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We present rate coefficients for rotational transitions induced in collisions between H2 molecules. Rotational levels J  ≤ 8 and kinetic temperatures T  ≤ 1000 K are considered. The interaction potential computed by Schwenke has been used, together with the quantal coupled channels method of calculating the cross-sections. Comparison is made with the more recent of previous results.  相似文献   

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The nearby Mira-like variable L2 Pup is shown to be undergoing an unprecedented dimming episode. The stability of the period rules out intrinsic changes to the star, leaving dust formation along the line of sight as the most likely explanation. Episodic dust obscuration events are fairly common in carbon stars but have not been seen in oxygen-rich stars. We also present a 10-μm spectrum, taken with the Japanese Infrared Telescope in Space satellite, showing strong silicate emission that can be fitted with a detached, thin dust shell, containing silicates and corundum.  相似文献   

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The neighbouring lines a 6D5/2– x 6Po3/2 (1272.617 Å) and a 6D5/2– w 2Po3/2 (1272.657 Å) have been observed in the UV spectrum of χ Lupi to be of comparable intensity. The latter, Δ S  = 2, transition would be expected to be very weak. The two upper states should display negligible mixing. We give a detailed, quantitative discussion of how the two upper states are in fact strongly mixed through their mixing with 3d6(3D)4p 4Po3/2, and hence we explain the relative strengths of the two UV lines.  相似文献   

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The stability of C60 and C70 fullerenes in the interstellar medium deposited on dust surface or embedded in meteorites and comets has been simulated with γ irradiation and with He+ ion bombardment. It is shown by vibrational spectroscopy that a γ radiation dose of 2.6 MGy (1 Gy = 1 joule absorbed energy per kilogram) causes partial oligomerization of both C60 and C70 fullerenes. Oligomers are made by fullerene cages chemically connected each other which can yield back free fullerenes by a thermal treatment. The amount of irreversibly polymerized fullerenes caused by 2.6 MGy as deduced as the toluene insoluble fraction has been determined as 1.7 and 15 per cent by weight, respectively, for C60 and C70 fullerene. The radiation dose generated by radionuclides decay and expected to be delivered to fullerenes buried at a depth of more than 20 m in comets and meteorites is about 3 MGy per 109 yr. Since fullerenes are by far resistant to such radiation dose they can survive for at least some billion years inside comets and meteorites and in fact have been detected inside certain carbonaceous chondrites. On the other hand, the direct exposure of fullerenes to cosmic rays for instance when they are adsorbed or deposited on the surface of carbon dust corresponds to the delivery of a radiation dose comprised between 30 and 65 MGy per 109 yr. Experimental bombardment of both C60 and C70 fullerenes for instance with He+ ions has shown that the complete amorphization occurs at about 250 MGy. Thus in ∼4 Gyr exposure to cosmic rays it is expected a complete amorphization.  相似文献   

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Radiative transfer modelling of the Infrared Space Observatory ( ISO ) spectrum of IRAS 22036+5306 has shown that its unusual 11-μm band can be suitably modelled with an alumina-olivine mixture substantially dominated by the former. The results of this work add further credence to recent findings that significant amounts of Al  2O3  dust grains are present in the dust shells of stars near or beyond the tip of the asymptotic giant branch. Indeed, in the case of IRAS 22036+5306, Al  2O3  dominates the dust composition to the extent that it shifts the 9.8-μm band due to amorphous silicates to 11 μm. IRAS 22036+5306 may be an unusual case in that the inner dust torus is maintained at a sufficiently high temperature for Al  2O3  condensation, but not silicate.  相似文献   

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We investigate the possibility of interstellar masers in transitions of the methanol isotopomers CH3OD, 13CH3OH and CH318OH, and of CH3SH. The model used, in which masers are pumped through the first and second torsionally excited states by IR radiation, has accounted successfully for the Class II masers in main species methanol, 12CH316OH. Several potential maser candidates are identified for CH3OD, their detectability depending on the enrichment of this species in star-forming regions. In 13CH3OH and CH318OH the best maser candidates are direct counterparts of the well-known 6.7- and 12.2-GHz methanol masers, but the lower interstellar abundance of these substituted species means that the expected brightness is greatly reduced. The maser candidates in CH3SH are also weak. By comparing these species we find that the large b -component of the dipole moment in methanol plays a significant role in its propensity to form masers, as does the strong torsion–rotation interaction due to the light hydroxyl frame. Thus the exceptional brightness of interstellar methanol masers is due to a favourable combination of molecular properties as well as high interstellar abundance.  相似文献   

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The evolution of the abundance of galaxy clusters depends sensitively on the value of the cosmological density parameter, Ω0. Recent ASCA data are used to quantify this evolution as measured by the cluster X-ray temperature function. A χ2 minimization fit to the cumulative temperature function, as well as a maximum-likelihood estimate (which requires additional assumptions about cluster luminosities), leads to the estimate Ω0 ≈ 0.45 ± 0.25 (1σ statistical error). Various systematic uncertainties are considered, none of which significantly enhances the probability that Ω0 = 1. These conclusions hold for models with or without a cosmological constant, i.e., with Λ0 = 0 or Λ0 = 1 − Ω0. The statistical uncertainties are at least as large as any of the individual systematic errors that have been considered here, suggesting that additional temperature measurements of distant clusters will allow an improvement in this estimate. An alternative method that uses the highest redshift clusters to place an upper limit on Ω0 is also presented and tentatively applied, with the result that Ω0  1 can be ruled out at the 98 per cent confidence level. Whilst this method does not require a well-defined statistical sample of distant clusters, there are still modelling uncertainties that preclude a firmer conclusion at this time.  相似文献   

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The Cepheus A star-forming region has been investigated through a multiline H2S and SO2 survey at millimetre wavelengths. Large-scale maps and high-resolution line profiles reveal the occurrence of several outflows. Cep A East is associated with multiple mass-loss processes: in particular, we detect a 0.6-pc jet-like structure which shows for the first time that the Cep A East young stellar objects are driving a collimated outflow moving towards the south.
The observed outflows show different clumps associated with definitely different H2S/SO2 integrated emission ratios, indicating that the gas chemistry in Cepheus A has been altered by the passage of shocks. H2S appears to be more abundant than SO2 in high-velocity clumps, in agreement with chemical models. However, we also find quite small H2S linewidths, suggestive of regions where the evaporated H2S molecules had enough time to slow down but not to freeze out on to dust grains. Finally, comparison between the line profiles indicates that the excitation conditions increase with the velocity, as expected for a propagation of collimated bow shocks.  相似文献   

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The attempt to understand the temperature dependence of the HNC/HCN abundance ratio in interstellar clouds has been long standing and indecisive. In this paper we report quantum chemical and dynamical studies of two neutral–neutral reactions thought to be important in the formation of HNC and HCN, respectively – C+NH2→HNC+H, and N+CH2→HCN+H. We find that although these reactions do lead initially to the products suggested by astronomers, there is so much excess energy available in both reactions that the HCN and HNC products are able to undergo efficient isomerization reactions after production. The isomerization leads to near equal production rates of the two isomers, with HNC slightly favoured if there is sufficient rotational excitation. This result has been incorporated into our latest chemical model network of dense interstellar clouds.  相似文献   

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