共查询到20条相似文献，搜索用时 31 毫秒
1.
热带地区火山岛/岛弧的化学风化对全球碳循环和海水的Sr同位素演化均有着重要的作用。文章对中国热带海南岛的玄武岩、花岗岩小流域和大河流域进行了河水、地下水、雨水以及基岩和沉积物的综合研究,分析了水样和固体样品的元素含量和Sr同位素比值。结果显示,河床沉积物的化学蚀变指数（CIA）与87Sr/86Sr之间存在着一定的变化关系,而这主要归因于沉积物的阶段性差异风化：风化早期阶段以黑云母占主导,87Sr/86Sr较高。此后斜长石开始风化,87Sr/86Sr逐渐下降。在风化程度中等阶段,斜长石大量分解后,各种富钾矿物风化加剧,87Sr/86Sr值升至最高点。在高风化程度阶段,随着富钾矿物逐渐减少,稳定的风化残余物质占据主导,87Sr/86Sr值逐渐下降。与年轻的活火山岛——加勒比海小安的列斯群岛和印度洋的留尼汪岛相比（其地下化学风化速率2~5倍于地表风化速率）,由于相对较低的降水量和老死火山低的孔隙度,海南岛地下水的流量和固溶物总量（TDS）要低的多,导致海南岛的地下化学风化速率低于地表风化速率,仅与高纬的俄罗斯堪察加活火山岛相近,为小安的列斯群岛和留尼汪岛的约6%~25%,属于全球地下风化贡献最低的区域之一。海南岛玄武岩区的地表化学风化和CO2消耗速率高于法国中央高原和西伯利亚,略低于夏威夷和德干,而显著小于东南亚的爪哇岛和
吕宋岛。在温度相近的条件下,径流量对化学风化速率有着非常明显的控制作用。由于较低的年径流量,热带区域的海南岛,其对大气CO2的消耗能力只是处于一个全球平均的范围内。 相似文献
2.
The Erlangmiao granite intrusion is located in the eastern part of the East Qinling Orogen.The granite contains almost 99 vol.％ felsic minerals with accessory garnet,muscovite,biotite,zircon,and Fe-Ti ... 相似文献
3.
Sr isotope and Ca/Mg/Sr chemical compositions of freshwater ostracode tests separated from a sediment core represent the last 16 ka of sedimentation in Lake Constance, Central Europe. The chemical evolution of the paleowater's dissolved load of Lake Constance was estimated by correcting the ostracode data for Ca/Mg/Sr fractionation due to biogenic calcification. Since the Late Pleistocene deglaciation, the Ca/Sr molar ratios of paleowaters increased systematically from about 100 (a near marine signature) to about 200. Ca/Mg molar ratios varied in the range of 1–25. The 87Sr/86Sr ratios indicate Late Pleistocene paleowater compositions of 0.7086–0.7091, significantly more radiogenic than present day waters (0.7085). Sr isotopes and Ca/Mg/Sr chemical data together show that weathering of Mesozoic evaporites consistently dominated the dissolved Sr load (80–90%). Carbonate and silicate weathering were less important (1–10%). Trends of Sr dissolved loads were therefore not related to Mg which was mainly mobilized by carbonate weathering. Biotite weathering was an important source of radiogenic Sr in the paleowaters. The short-term release (duration about 600–800 years) of radiogenic Sr during glacier retreat started 15.2 ka ago and was due to enhanced biotite weathering at the glacier base. Long-term release of radiogenic Sr was due to biotite weathering in glacial soils and silicate rocks, and has gradually declined since the Late Pleistocene/Holocene transition. 相似文献
4.
Deformed Hercynian peraluminous granitoids ranging from tonalite to granite crop out in the Rebordelo–Agrochão area, northern Portugal and some of them contain tonalitic and granodioritic enclaves. Variation diagrams of major and trace elements of the rocks, biotites and sphenes show fractionation trends. The most- and the least-deformed samples of granite and their biotites also define fractionation trends. There is decrease in all rare earth element (REE) contents and increase in the Eu anomaly in REE patterns from the most- to the least-deformed samples of granite. All the granitoids define a whole-rock Rb–Sr errorchron. A whole-rock Rb–Sr isochron for the least-deformed samples of granite yields an age of 357±9 Ma and an initial 87Sr/86Sr ratio of 0.7087±0.0007. Geochemical modelling suggests that the tonalitic magma evolved by AFC (fractional crystallization of magnesiohornblende, plagioclase, quartz, biotite and ilmenite, and assimilation of metasediments) to originate tonalitic and granodioritic enclaves, granodiorite and granite. δ18O values support this mechanism. The tonalite is hybrid and derived by interaction of a mantle-derived magma and crustal materials. 相似文献
5.
Water–granite interaction: Clues from strontium,neodymium and rare earth elements in soil and waters
《Applied Geochemistry》2006,21(8):1432-1454
Strontium-, Nd-, and rare-earth-element-isotope data are presented from rock, weathered rock (arene) and saprolite, sediment and soil, shallow and deep groundwater (e.g. mineral-water springs), and surface waters in the Margeride massif, located in the French Massif Central. Granitoid rock and gneiss are the main lithologies encountered in the Margeride, which corresponds to a large and 5-km-deep laccolith. Compared to bedrock, the Sr isotopes in arene, regolith, sediment and soil strongly diverge with a linear increase in the 87Sr/86Sr and Rb/Sr ratios. Neodymium isotopes fluctuate least between bedrock and the weathering products. In order to characterise the theoretical Sr isotopic signature IRf(Sr) of water interacting with granite, a dissolution model was applied, based on the hypothesis that most of the Sr comes from the dissolution of plagioclase, K-feldspar and biotite. Similar to the Sr model, an approach was developed for modelling the theoretical Nd isotopic signature IRf(Nd) of water interacting with a granite, assuming that most Nd originates from dissolution of the same minerals as those that yield Sr, plus apatite. The IRf(Sr) ratio of water after equilibration with the Sr derived from minerals was calculated for the Margeride granite and compared to values measured in surface- and groundwaters. Comparison of the results shows agreement between the calculated IRf(Sr) and the observed 87Sr/86Sr ratios. When calculating the IRf(Nd) ratio of water after equilibration with the Nd derived from minerals of the Margeride granite, the results indicated good agreement with surface-water values, whereas mineralised waters analysed within the Margeride hydrosystem could not be directly linked to weathering of the granite alone. Because the recharge area of deep groundwater is located on the Margeride massif, very deep circulation involving interaction with other rocks (e.g. shales) at depths of >5 km must be considered. 相似文献
6.
苏皖玄武岩土壤中风尘的识别及风化特征 总被引：1，自引：0，他引：1
风尘传输与沉降影响生态系统和元素的生物地球化学循环,对其在成壤作用中的识别与贡献进行研究有重要意义。文章选择在非风尘沉降区的苏皖玄武岩台地典型的两个风化剖面（安徽明光梅花村和江苏盱眙宝塔村）和部分表土及水系沉积物样品,系统分析主要矿物、粘土矿物、常量元素、微量元素及Sr、Nd同位素组成。结果显示,玄武岩基岩基本由斜长石和辉石组成,而风化基岩则主要由蒙脱石构成,风化土壤则出现基岩和风化基岩中未出现的石英、伊利石等风尘特征矿物;基岩和风化基岩以高Mg,低Si、K,无Eu异常等特征,风化土壤则以高Si、K,低Mg,负Eu异常等特征;基岩和风化基岩的εNd偏正,86Sr/87Sr值较低,而风化土壤εNd偏负,86Sr/87Sr值较高;各种证据都显示风尘对风化土壤有重要贡献,通过Nd同位素混合模式计算,风尘对土壤的贡献达60%以上。玄武岩风化表现为完全的蒙脱石化,为显著的去Ca、Mg作用,在梅花村剖面,表层土壤出现Ce负异常,而在下部层位出现Ce正异常,研究还发现在风尘的加积作用,土壤的Si、K含量得以上升。受相对较大的玄武岩台地高程差影响,玄武岩风化产物和沉降的风尘易被降水侵蚀,造成风化剖面较薄,促使玄武岩风化处于“供应限制”模式。本次工作为玄武岩的风化机制,风尘在元素地球化学循环中的作用等提供了新的地质证据。 相似文献
7.
At Telões, a subaluminous medium- to coarse-grained porphyritic biotite granite, crops out along the Vila Real NNE–SSW fault. It is a post-tectonic granite of 299±3 Ma old given by U–Pb isotopic data on zircon. It contains metaluminous to subaluminous tonalitic, granodioritic and monzogranitic enclaves. All granitoids have Fe2+-biotite and some enclaves contain magnesiohornblende and subsolidus actinolite. Monzogranitic enclaves show obvious similarities to the host granite. Linear array between enclaves and host granite is observed in Rb–Sr typical isochron diagram and gives the age of 286±11 Ma and (87Sr/86Sr)0=0.7063±0.0011. Microgranular enclaves have δ18O values similar to those of the hosting granite. Microgranular enclaves are hybrid rocks probably formed by mixing between a tonalitic enclave magma and a host granite magma as supported by the modelling of major and trace elements. The similar isotopic signatures suggest a subsequent partial equilibration of the enclaves and granite magmas. 相似文献
8.
鄂东南地区程潮大型矽卡岩型铁矿区岩体成因探讨 总被引：2，自引：0，他引：2
湖北程潮铁矿是鄂东南矿集区内最大的矽卡岩型铁矿床。为了系统研究矿区内不同侵入体的成因,对程潮矿区内不同时代的侵入体进行了矿物学、地球化学和Sr-Nd-Pb同位素研究。矿区内花岗岩、石英二长斑岩、闪长岩中的黑云母成分特征暗示它们均为壳幔物质混合成因的镁质黑云母;与成矿相关的花岗岩、石英二长斑岩中原生黑云母矿物学成分显示出原始岩浆具有高氧逸度的特征,高氧逸度为磁铁矿的形成提供了有利条件。岩石地球化学特征研究表明,不同类型的岩石都具有富钾和准铝质的特征,富集Rb、Ba、K等大离子亲石元素和轻稀土元素,亏损Nb、Ta、Ti等高场强元素。矿区岩石的(87Sr/86Sr)i值为0.705 0~0.709 1,εNd(t)值为-14.16~-6.95,206Pb/204Pb值为17.636~18.919,207Pb/204Pb值为15.451~15.613,208Pb/204Pb值为37.833~39.556。矿物学、地球化学、Sr-Nd-Pb同位素特征暗示矿区岩体为富集地幔发生部分熔融并同化混染了不同比例下地壳物质的产物,早期闪长岩（（140±1） Ma）比晚期花岗岩和石英二长斑岩（（128±1） Ma）的源区有更多的地幔成分,花岗岩和石英二长斑岩与闪长岩具有相近的锆石饱和温度（平均值分别为783、788、765℃）。 相似文献
9.
Three types of chemically and isotopically distinct pore fluids from the southern San Joaquin basin previously recognized by J.B. Fisher and J.R. Boles also have distinctive 87Sr/86Sr ratios and Sr concentrations. Meteoric fluids have stable isotopic compositions which lie on or near the meteoric water line and low chlorinities. Sr concentrations are between 0.01 and 2.6 mg l−1, and 87Sr/86Sr ratios range from 0.7061 to 0.7078. Diagenetically modified connate marine fluids have δD-and δ18O-values more positive than −35‰ and 0‰, respectively, and have chlorinities generally comparable to seawater. Sr concentration are much higher than the meteoric group (16–198 mg l−1), although the 87Sr/86Sr ratios (0.7070–0.7081) are not distinctive. Mixed meteoric-modified connate fluids have δD, δ18O and chlorinity intermediate between the meteoric and modified connate groups. Sr concentrations are also intermediate, between 16 and 22 mg l−1, but 87Sr/86Sr ratios (0.7080–0.7087) are generally more radiogenic than either the meteoric or modified connate groups.
All of the fluids have 87Sr/86Sr ratios comparable to or lower than Tertiary seawater. Alteration of detrital plagioclase is the probable origin of the low isotopic ratios. Mass-balance calculations based on the Sr data suggest that essentially no transport of Sr occurred during diagenesis of sandstones containing modified connate pore fluids, while large amounts of Sr have been transported out of meteoric reservoirs by fluid flow. The chemically anomalous mixed meteoric-modified connate fluids contain the most radiogenic strontium in the basin. These fluids are spatially associated with major faults, and may represent clay mineral dehydration waters which have been transported upward from greater depth.
These results suggest that the three types of fluids identified by Fisher and Boles represent three distinct mass transport regimes: a largely stagnant deep-basin system containing modified connate pore fluids; an actively recharging meteoric system along the basin flanks; and a third system restricted to the southern basin which may be characterized by largescale cross-formational fluid flow, rather than dilution by meteoric waters. 相似文献
10.
Zheng Lai Ni Su Zhouyang Wu Ergang Lian Chengfan Yang Fangliang Li Shouye Yang 《地球科学进展》1986,35(7):691-703
The new non-traditional stable strontium (Sr) isotope has aroused great attention from academic scholars in terms of the continental weathering and marine Sr cycle. The analytical precision of stable Sr isotope using mass spectrometry is better than 0.03‰. The compiled δ88/ 86Sr values vary from -3.65‰ to 1.68‰ in natural reservoirs. Recent findings indicate that multiple processes can cause stable Sr isotope fractionation in Earth surface, including the incongruent dissolution of primary minerals, the formation and adsorption of secondary minerals, the precipitation of calcium carbonate, and the biological cycling. These processes lead to higher δ88/ 86Sr in the liquid phase and lower δ88/ 86Sr in the solid phase, and thus result in different geochemical behavior of stable Sr isotopes in water and sediment during the weathering processes. The δ88/ 86Sr values of river sediment decrease with the increase of weathering intensity, which has the potential to indicate chemical weathering intensity. Meanwhile, further study on the fractionation mechanisms and constraints of stable Sr isotopes in river water plays an important role in tracing chemical weathering processes within the watershed, which will lead to a better understanding of the global ocean Sr cycle. 相似文献
11.
澜沧江西侧的临沧花岗岩带和怒江以西的腾冲花岗岩带是滇西最主要的两个花岗岩带,它们形成于不同构造环境。Pb、Sr 同位素研究表明,腾冲花岗岩主要来源于1200-2000Ma 的上地壳(或未分异的地壳)物质,同位素组成变化范围较小,说明源区物质组分较均一。临沧带 Pb 同位素组成变化较大,其物源是上地壳、造山带和上地幔不均匀的混合物,基底时代为800-1600Ma。因此,临沧地区和腾冲地区的基底时代和性质不同,应视为两个不同的基底地体。 相似文献
12.
Dark green quartzo-feldspathic charnockitic ortho-gneisses from Arendal, southern Norway, have locally been decoloured in the vicinities of intrusive, undeformed granite sheets and pegmatite dikes. The result is a series of pink rocks which are macroscopically indistinguishable from primary augen granite gneisses. The main mineralogical changes associated with the secondary decolcuration occurred under relatively low-grade conditions, and mainly involved chlorite, serpentine ± actinolitic amphibole ± biotite growth. The alterations were initiated along narrow, irregularly spaced cracks. The primary ( 1540 m.y.) total rock Rb---Sr isotopic systems which relate to the charnockite mineralogy were disturbed, and sometimes reset, during the secondary event which occurred at 1060 m.y. Locality by locality, the decoloured samples yield linear arrays corresponding to 1457 ± 200 m.y., 1303 ± 50 m.y. and 1125 ± 185 m.y. The combined data (n = 19) give an apparent age of 1364 ± 43 m.y. with an 87Sr/86Sr initial ratio of 0.7011 ± 0.0018. This apparent age is unrelated to any geological event and there is no overlap at the 2δ level between the 87Sr/86Sr initial ratio and that defined by the primary event (0.70345 ± 0.00014). Any estimate of crustal residence time based on these decoloured samples would be in error. The weight of evidence is against significant involvement of Rb mobility in the isotopic resetting process which accompanied decolouration. A model involving modification of the 87Sr/86Sr ratios is preferred. 相似文献
13.
XIAODONG LIU LIGUANG SUN ZHOUQING XIE XUEBIN YIN RENBIN ZHU YUHONG WANG 《Boreas: An International Journal of Quaternary Research》2007,36(2):182-197
An 85-cm long sediment sequence from Mochou Lake on Mirror Peninsula in the Larsemann Hills, East Antarctica, was investigated for elemental geochemistry, biogeochemistry and strontium (Sr) isotopic composition in the acid-insoluble and acid-soluble fractions. The biogeochemical data showed that the freshwater lacustrine sediment originated after 2750 BP. The element Zn, Cu, F, P and Se fluxes displayed almost the same vertical distribution patterns, and their ratios over loss on ignition had strong positive correlations with each other, indicating a common source, probably from seabird droppings. The Sr isotopic compositions provided further evidence of the influence of seabirds on the freshwater lacustrine sediments. The 87Sr/86Sr ratios determined in the acid-soluble fraction were remarkably lower than those of the acid-insoluble fraction; with a bedrock 87Sr/86Sr signature, they were close to those of the marine-derived Sr and were negatively correlated with total amino acids. Using the ratio vs. depth profiles of P, Zn, Cu, Se, F, As, Cd and Ni fluxes over Al, we reconstructed the historical seabird population in the catchment area of Mochou Lake. During the past c. 2800 years, the seabird population has experienced substantial changes in the absence of human activity, and four troughs were identified. After comparison with the palaeoclimatic records and glacial advance and retreat history, the pronounced seabird population declines seem to be related to climatic deterioration. 相似文献
14.
Sr and Nd isotopic compositions have been determined on basaltic and acid trachyandesites (BTA-ATA) from the Sancy volcano (Mont-Dore massif, France). These represent more than 80% of the lavas erupted during its activity between 0.9 and 0.2 Ma. These lavas have been recently interpreted as the result of two-component magma mixing during and after repeated injections of basaltic magmas in trachytic reservoirs. Magmatic heterogeneities in the ATA's (large to small enclaves, banded lavas, megacrysts…) testify to the mingling event. Complete mixing is supposed to have been achieved in the “hybrid” BTA's which contain sanidine, plagioclase and clinopyroxene megacrysts in disequilibrium with their host. The megacrysts are interpreted as relicts of the trachytic end-member. Isotopic data on basic comagmatic enclaves and host ATA matrix samples from three different cycles of mingling (succession of heterogeneous pyroclastics, heterogeneous ATA lava flows or domes and occasionally homogeneous BTA lava flows) are not incompatible with two component mixing but could just reflect the heterogeneity of the analysed samples. However, the BTA's have Sr contents and Sr isotopic ratios which are too high to be simple binary mixing products between the postulated end-members. Three hypotheses are considered to explain this discrepancy: (1) the analysed end-members are not those involved in BTA genesis, (2) some crustal contamination occurred during and after the mixing event, (3) Sr-rich sanidine xenocrysts with radiogenic 87Sr/86Sr have been assimilated and digested in the BTA's. In this third hypothesis that I favour, it is not necessary to resort to magma mixing to explain the genesis of the BTA's: assimilation of xenocrysts by basaltic, hawaiitic or mugearitic magmas accounts for both mineralogical disequilibria and isotopic characteristics of these lavas. 相似文献
15.
Birger Schmitz Stephen L. Ingram David T. Dockery III Gran berg 《Chemical Geology》1997,140(3-4):275-287
Mixed marine, brackish-water and terrestrial vertebrate skeletal apatite is found in the late Paleocene-early Eocene Tuscahoma and Bashi Formations of Mississippi. The co-Occurrence in these near-coastal marine deposits of skeletal apatite with different provenances offers a unique opportunity for unraveling the effects of diagenesis on apatite 87Sr/86Sr composition, with bearings on the use of this isotope pair as paleosalinity indicator. The results show that the Sr isotopes of all originally poorly ordered phases of skeletal apatite have extensively re-equilibrated with pore water with significantly lower 87Sr/86Sr ratios than late Paleocene-early Eocene seawater. For example, marine shark and ray teeth from the Bashi Formation all have clearly nonmarine 87Sr/86Sr ratios, 0.7073-0.7075, compared with a coeval seawater ratio in the range 0.7077-0.7078. However, separated shark tooth enamel, with a high original crystallinity, appears to have retained all or most of its in vivo Sr isotopic signature until the present. Here we also show that 87Sr/86Sr results on recent vertebrate skeletal material from different environments are in good agreement with expected values for respective habitat.
Earlier analyses of calcite material from the Bashi Formation indicated the existence of a shift in seawater 87Sr/86Sr to a lower value at the Paleocene-Eocene boundary. The strong influence of pore water with low, nonmarine 87Sr/86Sr on the apatite in the Bashi Formation suggests that the proposed isotopic shift may be an artifact related to diagenetic processes. 相似文献
16.
The overwhelming part of the continental crust in the high-grade part of the Damara orogen of Namibia consists of S-type granites, metasedimentary rocks and migmatites. At Oetmoed (central Damara orogen) two different S-type granites occur. Their negative εNd values (− 3.3 to − 5.9), moderately high initial 87Sr/86Sr ratios (0.714–0.731), moderately high 206Pb/204Pb (18.21–18.70) and 208Pb/204Pb (37.74–37.89) isotope ratios suggest that they originated by melting of mainly mid-Proterozoic metasedimentary material. Metasedimentary country rocks have initial εNd of − 4.2 to − 5.6, initial 87Sr/86Sr of 0.718–0.725, 206Pb/204Pb ratios of 18.32–18.69 and 208Pb/204Pb ratios of 37.91–38.45 compatible with their variation in Rb/Sr, U/Pb and Th/Pb ratios. Some migmatites and residual metasedimentary xenoliths tend to have more variable εNd values (initial εNd: − 4.2 to − 7.1), initial Sr isotope ratios (87Sr/86Sr: 0.708–0.735) and less radiogenic 206Pb/204Pb (18.22–18.53) and 208Pb/204Pb (37.78–38.10) isotope compositions than the metasedimentary rocks. On a Rb–Sr isochron plot the metasedimentary rocks and various migmatites plot on a straight line that corresponds to an age of c. 550 Ma which is interpreted to indicate major fractionation of the Rb–Sr system at that time. However, initial 87Sr/86Sr ratios of the melanosomes of the stromatic migmatites (calculated for their U–Pb monazite and Sm–Nd garnet ages of c. 510 Ma) are more radiogenic (87Sr/86Sr: 0.725) than those obtained on their corresponding leucosomes (87Sr/86Sr: 0.718) implying disequilibrium conditions during migmatization that have not lead to complete homogenization of the Rb–Sr system. However, the leucosomes have similar Nd isotope characteristics than the inferred residues (melanosomes) indicating the robustness of the Sm–Nd isotope system during high-grade metamorphism and melting. On a Rb–Sr isochron plot residual metasedimentary xenoliths show residual slopes of c. 66 Ma (calculated for an U–Pb monazite age of 470 Ma) again indicating major fractionation of Rb/Sr at c. 540 Ma. However, at 540 Ma, these xenoliths have unradiogenic Sr isotope compositions of c. 0.7052, indicating depleted metasedimentary sources at depth. Based on the distinct Pb isotope composition of the metasedimentary rocks and S-type granites, metasedimentary rocks similar to the country rocks are unlikely sources for the S-type granites. Moreover, a combination of Sr, Nd, Pb and O isotopes favours a three-component mixing model (metasedimentary rocks, altered volcanogenic material, meta-igneous crust) that may explain the isotopic variabilty of the granites. The mid-crustal origin of the different types of granite emphasises the importance of recycling and reprocessing of pre-existing differentiated material and precludes a direct mantle contribution during the petrogenesis of the orogenic granites in the central Damara orogen of Namibia. 相似文献
17.
The Rio Espinharas pluton, northeastern Brazil, belongs to the shoshonitic series and consists mainly of syenogranite, quartz–monzonite and porphyritic quartz–monzonite, but diorite, quartz–monzodiorite, quartz–syenite and microsyenogranite also occur containing microgranular enclaves, except for the diorite. Most variation diagrams of rocks, amphiboles, biotites and allanites show linear trends, but K, Zr, Sr and Ba of rocks display curved scattered trends. The rocks ranging from diorite to syenogranite define a pseudo-errorchron and have similar REE patterns. Syenogranite and microsyenogranite are derived from two distinct pulses of granite magma with initial 87Sr/86Sr ratio of 0.7083±0.0003 and 0.7104±0.0007, respectively. Modelling of major and trace elements shows that the syenogranite evolved by fractional crystallization of plagioclase, microcline, edenite, biotite and titanite, whereas quartz–monzonite, porphyritic quartz–monzonite, quartz–monzodiorite and quartz–syenite resulted from simple mixing between an upper mantle-derived dioritic magma and the upper crust-derived syenogranite magma. Dioritic enclaves are globules of a mafic magma from the upper mantle. 相似文献
18.
Jong-Sik Ryu Andrew D. Jacobson Craig Lundstrom 《Geochimica et cosmochimica acta》2011,75(20):6004-7046
We dissolved Boulder Creek Granodiorite in a plug flow reactor for 5794 h at pH = 1 and T = 25 °C. The primary purpose of the experiment was to identify controls on dissolved δ44/40Ca, δ44/42Ca, and δ26/24Mg values during granite weathering. Herein, we also examine the origin of Ca and Mg isotopic variability among minerals composing the Boulder Creek Granodiorite, and we constrain fundamental characteristics of granite weathering important for quantifying the elemental and isotopic geochemistry of the reactor output. Nine Ca-bearing minerals display an 8.80‰ range of δ44/40Ca values and a 0.51‰ range of δ44/42Ca values. Three Mg-bearing minerals display a 1.53‰ range of δ26/24Mg values. These ranges expressed at the mineralogical scale are higher than the ranges thus far reported for bulk igneous rocks. Most of the δ44/40Ca variability reflects 40Ca enrichment in K-feldspar, and to a lesser extent, biotite, due to the radioactive decay of 40K over the 1.7 Ga age of the rock, whereas the entire range of δ44/42Ca values reflects mass-dependent isotope fractionation during igneous differentiation and crystallization. The range of δ26/24Mg values may represent either fractionation during the chloritization of biotite or interaction of the Boulder Creek Granodiorite with Mg-rich metamorphic fluids having low δ26/24Mg values.The elemental and isotopic composition of the reactor output varied substantially during the experiment. We synthesize the mineralogical and fluid data using coupled mass-conservation equations solved at non-steady-state. Model calculations reveal an intricate balance between increasing specific surface area and decreasing mineral concentrations. While surface area normalized dissolution rate constants were time-invariant, specific surface area increased as a power-law function of time through positive feedbacks between mechanical disaggregation, chemical dissolution, and mineral depletion. Variations in dissolved δ44/40Ca, δ44/42Ca, and δ26/24Mg values reflect conservative mixing rather than fractionation. Apatite and calcite initially control δ44/40Ca and δ44/42Ca values, followed by biotite, titanite, epidote, hornblende, and plagioclase. The release of radiogenic 40Ca clearly defines the period where biotite dissolution dominates. The brucite layer of chlorite initially controls δ26/24Mg values, followed by biotite, the TOT layer of chlorite, and hornblende. Through direct isotopic tracking, these results demonstrate that trace minerals, such as apatite and calcite in the case of Ca and brucite in the case of Mg, dominate elemental release during the incipient stages of granite weathering. The results further show that biotite dissolution dominates the middle stages of granite weathering and that plagioclase dissolution only becomes important during relatively late stages. The Ca and Mg isotope variations associated with these stages are distinct and potentially resolvable in soil mineral weathering studies. 相似文献
19.
冈底斯成矿带内的岩浆岩是印度板块与欧亚板块碰撞造山的产物,更是研究碰撞造山与成矿作用的理想对象。多仁则—桑阿卡地区位于冈底斯火山-岩浆弧中段中南部,区内含矿岩体为灰白色中细粒黑云母花岗闪长岩。LA-ICP-MS锆石U-Pb测年、岩石地球化学和Sr-Nd同位素研究表明：岩体就位年龄为（49.0±0.7）Ma,其形成时代为始新世;岩石具有高硅（w（SiO2）为67.13%）、高钾（w（K2O）为3.72%）、富碱（w（K2O+Na2O）为7.48%）、贫MgO（w（MgO）为1.34%,小于3%）的特征,为高钾钙碱性系列的高分异I型花岗岩;Eu负异常（δEu为0.70）和Sr的亏损暗示岩浆发生斜长石的分离结晶作用;岩石的微量元素表现出Th、U、K、Nd、Zr、Hf富集和Nb、Ta、Sr、Ti、P亏损的特征;全岩Sr-Nd同位素（（87Sr/86Sr）i为0.705 280~0.705 530、εNd（t）为-2.2~-1.6）、微量元素及元素比值揭示岩浆源区是壳幔混源,是在印度板块与欧亚板块俯冲-碰撞后板片断离构造背景下,热的软流圈地幔物质通过板片断离窗上涌,并诱发下地壳部分熔融,形成该地区壳幔混源岩浆-热液成矿作用。综合研究认为,多仁则—桑阿卡地区斑岩型-热液型铜多金属成矿作用是早始新世岩浆活动大爆发滞后的成矿响应,是与冈底斯成矿带内的壳幔花岗岩有关的Cu-Au-Mo-Fe-Pb-Zn成矿系统（52~47 Ma）的重要组成部分。 相似文献
20.
浙西南遂昌-大柘地区八都岩群在印支期变质事件影响下发生变质变形,通过详细野外调查和岩相学研究,可将其划分为3期变质变形序列：S1变形期,NW向片麻理记录的残留紧闭褶皱,共生矿物组合为石榴子石变斑晶及其内部定向分布的包裹体矿物,石榴子石+黑云母+石英（泥质）和石榴子石+角闪石+斜长石+石英（长英质）;S2变形期,区域性宽缓褶皱及NE向缓倾透入性片麻理,共生矿物组合为石榴子石变斑晶及定向分布的基质矿物,矽线石+石榴子石+黑云母+石英+斜长石±钾长石（泥质）和石榴子石+钾长石+斜长石+黑云母+石英（长英质）;S3变形期,NE向陡倾透入性片麻理及韧脆性断裂大部分被花岗斑岩脉填充,共生矿物组合为石榴子石变斑晶及其周围退变矿物,石榴子石+矽线石+堇青石+斜长石+黑云母+石英±钾长石（泥质）和角闪石+斜长石+黑云母+钛铁矿（长英质）。结合前人研究成果,八都岩群印支期变质事件峰期变质程度达到麻粒岩相,显示顺时针近等温降压（ITD）型的p-T演化轨迹,S1-S3变质变形反映出从俯冲碰撞到快速折返冷却的演化过程,伴随S3同期侵位的花岗斑岩锆石U-Pb定年结果,将该演化过程完成时间约束在229.7 Ma,可能是浙西南地区对印支期古特提斯洋域内印支-华南-华北板块之间俯冲-碰撞过程的响应。 相似文献