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韧性剪切过程中金沉淀富集的新机制 总被引：16，自引：3，他引：13
一般认为,金的沉淀是因为成矿热液在宏观上已达到金络合物失稳、分解的条件。笔者认为金在黄铁矿、毒砂等硫化物矿物中富集的原因,是这些矿物生长时造成了在其生长面附近的微区内会出现Ｅｈ值及（或）Ｓ＾２－、［ＡｓＳ］＾３－等浓度的局部降低,以致引起了金络合物在此微区内的失稳、分解,分解出来的金将就近附着在矿物的生长面上及随后被包围。成矿热液此时在宏观上不一定已达到金络合物的分解条件。韧性剪切过程中石英普遍会 相似文献
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化学蒸气发生-无色散原子荧光光谱法测定地质样品中微量和痕量金 总被引：1，自引：1，他引：0
试样用王水分解,采用特定的金化学发生增敏试剂使金在硼氢化物-酸体系中产生挥发物质,将其导入原子荧光光谱检测系统,检测金的原子荧光信号。通过对仪器工作参数和化学蒸气发生参数的优化,使金的可检测信号同比提高20倍以上,同时降低共存离子对金的化学蒸气发生的干扰。对微量和痕量金的测定方法具有灵敏度高、检出限低、基体干扰少等优点。方法检出限为0.23 ng/g,准确度(ΔlgC,n=12)为-0.004~0.02,精密度(RSD,n=12)为2.62%~8.79%。经国家一级标准物质分析验证,测定值与标准值相符。 相似文献
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通过试样分解方法,还原剂种类和用量及介质酸度和温度的研究,确定了天马山金矿中砷的分析方法。与经典卑磷酸盐容量法相比,降低了分析试剂成本的50％,缩短了分析流程时间近1／2。方法简单,快速、精密、准确。 相似文献
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本文介绍了用于野外分析金的氰化物分解阳极溶出伏安法。该法操作简单，节省时间，现场就可直接得到分析结果。 相似文献
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含金地质样品的分解和痕量金的提取 总被引：4，自引：1，他引：4
本文收集了60篇文献资料,系统综述了含金地质样品的预处理,各种分解方法以及痕量金的提取富集手段,特别是对与原子发射光谱和原子吸收光谱测定方法有关的进展情况作了简要评述。 相似文献
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锍镍试金富集-等离子体质谱法测定煌斑岩中铂族元素 总被引：8，自引：4，他引：4
试金配料中适量加入铁粉,控制硫化铁在锍扣中的含量在20%~40%,获得的锍扣直接用水浸泡粉化后加盐酸分解,分解结束后趁热过滤,沉淀用1mL王水溶解,定容后上机测定,Cs作内标。改进后的方法空白水平进一步降低,检出限得到显著改善,分析流程简化。采用改进后的锍镍试金富集-等离子体质谱法测定了云南哀牢山金矿带煌斑岩和国家一级标准物质GBW 07288(GPt-1)、GBW 07290(GPt-3)中的铂族元素(PGEs)含量,方法检出限为0.001~0.01ng/g,精密度(RSD,n=5)为7.49%~16.6%。 相似文献
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“四深”微生物是指深海、深地、深空和深时环境的微生物,特别是细菌、古菌、真菌、病毒等。人们对“四深”微生物的了解非常有限,是亟待突破的地球生物学前沿领域。“四深”微生物的研究对理解地球生命起源、界定生物圈的边界条件、促进地球科学与生命科学以及行星科学之间的交叉融合具有不可替代性的贡献。随着我国深海、深空、深地等重大工程计划的推进,一系列与“四深”微生物有关的前沿科学问题不断提出,包括地质微生物与气候环境的相互作用、地质微生物的生物安全与生态安全、地质微生物参与的隐匿地质过程等。特别是,“四深”环境活性氧自由基对微生物的影响、地质病毒对生物演化和地质过程的影响等前沿领域都亟待突破。活性氧自由基能对生物分子、细胞、组织和器官,乃至整个生物圈的演化以及微生物地质作用都产生重要影响。病毒引发了现代和近代诸多全球性疫情爆发,地质病毒则可能对生物的背景灭绝和大灭绝以及一些地质过程产生影响。 相似文献
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我国过去50a来降水变化趋势及其对水资源的影响(Ⅱ):月系列 总被引：13，自引：5，他引：8
应用全国范围内的678个气象站1951-1998年长系列逐月降水资料, 用线性回归方法研究降水量的变化趋势, 同时结合长江、黄河和松花江主要控制水文站同期的径流资料, 研究径流对气候变化的响应. 结果表明: 降水的年内变化表现出较大的区域特性, 最显著的变化特点是秋冬季 (8～12月) 东部地区降水量普遍减少, 1～3月江南地区降水有增加趋势. 气候的上述变化趋势对我国干旱的西北地区有利, 该区河流径流量有明显增加; 另一方面, 夏季降水的增加可能会导致洪水事件的濒发, 与此同时, 降水量的年内不均匀变化, 特别是在 8～12月长时间的降水减少趋势, 导致枯水期径流的减少, 从而加剧秋冬季水资源的供需矛盾. 长江、黄河和松花江主要控制水文站6个站1～4月径流基本上表现为增加趋势, 而6～12月大多表现为减少趋势, 只有黄河上游唐乃亥站6月, 长江下游大通站7月和松花江哈尔滨站8月径流为增加; 另外, 气候变暖使发源于青藏高原的长江(宜昌站3、 4月)和黄河上游(唐乃亥站4～6月)的春季的融雪过程提前, 融雪期径流增加. 相似文献
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关于沉积学发展的思考 总被引：13，自引：0，他引：13
笔者对地质学领域中一些学科近10多年以来的突破性进展做了扼要的评述,以及对沉积学发展中一些重要事件做了简短的回顾之后,提出了在当前高新科技时代有关研究工作的一些看法。认为在沉积学的研究中,必须采用高新技术,与其它学科同步进入高科技时代;要更新传统的观念;研究中注意学科渗透交叉,发展新的学科分支;注意全球变化的研究;研究工作要更加密切结合经济发展的需要。 相似文献
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《Sedimentary Geology》2006,183(3-4):269-295
The Peñas Rubias Syncline (southwestern Spain) exposes a well-preserved shallow-water platform succession containing a spectrum of facies corresponding to inner platform intertidal to supratidal environments, across to deeper-water middle to outer platform environments. Nineteen microfacies are recognized, which are grouped into seven facies association corresponding to: siliciclastic deltaic bars, mixed carbonate/siliciclastic shoals, carbonate mud mound boundstones, background platform carbonates, background platform siliciclastics, mixed tempestites and deep-water siliciclastic shales and sandstones. The age of the succession was determined mainly by foraminiferans and calcareous algae, which permit the succession to be assigned to the late Brigantian (latest Viséan). This upper Brigantian platform is the only record of sedimentation of this age in the region, and thus is key for interpreting the sedimentary and tectonic evolution of the Carboniferous rocks in Sierra Morena. Biotic and sedimentological features were analyzed in order to assess the controls on the sedimentation. Several factors have influenced sedimentological changes: turbidity, subsidence, siliciclastic discharges, storms and bioturbation. The siliciclastic discharges exerted a considerable control on the basal deposits, mostly in their percentage of quartz sand grains and as microconglomerates. However, they did not develop as large deltaic deposits, and their influence can be considered as virtually negligible in regards to the remaining part of the succession. Turbidity, as a result of higher percentage of silt and mud in suspension, seems to be the main factor controlling the change between the older intertidal deposits in the inner platform to the younger subtidal deposits of the middle and outer platform. As a result of the increase of the mud and silt in suspension, facies changed first to marlstones and nodular argillaceous limestones, and second, to predominantly calcimicrobial boundstones and shales in the uppermost part of the carbonate succession, as well as showing a marked change from photic-controlled benthic faunal and microfloral assemblages to assemblages more tolerant or better adapted to muddier dysphotic substrates. Bioturbation is also interpreted as one of the main controls influencing the different type of boundstones in the middle platform, permitting the vertical growth of dome-shaped mud-mounds or as sheet-like deposits. Storm influences seem to have exerted some control on the positive relief of the dome-shaped boundstones, which are usually capped by tempestites. The differential subsidence observed in the northwestern sector of the platform allowed the accumulation of many stacked dome-shaped mounds, a feature not recognized in southeastern parts. The general stratigraphical sequence seems to be controlled by eustasy and synsedimentary tectonics. The overall succession exhibits a pronounced deepening-upwards transgressive sequence from siliciclastic delta bars, mixed shoals, carbonates and shales of the middle platform with the growth of calcimicrobial boundstones and dark green shales, passing up into black shales at the top of the sequence, in the outer platform and, possibly, submarine slope settings. Although this transgressive sequence is in harmony with the 3rd-order glacioeustatic cycle defined for the late Brigantian in the western Palaeotethys, all these Brigantian rocks accumulated in a synsedimentary extensional regime, which is related to the initiation of a sinistral strike–slip regime, previously recognized as affecting only Serpukhovian and younger rocks in Sierra Morena. These synsedimentary faults allow us to recognize significant lateral variations in thickness over short distances. 相似文献
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农田土壤盐碱化是农业可持续发展的主要威胁之一,为创建适应现代生态农业发展的农田水盐调控方法,在总结农田盐分来源及其累积动力特征的基础上,从土壤盐分影响土壤供养能力和作物生产能力两大方面,分析土壤盐分对土壤-作物系统功能的影响途径,明确农田水盐高效调控方向。根据不同时代的治盐理念,将水盐调控发展历程分成4个阶段,以抑制盐碱胁迫对土壤和作物的危害为切入点,解析水利措施、化学措施、生物措施和农艺措施的作用特点和调控目标及适用范围。根据现代农业绿色发展与提质增效需求,凝练盐碱胁迫农田控害增效水盐调控理念,提出水盐调控策略,即调控根际水盐传输动力特征,重构农田水盐分布空间格局,提升农业改土促生措施功效;指出农田控害增效水盐调控急需解决的关键技术,总结了创新水盐调控理论有待深入研究的基础科学问题,以期为盐碱胁迫农田绿色、高效和可持续利用提供指导。 相似文献
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Rice research for food security and sustainable agricultural development in Asia: Achievements and future challenges 总被引：1，自引：0，他引：1
Rice is the major staple food of Asia, and an important source of employment and income in rural areas, particularly in low-income countries. Research has contributed significantly in achieving food security by increasing the yield potential of rice in irrigated systems, reducing the crop maturity period and achieving yield stability by developing resistance against major insects and diseases in the modern high-yielding varieties. Poverty is, however, still extensive in fragile rainfed rice ecosystems where rice yield has remained low, as scientists have yet to develop high-yielding varieties resistant to abiotic stresses and problem soils. Rice production needs to be increased by another 70% over the next 30 years to meet growing food needs. This has to be achieved with less land, less water, and less labor to accommodate the demand for these inputs from the expanding nonagricultural sectors. The challenge to the rice research community is to make further shifts in yield potential of rice for the irrigated systems, to close the yield gaps in the rainfed systems through developing resistance of high yielding varieties to abiotic stresses, and greater understanding of the interactions between genotypes and environment, developing durable resistance against pests and diseases to reduce farmers' dependence on harmful agrochemicals, and to increase efficiency in the use of water, labor and fertilizers. As further intensification of rice cultivation is inevitable, scientists must understand the negative environmental side-effects of increasing rice productivity, to develop appropriate mitigation options. 相似文献
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The present study aims to evaluate a relationship between the mineralogy and structural analysis in the Halaban area and to document the tectonic evolution of Halaban and Al Amar faults. The collected samples were taken from deformed granitiods rocks (such as granite, gneisses and tonalite), metasedimentary, metavolcanic, metagabbro and carbonate rocks are trend to NE-SW with low dip angle in the Halaban area. These samples were 8 from granite, 14 metagabbro, 6 metavolcanics, 5 tonalite, 6 metasedimentary, 10 gneisses and 8 carbonate rocks. Our results are described for the different axial ratios of deformed rocks as the following: XZ sections range from 1.10 to 4.60 in the Fry method and range from 1.70 to 2.71 in the Rf/? method. YZ sections range from 1.10 to 3.34 in the Fry method and range from 1.62 to 2.63 in the Rf/Phi method. In addition, XY sections range from 1 to 3.51 in the Fry method and range from 1 to 1.27 in the Rf/? method for deformed granite rocks, metasedimentry rocks, and metagabbro. The stretch axes for measured samples in the X direction axes (SX) variety from 1.06 to 2.53 in the Fry method and vary from 1.20 to 1.45 in the Rf/? method. The values of the Y direction axes (SY) vary from 0.72 to 1.43 in the Fry method, which indicates contraction and extension in this direction and vary from 1.13 to 1.37 in the Rf/? method which indicates extension in this direction. Furthermore, the Z direction axes (SZ) varies from 0.09 to 0.89 in the Fry method and from 0.52 to 0.71 in the Rf/? method. The stretches axes in the Z direction (SZ) show a vertical shortening about 11% to 91% in the Fry method and show vertical shortening about 29% to 48% in the Rf/? method. The studied rock units are generally affected by brittle-ductile shear zones, which are sub-parallel to parallel NW or NNW trend. It assumed that different rock types of have similar deformation behavior. Based on these results, it is concluded that the finite strain is accumulated during the metamorphism after that was started the deformation by thrusting activity. The contacts between the different rock types were deformed during thrusting under semi-brittle to ductile deformation conditions by simple shear. A component of vertical shortening is also involved causing subhorizontal foliation in the Halaban area. 相似文献
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2013年青海北部春季旱涝急转的特征及其成因分析 总被引：2，自引：1，他引：1
利用1961-2013年3-5月的逐日降水、气温和高度环流场资料, 计算了月季降水、气温序列、气象干旱指数序列、高原地面加热场强度指数序列, 研究了春季旱涝急转的主要特征及其规律, 解释了2013年青海省春季降水前期偏少、后期偏多和旱涝急转的成因. 结果表明: 2013年3月1日-4月27日青海大部分地区降水偏少、气温偏高, 出现了大范围不同程度的气象干旱, 海北大部分地区出现50 a一遇的特大气象干旱, 西宁大部分地区出现25 a一遇的严重气象干旱; 4月28日-5月20日青海大部分地区降水偏多, 气温偏高幅度开始逐步减小, 前期的干旱得到缓解, 并出现了大范围不同程度的渍涝, 旱涝急转的台站达21个. 通过对比分析发现, 若极涡面积偏小、中亚和西亚低压槽维持时间长、冷空气主要在欧洲东部和亚洲西部地区堆积、进入中国的冷空气路径偏西、高原位势高度场偏低、东亚槽位置偏东、西太平洋副热带高压北界位置偏北时, 青海降水偏多, 容易出现渍涝. 在相反的环流形势下, 青海降水偏少, 容易发生干旱. 4月干旱和5月渍涝处在青海高原降水长期变化的大气候背景之下, 前期1-3月青藏高原地面加热场强度偏强、春夏季过渡时间提前也有助于青海5月异常降水的形成. 相似文献
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Abstract: The gold deposit at Ashanti occurs in the Proterozoic Birimian formation of Ghana. Two main ore types mined from the deposit are gold-bearing quartz veins, and gold-sulfide disseminations in metasediments and metavolcanics. The main sulfide minerals in the gold-sulfide disseminated ores are arsenopyrite, pyrite and pyrrhotite, and to a very minor extent, sphalerite and tetrahedrite. Carbonate alteration and sericitization are prominent in the metavolcanics and the metasediments, respectively. In the quartz veins, pyrite and arsenopyrite commonly occur in small amounts, but gold mostly occurs in contact with tetrahedrite, chalcopyrite, galena, aurostibite, and sphalerite. Pyrrhotite is absent in the quartz veins.
Microprobe studies indicate that As content of homogeneous arsenopyrite grains ranges from 27. 0 to 31. 7 atm%, and gives mineralization temperatures from 170 to 430°C, although mostly from 300 to 400°C. Chlorite geothermometry using temperature dependence of substitution of Al for Si in the tetrahedral site gives formation temeratures of 330 to 400°C, comparable to the arsenopyrite temperatures. Applying sphalerite–pyrite–pyrrhotite geobarometry to sphalerite with FeS contents from 13. 6 to 12. 5 mol%, the pressure was estimated to be in a range from 5. 9 to 7. 0 kb at the stage of elevated temperatures.
Mineralogical observations, especially absence of pyrrhotite in the quartz veins, together with microprobe data for gold and associated minerals suggest that the fluids having ascended through fissures in the Ashanti deposit were reduced by the reaction with carbonaceous materials in the metasediments during the declining stage of the regional metamorphism. 相似文献
Microprobe studies indicate that As content of homogeneous arsenopyrite grains ranges from 27. 0 to 31. 7 atm%, and gives mineralization temperatures from 170 to 430°C, although mostly from 300 to 400°C. Chlorite geothermometry using temperature dependence of substitution of Al for Si in the tetrahedral site gives formation temeratures of 330 to 400°C, comparable to the arsenopyrite temperatures. Applying sphalerite–pyrite–pyrrhotite geobarometry to sphalerite with FeS contents from 13. 6 to 12. 5 mol%, the pressure was estimated to be in a range from 5. 9 to 7. 0 kb at the stage of elevated temperatures.
Mineralogical observations, especially absence of pyrrhotite in the quartz veins, together with microprobe data for gold and associated minerals suggest that the fluids having ascended through fissures in the Ashanti deposit were reduced by the reaction with carbonaceous materials in the metasediments during the declining stage of the regional metamorphism. 相似文献