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Quality Requirements for Fresh Waters: Water Quality Targets, Water Quality Objectives, and Chemical Water Quality Classification In the Federal Republic of Germany, water quality requirements for the protection of inland surface waters against hazardous substances are formulated on the basis of a quality targets derivation concept developed jointly by the Federal Government and the Federal States. The quality requirements were termed “water quality targets” in order to make it clear that the values derived are orientational values rather than legally binding limit values. The international comparison of quality requirements for surface waters shows that, on the whole, the national quality targets ensure a high level of protection. According to present scientific knowledge, impairments of uses, such as supply of drinking water, or risks to aquatic communities need not to be expected if the quality targets are complied with. A comparison of water quality data with the water quality targets makes it possible, on the one hand, to identify those substances whose inputs must be further reduced; on the other hand, it also shows that, for a number of substances, there is no need at present for concern over their adversely water quality. A further differentiation of the aquatic hazard potential of pollutants allows a water quality classification system to be developed on the basis of the quality targets derivation concept. The basic elements of this water quality classification system are presented, and its application is explained by way of examples. 相似文献
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We synthesized series of polyfunctional aminooligomers by means of condensation from polychlorparaffine with ethylenediamine. After modifying them with dimethylsulphate watersoluble oligomers of (quaternary) polyamines are obtained, which can be successfully used as biocides for treating circulating cooling-waters from different refinery plants. The products have low foaming and formed foam is unsteady. The bactericide properties of the successful samples are good. For the interval time for two to twenty hours of treatment at static conditions the microbe number value decreases by more than 99.99% at a 50 mg/dm3 dose of a biological active substance. At dosing it up to seventy-two hours the biomass is finely dispersed and does not precipitate on the walls of the chemical set-equipment. 相似文献
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A combination of retention pond and reed bed was tested for its effectiveness in reducing non-point source runoff pollution from an urban area. This paper presents data on the development of reed plants (Phragmites australis Cav. Trin.), on the effectiveness of runoff purification and on the accumulation of contaminants in the pond sediment and the reed bed for the years 1993–1995. P. australis was well established and grew according to normal development. The measured length and biomass values of P. australis were larger on sand than on gravel and coarse materials. Toxic levels of heavy metals in the plants were not reached. Harvested plants can be composted. The purification system is effective within the following ranges: The rate of retention of suspended solids and heavy metals varies between 16% and 91%. For chemical oxygen demand the average values is 25%. Poor retention rates usually occur along with very low input concentrations. Generally retention within the reed bed is higher than in the pond. Between 1993 and 1995 the concentration of contaminants within the organic layer of the reed bed increased by 50% for lead and by 90% for poly aromatic hydrocarbons. Until 1994 the concentrations of mineral oil hydrocarbons also increased by 60%. Between 1994 and 1995 however the concentration of mineral oil hydrocarbons in the reed bed decreased rapidly by more than 50%: Mineral oil hydrocarbons underlie biological degradation within the reed bed. In the pond sediment a significant accumulation of heavy metals, poly aromatic hydrocarbons and mineral oil hydrocarbons has also been found. The concentrations of these contaminants are still far from inhibiting the function of the system. 相似文献
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Meteorological conditions, biochemical processes in water bodies and anthropogenic pressure of a region are the main factors to determine the atmosphere water-body gas exchange. Research on oxygen outflows in the Dnjepr estuary region has shown that though gas exchange with atmosphere permanently exists its intensity varies throughout a day, vegetation period, year. The process of evasion is the most active in the flood plain pools of the river. Oxygen exchange between the atmosphere and a river is to be determined with physical characteristics of water outflow and with the anthropogenic influence. Oxygen absorption from the atmosphere is dominating for the liman water area in spite of differences between its parts. The obtained results have shown that gas exchange between river estuary pools and the atmosphere is of great importance for the oxygen balance of these pools. 相似文献
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The X-ray fluorescence analysis is an important means for the determination of the heavy metal concentrations in sewage sludges and for the evaluation of their usability in agriculture. Analysis devices from the GDR were used for that. For the investigations there was used as the zero sample a sludge which was not loaded with heavy metals, homogeneous and constantly dried at 105 °C. The drying bed sludge samples were treated with different heavy metal solutions with different concentrations. Preparation of samples, measuring conditions and general spectra are described. The measuring results of tests up to 100 g heavy metal in 1 kg dry substance are critically evaluated. The analysis of a sewer sludge sample takes only about ten minutes. There are determined: Cr, Ni, Cu, Zn, Mo, Cd, Hg and Pb. 相似文献
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H. Jobst 《洁净——土壤、空气、水》1995,23(1):20-25
Chlorophenols and Nonylphenols in Sewage Sludges. Part I: Occurence in Sewage Sludges of Western German Treatment Plants from 1987 to 1989 Sewage sludges originating from all western German states from 1987 till 1989 have been analyzed for two groups of organic pollutants, which are not specified in the German sewage sludge regulations (Klärschlammverordnung) from 1992: the isomeric 4-nonylphenols and the chlorophenols. The applied analytical methods are presented, as well as the analytical results. In almost all 149 analyzed samples nonylphenols could be found, at an average of 128.2 mg/kg dry matter. In the case of chlorophenols, pentachlorophenol was the most pronounced in respect to amount and to frequency of positive results: i.e. in 85 samples investigated, the mean value was 59.5 μg/kg. Results are reported in percentils. The data correspond to sewage sludges from the past and will be used as a guideline in evaluating all following studies of sludges. Investigations will be continued. 相似文献
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W. Pietsch 《洁净——土壤、空气、水》1980,8(4):337-361
Die natürlichen Fähigkeiten und Eigenschaften von Makrophytenbeständen, insbesondere bestimmter Pflanzengruppen der überschwemmungswiesen, für Nährstoffeliminierung und Grundwasseranreicherung werden der biochemisch-makrophytischen Methode zugrunde gelegt. Am Beispiel von Kleinstsickerbecken wird die Methode zur Nährstoffelimination aus Oberflächenwässern beschrieben. Prinzip, Durchführung und Auswertung der Methode werden am Beispiel verschiedener Makrophytenarten für verschiedene hydrochemische Parameter anhand von Grenzwerten, Eliminierungs- und Infiltrationsraten dargestellt. Geeignete Einsatzmöglichkeiten der Methode für wasserwirtschaftliche und landeskulturelle Zwecke werden besprochen. 相似文献
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With the Water Framework Directive (WFD) the European Commission (EC) is requested to define environmental quality standards for pollutants to protect aquatic life in surface waters. Quality standards have to be derived by a scientific risk assessment and should not be exceeded. The recommended quality standards are mainly based on long term toxicological tests with algae, crustaceans and fish. The lowest effect concentration is divided by an assessment factor between 10 and 1000, which considers the data quality and quantity. In this work funded by the German Länder Working Party on Water (Länderarbeitsgemeinschaft Wasser – LAWA) environmental quality standards for 40 considered relevant substances were derived for aquatic ecosystems. The data sheets cover the identification of the compounds, their behaviour in the environment (physical‐chemical properties, biotic and abiotic degradation, sorption, bioaccumulation), information about mode of action, uses, analytical determination and available quality criteria. Ecotoxicological effect concentrations for bacteria, algae, protozoa, aquatic plants, crustaceans, fish, amphibians, insects and molluscs are listed. For 17 of the 40 hazardous substances investigated, quality objectives above 1 μg/L were derived. For 12 substances the values were between 0.1 μg/L and 1 μg/L and for 5 substances lower than 0.1 μg/L. Incomplete ecotoxicological data sets of the remaining compounds do not allow the derivation of quality standards. Especially for drugs further ecotoxicological test results are needed. 相似文献
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With the aid of the Soviet atomic-absorption two-channel spectrometer “Saturn” successful attempts were made to improve the sensitivity of the heavy-metal determination after the previous two-step separation and concentration technique. Compared with other combustible gases, the propane/nitrogen-oxide flame is preferred. Because of the possibility of the direct determination of the heavy metals in the water samples the duration of analyses could be reduced by fifty per cent. Besides the heavy-metal analytics, a rapid-determination technique for calcium and magnesium was developed. The results of the different determination techniques and the ranges of measurement are given in several tables. 相似文献
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There are investigated the variables O2, BOD5, seston, NO3-N, NH4-N and o-PO4 from at least five-year series of five stations along a river section of 50 km. After exclusion of a linear trend and substraction of the individual monthly mean values from the monthly mean of many years in order to eliminate the effect of the annual variation as well as testing for normal distribution, first the correlation coefficients of the variables to the flow rate Q and the temperatures of air and water are determined, which show directional changes just in the longitudinal profile of the river. The same holds for the correlation of the variables between the measuring points. From this the model structure is derived, according to which the concentration at one measuring station can be simulated by multiple regression to Q and T at the same level as well as the concentration at the upper level. The results are discussed in detail and evaluated with respect to their inclusion in longterm management models of water quantity management. 相似文献
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