit since the end of August 2000, indicating that the 18 August magma is the source of the gas emission. Based on the volatile content of the melt inclusions and the volcanic gas composition, the initial bulk volatile content of the magma was estimated to be 1.6–1.9 wt% H2O, 0.08–0.1 wt% CO2, 0.11–0.17 wt% S and 0.06–0.07 wt% Cl. The basaltic magma ascended from a deeper chamber (10 km) due to decrease in magma density caused by volatile exsolution with pressure decrease. The highly vesiculated magma, which had at least 30 vol% bubbles, may have come into contact with ground water at sea level causing the large explosion of 18 August 2000.Editorial responsibility: S. Nakada, T. DuittAn erratum to this article can be found at  相似文献   

10.
The mechanics of explosive eruptions influence magma ascent pathways. Vulcanian explosions involve a stop–start mechanism that recurs on various timescales, evacuating the uppermost portions of the conduit. During the repose time between explosions, magma rises from depth and refills the conduit and stalls until the overpressure is sufficient to generate another explosion. We have analyzed major elements, Cl, S, H2O, and CO2 in plagioclase-hosted melt inclusions, sampled from pumice erupted during four vulcanian events at Soufrière Hills volcano, Montserrat, to determine melt compositions prior to eruption. Using Fourier transform infrared spectroscopy, we measured values up to 6.7 wt.% H2O and 80 ppm CO2. Of 42 melt inclusions, 81 % cluster between 2.8 and 5.4 wt.% H2O (57 to 173 MPa or 2–7 km), suggesting lower conduit to upper magma reservoir conditions. We propose two models to explain the magmatic conditions prior to eruption. In Model 1, melt inclusions were trapped during crystal growth in magma that was stalled in the lower conduit to upper magma reservoir, and during trapping, the magma was undergoing closed-system degassing with up to 1 wt.% free vapor. This model can explain the melt inclusions with higher H2O contents since these have sampled the upper parts of the magma reservoir. However, the model cannot explain the melt inclusions with lower H2O because the timescale for plagioclase crystallization and melt inclusion entrapment is longer than the magma residence time in the conduit. In Model 2, melt inclusions were originally trapped at deeper levels of the magma chamber, but then lost hydrogen by diffusion through the plagioclase host during periodic stalling of the magma in the lower conduit system. In this second scenario, which we favor, the melt inclusions record re-equilibration depths within the lower conduit to upper magma reservoir.  相似文献   

11.
Late Cenozoic alkali basalts in the Ganseong area of South Korea contain abundant ultramafic xenoliths and clinopyroxene megacrysts. Anhydrous clinopyroxene‐rich wehrlite–clinopyroxenites make up the majority of the xenolith population and range from wehrlite through olivine clinopyroxenite to clinopyroxenite. This study investigates the petrogenesis of wehrlite–clinopyroxenite xenoliths and clinopyroxene megacrysts on the basis of petrography and mineral and whole‐rock chemistry. Observations such as an absence of carbonate or apatite, high Ti/Eu ratio, and clinopyroxene‐dominated mineralogy lead us to rule out peridotite–melt reactions as the origin of the Ganseong wehrlites– olivine clinopyroxenites. The whole‐rock compositions (e.g. high abundance of CaO at a given MgO content and low abundance of incompatible elements, such as U, K, P, and Ti compared with mafic melts) indicate that the pyroxenites do not represent crystallized magma itself, but are rather cumulates with a small amount of residual liquid. Anhydrous and orthopyroxene‐free mineral assemblages, crystallization sequence of olivine→clinopyroxene→plagioclase, and mineral chemistries (e.g. low Cr# and high TiO2 abundances in spinels and high TiO2 and Na2O abundances in clinopyroxenes at a given Mg#) suggest that relatively anhydrous intraplate alkaline basalt is the most likely candidate for the parent magma. Texture and compositions of the clinopyroxene megacrysts preclude a cognate origin via high‐pressure crystallization of the host magma. The clinopyroxene megacrysts occupy the Fe‐rich end of the compositional trends defined by wehrlite–pyroxenite clinopyroxenes. Progressive decreases in Mg# and an absence of significant compositional gaps between pyroxenite xenoliths and clinopyroxene megacrysts indicate fractionation and differentiation of a similar parental magma. We suggest that the clinopyroxene megacrysts represent fragments of pegmatitic clinopyroxenites crystallized from more advanced fractionation stages of the evolution of a series of magmatic liquids formed Ganseong wehrlite–clinopyroxenites.  相似文献   

12.
CO2 fluid inclusions in mantle minerals are an im-portant source for us to get the information of mantle fluids. Fluid inclusions are mainly composed of CO2, with minor CO, H2O, CH4, N2, H2S, SO2, F, etc., which were demonstrated by lots of Raman spec-trometer analyses in recent years. In contrast, there are very few researches on CO2-bearing melt inclusions since it is more difficult to do so. The available studies have found that the primary CO2-bearing melt inclu-sions are basaltic …  相似文献   

13.
Tholeiitic basalt glasses from the FAMOUS area of the Mid-Atlantic Ridge are among the most primitive basaltic liquids reported from the ocean basins. One of the more primitive of these[Mg/(Mg+Fe2+) = 0.68;Ni= 232ppm;TiO2 = 0.61] glasses (572-1-1) was selected for an experimental investigation. This study found olivine to be the liquidus phase from 1 atm to 10.5 kbar where it is replaced by clinopyroxene. The sequence of appearance of phases at 1 atm pressure is olivine (1268°C), plagioclase (1235°C) and clinopyroxene (1135°C). The sample is multiply saturated at 10.5 kbar with olivine (Fo88), clinopyroxene (Wo32En60Fs9), and orthopyroxene (Wo5En83Fs12). From the 1-atm data we have measured (FeO/MgO) olivine/(FeO*/MgO) liquid (K′D) for olivine-melt pairs equilibrated at 12 temperatures in the range 1268–1205°C.K′D varies from 0.30 at 1205°C to 0.27 at 1268°C. Analysis of high-pressure olivine melt pairs indicates a systematic increase inK′D with pressure.Evaluation of the 1-atm experiments reveals that fractionation of olivine followed by olivine + plagioclase can generate much of the variation in major element chemistry observed in the FAMOUS basalt glasses. However, it cannot account for the entire spectrum of glass compositions — particularly with respect to TiO2 and Na2O. The variations in these components are such as to require different primary liquids.Comparison of clinopyroxene microphenocrysts/xenocrysts found in oceanic tholeiites with experimental clinopyroxenes reveal that the majority of those in the tholeiites may have crystallized from the magma at pressures greater than ~ 10 kbar and are not accidental xenocrysts. Clinopyroxene fractionation at high pressures may be a viable mechanism for fractionating basaltic magmas.The major and minor element mineral/meltK′d's from our experiments have been used to model the source region residual mineralogy for given percentages of partial melting. These data suggest that ~20% partial melting of a lherzolite source containing 0–10% clinopyroxene can generate the major and minor element concentrations in the parental magmas of the Project FAMOUS basalt glasses.  相似文献   

14.
To investigate the relationship between volatile abundances and eruption style, we have analyzed major element and volatile (H2O, CO2, S) concentrations in olivine-hosted melt inclusions in tephra from the 2000 yr BP eruption of Xitle volcano in the central Trans-Mexican Volcanic Belt. The Xitle eruption was dominantly effusive, with fluid lava flows accounting for 95% of the total dense rock erupted material (1.1 km3). However, in addition to the initial, Strombolian, cinder cone-building phase, there was a later explosive phase that interrupted effusive activity and deposited three widespread ash fall layers. Major element compositions of olivine-hosted melt inclusions from these ash layers range from 52 to 58 wt.% SiO2, and olivine host compositions are Fo84–86. Water concentrations in the melt inclusions are variable (0.2–1.3 wt.% H2O), with an average of 0.45±0.3 (1σ) wt.% H2O. Sulfur concentrations vary from below detection (50 ppm) to 1000 ppm but are mostly ≤200 ppm and show little correlation with H2O. Only the two inclusions with the highest H2O have detectable CO2 (310–340 ppm), indicating inclusion entrapment at higher pressures (700–900 bars) than for the other inclusions (≤80 bars). The low and variable H2O and S contents of melt inclusions combined with the absence of less soluble CO2 indicates shallow-level degassing before olivine crystallization and melt inclusion formation. Olivine morphologies are consistent with the interpretation that most crystallization occurred rapidly during near-surface H2O loss. During cinder cone eruptions, the switch from initial explosive activity to effusive eruption probably occurs when the ascent velocity of magma becomes slow enough to allow near-complete degassing of magma at shallow depths within the cone as a result of buoyantly rising gas bubbles. This allows degassed lavas to flow laterally and exit near the base of the cone while gas escapes through bubbly magma in the uppermost part of the conduit just below the crater. The major element compositions of melt inclusions at Xitle show that the short-lived phase of renewed explosive activity was triggered by a magma recharge event, which could have increased overpressure in the storage reservoir beneath Xitle, leading to increased ascent velocities and decreased time available for degassing during ascent.  相似文献   

15.
Erta Ale volcano, Ethiopia, erupted in November 2010, emplacing new lava flows on the main crater floor, the first such eruption from the southern pit into the main crater since 1973, and the first eruption at this remote volcano in the modern satellite age. For many decades, Erta Ale has contained a persistently active lava lake which is ordinarily confined, several tens of metres below the level of the main crater, within the southern pit. We combine on-the-ground field observations with multispectral imaging from the SEVIRI satellite to reconstruct the entire eruptive episode beginning on 11 November and ending prior to 14 December 2010. A period of quiescence occurred between 14 and 19 November. The main eruptive activity developed between 19 and 22 November, finally subsiding to pre-eruptive levels between 8 and 15 December. The estimated total volume of lava erupted is ??0.006?km3. The mineralogy of the 2010 lava is plagioclase?+?clinopyroxene?+?olivine. Geochemically, the lava is slightly more mafic than previously erupted lava lining the caldera floor, but lies within the range of historical lavas from Erta Ale. SIMS analysis of olivine-hosted melt inclusions shows the Erta Ale lavas to be relatively volatile-poor, with H2O contents ??1,300?ppm and CO2 contents of ??200?ppm. Incompatible trace and volatile element systematics of melt inclusions show, however, that the November 2010 lavas were volatile-saturated, and that degassing and crystallisation occurred concomitantly. Volatile saturation pressures are in the range 7?C42?MPa, indicating shallow crystallisation. Calculated pre-eruption and melt inclusion entrapment temperatures from mineral/liquid thermometers are ??1,150?°C, consistent with previously published field measurements.  相似文献   

16.
Ultramafic inclusions from San Carlos, Arizona, are classified into two groups. Group I inclusions are dominated by magnesian (Mg/Mg + ΣFe= 0.86 – 0.91), olivine-rich peridotites containing Cr-rich clinopyroxene and spinel. The less abundant Group I pyroxenites (containing Mg- and Cr-rich pyroxenes) occur as discrete inclusions and as portions of composite inclusions where they have a sharp, planar interface with lherzolite. Group II inclusions are dominated by clinopyroxene-rich peridotites containing Al- and Ti-rich augite and commonly abundant, Al-rich spinel. Compared to Group I inclusions, they are more Fe-rich (Mg/Mg + ΣFe= 0.62 – 0.78) and more hetereogeneous in composition and modal proportions. Similar groups occur at many ultramafic inclusion localities.Our petrographic and geochemical results lead to the following conclusions. Olivine-rich Group I inclusions are not genetically related to the host basanite, and they are formed from two components. Component A is a partial melting residue; it comprises the major portion of these inclusions and determines the modal mineralogy and major and compatible trace element composition. Component B results from a small degree (<5%) of garnet peridotite melting (probably, within the low-velocity zone). This highly LIL-element-enriched melt has migrated upwards into the overlying component A where it crystallized primarily as clinopyroxene and amphibole, and thus, introduced LIL elements into the residual component A. Subsequent cooling and subsolidus recrystallization have removed textural evidence of this mixing. This model has also been proposed for olivine-rich Group I inclusions from Victoria, Australia. At Victoria and San Carlos some relatively clinopyroxene-rich Group I lherzolites are not contaminated by component B, and they represent the best estimates of upper mantle composition prior to melting. Group I orthopyroxenites may be fragments of tectonic layers formed in lherzolite, but they could also be early cumulates (now metamorphosed) from the melt in equilibrium with component A. Group I clinopyroxenites have geochemical features of clinopyroxene in equilibrium with a magma. Thus, they could also represent early cumulates (now metamorphosed) from a magma unrelated to the host basanite. Alternatively, their geochemical characteristics could result from more complex models such as residues from partial remelting of pyroxenite dikes and veins or intradike segregation processes such as filter pressing. All Group II inclusions studied appear to be cumulates derived from a SiO2-undersaturated magma, possibly an early magma in the same volcanic episode which culminated with eruption of the host basanite. The poikilitic texture of amphibole-rich (kaersutite) inclusions is consistent with a cumulate origin. The bulk compositions of Group II inclusions are not equivalent to typical basaltic compositions.  相似文献   

17.
Infrared spectroscopic analyses of melt inclusions in quartz phenocrysts from pantellerites erupted at Pantelleria, Italy, show that the magmas contained moderate pre-eruptive H2O contents, ranging from 1.4 to 2.1 wt.%. Melt H2O concentrations increase linearly with incompatible elements, demonstrating that H2O contents were not buffered significantly during fractionation by any crystalline or vapor phase. The relatively low H2O contents of pantellerites are consistent with an origin by partial melting of alkali gabbros rather than fractional crystallization of basalt. Preeruptive H2O concentrations do not correlate with the volume or explosivity of pantellerite eruptions; decompression history is critical in determining the style of pantellerite (and other) eruptions.  相似文献   

18.
Numerous summit and parasitic eruptions of moderate potassium magnesian and high-alumina basalts and basaltic andesites, their mineralogic and geochemical features, and the composition of in situ chilled melt inclusions in the olivine of cinder lapilli discharged by Klyuchevskoi Volcano all provide evidence of the presence of magma chambers beneath the volcano. This is also supported by a dualism in the variation of CaO and Al2O3 concentrations in olivine and clinopyroxene during crystallization. The mineralogic features in the high-alumina basalts that were discharged by all parasitic eruptions of Klyuchevskoi provide evidence of magnesian magma being emplaced from a deeper chamber into a shallow high-alumina chamber. The distribution of incoherent elements in the volcano’s magnesian and aluminiferous rocks shows that they came from a single mantle source. The geochemical and mineralogic data are in good agreement with the results of geophysical surveys that concern the structure and properties of the lithosphere beneath Klyuchevskoi.  相似文献   

19.
长白山天池火山在全新世曾多次喷发,以往研究结果基本上认定至少有3期喷发物:距今约5,000a前淡黄色碱流质浮岩、距今约1,000a前灰白色碱流质浮岩和碎屑流以及距今约300a的黑色粗面质浮岩和熔结凝灰岩。喷发物斑晶矿物中含有众多熔体包裹体,形貌特征各有不同。经Leitz1350高温热台对天池火山全新世3期喷发物长石中熔体包裹体的均一法测温实验,结果表明第1,3喷发期的岩浆温度相差不大,而千年大喷发期较为复杂,揭示当时有2个不同温度段的熔体存在,为大喷发可能由2种岩浆注入和混合而触发的论点提供了线索。实验还证实,个体小的熔体包裹体易于均一,而个体较大的、尤其是含有大量子晶的熔体包裹体则很难均一;均一温度与熔体包裹体大小、何时从较快升温速率变为较慢升温速率、是否为初次升温时测量得出有关。同一颗熔体包裹体多次数升温至均一,每次得到的均一温度不同,而且每升温一次得到的均一温度均比前一次高,证实了均一过程中的确有H扩散的现象  相似文献   

20.
Two groups of rhyolites have been recognized at San Vincenzo (Tuscany, Italy). Group A rhyolites are characterized by plagioclase, quartz, biotite, sanidine and cordierite mineral assemblages. They show constant MgO and variable CaO and Na2O contents. Initial87Sr/86Sr ratios in group A samples range between 0.71950 and 0.72535, whereas the Nd isotopic compositions are relatively constant (0.51215–0.51222). Group B rhyolites are characterized by orthopyroxene and clinopyroxene as additional minerals, and show textural, mineralogical and chemical evidence of interaction with more mafic magmas. The Sr and Nd isotopic ratios range between 0.71283–0.71542 and 0.51224–0.51227 respectively. Magmatic inclusions of variable size (1 mm to 10 cm) were found in groups B rhyolites. These inclusions consist mainly of diopsidic clinopyroxene and minor olivine and biotite. They are latitic in composition and represent blobs of hybrid intermediate magmas entrained in the rhyolitic melts. These magmatic inclusions have relatively high Sr contents (996–1529 ppm) and Sr and Nd isotope-ratios of 0.70807–0.70830 and 0.51245–0.51252 respectively.87Sr/87Sr data on minerals separated from both group A and B rhyolites and magmatic inclusions reveal strong isotopic disequilibria due to the presence of both restitic and newly crystallized phases in group A rhyolites and due to interaction of rhyolites with a mantle-de-rived magma in group B rhyolites. Isotopic data on whole rocks and minerals allow us to interpret the group A rhyolites as representative of different degrees of melting of an isotopically fairly homogeneous pelitic source; conversely, group B rhyolites underwent interactions with a mantle-derived magma. The crustal source as inferred from isotopic systematics would be characterized by87Sr/86Sr and143Nd/144Nd ratios close to 0.7194 and 0.51216 respectively. The sub-crustal magma would have Sr isotopic composition close to 0.7077 and a143Nd/144Nd ratio greater than or equal to 0.51252. These isotopic features are different from those reported for the parental magmas postulated for Vulsini and Alban Hills in the nearby Roman Magmatic Province, and are similar to those of the Vesuvius and Ischia magmas.  相似文献   

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