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1.
内陆水体好氧甲烷氧化过程研究进展 总被引：1，自引：0，他引：1
内陆水体是全球碳循环的关键组成部分,是大气中甲烷(CH_4)的重要来源,每年从内陆淡水与自然湿地排放进入大气的CH4约为185～357 Tg/a.通常,内陆水体中CH_4主要由分布于水层底部的厌氧区或沉积层内的产甲烷菌介导产生,其向水层表面传输的过程中易被甲烷氧化菌所氧化.甲烷氧化菌可分为好氧甲烷氧化菌和厌氧甲烷氧化菌,有氧条件下,由好氧甲烷氧化菌介导的好氧甲烷氧化过程是水体中甲烷氧化过程的主要形式,湖泊底部产生的CH_4总量中约有99%可以被上覆水体中的好氧甲烷氧化过程所消耗.本文收集文献综合分析阐明,好氧甲烷氧化过程是由水环境因子、水文条件以及不同内陆水体的生态系统特征共同调控,同时也表现在了好氧甲烷氧化菌的生境偏好上.复杂的调控过程构建了内陆水体向大气输送CH_4的动态平衡,并最终反映在内陆水体对全球CH_4循环、碳循环作出的贡献上. 相似文献
2.
Elimination of Swimming Pool Water Disinfection By‐products with Advanced Oxidation Processes (AOPs)
Ozonation is a treatment step which was first applied in the 1960s in pool water treatment for disinfection as well as for oxidation of pool water contaminants. Contact time between ozone and pool water was identified to be of significance with an increased elimination efficiency regarding chloramines, trihalogenmethane formation potential and the permanganate index for longer reaction times. Oxidation via OH radicals might be the dominating pathway. In this study ozonation was compared with the ozone based advanced oxidation processes ozone/UV and ozone/hydrogen peroxide regarding the elimination efficiency of both disinfection by‐products (DBPs) and DBP precursors. It was observed that AOPs in comparison to ozonation showed an increased elimination efficiency regarding total organic carbon (TOC), the organically bound halogens adsorbable on activated carbon (AOX) and AOX formation potential. A contact time of 3 minutes between pool water and oxidant turned out to be practically sufficient. Just for the trihalomethane (THM) formation potential ozonation showed a slight advantage compared to the AOPs because ozonation is a highly selective oxidant and OH radical reactions are known to produce small reactive molecules which are easier transformed to THMs. Combination of membrane filtration and AOPs resulted in an elimination of 10 to 90 % of the DBPs and their precursors. The ozone/hydrogen peroxide process is suggested for pool water treatment because of the higher elimination rates compared to ozonation and of economic reasons compared to the ozone/UV process. 相似文献
3.
The catalytic activity of horseradish (Armoracia lapathifolia) peroxidase in the oxidation reactions of benzo(a)pyrene (BP) and phenols, separately and in admixture, has been studied. Experiments were carried out with model phenols from industrial sewage (phenol, m-, p-cresols, catechol, hydroquinone, resorcinol, orcinol), keeping to the real concentration ratio of reagents, 0.5 mM for phenols, 0.1 nM for benzo(a)pyrene. The total oxidation process for all reagents tested is described by the second-order formal kinetic equation up to 60 … 90% of their conversion. Addition of peroxidase increases the rate of oxidation of benzo(a)pyrene and phenols 2 … 6 times as compared with the control test (with hydrogen peroxide), whereas a linear dependence of the rate of benzo(a)pyrene oxidation on the enzyme concentration is observed. By cooxidation a mutual inhibition of benzo(a)pyrene and phenols is established whose degree depends on the phenol-chemical structure and varies in the range of 23 … 58% for BP under the influence of phenols and 35 … 80% for phenols under the influence of benzo(a)pyrene. The results obtained permit a supposition that peroxidase containing plants are capable of simultaneously transforming carcinogenic benzo(a)pyrene and toxic phenols in water reservoirs and in the soil, thus promoting the detoxication of environment. 相似文献
4.
A directional distribution of — compounds with different oxidation degree between phases in the carbon-water system was established. The results of modeling are used to explain the formation process of carboxylic acid and methane water, as well as waters of hydrocarbonate and carbonate composition. A three-stage scheme of the physicochemical interaction in the carbon-aqueous solution system is proposed. 相似文献
5.
Takatoshi Akimoto Hajimu Kinoshita Toshio Furuta 《Earth and Planetary Science Letters》1984,71(2):263-278
Partially oxidized titanomagnetite grains in various kinds of volcanic rocks were investigated by electron probe microanalyzer (EPMA) in order to clarify the process of oxidation at low temperature. The following results were obtained by the present investigation: (1) Primary composition of titanomagnetite is homogeneous in individual grains, although variation in composition among different grains is observed on each thin section. (2) Migration of Fe cations during low-temperature oxidation is clearly seen in all oxidized grains. Some other constituent cations are also bleached and consequently the relative content of the remaining cations becomes large. (3) The detailed internal structures of titanomagnetite grains are observed as backscattered electron images (BEI) with an electronprobe microanalyzer, and it seems likely that the structures depend upon the degree of low-temperature oxidation. (4) The chemical and physical properties of oxidized titanomagnetites imply that low-temperature oxidation is not a simple process but a complex one. Such an oxidation process is correlatable to both the mobility of cation and the oxidation condition such as a circulation of some active hydrothermal materials at low temperature. 相似文献
6.
研究湿地底泥污染特性及水-土界面边界层性质是明确大型人工湿地长期运行下底泥内源污染问题的关键.本文以典型人工湿地为例,通过综合布点垂向分层监测湿地底泥理化性质,明确底泥污染特性,分析水-土界面边界氧化层现象、性质及形成机理,探讨其性质成因.结果表明：与湖泊类似,长期运行人工湿地底泥也会产生氧化层,垂向由上到下分为氧化层、污染层、过渡层和健康层;运行6年的湿地底泥可形成厚约1 cm、无明显臭味、棕黄色可塑状的氧化层;与污染层相比,氧化层色味变淡、流动性减弱,含水率、d（0.9）、亚铁、总有机碳和总氮含量分别降低7.20%、54.04%、54.59%、17.89%和7.00%,氧化还原电位和总磷含量分别升高150.41%和18.17%;氧化层是由氧化、沉降协同作用下形成的底泥表层氧化态微环境,其中上覆水溶解氧水平越高越有利于提高氧化层致密程度,降低氧化层有机质、总氮含量,上覆水悬浮物浓度越高、水深越深越有利于增加氧化层厚度. 相似文献
7.
湖泊生态系统产甲烷与甲烷氧化微生物研究进展 总被引：3，自引：1，他引：2
湖泊生态系统是重要的大气甲烷来源,其甲烷释放量占全球自然生态系统的40%.产甲烷和甲烷氧化微生物在湖泊甲烷生产和消耗过程中发挥关键作用.本文综述了近期有关湖泊生态系统甲烷产生与氧化过程的研究进展,重点介绍产甲烷与甲烷氧化微生物在湖泊中的分布特征、代谢途径以及调控机制.现有研究表明,湖泊中甲烷的生成不仅仅依靠赋存于沉积物和水体厌氧层的产甲烷古菌,还可能来自有氧环境中其他产甲烷微生物的代谢作用.湖泊中的甲烷在脱离水体逸散至大气之前,被甲烷氧化微生物利用,转化成二氧化碳和小分子有机化合物(如甲醇、甲醛和甲酸等).除了传统依赖氧气作为电子受体的好氧氧化过程外,新近研究还揭示了多种厌氧甲烷氧化过程,包括依赖还原硫酸盐、硝酸盐和亚硝酸盐以及Fe~(3+)/Mn~(4+)等金属离子的甲烷氧化过程.文献综合分析表明,反硝化型厌氧甲烷氧化过程主要发生在淡水湖泊中,而硫酸盐还原型主要发生在高盐度或者高碱度湖泊中.水体温度、溶解氧浓度可以显著影响产甲烷与甲烷氧化微生物的丰度与群落结构,其他湖泊环境条件,如盐度、pH和有机质类型等都可能改变产甲烷与甲烷氧化微生物的分布和代谢活性.不同湖泊类型的比较研究,有助于全面掌握影响湖泊产甲烷与甲烷氧化微生物的时空分布与代谢特征的主导因素. 相似文献
8.
针对河流模拟中未知不确定性源对模拟精度的影响,以巢湖流域南淝河为研究对象,建立了基于四维变分同化方法的南淝河干流水质模型,研究了含未知污染源的南淝河水质过程模拟.模型以未知污染负荷的动态变化过程为控制变量,通过同化沿河不同断面的逐日水质监测数据,识别不同河段的逐日入河污染负荷过程来实现水质过程的模拟,改变了常规模型模拟需提前预知并输入污染负荷的应用前提.模拟结果表明,采用四维变分同化方法的水质模拟结果有明显改进,重点河段水质模拟的纳什效率系数从小于0提高到0.5以上.识别的入河污染过程与降雨过程波动总体一致,证实南淝河的入河污染与降雨过程密切;同时,模型也可识别异常的入河负荷,提高模型对水环境问题的诊断分析能力.该方法可推广应用于复杂河流系统,为巢湖等流域污染来源定量解析、水质预测预警及污染管控提供支持. 相似文献
9.
The electrochemical transfer characteristics of nickel sulphides from six West Australian localities are examined by the nonlinear complex resistivity (nlcr ) method. Ores are classified on the basis of their state of oxidation (supergene, transition zone and primary ores) in an equivalent mine water electrolyte; evidence is found for a systematic change of electrical response with oxidation that is symptomatic of electrochemical reactions varying from diffusion to charge-transfer controlled processes. The analysis is based on the assumption that the Randies’ circuit is an effective model of a rock's electrical response in its natural electrolyte. Both complex impedance plane graphs and computer inversion are used to study the model. Harmonic distortion is a useful aid in this interpretation. 相似文献
10.
During treatment to remove volatile organic compounds from contaminated ground water, inorganic scale sometimes precipitates in an air stripper tower. This leads to increased costs and down-time associated with tower media replacement. In order to determine the kind, quantity, and rate of scale formation, the ground water from five locations in Florida was simulated using an aqueous equilibrium chemistry and flow process model. In all cases the pH of the outflow water is higher than that of the inflow water because of degassing of CO2 . This often results in the precipitation of calcium carbonate. The addition of air to reduced ground water results in the oxidation of iron and the precipitation of ferric hydroxides. Model estimates of scale formation are about a factor of two to five too high. This indicates that the precipitation reactions do not reach equilibrium within the air stripper. Future work will require the inclusion of biological fouling and a kinetic expression to account for the observed non-equilibrium. 相似文献
11.
V. A. Vavilin 《洁净——土壤、空气、水》1982,10(3):211-242
Various models, applied to the design of aeration tanks, trickling filters and rotating discs, are compared. The adequacy of the models is established from the minimal mean square deviation of the measured and calculated values of the effluent concentration of a pollutant. It is shown that at the oxidation of simple substrates of the glucose type Moser's model is an adequate model and Monod's model is a particular case of this model. If a single substrate has a large concentration, activated sludge or biofilm become “saturated” and the oxidation kinetics follows the zero order. As the processing of the results of some experiments showed, the classical Monod model and its extreme case—the first-order equation of a reaction—are not adequate to the processes of the oxidation of multicomponent municipal sewage water. Equations for reactions of higher orders are true for them. The rate constant of the first-order reaction correlates well with the effluent concentration-influent concentration ratio, i.e., it is variable and depends on the treatment conditions and, above all, it is inversely proportional to the level of treatment. 相似文献
12.
In the process of methane oxidation by nitrite ion, the latter, when in high concentration, inhibits the oxidation process. The effect of inhibition is incorporated in the proposed model, describing the dynamics of anaerobic oxidation of methane and its heavy fractions δ13CH4 and δC2H1H3 by nitrite ion. Two substrates—methane and nitrite—are considered in a modified Monod function, describing the oxidation rate. The model is calibrated against experimental data given in [8]. The dynamic behavior of the system under a deficiency of methane or nitrite ion is described. The dynamics of δ13CH4 and δC2H1H3 are shown to be governed by the oxidation dynamics of total methane CH4. By contrast to the conventional opinion that Rayleigh equation corresponds to 1st-order kinetics in terms of substrate concentration, this study shows that Rayleigh equation can be derived from dynamic equations for methane with heavy isotopes (13C and 2H), whatever the kinetic type of total methane oxidation. 相似文献
13.
The available observational data on the pollution of tributaries and areas of the Caspian Sea by petroleum hydrocarbons and
products are examined. The possible petroleum input from sources in the sea is assessed using up-to-date data of satellite
observations of sea surface pollution by oil films. The hydroecological CNPSi-model is applied to studying water pollution
processes by petroleum hydrocarbons in ten areas chosen in the Caspian Sea and the subsequent biodegradation of those pollutants.
The model calculations of the within-year dynamics of petroleum hydrocarbon concentrations use mean annual observational data
on within-year variations in water mediium characteristics (water temperature, light intensity, and transparency), as well
as the morphometric parameters of sea areas (the area, mean depth, and water volumes). The characteristics of water exchange
between the areas were evaluated using a hydrodynamic model. The model calculations were used to characterize the within-year
variations in petroleum hydrocarbon concentrations, the biomasses of petroleum-oxidizing bacteria, the characteristics of
their oxidation activity and bioproduction, and the internal fluxes of petroleum hydrocarbons (their input from various sources,
horizontal and vertical transport, and biotransformation) in different sea areas. Calculation results were used to compile
annual balances for the processes of input and consumption of petroleum hydrocarbons in the chosen and aggregated sea areas. 相似文献
14.
15.
Implementation of aquifer storage recovery (ASR) for water resource management in Florida is impeded by arsenic mobilization. Arsenic, released by pyrite oxidation during the recharge phase, sometimes results in groundwater concentrations that exceed the 10 µg/L criterion defined in the Safe Drinking Water Act. ASR was proposed as a major storage component for the Comprehensive Everglades Restoration Plan (CERP), in which excess surface water is stored during the wet season, and then distributed during the dry season for ecosystem restoration. To evaluate ASR system performance for CERP goals, three cycle tests were conducted, with extensive water‐quality monitoring in the Upper Floridan Aquifer (UFA) at the Kissimmee River ASR (KRASR) pilot system. During each cycle test, redox evolution from sub‐oxic to sulfate‐reducing conditions occurs in the UFA storage zone, as indicated by decreasing Fe2+/H2S mass ratios. Arsenic, released by pyrite oxidation during recharge, is sequestered during storage and recovery by co‐precipitation with iron sulfide. Mineral saturation indices indicate that amorphous iron oxide (a sorption surface for arsenic) is stable only during oxic and sub‐oxic conditions of the recharge phase, but iron sulfide (which co‐precipitates arsenic) is stable during the sulfate‐reducing conditions of the storage and recovery phases. Resultant arsenic concentrations in recovered water are below the 10 µg/L regulatory criterion during cycle tests 2 and 3. The arsenic sequestration process is appropriate for other ASR systems that recharge treated surface water into a sulfate‐reducing aquifer. 相似文献
16.
Hill MC 《Ground water》2006,44(6):775-781
The advantages of starting with simple models and building complexity slowly can be significant in the development of ground water models. In many circumstances, simpler models are characterized by fewer defined parameters and shorter execution times. In this work, the number of parameters is used as the primary measure of simplicity and complexity; the advantages of shorter execution times also are considered. The ideas are presented in the context of constructing ground water models but are applicable to many fields. Simplicity first is put in perspective as part of the entire modeling process using 14 guidelines for effective model calibration. It is noted that neither very simple nor very complex models generally produce the most accurate predictions and that determining the appropriate level of complexity is an ill-defined process. It is suggested that a thorough evaluation of observation errors is essential to model development. Finally, specific ways are discussed to design useful ground water models that have fewer parameters and shorter execution times. 相似文献
17.
This work introduces water–air two‐phase flow into integrated surface–subsurface flow by simulating rainfall infiltration and run‐off production on a soil slope with the finite element method. The numerical model is formulated by partial differential equations for hydrostatic shallow flow and water–air two‐phase flow in the shallow subsurface. Finite element computing formats and solution strategies are presented to obtain a numerical solution for the coupled model. An unsaturated seepage flow process is first simulated by water–air two‐phase flow under the atmospheric pressure boundary condition to obtain the rainfall infiltration rate. Then, the rainfall infiltration rate is used as an input parameter to solve the surface run‐off equations and determine the value of the surface run‐off depth. In the next iteration, the pressure boundary condition of unsaturated seepage flow is adjusted by the surface run‐off depth. The coupling process is achieved by updating the rainfall infiltration rate and surface run‐off depth sequentially until the convergence criteria are reached in a time step. A well‐conducted surface run‐off experiment and traditional surface–subsurface model are used to validate the new model. Comparisons with the traditional surface–subsurface model show that the initiation time of surface run‐off calculated by the proposed model is earlier and that the water depth is larger, thus providing values that are closer to the experimental results. 相似文献
18.
采用水沙模型对流域水沙过程进行计算是目前分析和研究黄土地区水土流失、水沙锐减等问题的有效途径由于降雨的时段均化和缺测、漏测、误测等问题,导致水沙模型的重要输入项和动力因子——降雨资料存在误差,进而影响水流和泥沙过程模拟精度因此,本研究将降雨动态系统响应曲线的误差修正方法与概念性水沙模拟模型相结合以提高水沙过程模拟精度此方法将水沙模型的水流模拟部分看作响应系统,通过修正水沙模型的重要输入项——面平均雨量,利用修正之后的面平均雨量系列,通过模型重新计算以提高模型对产汇流和产汇沙过程的模拟精度通过理想案例验证该方法可行性后,选择黄土地区曹坪流域进行检验,结果表明修正后的水流和泥沙过程模拟精度均有显著提高,平均提高幅度分别为17.56%和15.86%. 相似文献
19.
Hassan AE 《Ground water》2004,42(2):277-290
Many sites of ground water contamination rely heavily on complex numerical models of flow and transport to develop closure plans. This complexity has created a need for tools and approaches that can build confidence in model predictions and provide evidence that these predictions are sufficient for decision making. Confidence building is a long-term, iterative process and the author believes that this process should be termed model validation. Model validation is a process, not an end result. That is, the process of model validation cannot ensure acceptable prediction or quality of the model. Rather, it provides an important safeguard against faulty models or inadequately developed and tested models. If model results become the basis for decision making, then the validation process provides evidence that the model is valid for making decisions (not necessarily a true representation of reality). Validation, verification, and confirmation are concepts associated with ground water numerical models that not only do not represent established and generally accepted practices, but there is not even widespread agreement on the meaning of the terms as applied to models. This paper presents a review of model validation studies that pertain to ground water flow and transport modeling. Definitions, literature debates, previously proposed validation strategies, and conferences and symposia that focused on subsurface model validation are reviewed and discussed. The review is general and focuses on site-specific, predictive ground water models used for making decisions regarding remediation activities and site closure. The aim is to provide a reasonable starting point for hydrogeologists facing model validation for ground water systems, thus saving a significant amount of time, effort, and cost. This review is also aimed at reviving the issue of model validation in the hydrogeologic community and stimulating the thinking of researchers and practitioners to develop practical and efficient tools for evaluating and refining ground water predictive models. 相似文献
20.
A hydroecological model is used for simultaneous studying water pollution processes by petroleum hydrocarbons and their decay
under the oceanographic conditions of Tatar Strait. The model calculations were based on long-term averaged observational
data on interannual variations of water temperature, light intensity, and transparency. Some oceanographic characteristics
of the strait were reconstructed with the help of GIS “Sakhalin Shelf.” The strait’s water area was divided into three regions,
and water exchange between them and the neighboring regions of the Sea of Japan was estimated by a hydrodynamic model. The
results of the study made it possible to assess interannual variations in the concentrations and inner fluxes of petroleum
hydrocarbons, oil-oxidizing bacteria biomasses, and the characteristics of their oxidation activity. 相似文献