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1.
The Tarutung Basin is located at a right step-over in the northern central segment of the dextral strike-slip Sumatran Fault System (SFS). Details of the fault structure along the Tarutung Basin are derived from the relocations of seismicity as well as from focal mechanism and structural geology. The seismicity distribution derived by a 3D inversion for hypocenter relocation is clustered according to a fault-like seismicity distribution. The seismicity is relocated with a double-difference technique (HYPODD) involving the waveform cross-correlations. We used 46,904 and 3191 arrival differences obtained from catalogue data and cross-correlation analysis, respectively. Focal mechanisms of events were analyzed by applying a grid search method (HASH code). Although there is no significant shift of the hypocenters (10.8 m in average) and centroids (167 m in average), the application of the double difference relocation sharpens the earthquake distribution. The earthquake lineation reflects the fault system, the extensional duplex fault system, and the negative flower structure within the Tarutung Basin. The focal mechanisms of events at the edge of the basin are dominantly of strike-slip type representing the dextral strike-slip Sumatran Fault System. The almost north–south striking normal fault events along extensional zones beneath the basin correlate with the maximum principal stress direction which is the direction of the Indo-Australian plate motion. The extensional zones form an en-echelon pattern indicated by the presence of strike-slip faults striking NE–SW to NW–SE events. The detailed characteristics of the fault system derived from the seismological study are also corroborated by structural geology at the surface.  相似文献   

2.
A conceptual groundwater flow model was developed for the crystalline aquifers in southeastern part of the Eastern region, Ghana. The objective was to determine approximate levels of groundwater recharge, estimate aquifer hydraulic parameters, and then test various scenarios of groundwater extraction under the current conditions of recharge. A steady state groundwater flow model has been calibrated against measured water levels of 19 wells in the area. The resulting recharge is estimated to range from 8.97 × 10?5 m/d to 7.14 × 10?4 m/d resulting in a basin wide average recharge of about 9.6% of total annual precipitation, which results in a basin wide quantitative recharge of about 2.4 million m3/d in the area. This compares to recharge estimated from the chloride mass balance of 7.6% of precipitation determined in this study. The general groundwater flow in the area has also been determined to conform to the general northeast–southwest structural grain of the country. The implication is that the general hydrogeology is controlled by post genetic structural entities imposed on the rocks to create ingresses for sufficient groundwater storage and transport. Calibrated aquifer hydraulic conductivities range between 0.99 m/d and over 19.4 m/d. There is a significant contribution of groundwater discharge to stream flow in the study area. Increasing groundwater extraction will have an effect on stream flow. This study finds that the current groundwater extraction levels represent only 0.17% of the annual recharge from precipitation, and that groundwater can sustain future increased groundwater demands from population growth and industrialization.  相似文献   

3.
Groundwater at the southern and eastern edges of France’s Paris Basin has a selenium content that at times exceeds the European Framework Directive’s drinking-water limit value of 10 μg/L. To better understand the dynamics of the Chalk groundwater being tapped to supply the city of Lille and the Se origins, we used a combination of geochemical and isotopic tools. Strontium isotopes, coupled with Ca/Sr, Mg/Sr and Se/Sr ratios, were used to identify the main groundwater bodies and their mixings, with the Mg/Sr and Se/Sr ratios constraining a ternary system. Groundwater in the agricultural aquifer-recharge zone represents a first end-member and displays the youngest water ages of the catchment along with the highest Sr isotopic signature (0.70842) and low Se contents. Anaerobic groundwater constitutes a second major end-member affected by water-rock interactions over a long residence time, with the lowest Sr isotopic signature (0.70789) and the lowest Se content, its low SF6 content confirming the contribution of old water. Se-rich groundwater containing up to 30 μg/L of Se represents a third major end-member, with an intermediate Sr isotopic ratio (0.70826), and is mainly constrained by the clayey Se-rich formation overlying the Chalk aquifer. The spatial and temporal Se variability in the groundwater is clearly linked to the presence of this formation identified as Tertiary and also to the hydrological conditions; saturation of the Se-rich clays by oxygenated groundwater enhances Se mobility and also Sr adsorption onto the clays. This multi-tool study including Sr isotopes successfully identified the Se origins in the aquifer and has led to a better understanding of the regional mixing and processes affecting the Chalk groundwater.  相似文献   

4.
Understanding the roles of Cenozoic strike-slip faults in SE Asia observed in outcrop onshore, with their offshore continuation has produced a variety of structural models (particularly pull-apart vs. oblique extension, escape tectonics vs. slab-pull-driven extension) to explain their relationships to sedimentary basins. Key problems with interpreting the offshore significance of major strike-slip faults are: (1) reconciling conflicting palaeomagnetic data, (2) discriminating extensional, and oblique-extensional fault geometries from strike-slip geometries on 2D seismic reflection data, and (3) estimating strike-slip displacements from seismic reflection data.Focus on basic strike-slip fault geometries such as restraining vs. releasing bends, and strongly splaying geometries approach the gulfs of Thailand and Tonkin, suggest major strike-slip faults probably do not extend far offshore Splays covering areas 10,000’s km2 in extent are characteristic of the southern portions of the Sagaing, Mae Ping, Three Pagodas and Ailao Shan-Red River faults, and are indicative of major faults dying out. The areas of the fault tips associated with faults of potentially 100 km+ displacement, scale appropriately with global examples of strike-slip faults on log–log displacement vs. tip area plots. The fault geometries in the Song Hong-Yinggehai Basin are inappropriate for a sinistral pull-apart geometry, and instead the southern fault strands of the Ailao Shan-Red River fault are interpreted to die out within the NW part of the Song Hong-Yinggehai Basin. Hence the fault zone does not transfer displacement onto the South China Seas spreading centre. The strike-slip faults are replaced by more extensional, oblique-extensional fault systems offshore to the south. The Sagaing Fault is also superimposed on an older Paleogene–Early Miocene oblique-extensional rift system. The Sagaing Fault geometry is complex, and one branch of the offshore fault zone transfers displacement onto the Pliocene-Recent Andaman spreading centre, and links with the West Andaman and related faults to form a very large pull-apart basin.  相似文献   

5.
Qiongdongnan Basin is a Cenozoic rift basin located on the northern passive continental margin of the South China Sea. Due to a lack of geologic observations, its evolution was not clear in the past. However, recently acquired 2-D seismic reflection data provide an opportunity to investigate its tectonic evolution. It shows that the Qiongdongnan Basin comprises a main rift zone which is 50–100 km wide and more than 400 km long. The main rift zone is arcuate in map view and its orientation changes from ENE–WSW in the west to nearly E–W in the east. It can be divided into three major segments. The generally linear fault trace shown by many border faults in map view implies that the eastern and middle segments were controlled by faults reactivated from NE to ENE trending and nearly E–W trending pre-existing fabrics, respectively. The western segment was controlled by a left-lateral strike-slip fault. The fault patterns shown by the central and eastern segments indicate that the extension direction for the opening of the rift basin was dominantly NW–SE. A semi-quantitative analysis of the fault cut-offs identifies three stages of rifting evolution: (1) 40.4–33.9 Ma, sparsely distributed NE-trending faults formed mainly in the western and the central part of the study area; (2) 33.9–28.4 Ma, the main rift zone formed and the area influenced by faulting was extended into the eastern part of the study area and (3) 28.4–20.4 Ma, the subsidence area was further enlarged but mainly extended into the flanking area of the main rift zone. In addition, Estimates of extensional strain along NW–SE-trending seismic profiles, which cross the main rift zone, vary between 15 and 39 km, which are generally comparable to the sinistral displacement on the Red River Fault Zone offshore, implying that this fault zone, in terms of sinistral motion, terminated at a location near the southern end of the Yinggehai Basin. Finally, these observations let us to favour a hybrid model for the opening of the South China Sea and probably the Qiongdongnan Basin.  相似文献   

6.
Rock Mass Rating (RMR) measurements from 65 sites within Huntly East underground coal mine are presented. All measurements are in coal, for which the dominant discontinuities are vertical cleat. Basic RMR values using two discontinuity spacings are presented: overall RMR based on the average spacing of all individual discontinuities; and cleat zone RMR based on the average spacing between zones of cleat. Cleat orientations are highly variable, but on average approximately parallel horizontal stress axes (face cleat follows maximum horizontal stress axis, butt cleat follows minimum horizontal stress axis).Contours of RMR variations throughout the mine are used to compare rock mass conditions with geological structure. It is apparent that: (1) RMR is least within downthrown fault blocks, and particularly immediately on the downthrown sides of faults, and greatest in upthrown fault blocks; and (2) RMR contours parallel horizontal stress axes within fault-bounded blocks, and bend to parallel faults at block boundaries. From similar contours for parameters contributing to RMR, the Rock Quality Designation (RQD), groundwater rating, and discontinuity condition rating create most of the observed variations in RMR. RQD is determined from the measured discontinuity frequency and hence is a measure of the degree of fracturing of the rock mass. This is interpreted as influencing the groundwater and condition parameters directly by allowing greater water ingress. Discontinuity frequency is greatest (least spacing) in the immediate vicinity of faults, and in downthrown fault blocks, generating low RMR values. Within fault blocks RQD varies little, so RMR contours align with cleat orientations.As RMR contours, faults, stress field and cleat orientation are clearly interrelated, there is unequivocally a connection between RMR and structural geology; this allows some predictive capacity in terms of ground conditions. If geological features can be accurately defined through either drilling programs or seismic surveys, then ground conditions may be predicted before panels are driven.  相似文献   

7.
The 1200 km-long North Anatolian Transform Fault connects the East Anatolian post-collisional compressional regime in the east with the Aegean back-arc extensional regime to the west. This active dextral fault system lies within a shear zone reaching up to 100 km in width, and consists of southward splining branches. These branches, which have less frequent and smaller magnitude earthquake activity compare to the major transform, cut and divide the shear zone into fault delimited blocks. Comparison of palaeomagnetic data from 46 sites in the Eocene volcanics from different blocks indicate that each fault-bounded block has been affected by vertical block rotations. Although clockwise rotations are dominant as expected from dextral fault-bounded blocks, anticlockwise rotations have also been documented. These anticlockwise rotations are interpreted as due to anticlockwise rotation of the Anatolian Block, as indicated by GPS measurements, and the effects of unmapped faults or pre-North Anatolian Fault tectonic events.  相似文献   

8.
According to GPS monitoring, recent tectonic process between Tarim and West Siberia in the band within 80°–95° E is generated by the northward movement of the Tarim block. During the accompanying horizontal compression of the area, orogeny takes place within linear mobile zones when blocks are squeezed into the upper half-space. When the orientation of the mobile zones is transverse to the compression direction, the leading orogenic process is reverse faulting. When these directions intersect at an acute angle, the principal features of the mountain relief are formed by oblique-slip and strike-slip faults.The spatial distribution of seismic activity A10 over a 40-year period of instrumental observations within the mobile zones of the study area is extremely nonuniform. Seismic activity increases to the south, toward the source of deformations—the Indo-Eurasian collision. The maximum activity is observed at the reverse-fault boundaries of the eastern Tien Shan (~ 40). The seismic activity of the strike-slip fault boundaries of the Great Altai is considerably lower (0.11–0.16).  相似文献   

9.
《Applied Geochemistry》2005,20(2):241-254
The hydrochemistry in the largest polder of the Oder River, named Oderbruch, is affected by long-term infiltration of water from the Oder into the aquifer below an alluvial loamy top layer of the polder. These exceptional hydraulic conditions are a result of dyke constructions which were built more than 250 a ago. The objective of this investigation is a better understanding and a characterisation of the contact zone between the anaerobic groundwater and the surface water of a vast drainage system. Induced by changing water levels, different hydraulic conditions occur, which strongly influence the hydrochemistry of the shallow aquifer and therefore the natural sink function of the polder area.Field investigations with a hydrochemical and hydraulic characterisation of selected drainage ditch locations show considerable chemical interactions between groundwater and surface water. Depending on the drainage ditch type, which is defined by the hydraulic situation, the redox processes create a chemical gradient combined with a distinct enrichment of Fe and Mn. The source of the high amounts of Fe and Mn in the groundwater are reduced Fe- and Mn-hydroxides from the aquifer sediments.Under exfiltrating conditions interrupted by dry phases, more than 50 g kg−1 Fe and 0.25 g kg−1 Mn have accumulated in the drainage ditch floor sediments since the construction of the drainage ditches 35 a ago. The results show a very effective fixation of trace metals in the drainage ditch sediments under these conditions. Under permanent exfiltration conditions, the enrichment of Fe and Mn is relatively low. The maximum Fe content was 4 g kg−1 sediment and the Mn content reached only 0.4 g kg−1. This is less than 10% of the mobile Fe2+ and less than 1% of the Mn2+ which migrates from the aquifer into the surface water.  相似文献   

10.
Transient Electromagnetic (TEM), known also as Time Domain Electromagnetic (TDEM) and Magnetic Resonance Sounding (MRS) methods were applied jointly to investigate variations in lithology and groundwater salinity in the Nahal Hever South area (Dead Sea coast of Israel). The subsurface in this area is highly heterogeneous and composed of intercalated sand and clay layers over a salt formation, which is partly karstified. Groundwater is very saline, with a chloride concentration of 100–225 g/l. TEM is known as an efficient tool for investigating electrically conductive targets like saline water, but it is sensitive to both the salinity of groundwater and the porosity of rocks. MRS, however, is sensitive primarily to groundwater volume, but it also allows delineating of lithological variations in water-saturated formations. MRS is much less sensitive to variations in groundwater salinity in comparison with TEM. We show that MRS enables us to resolve the fundamental uncertainty in TEM interpretation caused by the equivalence between groundwater resistivity and lithology. Combining TEM and MRS, we found that the sandy Dead Sea aquifer filled with Dead Sea brine is characterized by a bulk resistivity of ρx > 0.4 Ωm, whereas zones with silt and clay in the subsurface are characterized by a bulk resistivity of ρx < 0.4 Ωm. These observations are confirmed by calibration of the TEM method performed near 18 boreholes.  相似文献   

11.
This study investigates the hydraulic conductivity field and the groundwater flow pattern as predicted by a calibrated steady state groundwater flow model for the Keta Strip, southeastern Ghana. The hydraulic conductivity field is an important parameter in evaluating aquifer properties in space, and in general basin-wide groundwater resources evaluation and management. This study finds that the general hydraulic conductivity of the unconsolidated unconfined aquifer system of the Keta Strip ranges between 2 m/d and 20 m/d, with an average of 15 m/d. The spatial variation in horizontal hydraulic conductivity appears to take the trend in the variations in the nature of the material in space. Calibrated groundwater recharge suggests that 6.9–34% of annual precipitation recharges the shallow aquifer system. This amount of recharge is significant and suggests high fortunes in terms of groundwater resources development for agriculture and industrial activities in the area. A spatial distribution of groundwater recharge from precipitation is presented in this study. The spatial pattern appears to take the form of the distribution in horizontal hydraulic conductivity, and suggests that the vertical hydraulic conductivity takes the same pattern of spatial variation as the horizontal hydraulic conductivity. This is consistent with observations in other areas. The resulting groundwater flow is dominated by local flow systems as the unconfined system is quite shallow. A general northeast – southwest flow pattern has been observed in the study area.  相似文献   

12.
《Applied Geochemistry》2006,21(7):1169-1183
The Cornia Plain alluvial aquifer, in Tuscany, is exploited intensely to meet the demand for domestic, irrigation and industrial water supplies. The B concentration of groundwater, however, is often above the European limit of 1 mg L−1, with the result that exploitation of these water resources requires careful management. Boron and Sr isotopes have been used as part of a study on the origin and distribution of B dissolved in groundwater, and indirectly as a contribution to the development of appropriate water management strategies.The geochemistry of the Cornia Plain groundwater changes from a HCO3 facies in the inland areas to a Cl facies along the coastal belt, where seawater intrusion takes place. The B concentration of groundwater increases towards the coastal areas, while the 11B/10B ratio decreases. This indicates that there is an increasing interaction between dissolved B and the sediments forming the aquifer matrix, whose B content is in the order of 100 mg kg−1. Adsorption–desorption exchanges take place between water and the sediment fine fraction rich in clay minerals, with a net release of B from the matrix into the groundwater, and a consequent δ11B shift from positive to negative values. The aquifer matrix sediments therefore seem to be the major source of B dissolved in the groundwater.The groundwater–matrix interactions triggered by the ionic strength increase caused by seawater intrusion can also be detected in the Ca–Na ion exchanges. Dissolved Sr follows a trend similar to that of Ca, while the 87Sr/86Sr ratio is equal to that of the exchangeable Sr of the aquifer matrix and therefore does not change significantly.These results have helped to define a new strategy for groundwater exploitation, with the final objective of reducing B concentration in the water extracted from the aquifer.  相似文献   

13.
We present analogue models of the formation of dilatant normal faults and fractures in carbonate fault zones, using cohesive hemihydrate powder (CaSO4·½H2O). The evolution of these dilatant fault zones involves a range of processes such as fragmentation, gravity-driven breccia transport and the formation of dilatant jogs. To allow scaling to natural prototypes, extensive material characterisation was done. This showed that tensile strength and cohesion depend on the state of compaction, whereas the friction angle remains approximately constant. In our models, tensile strength of the hemihydrate increases with depth from 9 to 50 Pa, while cohesion increases from 40 to 250 Pa. We studied homogeneous and layered material sequences, using sand as a relatively weak layer and hemihydrate/graphite mixtures as a slightly stronger layer. Deformation was analyzed by time-lapse photography and Particle Image Velocimetry (PIV) to calculate the evolution of the displacement field. With PIV the initial, predominantly elastic deformation and progressive localization of deformation are observed in detail. We observed near-vertical opening-mode fractures near the surface. With increasing depth, dilational shear faults were dominant, with releasing jogs forming at fault-dip variations. A transition to non-dilatant shear faults was observed near the bottom of the model. In models with mechanical stratigraphy, fault zones are more complex. The inferred stress states and strengths in different parts of the model agree with the observed transitions in the mode of deformation.  相似文献   

14.
《Applied Geochemistry》2005,20(2):295-316
A confined aquifer system has developed in argillaceous marine and freshwater sediments of Pliocene–Holocene age in the northeastern Osaka Basin (NEOB) in central Japan. The shallow groundwater (<100 m) in the system is recharged in a northern hilly to mountainous area with dominantly Ca-HCO3 type water, which changes as it flows toward the SW to Mg-HCO3 type and then to Na-HCO3 type water. Comparison of the chemical and Sr isotopic compositions of the groundwater with those of the bulk and exchangeable components of the underground sediments indicates that elements leached from the sediments contribute negligibly to the NEOB aquifer system. Moreover, model calculations show that contributions of paleo-seawater in the deep horizon and of river water at the surface are not major factors of chemical change of the groundwater. Instead, the zonal pattern of the HCO3-dominant groundwater is caused by the loss of Ca2+ from the water as it is exchanged for Mg2+ in clays, followed by loss of Mg + Ca as they are exchanged for Na + K in clays between the Ca-HCO3 type recharge water and the exchangeable cations in the clay layers, which were initially enriched in Na+. Part of this process was reproduced in a chromatographic experiment in which Na type water with high 87Sr/86Sr was obtained from Mg type water with low 87Sr/86Sr by passing it through marine clay packed in a column. The flux of recharge water into the confined aquifer system according to this chromatographic model is estimated to be 0.99 mm/day, which is compatible with the average recharge flux to unconfined groundwater in Japan (1 mm/day).  相似文献   

15.
Chemical and C–He isotopic compositions have been measured for N2-rich hydrothermal gases from the Liaodong (abbreviation of East Liaoning Province) Peninsula from which the oldest crustal rocks in China with ⩾3.8 Ga outcrop. With the exception of one sample containing tritogenic 3He and atmospheric 4He in Liaoyang, the observed 3He/4He ratios from 0.1 Ra to 0.7 Ra indicate 1–8% helium from mantle, 92–98% from crust and 0.1–0.8% from atmosphere. Despite the lack of Quaternary volcanism, such 3He/4He ratios suggest, together with geophysical evidences, the existence of intrusive magmas that contain mantle helium and heat within the Liaodong middle-lower crust. The 3He/4He ratios are high along the NE-trending Jinzhou faults and gradually decrease with the increase of distance from the faults. Such a spatial distribution suggests that the mantle helium exsolves from magmatic reservoir in the middle-lower crust, becomes focused into the root zones of Jinzhou faults, and subsequently traverses the crust via permeable fault zones. When transversely migrated by groundwater circulation in near surface, mantle helium with high 3He/4He ratio may have been further diluted to the observed values by addition of radiogenic helium produced in the crust. This pattern shows strong evidence that the major faults played an important role on mantle-derived components transport from mantle upwards.  相似文献   

16.
The Laowan metallogenic belt in China is an important metallogenic belt within the Tongbai orogenic belt, and contains the medium-sized Laowan and Shangshanghe gold deposits, the small Huangzhuyuan lead–zinc–silver–gold deposit and some gold and Cu–Pb occurrences. These deposits are hosted in Mesoproterozoic plagioclase amphibolite (or schist) and mica-quartz schist. The gold ores are mainly quartz veins and veinlets and disseminated altered ores. Subordinate ore types include massive sulfides and breccias. The Laowan gold deposit is characterized by three right-stepping en-echelon fracture-controlled alteration zones that dip gently to the south and includes disseminated, sheeted and stockwork ores. These lodes were formed by the interaction of ore-forming fluid with foliated-to laminated cataclasite within the transpressional faults. The Shangshanghe gold deposit is characterized by parallel ore lodes that dip steeply to the north, and includes quartz veins and breccias in addition to ores in altered wallrocks. These lodes were formed by focusing of fluids into transtensional faults. These ore controlling faults displaced early barren quartz veins 10 m horizontally with a dextral sense of motion. The ore-hosting structures at the Laowan and Shangshanghe deposits correspond to the P and R-type shears of a brittle dextral strike-slip fault system, respectively, which make angles of about 15° and − 15° to the Laowan and Songpa boundary faults. The ore-controlling fault system post-dated formation of a ductile shear zone, and peak regional metamorphism. This precludes a genetic relationship between hydrothermal mineralization and regional metamorphism and ductile shear deformation. These gold deposits are not typical orogenic gold deposits. The metallogenic belt displays district-scale-zoning of Mo → Cu–Pb–Zn–Ag → Au relative to Songpa granite porphyry dike zone, suggesting the mineralization may be closely related to the granite porphyry. Measured δ34S of sulfides and δ18O and δD of fluid inclusion waters in auriferous quartz also are consistent with a magmatic source for sulfur and ore fluids. The similarity of Pb isotope ratios between the ores and Yanshanian granitoids suggests a similar source. As the age (139 ± 3 Ma) of granite porphyry obtained by zircon U–Pb isotope overlaps the mineralization age (138 ± 1 Ma: Zhang et al., 2008a), the gold and polymetallic metallogenesis of the Laowan gold belt has close spatial, temporal and possibly genetic relationships with Yanshanian high level magmatism.  相似文献   

17.
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18.
《Earth》2006,74(1-4):245-270
New tephrochronologic, soil-stratigraphic and radiometric-dating studies over the last 10 years have generated a robust numerical stratigraphy for Upper Neogene sedimentary deposits throughout Death Valley. Critical to this improved stratigraphy are correlated or radiometrically-dated tephra beds and tuffs that range in age from > 3.58 Ma to < 1.1 ka. These tephra beds and tuffs establish relations among the Upper Pliocene to Middle Pleistocene sedimentary deposits at Furnace Creek basin, Nova basin, Ubehebe–Lake Rogers basin, Copper Canyon, Artists Drive, Kit Fox Hills, and Confidence Hills. New geologic formations have been described in the Confidence Hills and at Mormon Point. This new geochronology also establishes maximum and minimum ages for Quaternary alluvial fans and Lake Manly deposits. Facies associated with the tephra beds show that ∼3.3 Ma the Furnace Creek basin was a northwest–southeast-trending lake flanked by alluvial fans. This paleolake extended from the Furnace Creek to Ubehebe. Based on the new stratigraphy, the Death Valley fault system can be divided into four main fault zones: the dextral, Quaternary-age Northern Death Valley fault zone; the dextral, pre-Quaternary Furnace Creek fault zone; the oblique–normal Black Mountains fault zone; and the dextral Southern Death Valley fault zone. Post − 3.3 Ma geometric, structural, and kinematic changes in the Black Mountains and Towne Pass fault zones led to the break up of Furnace Creek basin and uplift of the Copper Canyon and Nova basins. Internal kinematics of northern Death Valley are interpreted as either rotation of blocks or normal slip along the northeast–southwest-trending Towne Pass and Tin Mountain fault zones within the Eastern California shear zone.  相似文献   

19.
《Applied Geochemistry》2005,20(11):1985-2002
Elevated levels of dissolved arsenic (∼300 μg L−1) have been detected beneath and in groundwater plumes extending away from a closed landfill in southern Maine. This study sought to determine the source of arsenic to the aquifer, the processes responsible for arsenic mobilization, and to evaluate the effectiveness of remediation efforts that have occurred at this site. The As appears to originate in the natural (glacial) aquifer solids, which contain ∼5 mg kg−1 As on a dry weight basis. This conclusion is supported by the relatively uniform distribution of As in sediment samples, results of laboratory batch incubation experiments, and comparisons with groundwaters in nearby wetlands, which also have high levels of dissolved As that do not appear to originate within the landfill. The As is mobilized in the subsurface by strongly reducing conditions beneath the landfill and in nearby wetlands. In the aquifer beneath the landfill, the average oxidation–reduction potential (ORP) is −95 mV (Eh + 105 mV), and these reducing conditions were primarily induced by landfill leachate. Remediation efforts at this site have included installation of a low permeability clay cap; groundwater extraction, oxidation, and re-injection; and subsurface oxidation by injection of magnesium peroxide. The natural source of arsenic within the aquifer solids, coupled with widespread reducing conditions, has severely limited the effectiveness of these interventions on groundwater arsenic concentrations.  相似文献   

20.
Managing transboundary groundwater resources requires accurate and detailed knowledge of aquifers and groundwater bodies. The Pannonian Basin is the largest intracontinental basin in Europe with a continuous succession of more than 7 km of Miocene to Quaternary sediments and with an average geothermal gradient of about 5 °C/100 m. Geographically the Pannonian basin overlaps eight countries (Hungary, Romania, Serbia, Croatia, Slovenia, Austria, Slovakia and Ukraine), so the issue of transboundary cold and thermal water resources is regionally very important. The T-JAM bilateral Hungarian–Slovenian (HU–SLO) project is the first to apply modern isotopic and chemical analyses in the characterization and correlation of a number of shared groundwater resources in the Mura-Zala Sub-basin of the Pannonian. The aims of this work were the identification of groundwater flow paths, the delineation of transboundary aquifers based on thermal and cold groundwater geochemical and isotope properties in the Mura-Zala Basin, and providing input to calibrate a hydraulic numerical model. Following a common groundwater sampling campaign, 24 cold and thermal groundwater samples from seven aquifers were collected for chemical, isotope, gas and noble gas analyses. Chemical analyses, and D, O and C isotopes were used to correlate cross border aquifers. A regional groundwater flow is hydrogeologically possible in some aquifers in the Mura-Zala Basin, and has been confirmed by hydrogeochemistry. The Újfalu (HU) and Mura (SLO) Formations are a part of the active regional thermal groundwater flow system, probably hydraulically separated from the shallower flow system of the Ptuj-Grad (SLO), Zagyva and Somló-Tihany (HU) Formations. The thermal water is of meteoric origin, reductive and alkaline. The predominant water type in the Quaternary and Pliocene aquifers is Ca–Mg–HCO3, changing to Na–HCO3 in the main Pannonian geothermal aquifer, and Na–Cl brine in deeper and older Miocene aquifers. Total dissolved solids and Na content generally increase with depth. Deuterium is in the range −87‰ to −75‰, 18O from −11.9‰ to −10.4‰, while 14C values are less than 6.1 pmC in the samples of the active regional thermal groundwater flow system. These and results of noble gas analyses indicate recharge during the Pleistocene interglacial period with temperatures around 6–7 °C. Regional thermal water resources are limited and environmental isotopes can be used as an early warning in the management of thermal water.  相似文献   

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