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1.
贵州省兴义市雄武地区金矿主要为卡林型,其次为红土型,矿床受断裂构造控制,矿石为中等含硫微细浸染状氧化矿石。目前浅部矿石已基本采完,深部矿石品位较低(0.8~1.8 g/t),因此有效提高低品位矿石浸出率和金回收率至关重要。研究表明,筑堆时矿石粒度和喷淋时氰化钠浓度是堆浸生产中的重要影响因素。矿石粒度大,金浸出率低;氰化钠浓度大,则成本增加。根据矿石物质成分和工艺特征研究,得到矿石冶炼时的最佳工艺条件:筑堆时矿石粒度为15~25 mm,氰化钠浓度为0.05%~0.08%。该研究有效提高了矿石浸出率,降低了运营成本,为金矿石堆浸实际生产提供了理论和实验依据。  相似文献   

2.
针对青海省某金矿采用常规的氰化浸出效果不佳(金浸出率仅为8.19%)和含较高的砷、硫的情况和特点,进行了可选性试验研究。摇床重选虽然可获得品位较高的金精矿,但其回收率太低。浮选试验表明,采用一粗三精三扫的浮选闭路流程,可获得品位为72.72g/t,回收率为88.74%的浮选金精矿,选别指标较为理想。确定的最佳操作条件为...  相似文献   

3.
微细浸染型金矿床主要产于长城系高硅质岩石和碳酸盐岩石中,但在其它时代的细碎屑岩——碳酸盐沉积建造中也有发现。推测金很可能呈超显微状态存在。目前世界上对此类型金矿,一般采用堆浸方法回收金。但是此方法对高硅质矿石的浸出率不理想。对此类难浸矿石均进行预处理,以提高金的浸出率。  相似文献   

4.
张渊  佘振宝  李俊锋 《世界地质》2001,20(3):267-271
研究分析对比了不同类型选金矿石的特点,采用复合处理剂湿法预处理-提金新方法使吉林白山地区微细浸染型难选金矿石选金回收率由27%-57%提高到92%以上。  相似文献   

5.
东大滩锑金矿微生物预氧化提金试验研究   总被引:1,自引:0,他引:1  
王金祥 《陕西地质》2001,19(1):93-98,102
介绍了东大滩难浸金矿石微生物预氧化的方法及结果。东大滩石英脉型锑金矿石因金被毒砂包裹而难浸,采用微生物预氧化处理后全泥氰化金的浸出率由原来的17.04%提高到70.80%,柱浸由15.39%提高到63.02%,且酸耗较低,各项指标合理,是解决该类矿石难浸的理想方法。  相似文献   

6.
高砷高锑金矿石属难处理矿石之一,通过对两岔河高砷高锑金矿石采用碱浸预处理后进行堆浸和池浸氰化提金试验,获得了金浸出率76.80%和86.76%的较好指标,为该矿床的开发利用提供了一个工艺简单、经济上可行的途径。  相似文献   

7.
张永奎  宋航 《矿物岩石》2003,23(4):80-84
四川某金矿是一种难浸金矿,因为矿石中的金被包裹于含铁硫化矿物中,而且含有机炭质物。细菌Hst能有效氧化金矿中的硫化矿物以提高金的浸出率。如果细菌氧化矿石中铁的浸出率大于90%,金几乎完全解离,金的氰化浸出率大于90%。研究表明,该金矿的难浸特性是因为金包裹于含铁硫化矿物中,有机炭质物和粘土矿物对金浸出影响甚微。  相似文献   

8.
在磨矿中加入助磨剂是有效提高磨矿效率的一个重要途径,但在我国的研究还很少。对吉林某金矿的磨矿进行了助磨剂的试验研究,试验表明:在选定的条件下,选用二氧化锰、乙醇作为助磨剂可以使磨矿时间由120min缩短到90min左右,磨矿效率提高20%左右,而且环境污染小。本试验对其它矿山的磨矿作业也有很大的参考价值。  相似文献   

9.
We investigate the performance of sample preparation of gold ores using vibratory (bowl, ring and puck type) mills in common use in mineral analytical laboratories. The main criteria for effective grinding are using reduced grinding charge masses ≤ ca. 50% of nominal bowl capacity and using a grinding aid to prevent caking. We show that gold particles of millimetre scale can be comminuted to ≤ 100 µm by grinding in silica flour, bauxite, synthetic carborundum, or mixtures of silica and these materials using times of up to 5 min and that 95% < 50 µm is achievable with extended grinding. This suggests that modified grinding techniques can be used to make sample masses ≤ 5 g viable for routine determination of gold in geological samples. We also demonstrate homogenisation of a gold‐bearing copper sulfide mineral flotation concentrate alone and in mixtures with silica by extended grinding at reduced charge masses. To support this work, we develop a convenient new benchmark of gold ore sample preparation performance ‘G’, an apparent maximum gold particle size interpolated from replicate analytical variance in order to overcome the limitations of laborious sieve fraction analysis of gold particle size. We show useful agreement between G and sieve fraction analysis of gold particle size in samples and test the viability of G experimentally and by analysis of literature data.  相似文献   

10.
卡林型金矿石中金的赋存状态分析新方法   总被引:1,自引:1,他引:0  
卡林型金矿富含有机质,金主要呈显微一超显微分散状态存在,利用工艺矿物学参数自动检测分析仪(MLA)及传统化学方法只能大致判断矿石中金的赋存趋势,无法对其赋存状态准确定量.本文利用MLA仪器系统分析贵州回龙卡林型金矿,测得矿石中金主要以显微-超显微状态包裹于黄铁矿和毒砂中,少量被脉石等其他矿石包裹;黄铁矿约66%完全解离,而毒砂仅30%完全解离,载金矿物与其他矿物连生或者被包裹,将不利于硫化物包裹金的浸出.结合回龙金矿石中金的赋存特征和富含有机质的特点,对传统的物相分析流程进行改进,调整了硫化物包裹金和碳酸盐包裹金的浸出顺序,提出裸露金-碳酸盐包裹金-硫化物包裹金-硅酸盐包裹金的浸出流程,在裸露金及碳酸盐包裹金浸出时加入活性炭,利用竞争吸附抑制矿石中有机炭对金的吸附,降低有机炭对分相的影响.对比试验结果表明,采用改进的方法,有机炭含量在1%左右的金矿石分相时加入活性炭对各相测定值的影响不大;先浸出碳酸盐包裹金,再测定硫化物包裹金,各相的测定数据更加准确.改进的方法(加活性炭)用于测定回龙金矿中裸露金和碳酸盐、硫化物、硅酸盐包裹金,含量分别为1.25%、84.17%、11.46%和3.13%,与选矿试验结果相一致,表明该法适合应用于卡林型金矿中金的赋存状态分析.  相似文献   

11.
A new mathematical model was developed for leaching of zinc ores containing silicates such as hemimorphite which produce a gel during leaching with sulfuric acid. This model is based on the shrinking core model in which the particle size and the reacting core shrink simultaneously. It was shown that the actual dissolution time of the ore particles is longer than the time corresponding to the dissolution of chemical zinc oxide itself. It was suggested that because of the existence of silicates in the ore, a gelatinous layer was formed around the reacting core. Since the gel product is soft, it breaks apart when the particles collide and as a result, the particles shrink. However, a thin gelatinous layer always covers the reacting core which increases the mass transfer resistance and increases the leaching time. This model was applied to leaching of a zinc-rich tailing containing hemimorphite and the thickness of the gelatinous layer as well as the diffusion coefficient in this layer was determined.  相似文献   

12.
Within the Eastern Desert of Egypt, there are more than a hundred vein-type gold deposits and occurrences. Gold was mined in the Dynastic and Roman periods of the Egyptian history and most of the attention was focused entirely on the near-surface high grade parts of these veins. Currently, besides the more problematic sulfide-rich quartz veins, which generally occur in the lower levels of the worked out auriferous quartz veins, some targets including wall-rock alteration, listwaenite, dumps and tailings of ancient mines, by-product gold hosted in volcanogenic massive sulfide deposits and gold-bearing Algoma-type BIF, as well as alluvial gold constitute the new targets for gold in the Eastern Desert of Egypt. In most of these targets, gold displays a bimodal distribution; occurring both as free-milling gold and in the form of sub-microscopic or “invisible” gold in refractory sulfides and sulfoarsenides such as pyrite, chalcopyrite, arsenopyrite, gersdorffite and pentlandite minerals.Characterizing gold in an ore is important in extraction metallurgy. Free-milling gold can be efficiently recovered by crushing, grinding and cyanidation without additional processing. In refractory ores, on the other hand, conventional milling can liberate the sulfides from the gangue allowing a low content of concentrate to be produced by a process such as flotation. However, direct leaching of the concentrate results in poor gold extractions as the cyanide lixiviant is unable to contact the gold locked within the refractory host. Oxidative pretreatment is required for such ores and the methods available for oxidation are roasting (calcination), pressure oxidation, and bacterial oxidation; all oxidize the refractory minerals in the ore to render the gold amenable to cyanidation. While such oxidative methods are capable of achieving reasonable recoveries, they increase the capital and operating costs. An alternative, applicable to the liberation of gold from the refractory host, is to continue the grinding process to reduce the particle size of the host mineral thereby exposing a part of the gold surface for contact with the cyanide solution. A benefit of this technique is that the environmental aspects of the oxidation reaction products are avoided, however the ultra fine grinding also adds more operating costs.Metallurgical studies carried out on some gold deposits, dumps and tailings of ancient gold mines in Egypt, proved that these ores are amenable to percolation leaching (concentration of KCN varies between 0.5 and 1 g/L) for the (− 10 mm) grain size, and consequently heap leaching is a successful technique as the results of these laboratory scale column tests show. In most of these studies, a marked improvement in the percent of gold recovery was gained when the crushed ore is agglomerated by the addition of water, lime and/or cement particularly in ores containing significant quantities of clay minerals and clay-forming minerals (e.g. sericite and muscovite), and by addition of kerosene which passivates the adsorption surfaces on the graphite.Placer gold is recovered by gravity methods utilizing the large difference in specific gravity between gold and commonly associated minerals such as quartz and feldspar. The equipments range from a simple pan to more complex devices used in gold recovery plants and dredges.Modern studies in Egypt point to the presence of different targets of gold; diverse in their gold content, mode of occurrence of gold and the metallurgical treatments required for extracting gold. With the advance of modern techniques such as Electron Microprobe Analyses (EMPA), laser Ablation Microprobe Inductively Coupled Plasma Mass Spectroscopy (LAM-ICP-MS), gold ores in Egypt should be re-characterized precisely to know the specifications of these ores and consequently predict the metallurgical regime required, and with the high world gold price, it has become necessary to take into consideration the presence of refractory gold ores as one of these targets in Egypt. Generally speaking, laboratory experiments conducted on gold processing in Egypt are encouraging to some extent; however the gold extraction rates of the free milling ores with conventional cyanidation and refractory ores with direct and pretreatment techniques can be improved by modifying the conditions of extraction to be consistent with the results obtained from the re-characterization stage. Otherwise any target for gold and whatsoever the mode of occurrence of gold in this target (i.e. free-milling and/or refractory) could be recovered directly by heap leaching technique and we should accept less than ideal gold recovery for any target when weighed against the capital expenditure required for processes such as roasting, and the continuous grinding processes which might improve recoveries by only a small percentage.  相似文献   

13.
Gold recovery from a refractory pyrrhotite ore by biooxidation   总被引:1,自引:0,他引:1  
The aim of the present investigation was to study the biooxidation of a refractory gold-bearing pyrrhotite, in order to increase the gold recovery during the subsequent conventional cyanidation.Bacterial cultures utilised in the biological test consisted predominantly of Thiobacillus genus. Tests were conducted at laboratory scale. The gold content of the ore sample, coming from Bolivia, was of 10 g t−1 Au.After 24 h leaching time by direct cyanidation, low gold recovery was obtained (<20% Au), with a high reagent consumption. On the other hand, a high gold recovery was achieved for the biooxidated samples: after 24 h cyanidation gold dissolution reached about 91% Au.Experimental results have shown the technical feasibility of the biooxidative pretreatment prior to conventional leaching and a complete circuit of treatment, on laboratory scale, has been developed considering also the subsequent gold recovery by carbon adsorption/desorption and electrowinning.A gold extraction yield of about 86% was determined in the whole process for gold extraction from pyrrhotite (biooxidation, solid–liquid separation, cyanidation, adsorption, desorption, electrowinning).  相似文献   

14.
蔡淑霞  张云 《地质与资源》1992,1(4):235-242
本文介绍了堆浸提金原理和在实验室进行金矿石堆浸可行性研究的方法.以我国辽宁猫岭金矿、四川茶铺子金矿和福建紫金山金矿为研究对象,研究了矿石粒度、氰化钠溶液浓度、浸出时间等因素对金浸出率的影响,从而确定堆浸提金最佳工艺条件.通过对上述三类矿石性质及堆浸性能的比较,认为矿石的物质组成和金的嵌布特性对金的浸出率影响较大.  相似文献   

15.
A comparative analysis of morphology and geochemistry was made for gold from the primary ores and weathering crust of the Suzdal' gold deposit, Eastern Kazakhstan. The deposit is localized in Carboniferous carbonaceous-terrigenous strata and is of gold-sulfide type. Study of gold from primary ores showed that it occurs mainly in two species: free and so-called invisible. Free gold is crystallomorphic segregations and irregular-shaped grains up to tens of microns in size; it occurs in intergrowths with sulfides, quartz, carbonate, and mica-chlorite aggregate. Most of gold particles have a fineness of 930–980‰, with some grains showing wide variations in composition. Invisible gold (probably chemically combined) is present in fine-acicular arsenopyrite and, less frequently, pyrite.Being transported to the weathering crust, all this gold served as a source for “neogenic” gold of diverse morphologic forms. We recognized crystalline (isometric, prismatic, acicular, and tabular) particles and drusoid gold aggregates in the form of exotic intergrowths of crystallomorphic and sinter-shelly grains. The grains tend to coarsen from bottom to top of the weathering crust. Several generations of gold of different granulometric classes are observed. We have revealed seed and layer growth and dissolution structures in crystals of early generations overgrown with fine grains. All these gold varieties are associated with hypergene minerals. Most of this gold is of high fineness (on the average, 995‰). The hypergene gold particles are chemically homogeneous high-grade, without rims.The results of studies suggest that the high-grade hypergene gold formed in the weathering crust as a result of the dissolution of invisible gold of sulfides and its local redistribution and deposition in oxidizing media. This is also evidenced from the tendency of gold to coarsen from bottom to top of the weathering crust. A distinctive feature of secondary gold is well-expressed crystals and their great diversity.  相似文献   

16.
甘肃天水李子金矿床物质组分及金银赋存状态研究   总被引:1,自引:0,他引:1  
刘云华 《地质与勘探》2011,47(5):837-845
甘肃天水李子金矿具有斑岩型和韧性剪切带型两种类型的金矿床。本文在详细野外工作的基础上,采用光薄片鉴定、人工重砂分析、化学成分分析、化学物相分析、电子探针波谱分析等技术方法,查明了矿床主要具有蚀变岩型和石英脉型两种金矿石类型,其中韧性剪切带型金矿矿石类型主要为石英脉型,斑岩型金矿矿石类型主要为斑岩型-蚀变岩型;韧性剪切带...  相似文献   

17.
陆文  孙骥  周超  郭爱民  彭薇 《地球学报》2020,41(3):384-394
雁林寺金矿位于雪峰弧形构造带(江南造山带湖南段)东段,是湘东北地区一个较为典型的金矿床。本文在前人研究的基础上,统计分析了矿区不同地质体Au元素含量、稀土元素地球化学、微量元素地球化学特征,对比研究了矿区含金石英的H-O同位素、Sr同位素地球化学特征及成矿流体组成特征。提出赋矿围岩冷家溪群浊积岩在沉积阶段就具有明显的金富集。矿区矿石、(矿化)蚀变围岩、未蚀变围岩稀土、微量元素地球化学特征呈现出高度相似性。含金石英的H-O同位素地球化学、Sr同位素地球化学及成矿流体成分特征表明成矿流体为变质流体。综合矿区地质特征、不同地质体金含量、稀土-微量元素地球化学特征、H-O同位素、Sr同位素及成矿流体成分特征,认为地层中的金元素为雁林寺金矿床提供了成矿物质。  相似文献   

18.
利用细菌对难处理金矿进行浸出处理,具有成本低廉、环境污染小、处理效率高等突出优点,已成为非常有前途的难处理金矿的预处理方法。笔者以河北遵化滑石峪金矿(含金黄铁矿)样品为例,在几种氧化亚铁硫杆菌中发现D3菌种处理此类难浸金矿有显著的增大提金率的效果。在200目粒度条件下,氰化提金率从单纯氰化的63.9%提高到细菌预处理后再氰化的88.2%,而且对100目以下的大粒度金矿,提金率也普遍提高10%以上;此外,还进行了该菌种处理金矿过程的条件实验,如粒度影响、pH值变化和物理方法强化的研究,得出了金矿在细菌氧化过程中的一些规律和在实际操作时的最优化控制条件。  相似文献   

19.
This paper, taking the finely disseminated gold deposits in southwestern Guizhou and northwestern Guangxi as examples, discusses the difference between the occurrence of primary ores and that of oxidized ores, analyzes the occurrence mechanism in terms of crystallochemistry and geochemistry, and especially studies the chemical model for supergene leaching transformation of clay minerals in the two types of ores. This study proposes a new idea for dressing and smelting technology for primary gold ores.  相似文献   

20.
金龙山金矿床位于南秦岭造山带的复理石褶冲带中,赋矿围岩为碎屑岩-碳酸盐建造,矿化明显受地层岩性与韧-脆性构造发育程度的控制。矿床稀土元素地球化学研究表明,地层岩石、矿石和热液矿物的轻重稀土分异程度和特征参数基本一致,表明成矿流体应主要来自于赋矿地层。铅同位素研究表明,地层岩石、矿石和热液矿物均具有较高的放射性成因的铅同位素组成,且均落入南秦岭造山带的泥盆系范围内,暗示铅也主要来自赋矿地层。对前人已有的碳-氧-硫-氢同位素组成和流体包裹体数据综合分析表明,碳和氧应主要来自海相碳酸盐的溶解作用,硫主要来自海相硫酸盐的热化学还原反应;从成矿早阶段到晚阶段,成矿流体的δ18O及δD值向大气降水线"漂移",指示成矿流体以盆地建造水和变质水为主,在晚阶段有大气降水加入。金龙山金矿床与卡林型金矿床的矿床地质-地球化学特征相似,应属于卡林型金矿床,其形成于秦岭造山带陆内造山作用过程中,多层次陆壳叠置加厚的地球动力学背景,是陆内碰撞造山作用的产物。  相似文献   

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