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1.
The morphological characteristics of the segmentation of the Central Indian Ridge (CIR) from the Indian Ocean Triple Junction (25°30S) to the Egeria Transform Fault system (20°30S) are analyzed. The compilation of Sea Beam data from R/VSonne cruises SO43 and SO52, and R/VCharcot cruises Rodriguez 1 and 2 provides an almost continuous bathymetric coverage of a 450-km-long section of the ridge axis. The bathymetric data are combined with a GLORIA side-scan sonar swath to visualize the fabric of the ridge and complement the coverage in some areas. This section of the CIR has a full spreading rate of about 50 mm yr–1, increasing slightly from north to south. The morphology of the CIR is generally similar to that of a slow-spreading center, despite an intermediate spreading rate at these latitudes. The axis is marked by an axial valley 5–35 km wide and 500–1800 m deep, sometimes exhibiting a 100–600 m-high neovolcanic ridge. It is offset by only one 40km offset transform fault (at 22°40S), and by nine second-order discontinuities, with offsets varying from 4 to 21 km, separating segments 28 to 85 km long. The bathymetry analysis and an empirical orthogonal function analysis performed on across-axis profiles reveal morphologic variations in the axis and the second-order discontinuities. The ridge axis deepens and the relief across the axial valley increases from north to south. The discontinuities observed south of 22°S all have morphologies similar to those of the slow-spreading Mid-Atlantic Ridge. North of 22°S, two discontinuities have map geometries that have not been observed previously on slow-spreading ridges. The axial valleys overlap, and their tips curve toward the adjacent segment. The overlap distance is 2 to 4 times greater than the offset. Based on these characteristics, these discontinuities resemble overlapping spreading centers (OSCs) described on the fast-spreading EPR. The evolution of one such discontinuity appears to decapitate a nearby segment, as observed for the evolution of some OSCs on the EPR. These morphological variations of the CIR axis may be explained by an increase in the crustal thickness in the north of the study area relative to the Triple Junction area. Variations in crustal thickness could be related to a broad bathymetric anomaly centered at 19°S, 65°E, which probably reflects the effect of the nearby Réunion hotspot, or an anomaly in the composition of the mantle beneath the ridge near 19°S. Other explanations for the morphological variations include the termination of the CIR at the Rodriguez Triple Junction or the kinematic evolution of the triple junction and its resultant lengthening of the CIR. These latter effects are more likely to account for the axial morphology near the Triple Junction than for the long-wavelength morphological variation.  相似文献   

2.
The morphotectonic setting of the East Pacific Rise (EPR) between21°12 and 22°40 S and its recent and past hydrothermalactivity were the focus of the Russian R/V Geolog Fersmans expeditionin 1987–1988.The EPR axial zone in the study area is comprised of three segmentsseparated by overlapping spreading centers (OSCs) near 21°44 and22°08 S. The northern segment is the shallowest of three and hasa distinct massive axial ridge, trapeziodal in cross-section, toppedby a very wide flat summit surface and cut by a well-developedcentral graben. These features testify to intense magmatism and to avoluminous crustal magmatic chamber underlying the whole segment.Fine-scale segmentation is most clearly revealed in the structure ofthe central graben within which several 4th-order segments can bedistinguished. This scale of segmentation is also reflected on flanks of theaxis by variations in the character and intensity of faulting.According to structural and petrologic data, the magmatism is mostintense in the central part of the segment which is probably locateddirectly over a magmatic diapir supplying the melt to the whole segment.Magma migration at the subcrustal level from the center towards the ends ofthe segment with discrete injection into the crustal magmatic chamber ispresumed.The central segment is broken into two morphologically distinct partsseparated by a deval. In the subsided northern part, the wide summit of theaxial ridge is cut by a well-developed, intensely fractured axialgraben. In the southern part, the axial ridge is relatively elevated, butnarrow with an ephemeral graben along its crest. The character and intensityof faulting on the axial flanks are also considerably different in thenorthern and southern parts of the segment. Thus, the magmatic supply tothese two parts is thought to originate from two different sources. If so,then at present the magma chamber underlying the southern part of thesegment is probably at the stage of replenishment, while in the north it isat the stage of deep cooling.The southern segment is structurally similar to the central one. Howeverthere is considerably less intensive magmatic activity in this region,especially south of 22°30 S where the axial ridge is narrow, andtriangular in cross-section.Both OSCs studied are marked by abrupt narrowing and sharp subsidence ofthe tips of axial ridges within the northern limbs. The southern OSC limbsare morphologically similar to normal sections of axial ridges. In bothcases the flanks are structurally and morphologically disrupted adjacent tothe OSCs and oblique structures can be traced far southward of the OSCflanks. Due to the spatial position of oblique structures on the the flanksit is presumed that the OSC near 22°07 S is migrating northward.The 21°44 S OSC zone has apparently undergone small spatialoscillations. In spite of the small amplitude of lateral displacement, thiszone is marked by prominent bathymetric anomalies.Numerous massive sulfide deposits were discovered atop the axial ridgealong the entire length of the uplifted and hydrothermally active northernsegment. Ore metal concentrations in near-bottom waters are maximumover the southern part of the northern segment, while maximum concentrationsof the same metals in surficial sediments are confined to the central partof the same segment. We surmise that there has been a recentalong-axis shift of the zone of maximum hydrothermal activity fromthe middle of the segment to its present position in the southern part ofthe segment. Considering sedimentation rates, the age of this shift can beapproximately estimated to be 5 to 10 thousand years before the present.The relatively Mg-enriched basalts of the middle part of thenorthern segment represent a tike of a more primitive pattern, while therelatively Fe-rich rocks of its southern part probably reflect alarge degree of fractionation at shallow crustal levels. Considering thistrend, in addition to morphotectonic data we presume that subaxial magmaflow from the middle to the southern part of the segment is responsible forthe along-axis shift of hydrothermal activity.In the central segment of the study area, massive sulfides have only beendiscovered south of the 21°55 S deval, where the axial ridgeshoals and where the existence of a subjacent magma chamber is presumed.The very weak manifestations of recent volcanism within the southernsegment explain the absence of hydrothermal activity and sulfide depositswithin this segment.  相似文献   

3.
Heat fluxes are estimated across transatlantic sections made at 4°30′S and 7°30′N in January–March 1993, following Hall and Bryden (1982. Deep-Sea Research 29, 339–359). Particular care is given to the computation of Ekman volume and heat fluxes, which are assessed both (a) from the windstress data for the period of the cruise and (b) from the comparison between geostrophic and Vessel Mounted Acoustic Doppler Current Profiler (VM-ADCP) velocities. In contrast with previous studies, the two estimates for Ekman fluxes do not converge for either section: (a) (11.5±0.5 Sv; 1.01±0.05 PW) across 7°30′N and (−9.3±1.2 Sv; −0.85±0.12 PW) across 4°30′S when windstress data at the date of the hydrographic stations are used; (b) (6.3±1.1 Sv; 0.56±0.09 PW) across 7°30′N and (−3.4±3.0 Sv; −0.35±0.24 PW) across 4°30′N when the ageostrophic transport above the thermocline is used. The divergence would have been even greater at 4°30′S if the strong ageostrophic signal beneath the thermocline, which brings a transport of (8.4 Sv; 0.82 PW), had been considered. The corresponding total meridional heat fluxes are: (a) 1.40±0.16 PW and (b) 0.95±0.20 PW across 7°30′N, (a) 1.05±0.12 PW and (b) 1.67±0.14 PW (2.39±0.14 PW when the subthermocline ageostrophic transport is taken into account) across 4°30′S.The estimates based on windstress data are compared with the results from an inverse model (Lux and Mercier, 1999) to show the importance of the heat flux due to the deviation of the local depth-averaged potential temperature from its average over the section, which is neglected in the Hall and Bryden (1982. Deep-Sea Research 29, 339–359) method but is not negligible in our computation in which we do not isolate the transport of the western boundary current east of the 200 m isobath; this corrective flux amounts here to −0.19 PW across 7°30′N and 0.33 PW across 4°30′S.The seasonal variability of the meridional heat flux across 7°30′N is studied through the hydrographic data collected during the ETAMBOT 1–2 cruises, which repeated the 7°30′N section west of 35°W in September 1995 and April 1996. When the section is completed east of 35°W with CITHER 1 data and when windstress data are used for the computation of the Ekman transport, the estimates for the meridional heat fluxes are 0.20±0.14 PW in September 1995 and 1.69±0.27 PW in April 1996. The estimates fit well with results from numerical models.  相似文献   

4.
对东太平洋海隆(EPRⅠ区和Ⅱ区)和南大西洋中脊(SMAR)6个站位新鲜的玄武岩样品进行了岩石学及地球化学研究。结果显示,EPR玄武岩样品可分为辉石玄武岩、气孔玄武岩和玻基玄武岩3种类型,SMAR玄武岩样品主要为辉石玄武岩。EPR和SMAR玄武岩样品的标准矿物组合相同,均出现了石英和紫苏辉石标准矿物,为典型的拉斑玄武岩。EPRⅠ区和SMAR玄武岩表现出轻稀土富集的配分模式,可能受到了富集地幔源区(EMORB)的影响,其玄武岩可能形成于未经历早期熔融事件的富集地幔或部分熔融程度相对较低。EPRⅡ区玄武岩为正常型洋中脊玄武岩(N-MORB),其源区为经历了早期熔融事件的、亏损洋中脊地幔源区(DMM),且源岩部分熔融程度较高。EPRⅠ区与Ⅱ区不同的幔源特征说明东太平洋海隆地幔源区存在不均一性。  相似文献   

5.
《Oceanologica Acta》1999,22(3):249-263
Mean conditions, seasonal, and ENSO-related (El Niño Southern Oscillation) variability in the vicinity of Wallis, Futuna, and Samoa islands (13°–15° S, 180°–170° W) over the 1973–1995 period are analysed for wind pseudo-stress, satellite-derived and in situ precipitation, sea surface temperature (SST) and salinity (SSS), sea level, and 0–450 m temperature and geostrophic current. The mean local conditions reflect the presence of the large scale features such as the western Pacific warm pool, the South Pacific Convergence Zone (SPCZ), and the South Pacific anticyclonic gyre. The seasonal changes are closely related to the meridional migrations of the SPCZ, which passes twice a year over the region of study. During the warm phase of ENSO (El Niño), we generally observe saltier-than-average SSS (of the order of 0.4), consistent with a rainfall deficit (0.4 m yr−1), a hint of colder-than-average surface temperature is also identified in subsurface (0.3°C), a weak tendency for westward geostrophic current anomalies (2 cm s−1 at the surface), a sea level decrease (5–10 cm), together with easterly (5 m2s−2) and well marked southerly (10 m2s−2) wind pseudo-stress anomalies. Anomalies of similar magnitude, but of opposite sign, are detected during the cold phase of ENSO (La Niña). While these ENSO-related changes apply prior to the 1990s, they were not observed during the 1991–1994 period, which appears atypical.  相似文献   

6.
Sediment thickness was evaluated on the western flank of the East Pacific Rise (EPR) at 45°S, based on high-resolution seismic data gathered during cruise 213/2 of R/V Sonne in 2011. Two zones with distinctly different sediment thickness were identified, separated by a transitional zone bordering a pseudo-fault. Sediment in the more distal zone 2 is almost twice as thick (~120 m) as in zone 1 close to the EPR. This is in contrast to the expected progressive sedimentary column thickening with seafloor age and distance from the spreading axis. The younger of two seismic units detected within the sedimentary column (EPR-2) occurs mainly in the distal zone on crust older than 9 Ma, whereas on younger crust it is present only in small isolated bodies. Both sedimentary units drape the basement. The drape is interpreted to represent particle settling from suspension and a generally low regional primary productivity. The spatial variation in sediment thickness cannot be explained by existing models, and other processes considered in the present case are (1) higher productivity in the western sector of the survey area, where thicker sediments were observed (zone 2), (2) the formation of sediment drifts near basement highs (‘seamount effect’), due to flow of Lower Circumpolar Deep Water affecting sediment deposition, and (3) erosion and/or non-deposition of the younger EPR-2 unit, due to elevated bed shear stresses associated with eddies transferring kinetic energy to the seafloor  相似文献   

7.
Multichannel seismic reflection data recorded between Arauco Gulf (37°S) and Valdivia (40°S), on the Chilean continental margin, were processed and modeled to obtain seismic images and sub-surface models, in order to characterize the variability of the bottom-simulating reflector (BSR), which is a geophysical marker for the presence of gas hydrates. The BSR is discontinuous and interrupted by submarine valleys, canyons, as well as by faults or fractures. The BSR occurrence is more common south of Mocha Island due to moderate slopes and greater organic matter contribution by rivers in that area. Tectonic uplift and structural instability change the stability gas hydrate zone and consequently the BSR position, creating in some cases missing or double BSRs. Our modeling supports the presence of gas hydrate above the BSR and free gas below it. Higher BSR amplitudes support higher hydrate or free gas concentrations. In the study area, gas hydrate concentration is low (an average of 3.5%) suggesting disseminated gas hydrate distribution within the sediments. Also higher BSR amplitudes are associated with thrust faults in the accretionary prism, which serve as conduits for gas flow from deeper levels. This extra gas supply produces a wider thickness of gas hydrates or free gas.  相似文献   

8.
By analyzing a data set collected using a moored instrument array and CTD during TOGA-COARE, it is found that there exist remarkable internal tides in the western equatorial Pacific Ocean around 1°45′S,156°E, whose horizontal wavenumber (wavelength), vertical wavenumber, h 156° orizontal propagation speed and vertical propagation speed are 3.3×10-2km-1(210 km),-1.6×10-3m, 2.0 m/s and -3.8 cm/s, respectively, that is, the waveform propagates downwards slantingly. Moreover, the propagating direction rotates statistically clockwise as the depth increases and its cause is unclear.  相似文献   

9.
We discuss nitrous oxide (N2O) and methane (CH4) distributions in 49 vertical profiles covering the upper ∼300 m of the water column along two ∼13,500 km transects between ∼50°N and ∼52°S during the Atlantic Meridional Transect (AMT) programme (AMT cruises 12 and 13). Vertical N2O profiles were amenable to analysis on the basis of common features coincident with Longhurst provinces. In contrast, CH4 showed no such pattern. The most striking feature of the latitudinal depth distributions was a well-defined “plume” of exceptionally high N2O concentrations coincident with very low levels of CH4, located between ∼23.5°N and ∼23.5°S; this feature reflects the upwelling of deep waters containing N2O derived from nitrification, as identified by an analysis of N2O, apparent oxygen utilization (AOU) and NO3, and presumably depleted in CH4 by bacterial oxidation. Sea-to-air emissions fluxes for a region equivalent to ∼42% of the Atlantic Ocean surface area were in the range 0.40–0.68 Tg N2O yr−1 and 0.81–1.43 Tg CH4 yr−1. Based on contemporary estimates of the global ocean source strengths of atmospheric N2O and CH4, the Atlantic Ocean could account for ∼6–15% and 4–13%, respectively, of these source totals. Given that the Atlantic Ocean accounts for around 20% of the global ocean surface, on unit area basis it appears that the Atlantic may be a slightly weaker source of atmospheric N2O than other ocean regions but it could make a somewhat larger contribution to marine-derived atmospheric CH4 than previously thought.  相似文献   

10.
1Introduction DuringtheTOGA COARE,extensivejointin ternationaloceanicobservationswerecarriedoutin thewesternequatorialPacificOceanandavasta mountofvaluabledatawereobtained.Themaindata usedhereincludethedatafromasinglemooringin strumentarrayat1°45′S,156°E,deployedbythe WoodsHoleOceanographicInstitution(WHOI)and theCTD(profilerofconductivity-temperature-depth)datacollectedbytheChineseRVXiangy anghongNo.5.Fangetal.(2000)described brieflytheseobservationdataandanalyzedthedis persion…  相似文献   

11.
Variations of water properties in surface and intermediate layers along 32°S in the southern Indian Ocean were examined using a 50-year (1960–2010) time series reproduced from historical hydrographic and Argo data by using optimum interpolation. Salinity in the 26.7–27.3σθ density layer decreased significantly over the whole section, at a maximum rate of 0.02 decade−1 at 26.8–26.9σθ, for the 50-year average. Three deoxygenating cores were identified east of 75°E, and the increasing rate of apparent oxygen utilization in the most prominent core (26.9–27.0σθ) exceeded 0.05 ml l−1 decade−1. The pycnostad core of Subantarctic Mode Water (SAMW) and the salinity minimum of Antarctic Intermediate Water shifted slightly toward the lighter layers. Comparisons with trans-Indian Ocean survey data from 1936 suggest that the tendencies found in the time series began before 1960. Interestingly, cores of many prominent trends were located just offshore of Australia at 26.7–27.0σθ, which is in the SAMW density range. Spectrum analysis revealed that two oscillation components with time scales of about 40 and 10 years were dominant in the subsurface layers. Our results are fairly consistent with, and thus support, the oceanic responses in the southern Indian Ocean to anthropogenic climate change predicted by model studies.  相似文献   

12.
Spatial and temporal variability of the island mass effect (IME; defined as local increases of phytoplankton associated with the presence of islands) at the Juan Fernández Archipelago (JFA) is analyzed using chlorophyll-a (Chl-a) satellite data, altimetry, sea surface temperature, wind, geostrophic currents and net heat flux over a ten year period (2002–2012). The the JFA islands (Robinson Crusoe-Santa Clara (RC-SC) and Alejandro Selkirk (AS)) present wakes with significant Chl-a increases, mainly during spring time. These wakes can reach Chl-a values of one order of magnitude higher (~1 mg m−3) than the surrounding oligotrophic waters (<0.1 mg m−3). The wakes are similar to von Kármán vortex streets which have been used to explain the impact of IME on Chl-a increases in numerical models. The wakes are formed from a high productivity area in the lee of the island, extending to the oceanic region as high Chl-a patches associated with submesoscale eddies that are detached from the islands and connected by less-productive zones. This pattern coincides with previous models that predict the effects of island-generated flow perturbations on biological production variability. The IME is a recurrent feature of islands that has even been observed in decadal average fields. In such average fields, the Chl-a values in RC-SC and AS islands can exceed values found in a Control Zone (a zone without islands) by ~50% and 30%, respectively. Seasonal and interannual variability reveals that, as a consequence of the IME, the winter Chl-a maximum associated with the development of winter convection and mesoscale eddies that propagate from the continental zone, promote that the Chl-a maximum extends towards spring. The IME has an impact on the island on both a local as well as a more regional scale that affects an area of ~40,000 km2 (1°Latitude×4°Longitude) centered on the islands. The transport of high productivity patches associated with submesoscale eddies may be responsible for IME propagation at a regional scale. Around the islands, the presence of a weak oceanic incident flow and strong and recurrent wind-wakes, suggest that the generation of Chl-a wakes result from a combined effect between both forcings.  相似文献   

13.
The comparative estimation of the parameters of the lithosphere of the Mid-Ocean Southwestern Indian range in the areas westwards and eastwards of the Atlantis II transform fault zone shows that, within this zone, an alteration in the basalt composition occurred. Eastwards of this zone, a decrease of the anomaly of the magnetic field occurred and increased average depths of the axial part (4.7 km) and thinning (up to 4–5 km) of the ocean crust with increased rates of seismic waves in the upper mantle were observed. This, first of all, indicates an anomalously cold mantle below the oceanic crust. The changes that occurred in the location of the Euler pole within the last millions of years resulted in slanting spreading in the area of the investigation with rates of opening lower than 1.8 cm/year probably accompanied by the phenomena of transtension in the active parts of the transform faults. The interaction between the Landly and Somali lithosphere plates occurred along the diffusion boundary and was accompanied by problems with tracing the chrones between the neighboring profiles of geomagnetic observations. Consequently, the more detailed investigation of the configuration of the diffusion boundary will contribute to the more accurate reconstruction of the paleogeodynamics of the central part of the Indian Ocean.  相似文献   

14.
The third in a series of cruises designed to establish the present-day concentrations of trace elements and synthetic organic compounds in major water masses of the ocean, the 1996 Intergovernmental Oceanographic Commission Contaminant Baseline Survey occupied six vertical profile stations in the subtropical and tropical Atlantic. Underway surface samples also were acquired in the transects between these stations. This paper uses the temperature, salinity, oxygen, nutrient, and chlorophyll results from the cruise to set the hydrographic background for the other papers in this special volume. Major features sampled during the surface transect include the Brazil Current, the South Equatorial Current, and the offshore Amazon Plume. Utilizing the above parameters to identify water masses, we observed Antarctic Bottom Water (AABW) that ranged from a relatively undiluted form at 33°S (Station 10) to a highly attenuated form at 8°N (Station 6). Similarly, North Atlantic Deep Water (NADW) was obtained in various mixing stages along its flow path, and samples of NADW and AABW exchanging through the Romanche Fracture Zone to the eastern Atlantic basins were also taken. In addition to these deep water masses, representative samples of Antarctic Intermediate Water and Circumpolar Deep Water were acquired. Besides standard hydrography, these data also were used to verify the sampling integrity of the trace metal-clean, Go Flo bottles deployed on a Kevlar hydrographic cable.  相似文献   

15.
Swath MR1 data from the remnant Colville and active Kermadec arc margins, south of 33°30 S (SW Pacific), record the structural morphology and evolution of the rifted, and now separate portions, of the proto-Colville–Kermadec arc flanking the actively widening southern Havre Trough back-arc basin associated with Pacific-Australian plate convergence. Both the remnant Colville and active Kermadec arc margins comprise opposing, asymmetric, partially basement exposed, segmented ridges. Differences in morphology between the two ridges are, however, observed. The single, near linear, border fault system, with relief of 1000 m, along the western edge of the Kermadec margin is interpreted to be the exposed fault escarpment of a major, west-dipping, detachment fault. In contrast, two major zig-zag border fault systems along the eastern edge of the Colville Ridge, bounding a back-tilted ridge flank terrace, are interpreted as major antithetic faults between the remnant arc and back-arc region. This contrast in structural morphology coincides with, respectively, lesser and greater degrees of both active tectonism and channel-canyon erosion, on the remnant Colville and active Kermadec margins. These differences are interpreted to reflect the progressive trenchward collapse and associated greater rift flank uplift and incisive erosion of the Kermadec foot-wall contrasting with the non-collapse and relatively lesser rift flank uplift and ridge erosion of the Colville hanging-wall. The data provide further constraints on the early evolution of the Havre Trough in particular, and back-arc basins in general.  相似文献   

16.
pH and alkalinity measurements from a coastal upwelling area located near 30°S (Coquimbo, Chile), are used to describe the short-term variations of CO2 air–sea exchanges over a period of one week in summer 1996. A 180 km ocean–coastal transect, together with two almost-synoptic grid surveys off Coquimbo covering approximate 2500 km2 each, showed that during and immediately after a 4 day long southwesterly wind event (24–28 January) a large area of cold surface water (≈14°C), highly supersaturated in CO2 (fCO2 up to 900 μatm), was located near the coast. Three days after the end of the event, the second grid survey showed that in most of the study area the surface temperature and pH had increased significantly (by 1–3°C and 0.05–0.2, respectively), and that the surface water was no longer supersaturated in CO2. The CO2-supersaturated water observed in the first grid survey was identified as upwelled subsurface equatorial water, a water mass with its core at about 200 m depth: the depth from which the water upwells is a major determinant of the surface water fCO2. Integrated C fluxes within a 20 km wide coastal strip (1900 km2) indicate a strong outgassing of CO2 from the ocean under upwelling conditions (Grid 1; 121 t C day-1), while the net C exchange was directed to the ocean during the relaxation period (Grid 2; 19 t C day-1). Estimates of CO2 fluxes in upwelling areas based on surface water fCO2 measurements must therefore take into account these short-term variations: reliance on longer-term averages and interpolation will lead to erroneous results.  相似文献   

17.
A seafloor hydrothermal field, named Deyin-1 later, near 15°S southern Mid-Atlantic Ridge(SMAR) was newly found during the 22 nd cruise carried out by the China Ocean Mineral Resources Research Development Association(COMRA). Sulfide samples were collected at three stations from the hydrothermal field during the26 th cruise in 2012. In this paper, mineralogical characteristics of the sulfides were analyzed with optical microscope, X-ray diffractometer, scanning electron microscope and electron microprobe to study the crystallization sequence of minerals and the process of hydrothermal mineralization. According to the difference of the ore-forming metal elements, the sulfide samples can be divided into three types:(1) the Ferich sulfide, which contains mainly pyrite and chalcopyrite;(2) the Fe-Cu-rich sulfide consisting predominantly of pyrite, chalcopyrite and isocubanite, with lesser amount of sphalerite, marmatite and pyrrhotine; and(3) the Fe-Zn-rich sulfide dominated by pyrite, sphalerite and marmatite, with variable amounts of chalcopyrite, isocubanite, pyrrhotine, marcasite, galena and gratonite. Mineral precipitations in these sulfides are in the sequence of chalcopyrite(isocubanite and possible coarse pyrite), fine pyrite,sphalerite(marmatite), galena, gratonite and then the minerals out of the dissolution. Two morphologically distinct generations(Py-I and Py-II) of pyrite are identified in each of the samples; inclusions of marmatite tend to exist in the coarse pyrite crystals(Py-I). Sphalerite in the Fe-Zn-rich sulfide is characterized by a"chalcopyrite disease" phenomenon. Mineral paragenetic relationships and a wide range of chemical compositions suggest that the environment of hydrothermal mineralization was largely changing. By comparison, the Fe-rich sulfide was formed in a relatively stable environment with a high temperature, but the conditions for the formation of the Fe-Cu-rich sulfide were variable. The Fe-Zn-rich sulfide was precipitated during the hydrothermal venting at relatively low temperature.  相似文献   

18.
Aerobic NH4+ oxidation rates were measured along the strong oxygen gradient associated with the oxygen minimum zone (OMZ) of the eastern tropical South Pacific off northern Chile (∼20°S) during 2000, 2003, and 2004. This process was examined by comparing NH4+ rates of change during dark incubations, with and without the addition of allylthiourea, a classical inhibitor of the ammonia monooxygenase enzyme of ammonium-oxidizing bacteria. The contribution of aerobic NH4+ oxidation in dark carbon fixation and NO2 rates of change were also explored. Thirteen samples were retrieved from the oxycline (252 to ⩽5 μM O2; 15 to ∼65 m depth) and three from the oxygen minimum core (⩽5 μM O2; 100–200 m depth). Aerobic NH4+ oxidation rates were mainly detected in the upper part (15–30 m depth) of the oxycline, with rates ranging from 0.16 to 0.79 μM d−1, but not towards the oxycline base (40–65 m depth). In the oxygen minimum core, aerobic NH4+ oxidation was in the upper range and higher than in the upper part of the oxycline (0.70 and 1.0 μM d−1). Carbon fixation rates through aerobic NH4+ oxidation ranged from 0.18 to 0.43 μg C L−1 d−1 and contributed between 33% and 57% of the total dark carbon fixation, mainly towards the oxycline base and, in a single experiment, in the upper part of the oxycline. NO2 consumption was high (up to 10 μM d−1) towards the oxycline base and OMZ core, but was significantly reduced in experiments amended with allylthiourea, indicating that aerobic NH4+ oxidation could contribute between 8% and 76% of NO2 production, which in turn could be available for denitrifiers. Overall, these results support the important role of aerobic NH4+ oxidizers in the nitrogen and carbon cycling in the OMZ and at its upper boundary.  相似文献   

19.
The distribution of pH and alkalinity has been used to calculate the distribution of total inorganic carbon (TC) and fugacity of carbon dioxide (fCO2) in the upper 200 m of the water column in coastal upwelling areas off northern Chile (23–24°S, near Antofagasta) and central Chile (30–31°S, near Coquimbo) during austral summer 1997. In these upwelling areas, colder surface waters were oxygen poor and strongly CO2 supersaturated (100% near Antofagasta and 200% near Coquimbo), although below the pycnocline the CO2 supersaturation invariably exceeded 200% in both areas. The larger surface CO2 supersaturation and outgassing at 30°S were associated with stronger winds that promoted the upwelling of denser water (richer in CO2) as well as a higher air–sea CO2 transfer velocity. The consistent decrease in intensity of the southerly winds (as derived from NSCAT scatterometer data) from 30–31°S to 23–24°S suggests a corresponding decline in the intensity of the CO2 outgassing due to upwelling. Additionally, we suggest here that the intensity of the local upwelling forcing (i.e. alongshore–equatorward winds) plays a role in determining the water mass composition and phytoplankton biomass of the coastal waters. Thus, while deep upwelling of salty and cold water resulted in high fCO2 (up to 1000 μatm) and very low phytoplankton biomass (chlorophyll a concentration lower than 0.5 mg m−3), the shallow upwelling of less salty (e.g. salinity <34.5) and less CO2-supersaturated water resulted in a higher phytoplankton biomass, which further reduced surface water fCO2 by photosynthesis.  相似文献   

20.
A comparison of monthly wind stress derived from winds of NCEP/NCAR (National Centers for Environmental Prediction/National Center for Atmospheric Research) reanalysis and UWM/COADS (The University of Wisconsin-Milwaukee/Comprehensive Ocean-Atmosphere Data Set) dataset (1950–1993), and of NCEP/NCAR reanalysis and satellite-based QuikSCAT dataset (2000–2006), is made over the South Atlantic (10°N–40°S). On a mean seasonal scale, the comparison shows that these three wind stress datasets have qualitatively similar patterns. Quantitatively, in general, from about the equator to 20°S in the mid-Atlantic the wind stress values are stronger in NCEP/NCAR data than those in UWM/COADS data. On the other hand, in the Intertropical Convergence Zone (ITCZ) area the wind stress values in NCEP/NCAR data are slightly weaker than those in UWM/COADS data. In the South Atlantic, between 20° S–40°S, the QuikSCAT dataset presents complex circulation structures which are not present in NCEP/NCAR and UWM/COADS data. The wind stress is used in a numerical ocean model to simulate ocean currents, which are compared to a drifting-buoy observed climatology. The modeled South Equatorial Current agrees better with observations between March–May and June–August. Between December–February, the South Equatorial Current from UWM/COADS and QuikSCAT experiments is stronger and more developed than that from NCEP/NCAR experiment. The Brazil Current, in turn, is better represented in the QuikSCAT experiment. Comparison of the annual migration of ITCZ at 20° and 30°W in UWM/COADS and NCEP/NCAR data sources show that the southernmost position of ITCZ at 30°W in February, March and April coincides with the rainy season in NE Brazil, while the northernmost position of ITCZ at 20°W in August coincides with the maximum rainfall of Northwest Africa.  相似文献   

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