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1.
Lead isotope analyses were carried out on fragments of White Slip II ware, a Late Bronze Age Cypriote pottery ware, and on raw materials possibly used for their production. Sherds originate from three Late Bronze Age sites (Hala Sultan Tekke and Sanidha in Cyprus and Minet el-Beida in Syria) and clays come from the surroundings of Sanidha, a production site for White Slip ware. X-ray fluorescence (XRF) and a Principal Component Analysis (PCA) are combined with Pb isotope analyses to further investigate the effectiveness of the latter method within a multiproxy approach for pottery provenance study. The pottery sherds from the three sites are compared between themselves and with potential raw material. Additional X-ray diffraction (XRD) and analyses using a scanning electron microscope (SEM) equipped with an energy dispersive X-ray detection (EDX) facility were performed on selected sherds and clays. This work confirms that the clay source used for pottery production in Sanidha derives from local weathered gabbro. It also shows that different origins can be proposed for White Slip II ware sherds from Hala Sultan Tekke and Minet el-Beida and that clays were prepared prior to White Slip II ware production. It finally confirms the effectiveness of Pb isotopes in tracing pottery provenance not only by comparing sherd assemblages but also by comparing sherds to potential raw materials.  相似文献   

2.
Normally, the use of clays as reference materials in chemical provenance studies of ancient ceramics is complicated due to the original clay paste processing. The primary mixing and/or refining of raw materials during pottery production makes a straightforward comparison of archaeological ceramics with extant geological materials difficult if not impossible in many cases. However, in the case of Pliocene clays from Aegina (Greece), which were examined chemically and mineralogically and compared with Bronze Age pottery produced on the island, a successful exception can be presented. The chemical composition of a large group of Aeginetan pottery resembles the chemical composition of clays from a deposit in close vicinity to the main Bronze Age settlement of the island. Clays from specific outcrops exhibit considerable chemical and mineralogical homogeneity, and the suitability of those clays for pottery production apparently made substantial clay paste processing unnecessary. © 2004 Wiley Periodicals, Inc.  相似文献   

3.
The mineralogy and bulk chemical compositions of 15 Kintampo (Late Stone Age) potsherds from the Birimi site on the Gambaga Escarpment and eight samples of local sediment were determined with the intent of characterizing these wares and identifying the material used in their manufacture. Sediment from clay pits still used by potters north of the escarpment contains iron‐rich laterite clasts (100 × XFeOt = 100 × FeOt/[FeOt + Al2O3 + SiO2] ≥10). Sedimentary clasts in stream sediments are relatively siliceous and iron‐poor (100 × XFeOt < 10). Bulk geochemical data together with the compositions of lithic clasts (laterite, siltstone/sandstone) link the pottery to sediment sources, including escarpment sediments not presently used by Ghanaian potters. Fresh granite clasts found in some of the sherds were not found in the analyzed sediment samples, although some of their distinctive mineralogical constituents (e.g., variably barian alkali feldspar) are present. The analytical data suggest that pots found at Birimi were made locally by mixing escarpment sediment with clay and stream sediment brought in from below the escarpment. This contrasts with present‐day practice, whereby the pots themselves are imported. The place where Birimi pottery was made and the outcrop source of aluminous sediment (mudstone with an “escarpment” trace element signature) used in these wares, however, remain unidentified. © 2013 Wiley Periodicals, Inc.  相似文献   

4.
In an effort to further characterize the Middle and Late Helladic pottery industry on Aegina, we have analyzed amphibole in 23 sherds imported to the coastal settlement of Asine. The sherds derive from vessels of different classes and shapes and range in age from MH I‐II to LH IIIB‐IIIC Early. All sherds come from vessels that carry manufacturing marks, and their amphiboles have compositions that are incompatible with those of Methana, Poros, and Melos. Twenty of the sherds have amphiboles that are identical in composition and overlap a narrow range of amphibole compositions found in specific lava flows on the northern portion of Aegina. Given that the dacites across Aegina contain amphiboles with a wide range in compositions, we suggest that the narrow range of amphibole compositions in the sherds indicates that they were derived from either a specific clay source on the island, located in a stream system southeast of the prehistoric settlement at Kolonna, or that the potters used a specific temper source along the same stream system. Multiple clay or temper sources would have produced sherds with a broader range of amphibole compositions reflecting the diversity of amphibole compositions found on Aegina. One sherd has amphibole compositions indicative of an additional Aeginetan component that is not found in the other sherds. Two sherds have amphiboles with compositions that do not match any known reference amphiboles for Aegina, Methana, Poros, or Melos. These may have been derived from still unsampled dacites on Aegina or have been manufactured from materials located outside the Saronic Gulf. © 2004 Wiley Periodicals, Inc.  相似文献   

5.
Leptiminus, a Roman port city on the west coast of Tunisia, North Africa, exported olive oil and a garum fish paste to Rome. Excavations have uncovered many facilities including kilns and a potter's workshop, indicating an extensive ceramic industry. The vessels, manufactured at Leptiminus, included African red‐slip fineware, coarseware, and amphorae. A petrographic study of pottery sherds showed them to contain very similar temper, rounded aeolian sand grains and limestone, but varying in proportions to produce different textures. An investigation of the source of raw materials for the pottery found three distinct types of clay within a 50 km radius of Leptiminus: grey Miocene, brown Pliocene, and green Late Pliocene clay. Statistical analysis of trace element compositions, using induced neutron activation, of clays and sherds showed that the Pliocene brown clay was used to create all types of pottery. The specific clay horizon, used in Roman times, has apparently been removed by quarrying. However, a lateral continuation of this bed was found 7 m beneath the Leptiminus site 290. © 2002 Wiley Periodicals, Inc.  相似文献   

6.
7.
New data on the geology and tectonics of the main structural elements of the East Transbaikalian segment of the Central Asian Foldbelt are discussed. Correlation charts of the main stratified and igneous complexes are compiled. The rocks of the Baikal-Patom and Baikal-Muya belts, as well as the Barguzin-Vitim Superterrane, are characterized by new Nd isotopic data, which have allowed us to establish the sources of these rocks, to separate isotopic provinces, and to distinguish two stages of crust-forming processes: the Early Baikalian (1.0–0.8 Ga) and the Late Baikalian (0.70–0.62 Ga). The Early Baikalian crust was formed in relatively narrow and spatially isolated troughs of the Baikal-Muya Belt and probably in the Amalat Terrane, whereas the Late Baikalian continental crust was formed and reworked in the Karalon-Mamakan, Yana, and Katera-Uakit zones of the Baikal-Muya Belt. The Baikal-Patom Belt and most of the Anamakit-Muya Zone in the Baikal-Muya Belt are characterized by remobilization of the Early Precambrian continental crust and by a subordinate role of Late Riphean juvenile sources. Reworking of the mixed Late Riphean and Early Precambrian crustal sources is typical of the Barguzin-Vitim Superterrane. The origination and evolution of the continental crust in the studied region are considered in light of new data; alternative versions of paleogedynamic reconstructions are discussed.  相似文献   

8.
The Haji‐Abad ophiolite in SW Iran (Outer Zagros Ophiolite Belt) is a remnant of the Late Cretaceous supra‐subduction zone ophiolites along the Bitlis–Zagros suture zone of southern Tethys. These ophiolites are coeval in age with the Late Cretaceous peri‐Arabian ophiolite belt including the Troodos (Cyprus), Kizildag (Turkey), Baer‐Bassit (Syria) and Semail (Oman) in the eastern Mediterranean region, as well as other Late Cretaceous Zagros ophiolites. Mantle tectonites constitute the main lithology of the Haji‐Abad ophiolite and are mostly lherzolites, depleted harzburgite with widespread residual and foliated/discordant dunite lenses. Podiform chromitites are common and are typically enveloped by thin dunitic haloes. Harzburgitic spinels are geochemically characterized by low and/or high Cr number, showing tendency to plot both in depleted abyssal and fore‐arc peridotites fields. Lherzolites are less refractory with slightly higher bulk REE contents and characterized by 7–12% partial melting of a spinel lherzolitic source whereas depleted harzburgites have very low abundances of REE and represented by more than 17% partial melting. The Haji‐Abad ophiolite crustal sequences are characterized by ultramafic cumulates and volcanic rocks. The volcanic rocks comprise pillow lavas and massive lava flows with basaltic to more‐evolved dacitic composition. The geochemistry and petrology of the Haji‐Abad volcanic rocks show a magmatic progression from early‐erupted E‐MORB‐type pillow lavas to late‐stages boninitic lavas. The E‐MORB‐type lavas have LREE‐enriched patterns without (or with slight) depletion in Nb–Ta. Boninitic lavas are highly depleted in bulk REEs and are represented by strong LREE‐depleted patterns and Nb–Ta negative anomalies. Tonalitic and plagiogranitic intrusions of small size, with calc‐alkaline signature, are common in the ophiolite complex. The Late Cretaceous Tethyan ophiolites like those at the Troodos, eastern Mediterranean, Oman and Zagros show similar ages and geochemical signatures, suggesting widespread supra‐subduction zone magmatism in all Neotethyan ophiolites during the Late Cretaceous. The geochemical patterns of the Haji‐Abad ophiolites as well as those of other Late Cretaceous Tethyan ophiolites, reflect a fore‐arc tectonic setting for the generation of the magmatic rocks in the southern branch of Neotethys during the Late Cretaceous. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

9.
In Okinawa, locally produced pottery dates back to the Initial Jomon period (˜6500 14C yr B.P.). Later in time, especially during the Early Yayoi‐Heian period (˜300 B.C.–A.D. 300), ceramic assemblages appear to contain mainland (Japan) Yayoi pottery. A greater number of these sherds present in Okinawa over time coincide with an increasing amount of interaction with mainland Japan, as evidenced by other exchange items. In this preliminary study, the authors analyzed sherds from several Early Yayoi‐Heian period deposits from sites in Okinawa using thin‐section petrography and laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS). The objective was to examine the applicability of these techniques for Okinawan ceramic provenance studies, assess intra‐ and intersite variation in mineralogical and chemical composition, and determine whether some sites exhibited a higher frequency of pottery from one locale versus another that might suggest the importation of pottery from mainland Japan. Results are equivocal, suggesting that the region's geological complexity may inhibit successful provenance study of ceramics using these and possibly other compositional techniques. © 2006 Wiley Periodicals, Inc.  相似文献   

10.
Artifacts made from volcanic glass have been found in archaeological contexts dating from the Late Palaeolithic (ca. 20,000 yr B.P.) through to the end of the Bronze Age (ca. 2700 yr B.P.) in the southern Primorye region of Far East Russia. A geoarchaeological survey of volcanic glass outcrops assessed the various potential sources to determine their potential for sustained exploitation. A characterization study of source samples and artifacts from 27 spatially and temporally dispersed sites using a combination of PIXE‐PIGME and relative density identified which sources had actually been exploited and a technological analysis of the assemblages described patterns of use. The combination of these three approaches shows the impact of a relatively stable geological environment on patterns of procurement and exchange. © 2008 Wiley Periodicals, Inc.  相似文献   

11.
This paper reports 48 feldspar lead isotope analyses from 27 granitic intrusions,which formed from the Late Proterozic to Mesozoic within the Eastern Qinling oregenic belt. Itis found that the granitic rocks of South Qinling are characterized by a strong block-effect anddepletion in U-Pb and Th-Pb, showing that these rocks came from the same lead isotopetectono-geochemical province, while those of North Qinling are characterized by higher U-Pband Th-Pb for Late Proterozoic to Early Paleozoic ones and lower U-Pb and Th-Pb forLate-Palaeozoic and younger ones in their feldspar lead isotopic composition. In the NorthQinling block, lead isotopic signatures reflect that the source of granitic magma had changedsince the Late Palaeozoic. Comparison of feldspar lead isotopic composition between SouthQinling and North Qinling shows that there is marked difference in lead isotopic compositionfor pre-Palaeozoic granitoids, indicating that the South Qinling and the North Qinling blocksbelong to different tectonic units, but the similarities in lead isotopic composition are quiteclear, which indicates that the South Qinling block had been welded with the North Qinlingblock and that the magma sources of both blocks were identical. The analysis provides directevidence for underplating of the continental crust of South Qinling beneath the North Qinlingblock in the continent-continent interaction stage of the Eastern Qinling oregenic belt.  相似文献   

12.
The arable soils from two multiperiod settlements were analyzed to identify changes in agricultural methods over time. The settlement middens were also analyzed to determine whether potential fertilizers were discarded unused. Results suggest that in the Neolithic period (˜4000–2000 B.C. in the UK) the arable soils at Tofts Ness, Orkney, and Old Scatness, Shetland, were created by flattening and cultivating the settlements' midden heaps in situ. The arable area at Tofts Ness was expanded in the Bronze Age (˜2000–700 B.C. in the UK), and the new land was improved by the addition of ash, nightsoil, and domestic waste. Cultivation continued briefly after the fields were buried in windblown sand in the Late Bronze Age or Early Iron Age, but by the Early Iron Age cultivation ceased and organic‐rich material was allowed to accumulate within the settlement. By contrast, at Old Scatness, arable production was increased in the Iron Age (˜700 B.C.–A.D. 550 in Scotland) by the intensive use of animal manures. The results indicate that during the lifespan of the two settlements the arable soils were fertilized to increase production, which was intensified over time. © 2006 Wiley Periodicals, Inc.  相似文献   

13.
The use of lead, some of which is characterized by a highly radiogenic signature, sharply distinguishes Bronze Age China from the rest of Eurasia. Scholars have long hypothesized that silver can offer an independent proxy to characterize lead minerals. The summary of silver distribution associated with Shang and Western Zhou bronzes in this paper reveals an important difference between the south (Sanxingdui, Hanzhong, Jinsha, Panlongcheng, Xin’gan) and the Central Plains. Correlating silver with lead content as well as with the isotopic signature indicates that south China and the Central Plains had different lead sources during the late Shang period, and also that the highly radiogenic and common lead used at Anyang come from geochemical environments which cannot be distinguished by the level of silver.  相似文献   

14.
Uranium–lead age patterns of detrital zircons in Otago Schist meta-sandstones from eastern Otago, including areas of orogenic gold mineralisation, are mostly consistent with a Rakaia Terrane (Torlesse Composite Terrane) accretionary wedge protolith. Southwest of the Hyde-Macraes and Rise & Shine shear zones the depositional age is regarded as Middle–Late Triassic. At the south and west margins, there are two areas in the Late Triassic Waipapa Terrane protolith. Northeast of the Hyde-Macraes Shear Zone, the schist protolith has Middle to Late Triassic and middle to late Permian depositional ages of Rakaia Terrane affinity. At the northeastern margin of the Hyde-Macraes Shear Zone, there is a narrow strip with a mid-Carboniferous protolith, which may be a counterpart of the Carboniferous accretionary wedge in the New England Orogen, eastern Australia. Ordovician–Silurian zircons are a minor but distinctive feature in many of the protolith age patterns and form significant age components at hard-rock gold locations. These constrain the provenance of Rakaia Terrane protolith sediments to Late Triassic time and within the Permian–Triassic magmatic arcs at the northeastern Australian continental margin and partly within the Ordovician–Silurian granitoids of the Charters Towers Province hinterland and environs. The latter have extensive gold mineralisation and thus upon exhumation might be the origin of Otago gold.  相似文献   

15.
The alluvial deposits near Gibala-Tell Tweini provide a unique record of environmental history and food availability estimates covering the Late Bronze Age and the Early Iron Age. The refined pollen-derived climatic proxy suggests that drier climatic conditions occurred in the Mediterranean belt of Syria from the late 13th/early 12th centuries BC to the 9th century BC. This period corresponds with the time frame of the Late Bronze Age collapse and the subsequent Dark Age. The abrupt climate change at the end of the Late Bronze Age caused region-wide crop failures, leading towards socio-economic crises and unsustainability, forcing regional habitat-tracking. Archaeological data show that the first conflagration of Gibala occurred simultaneously with the destruction of the capital city Ugarit currently dated between 1194 and 1175 BC. Gibala redeveloped shortly after this destruction, with large-scale urbanization visible in two main architectural phases during the Early Iron Age I. The later Iron Age I city was destroyed during a second conflagration, which is radiocarbon-dated at circa 2950 cal yr BP. The data from Gibala-Tell Tweini provide evidence in support of the drought hypothesis as a triggering factor behind the Late Bronze Age collapse in the Eastern Mediterranean.  相似文献   

16.
《Quaternary Science Reviews》2007,26(11-12):1476-1498
Palynological and sedimentological studies were performed at two Holocene profiles in erosion gullies (Ze’elim and Ein Feshkha) which dissect the retreating western shore of the Dead Sea. The aim of the project was to analyse possible links between climate, lithology, and vegetation development. The section in Ze’elim shows both lacustrine and fluvial sediments, whereas sedimentation at Ein Feshkha is predominantly lacustrine. The Ze’elim profile, previously used for paleo-lake reconstruction provides an opportunity to compare climate triggered lake levels as paleo-hydrological indicators and vegetation history by use of palynology. The vegetation development in Ze’elim and Ein Feshkha is influenced by both climate and human impact. The pollen record of Ze’elim begins in the Pottery Neolithic, the section of Ein Feshkha in the Late Bronze Age, both records end in the Middle Ages. The Ze’elim section is characterized by sedimentary hiati between the beginning of the Chalcolithic Period until the Middle Bronze Age and within the Late Bronze Age. Settlement periods during the Middle Bronze Age, Iron Age and Hellenistic–Roman–Byzantine Period are indicated by high values of anthropogenic indicators and/or Mediterranean trees. Collapses of agriculture, which can be related to climate effects, are evident during the Late Bronze Age, during the Iron Age and at the end of the Byzantine Period when the lake level curve indicates arid conditions. A comparison of the two pollen records, from different environments, illustrates a more prominent influence of Mediterranean vegetation and cultivated plants in the pollen diagram of Ein Feshkha. The southern Dead Sea region (at the desert fringe) is more vulnerable to regional climate change.  相似文献   

17.
The Akamas ophiolite is shown to be a distal, off-axis extension of the main outcrop of Cretaceous ophiolite in the Troodos complex of Cyprus. Mantle-sequence harzburgites of both ophiolites share similarly oriented mantle-flow fabrics and the same Tertiary magnetizations acquired during exhumation. However, compared with the Troodos mantle sequence rocks, the Akamas ferromagnetic mineralogy is more oxidized and remanences with lower blocking temperatures were acquired chemically. Paleopoles calculated from published vectors and our own new data define an apparent polar wander path (APWP) for the Troodos microplate. The APWP shows that between 88 and 50 Ma the Troodos microplate was equatorial and the vertical axis for its 60° anticlockwise rotation was located within the microplate. Subsequently, the microplate drifted northward to 34°N with minor anticlockwise rotation at a reduced rate. That requires microplate-rotation about a vertical axis located to the west of Cyprus in the last 50 Ma. The allochthonous Triassic Mamonia terrane docked with the Cretaceous Troodos terrane in SW Cyprus. Within it, disrupted tectonized ophiolite has been regarded as part of a Triassic ocean floor or as sheared fragments of Cretaceous Troodos ophiolite, incorporated into the Mamonia terrane when it docked with the Troodos terrane. Whatever their provenance, their paleomagnetic signals postdate their penetrative deformation and metamorphism and their paleopoles may still be used to track their post-strain motion. Our calculations of paleopoles from published vectors for the Mamonia terrane smear along an extension of the APWP for the Troodos microplate that is, moreover, concentric with the Troodos microplate. This suggests that the paleopole dispersion of the Triassic Mamonia rocks and their post-magnetization disruption occurred during their accretion onto the anticlockwise-spinning Troodos microplate.  相似文献   

18.
Recent transportation infrastructure works in Naples, Italy, provided important discoveries related to the production of pottery in the Hellenistic workshop area of Piazza Nicola Amore. A minero‐petrographic investigation was conducted on 35 samples belonging to the widespread Campana A ware and production indicators (clayey raw materials, unfired Graeco‐Italic amphorae, kiln wastes, workshop tools). Additional analysis was conducted on black‐glaze and common ware samples for comparison. The analyses reveal compositional and technological homogeneity of Campana A ware. Samples are characterized by low CaO content with evidence of both volcanic and sedimentary components, suggesting that different clay sources were properly mixed to prepare a standard recipe. Production indicators, black‐glaze and common wares, have a composition well consistent with the calcareous clays from the island of Ischia. Leucite‐ and garnet‐bearing temper from the Somma Volcano were used for the preparation of coarse‐grained pastes, unfired Graeco‐Italic amphorae, and clayey raw materials, thus suggesting that they represented the clay sources for amphorae production. Our results reveal new technological and socioeconomic aspects of Hellenistic pottery production in the Bay of Naples, in particular for the Campana A ware, now representing a new reference group: Neapolis.  相似文献   

19.
Continuous high-resolution sedimentary record of heavy metals (chromium (Cr), copper (Cu), lead (Pb), zinc (Zn), manganese (Mn), and mercury (Hg)), from lakes Lucerne and Meidsee (Switzerland), provides pollutant deposition history from two contrasting Alpine environments over the last millennia. The distribution of conservative elements (thorium (Th), scandium (Sc) and titanium (Ti)) shows that in absence of human disturbances, the trace element input is primarily controlled by weathering processes (i.e., runoff and erosion). Nonetheless, the enrichment factor (EF) of Pb and Hg (that are measured by independent methods), and the Pb isotopic composition of sediments from the remote lake Meidsee (which are proportionally more enriched in anthropogenic heavy metals), likely detect early mining activities during the Bronze Age. Meanwhile, the deposition of trace elements remains close to the range of natural variations until the strong impact of Roman activities on atmospheric metal emissions. Both sites display simultaneous increases in anthropogenic trace metal deposition during the Greek and Roman Empires (ca 300 BC to AD 400), the Late Middle Ages (ca AD 1400), and the Early Modern Europe (after ca AD 1600). However, the greatest increases in anthropogenic metal pollution are evidenced after the industrial revolution of ca AD 1850, at low and high altitudes. During the twentieth century, industrial releases multiplied by ca 10 times heavy metal fluxes to hydrological systems located on both sides of the Alps. During the last decades, the recent growing contribution of low radiogenic Pb further highlights the contribution of industrial sources with respect to wood and coal burning emissions.  相似文献   

20.
We performed petrophysical analyses on 34 clayey samples of different geological origin within the Campania region of Italy in order to determine possible sources of raw materials used to produce ancient pottery. Possible raw material sources can be grouped into high‐CaO clays (HCC) and low‐CaO clays (LCC). HCC are mainly represented by more recent (Miocene‐Pleistocene) basinal sediments whereas LCC tend to be associated with basinal, alluvial, and pyroclastic deposits. A chemical comparison between clayey raw materials, modern ceramic replicas, and Campanian archaeological ceramics of several typologies (common ware, cooking ware, fine tableware, amphorae, and bricks) from 8th century B.C. to the Middle Ages (a total of 350 ceramic samples) indicates that HCC were extensively used for common wares and that these were either mixed with temper or levigated. In contrast, most of the LCC were used for the production of cookware. We also analyzed the technological potential of the sampled raw materials, taking into consideration their actual and possible uses. We observed that most HCC deposits were well suited for tableware and amphorae, whereas LCC were better for cookware and some fine tableware.  相似文献   

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