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辽东湾北部浅海区底泥镉元素形态特征 总被引：1，自引：0，他引：1
依据辽东湾浅海区底泥的52件样品中镉元素全量和各形态的测试数据,研究了镉元素存在形态的分布特征和相关性,并探讨了底泥镉形态的环境因素和生态效应.结果表明,底泥中的镉含量为较高水平,非残渣态含量极高,占总量的90%.非残渣态镉主要为离子交换态（44.38%）和碳酸盐结合态（21.38%）.镉的全量与各种形态都有极显著的相关性,并且分布特征一致,最高样点都分布在锦州湾.底泥镉的各种形态与底泥的有机质和海水环境中镉存在显著的相关性.底泥的离子交换态镉与脉红螺的镉有正相关关系. 相似文献
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辽河流域土壤镉有效性的地球化学研究 总被引：2，自引：0，他引：2
利用辽宁省辽河流域生态地球化学调查中取得的土壤镉深表层含量及形态分析等测试数据,对土壤镉的存在形态及其影响因素进行了系统对比研究,结果表明：辽河流域土壤镉主要以离子交换态、水溶态、铁锰氧化态、碳酸盐结合态、强有机结合态、腐殖酸结合态及残渣态等七种形态存在,其中离子交换态及水溶态是可被生物吸收利用的有效态,其含量主要受土壤镉全量、pH值、有机质、土壤粘度等因素制约。 相似文献
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北京城区土壤中Hg、Pb、Cd、Cu及Zn化学形态及环境效应 总被引：1，自引：0，他引：1
为弄清北京城区土壤中Hg、Pb、Cd、Cu及Zn五种重金属元素的化学形态分布特征,系统采集了126件城区表层土壤样品,采用连续提取法对重金属元素各化学形态含量进行了测定。结果表明:土壤中土壤中Hg、Pb、Cd、Cu、Zn含量差异显著。Hg元素以残渣态和强有机结合态为主,Cd元素离子交换态、碳酸盐结合态、残渣态、铁锰氧化物结合态含量较高,Pb、Cu、Zn元素以残渣态、铁锰氧化物结合态为主。Hg元素的有效态含量最低(不足1%),现情况下不会对环境造成污染;Cd元素的有效态含量最高(40%),生物有效性和潜在生态危害性较大,运用植物修复技术对其治理为经济有效的方法;Pb、Cu、Zn有效态含量较低(约10%),生物有效性和潜在生态危害性均有限。各元素形态与全量之间相关程度虽有差别,但基本呈正相关关系。 相似文献
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福建龙海土壤重金属含量特征及影响因素研究 总被引：1，自引：0，他引：1
为有效预防土壤重金属生态风险,以福建龙海市表层土壤为研究对象,应用经典统计分析、随机森林等方法,研究重金属元素含量特征及其影响因素。结果表明：(1)第四纪冲洪(海)积成因水稻土中多数重金属元素含量较高;(2)燕山期中酸性岩风化形成的残坡积红壤中重金属元素活动态含量较高;(3)As、Cu、Ni形态含量与全量相关性较好,而Cd、Cr、Hg的多数形态含量与全量相关性较差;(4)除元素全量外,土壤有机质对弱有机结合态重金属(不包括Ni、Pb元素)以及离子交换态、碳酸盐结合态Cd、Zn有重要影响,阳离子交换量对各形态Ni,(Fe×Al)/Si对各形态Cu具有重要影响,而土壤成因、土壤类型对重金属形态组成的影响较小。研究表明土壤重金属形态组成及其富集区与其全量不尽一致,土壤重金属生态风险评价应考虑土壤重金属形态分布特征。 相似文献
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对内蒙古巴彦淖尔市临河区的富硒耕地范围内51个表层土壤样品进行硒形态研究,探讨硒含量特征、形态特征及其影响因素。结果表明,研究区表层土壤总硒含量在(0.19～0.48)×10-6,平均值为0.33×10-6,属于适量—高硒土壤环境。7种硒形态中,残渣态、腐植酸结合态与强有机结合态为主要赋存形态,水溶态、离子交换态、铁锰氧化物结合态与碳酸盐结合态合计占比仅为13.67%。水溶态硒分级以中等—高硒为主,合计占比达到92.16%,不存在水溶态硒缺乏状态。土壤各形态硒含量与总硒含量相关性较高。土壤有机质含量、pH值、Eh值和CEC等因素对硒形态分布特征均有不同程度的影响。 相似文献
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金沙江(攀枝花段)水系沉积物中重金属的形态特征 总被引：2，自引：0，他引：2
采用连续提取法,并用原子吸收光谱法进行分析研究了金沙江攀枝花段水系沉积物中重金属的形态及分布特征。研究发现:①各重金属的形态以残渣态为主,离子交换态含量很少;②各元素的形态有自己的特点。铜在有机硫化物结合态中的含量较高,钴在碳酸盐结合态中的含量较高,铅锌钴的铁锰氧化物结合态均较高;③有效态对水环境质量具有潜在的危害。 相似文献
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滇西沘江流域水体中重金属元素的地球化学特征 总被引：6，自引：1，他引：5
通过测定流经兰坪金顸铅锌矿区的沘江水体中Pb、Zn、Cd、As的含量和底泥中重金属元素的化学形态的含量,分析了重金属元素的分布和化学形态的变化。结果表明,沘江水遭到了Cd污染,底泥已经成为重金属元素的蓄积库,以国家土壤环境质量标准（Ⅲ级）衡量,Pb、Zn、Cd和舡分别超标3．4倍、15．8倍、106倍和2．6倍。沘江水中重金属元素含量的峰值在矿山附近的下游,而底泥中重金属元素的峰值在矿山下游30-50km的地方,矿业活动、水流变缓、pH等水体环境条件的变化都能影响水和底泥中重金属元素的含量。底泥中的Pb以碳酸盐结合态为主,Zn和Cd以铁锰氧化物结合态为主,而As以残渣态为主。Pb、Cd、Zn三种元素的环境有效态含量比较高,对沘江流域生态环境具有潜在的巨大的危害。 相似文献
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耕地中重金属含量超标直接影响农作物和灌溉水的质量,而且严重影响人体健康.通过调查内蒙古包头工业区周边灌溉水、化肥、农作物及根系土中砷和镉含量及形态特征,研究其转化和富集规律,结果表明,区内土壤和灌溉水呈偏碱性,灌溉水和化肥中砷、镉含量符合国家标准;玉米、向日葵、甘蓝、葱的根系土和可食部分砷含量均未超标,砷主要以残渣态形式存在;4种农作物根系土中镉有不同程度超标现象,向日葵籽粒镉含量超标50%,其余作物可食部分镉含量均未超标.通过分析发现,向日葵籽粒镉超标的原因是与镉赋存形态主要为碳酸盐态和腐殖酸态及向日葵籽粒对镉的富集高于其他植物有关. 相似文献
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Speciation and natural attenuation of arsenic and iron in a tidally influenced shallow aquifer 总被引：2，自引：0，他引：2
Robert A. Root Dimitri Vlassopoulos Nelson A. Rivera Michael T. Rafferty Charles Andrews Peggy A. O&#x;Day 《Geochimica et cosmochimica acta》2009,73(19):5528-5553
The mobility of subsurface arsenic is controlled by sorption, precipitation, and dissolution processes that are tied directly to coupled redox reactions with more abundant, but spatially and temporally variable, iron and sulfur species. Adjacent to the site of a former pesticide manufacturing facility near San Francisco Bay (California, USA), soil and groundwater arsenic concentrations are elevated in sediments near the prior source, but decrease to background levels downgradient where shallow groundwater mixes with infiltrating tidal waters at the plume periphery, which has not migrated appreciably in over two decades of monitoring. We used synchrotron X-ray absorption spectroscopy, together with supporting characterizations and sequential chemical extractions, to directly determine the oxidation state of arsenic and iron as a function of depth in sediments from cores recovered from the unsaturated and saturated zones of a shallow aquifer (to 3.5 m below the surface). Arsenic oxidation state and local bonding in sediments, as As-sulfide, As(III)-oxide, or As(V)-oxide, were related to lithologic redox horizons and depth to groundwater. Based on arsenic and iron speciation, three subsurface zones were identified: (i) a shallow reduced zone in which sulfide phases were found in either the arsenic spectra (realgar-like or orpiment-like local structure), the iron spectra (presence of pyrite), or both, with and without As(III) or As(V) coordinated by oxygen; (ii) a middle transitional zone with mixed arsenic oxidation states (As(III)–O and As(V)–O) but no evidence for sulfide phases in either the arsenic or iron spectra; and (iii) a lower oxidized zone in the saturated freshwater aquifer in which sediments contained only oxidized As(V) and Fe(III) in labile (non-detrital) phases. The zone of transition between the presence and absence of sulfide phases corresponded to the approximate seasonal fluctuation in water level associated with shallow groundwater in the sand-dominated, lower oxic zone. Total sediment arsenic concentrations showed a minimum in the transition zone and an increase in the oxic zone, particularly in core samples nearest the former source. Equilibrium and reaction progress modeling of aqueous-sediment reactions in response to decreasing oxidation potential were used to illustrate the dynamics of arsenic uptake and release in the shallow subsurface. Arsenic attenuation was controlled by two mechanisms, precipitation as sulfide phases under sulfate-reducing conditions in the unsaturated zone, and adsorption of oxidized arsenic to iron hydroxide phases under oxidizing conditions in saturated groundwaters. This study demonstrates that both realgar-type and orpiment-type phases can form in sulfate-reducing sediments at ambient temperatures, with realgar predicted as the thermodynamically stable phase in the presence of pyrite and As(III) under more reduced conditions than orpiment. Field and modeling results indicate that the potential for release of arsenite to solution is maximized in the transition between sulfate-reduced and iron-oxidized conditions when concentrations of labile iron are low relative to arsenic, pH-controlled arsenic sorption is the primary attenuation mechanism, and mixed Fe(II,III)-oxide phases do not form and generate new sorption sites. 相似文献
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安徽巢北地区栖霞组臭灰岩段富有机质成因探讨 总被引：3，自引：0，他引：3
以安徽巢北地区二叠纪栖霞组臭灰岩段为研究对象,从岩石学、古生物学及沉积学特征出发,探讨臭灰岩段富有机质与风暴事件沉积之间的关系。臭灰岩段岩性整体为灰黑色中厚层状石灰岩,层间夹数毫米至数厘米厚灰黑色钙质泥岩,整套岩层富含有机质;其中生物化石丰富,整体为热带、亚热带正常盐度浅水生物组合为特征;为正常浅海碳酸盐岩台地沉积,沉积期表现为一个明显的海侵过程,并受风暴作用的频繁扰动。臭灰岩段沉积环境并非“贫氧或缺氧”条件,而是正常富氧环境。富有机质特征一方面得益于沉积期较高的生物产率,同时还与风暴事件沉积作用密切相关,即在风暴作用下,沉积物发生快速堆积,有机质未来得及与富氧水体发生长期接触即被埋藏覆盖,从而导致有机质被良好保存,形成臭灰岩段富有机质特征。风暴作用频发与研究区臭灰岩段沉积期所处的低纬度特征有关。 相似文献
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Diurnal variation in rates of calcification and carbonate sediment dissolution in Florida Bay 总被引：2，自引：0，他引：2
Water quality and criculation in Florida Bay (a shallow, subtropical estuary in south Florida) are highly dependent upon the
development and evolution of carbonate mud banks distributed throughout the Bay. Predicting the effect of natural and anthropogenic
perturbations on carbonate sedimentation requires an understanding of annual, seasonal, and daily variations in the biogenic
and inorganic processes affecting carbonate sediment precipitation and dissolution. In this study, net calcification rates
were measured over diurnal cycles on 27 d during summer and winter from 1999 to 2003 on mud banks and four representative
substrate types located within basins between mud banks. Substrate types that were measured in basins include seagrass beds
of sparse and intermediate densityThalassia sp., mud bottom, and hard bottom communities. Changes in total alkalinity were used as a proxy for calcification and dissolution.
On 22 d (81%), diurnal variation in rates of net calcification was observed. The highest rates of net carbonate sediment production
(or lowest rates of net dissolution) generally occurred during daylight hours and ranged from 2.900 to −0.410 g CaCO3 m−2d−1. The lowest rates of carbonate sediment production (or net sediment dissolution) occurred at night and ranged from 0.210
to −1.900 g CaCO3 m−2 night−1. During typical diurnal cycles, dissolution during the night consumed an average of 29% of sediment produced during the day
on banks and 68% of sediment produced during the day in basins. Net sediment dissolution also occurred during daylight, but
only when there was total cloud cover, high turbidity, or hypersalinity. Diurnal variation in calcification and dissolution
in surface waters and surface sediments of Florida Bay is linked to cycling of carbon dioxide through photosynthesis and respiration.
Estimation of long-term sediment accumulation rates from diurnal rates of carbonate sediment production measured in this study
indicates an overall average accumulation rate for Florida Bay of 8.7 cm 1000 yr−1 and suggests that sediment dissolution plays a more important role than sediment transport in loss of sediment from Florida
Bay. 相似文献
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《International Geology Review》2012,54(1):17-23
Sedimentation processes in the Sea of Japan are characterized by certain, specific features, depending on the climatic zonality, the hydrologic environment, the geological shore-line structure and the bottom morphology of the basin. In consequence of gravel and pebbles being scattered over great distances by floating ice, accumulation of glacial marine deposits takes place in the northwest part of the sea and the Tartar Strait. Zones of sediments with high organic-carbon content are confined to fine-silt deposits of the continental piedmont slope. The organic-carbon content in the sediments decreases considerably towards the central part of the basin. Evidently, this depends on the fact that marine water contains great quantities of free oxygen and the organic matter is oxidized during the prolonged period of settlement anddeposition, on the sea bottom. The distribution of such organic sediment constituents as amorphous O2 and calcium carbonate fully depends on the distribution of cold and warm currents. The zone of maximum SiO2-content forms a band along the western sea shore skirted by the cold Primor'ye current. Calcium carbonate accumulation in the sediments takes place chiefly in arenaceous sediments of the Futhern part, within the warm Tsushima current zone. Zones of maximum iron and manganese contents in the sediments are found near the western coast which is composed cheifly of basic magmatic rocks. A study of recent Sea of Japan sediments shows that the specific features of each individual basin exercise considerable influence upon the laws governing the sedimentation process.—Auth. English summ. 相似文献
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以深港西部通道填海区淤泥为研究对象,研究了重金属的化学形态特征,分析了填海工程活动带来的填海区地下水物理化学条件变化对重金属各个形态的影响。结果表明:除残留态外,填海区重金属存在形态主要为铁锰结合态、碳酸盐结合态和硫化物及有机结合态,其中,Pb和Ni以铁锰氧化物结合态和碳酸盐结合态为主,Cu以碳酸盐结合态和有机结合态为主,Zn以有机结合态和铁锰氧化物结合态为主,而Cd则以碳酸盐结合态为主。各金属在深港西部通道填海区淤泥的潜在迁移能力序列如下:Pb(39.68%)>Cu(31.59%)>Zn(20.49%)>Cd(12.80%)>Ni(10.98%)。 相似文献
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The basin-fill aquifers of the Western U.S. contain elevated concentrations of arsenic in the groundwater due to ancient volcanic deposits that host arsenic minerals. Microcosms were constructed using two oxidized sediments and, by contrast, a reduced sediment collected from a shallow basin-fill aquifer in the Cache Valley Basin, Northern Utah to evaluate the fate of geologic arsenic under anoxic conditions. Sequential extractions indicated the primary arsenic host mineral was amorphous iron oxides, but 13%–17% of the total arsenic was associated with carbonate minerals. Arsenic was solubilized from the sediments when incubated with groundwater in the presence of native organic carbon. Arsenic solubilization occurred prior to iron reduction rather than the commonly observed co-reactivity. Arsenic(V) associated with carbonate minerals was the main source of arsenic released to solution and redistributed onto less soluble minerals, including FeS and siderite as defined by chemical extraction. Arsenic reduction occurred only in the site-oxidized sediments. The addition of a carbon and energy source, glucose, resulted in enhanced arsenic solubilization, which was coupled with iron reduction from the site-oxidized sediments. Adding glucose promoted iron reduction that masked the role of carbonate minerals in arsenic solubilization and retention as observed with incubation with groundwater only. 相似文献