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1.
铜陵地区硫化物矿床成矿过程的热传导和物质输运动力学 总被引：7，自引：3，他引：7
根据热传导和热致流体流动以及化学物质输运动力学原理，模拟和分析了铜陵地区铜金硫化物矿床成矿过程的温度场和流体动场。根据矿区温度空间分布模式和流体流线的展布模式，可以预测矿床的溶解地段和成矿物质的堆积场所。研究表明：（1）能量流和物质流是热液成矿的关键因素，而岩浆侵位带进的热是驱动流体流动的原动力；（2）侵入体的产状、不同化学性质围岩的空间分布的组合方式、围岩的孔隙度和渗透率差异等因素共同限定了成矿物质的沉淀堆积场所；（3）矿区中铁和硫主要来自五通组高孔隙度的含黄铁矿砂岩。在砂岩和灰岩之间的白云岩层强烈碎裂形成有利的成矿空间，白云岩与砂岩之间的化学位差是构成成矿化学反应发生的动力。 相似文献
2.
构造成矿非线性动力学:1.递增应力流变学模型 总被引：1，自引：1，他引：1
本文提出了构造成矿作用动力学研究的递增应力流变学方法。利用该方法将构造变形、应力、流体流动、地球化学反应及成岩成矿作用等多过程耦合起来，可以从多种地质过程的耦合与反馈作用对构造成矿的动力学演化过程进行１～３维数值模拟。模拟的主要内容是在各种过程耦合作用下，以下描述构造成矿体系的主要变量的时空演化：（１）与成矿流体的形成和性质有关的变量，如地层中矿物（包括成矿物质）的溶解速率、流体中各组分的浓度与饱和度、流体温度、压力、离子强度等；（２）与构造变形和流体运移有关的各变量，如应力与变形速率、岩石孔隙度、构造（断裂）渗透率等；（３）与沉淀成矿有关的变量，如矿物（金瞩矿物和脉石矿物）的成核速率、各矿物的沉淀量等；（４）上述各有关变量间的时空耦合关系，如断裂渗透率时空演化与流体流动、汇聚和成矿的耦合关系等。 相似文献
3.
砂岩对热流体作用的响应及识别标记--以珠江口盆地西部为例 总被引：6，自引：1，他引：5
沉积盆地中流体的作用越来越受到人们的关注,在整个地球范围内研究流体与岩石、流体与流体的相互作用是地学界当前乃至今后重要的课题。砂岩因其发育孔隙为流体的流动和流体与岩石的相互作用提供了场所。地表以下较深处形成的热流体运移到较浅部时,与“冷”砂岩之间存在着温度、成分等多方面的差异,两者之间必然发生化学反应。通过研究砂岩的物质成分,砂岩的格架颗粒的蚀变现象,新生胶结物矿物的形成,储层砂岩孔隙度在垂向上的变化,碳酸盐矿物、石英次生加大边和石英裂隙中的包裹体温度以及镜质体反射率的变化情况追踪砂岩对热流体作用的响应标记,同时探讨了砂岩与热流体作用的机理,为进一步研究油气运移与砂岩储层的质量及储层预测有理论意义和实践意义。 相似文献
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Most Mississippi Valley Type (MVT) Pb–Zn deposits have a common host-rock lithofacies sequence known as the hydrothermal dolomite (HTD) facies; however, the spatial and temporal relationships between dolomitization and Pb–Zn mineralization remain unclear. In this paper, we report a detailed cathodoluminescence (CL) study on the HTD facies of the No. II orebody in the Maoping Pb–Zn deposit in northeastern Yunnan Province, southwestern China. The results indicate that the dolomite in the Carboniferous limestone is part of a spectrum of hydrothermal mineral deposits, and the diagenesis and mineralization processes, in which the acidity of fluids played an important role, can be divided into six steps. A dolomite prototype formed during the first and second steps. In the third step, acid fluids produced by sulfide precipitation interacted with the dolomite prototype, resulting in dissolution and alteration, thus forming cavities. The fluid that formed during the first three steps flowed along open tensional faults. Dolomitization in the first step covered most of the region of later mineralization and gradually extended toward the center of the orebody. In the fourth and fifth steps, vugs and fractures were the main pathways for fluids, with only a small volume of fluid in the fifth step. Dedolomitization occurred in the sixth step and vugs were filled mostly by calcite. However, the fact that voids are present in only a small number of vugs is indicative of fluid exhaustion. Dolomite with growth zoning is characteristic of precipitation by ore-forming fluids accompanied by pulsed filling. There is no significant correlation between vugs and the locus of mineralization. Rather, the vugs indicate that the ore-forming fluids had passed through them, and the locus of massive ore formation was the center of the migrating fluid body. The saddle dolomite was deposited during pauses in sulfide precipitation. Cathodoluminescent zonation of HTD can be used as an aid in understanding the ore-forming process and for mineral prospecting in the Maoping deposit and other MVT deposits. 相似文献
6.
We use a reactive diffusion model to investigate what happens to CO2 injected into a subsurface sandstone reservoir capped by a chlorite- and illite-containing shale seal. The calculations simulate reaction and transport of supercritical (SC) CO2 at 348.15 K and 30 MPa up to 20,000 a. Given the low shale porosity (5%), chemical reactions mostly occurred in the sandstone for the first 2000 a with some precipitation at the ss/sh interface. From 2000 to 4000 a, ankerite, dolomite and illite began replacing Mg–Fe chlorite at the sandstone/shale interface. Transformation of chlorite to ankerite is the dominant reaction occluding the shale porosity in most simulations: from 4000 to 7500 a, this carbonation seals the reservoir and terminates reaction. Overall, the carbonates (calcite, ankerite, dolomite), chlorite and goethite all remain close to local chemical equilibrium with brine. Quartz is almost inert from the point of its dissolution/precipitation. However, the rate of quartz reaction controls the long-term decline in aqueous silica activity and its evolution toward equilibrium. The reactions of feldspars and clays depend strongly on their reaction rate constants (microcline is closer to local equilibrium than albite). The timing of porosity occlusion mostly therefore depends on the kinetic constants of kaolinite and illite. For example, an increase in the kaolinite kinetic constant by 0.25 logarithmic units hastened porosity closure by 4300 a. The earliest simulated closure of porosity occurred at approximately 108 a for simulations designed as sensitivity tests for the rate constants.These simulations also emphasize that the rate of CO2 immobilization as aqueous bicarbonate (solubility trapping) or as carbonate minerals (mineral trapping) in sandstone reservoirs depends upon reaction kinetics – but the relative fraction of each trapped CO2 species only depends upon the initial chemical composition of the host sandstone. For example, at the point of porosity occlusion the fraction of bicarbonate remaining in solution depends upon the initial Na and K content in the host rock but the fraction of carbonate mineralization depends only on the Ca, Mg, Fe content. Since ankerite is the dominant mineral that occludes porosity, the dissolved concentration of ferrous iron is also an important parameter. Future efforts should focus on cross-comparisons and ground-truthing of simulations made for standard case studies as well as laboratory measurements of the reactivities of clay minerals. 相似文献
7.
PENG Bo LI Zongxing LI Guorong LIU Chenglin ZHU Shif ZHANG Wang ZUO Yinhui GUO Yingchun WEI Xiaojie 《《地质学报》英文版》2018,92(1):311-332
The Precambrian Dengying Formation is a set of large-scale, extensively dolomitized, carbonate reservoirs occurring within the Sichuan Basin. Petrographic and geochemical studies reveal dolomitization was a direct result of precipitation by chemically distinct fluids occurring at different times and at different intensities. Based on this evidence, dolomitization and multiple fluid flow events are analyzed, and three types of fluid evolution models are proposed. Results of analysis show that Precambrian Dengying Formation carbonates were deposited in a restricted peritidal environment(630–542 Ma). A high temperature and high Mg~(2+) concentration seawater was a direct result of dolomitization for the micrite matrix, and for fibrous aragonite in primary pores. Geochemical evidence shows low δ~(18)O values of micritic dolomite varying from-1.29‰ to-4.52‰ PDB, abundant light rare earth elements(REEs), and low dolomite order degrees. Microbes and meteoric water significantly altered dolomite original chemical signatures, resulting in algal micritic dolomite and the fine-grained, granular, dolosparite dolomite having very negative δ~(18)O values. Finely crystalline cement dolomite(536.3–280 Ma) and coarsely crystalline cement dolomite have a higher crystallization degree and higher order degree. The diagenetic sequence and fluid inclusion evidence imply a linear correlation between their burial depth and homogenization temperatures, which closely resemble the temperature of generated hydrocarbon. Compared with finely crystalline dolomite, precipitation of coarsely crystalline dolomite was more affected by restricted basinal fluids. In addition, there is a trend toward a more negative δ~(18)O value, higher salinity, higher Fe and Mn concentrations, REE-rich. Two periods of hydrothermal fluids are identified, as the exceptionally high temperatures as opposed to the temperatures of burial history, in addition to the presence of high salinity fluid inclusions. The early hydrothermal fluid flow event was characterized by hot magnesium-and silicon-rich fluids, as demonstrated by the recrystallized matrix dolomite that is intimately associated with flint, opal, and microcrystalline quartz in intergranular or intercrystalline pores. This event was likely the result of a seafloor hydrothermal chimney eruption during Episode I of the Tongwan Movement(536.3±5.5 Ma). In contrast, later hydrothermal fluids, which caused precipitation of saddle dolomite, were characterized by high salinity(15–16.05 wt% NaCl equivalent) and homogenization temperatures(250 to 265°C), δ~(18)O values that were more enriched, and REE signatures. Geochemical data and the paragenetic sequence indicate that this hydrothermal fluid was related to extensive Permian large igneous province activity(360–280 Ma). This study demonstrates the presence of complicated dolomitization processes occurring during various paleoclimates, tectonic cycles, and basinal fluids flow; results are a useful reference for these dolomitized Precambrian carbonates reservoirs. 相似文献
8.
碎屑岩储层成岩作用复杂而强烈,对储层物性有着重要影响。应用岩相学研究方法,在对鄂尔多斯盆地姬塬地区延长组长4+5低渗砂岩储层成岩作用及其对物性影响定量研究基础上,探讨了低渗储层成因机理。成岩作用和孔隙演化研究表明,压实作用虽然造成12%～20%的孔隙度损失,但是压实后剩余孔隙度仍高达15%～23%,早期胶结作用使孔隙度损失很小,压实作用和早期胶结作用并没有使储层致密,不影响油气渗流。溶蚀作用进一步改善了储层,晚成岩阶段A期-B期形成的钠长石、亮晶方解石、白云石、自生高龄石和铁绿泥石等大量胶结物的晚期胶结作用使储层孔隙度仅有4%～6%,储层因此而致密,由此影响油气渗流。晚期裂隙作用对储层孔隙度贡献为6%～8%,改善了储层物性而使其成为有效储层。盆地演化及与之对应的成岩事件研究认为,印支运动前,姬塬地区长4+5储层处于浅埋藏阶段,经历压实作用和早期胶结作用,早-中侏罗世长 7烃源岩进入未成熟-低熟阶段,形成富含有机酸流体进入储层而发生溶蚀作用,早白垩世中-晚期进入深埋藏成岩阶段,晚期胶结物大量形成而使储层致密。生烃增压作用导致的裂隙以及晚白垩世以来的构造运动形成的裂缝对研究区长4+5有效储层形成具有非常重要意义,同时对低渗油气藏勘探也具有指导意义。 相似文献
9.
《Sedimentology》2018,65(1):209-234
Dolomites of varied ages exhibit metre‐scale nested patterns of lateral periodic variation in permeability and porosity and, by inference, dolomite abundance as most examples are 100% dolomite. Two‐dimensional reaction–transport modelling simulations of bed‐scale dolomitization were used to assess whether those patterns in dolomite abundance could form during near‐surface replacement dolomitization. Simulations used a 2 m high and 18 m long model domain, a low‐Mg calcite grainstone precursor and an evaporated Mississippian seawater brine (430 parts per thousand salinity) as the dolomitizing fluid. The domain was initially populated with random variations in porosity and/or grain size. Results reveal that spatial patterns in dolomite abundance emerge when there is as little as 1% dolomite formed, with similarities between the modelled patterns and outcrop‐documented patterns. The nested patterns include a near‐random component that constitutes ≤40% of the total variance, short‐range correlation ranging from 1·5 to 3·3 m and a longer‐range periodic trend with a wavelength up to 6·5 m. The emergence of pattern in dolomite abundance is the result of an autogenic self‐organizing phenomenon. It is triggered by variation in initial calcite reactive surface area that occurs due to the random heterogeneities in initial porosity and/or grain sizes. The pattern develops due to a combination of kinetic disequilibrium reactions (dolomite precipitation and calcite dissolution) and positive feedbacks between dolomite growth, calcite dissolution and fluid flow. Flow is around loci of higher dolomite, lower porosity and higher reactive surface areas, but through loci of lower dolomite, higher porosity and lower reactive surface areas. The resulting less porous/more dolomite and more porous/less dolomite structures at the metre‐scale arise from those localized interactions. This self‐organizing mechanism for pattern formation constitutes a new model for geochemical self‐organization during dolomitization and is the only self‐organization model that is proven applicable to the formation of metre‐scale patterns during early, near‐surface dolomitization. 相似文献
10.
马朗凹陷芦草沟组泥页岩储层含油性特征与评价 总被引：1，自引：0，他引：1
通过泥页岩常规岩芯与密闭取芯的地球化学分析、物性分析、压汞实验分析等,评价马朗凹陷二叠系芦草沟组泥页岩储层的含油性,结合试油情况,研究其富油机制以及有利储层分布特征。结果表明,芦草沟组泥页岩储层含油性受有机质丰度和孔隙度影响,有利层段总有机碳要大于4%,孔隙度大于3%。体积含油率比含油饱和度更能准确表征泥页岩的含油性,油层要求含油率大于1%。压汞分析显示,泥页岩的储层富油机制与常规砂岩不同,包括未运移烃类的就地滞留富集和经历短距离初次运移在与优质源岩临近的次源岩层系中富集两个过程。芦草沟组页岩油的富集受岩性组合类型的影响,以泥岩为主,夹（薄层）泥质灰岩、泥质白云岩或者以灰质泥岩、白云质泥岩为主,为该区最有利岩性组合,含油性最好,对应于深湖-半深湖的沉积环境。 相似文献
11.
四川盆地西部须家河组砂岩储层成岩作用及致密时间讨论 总被引：1，自引：0，他引：1
运用沉积及成藏理论对四川盆地西部地区须家河组砂岩的岩石类型、成岩作用及其成藏时间研究表明:砂岩储层的主要成岩作用有压实和压溶作用、胶结作用,溶蚀作用、破裂作用以及自生矿物的沉淀作用.压实作用是砂岩粒间孔隙减少的主要因素,然而,方解石的强烈胶结作用以及石英的次生加大作用是造成须家河组砂岩储层致密的关键因素.方解石胶结物和石英次生加大包裹体的温度测定表明方解石胶结物主要发育在100℃～140℃之间,石英次生加大主要发生在80℃～126℃之间,在此温度区间,有机质演化已到了成熟期,并在60℃～80℃之间就开始发生运移.因此,砂岩储层的致密时间晚于天然气的生成和运移时间,砂岩储层的致密时间应该在燕山构造活动期,大约在1.5×10~8 a左右. 相似文献
12.
Juan Reynerio Fagundo-Castillo Joel José Carrillo-Rivera Iñaki Antigüedad-Auzmendi Patricia González-Hernández Roberto Peláez-Díaz Rebeca Hernández-Díaz Dámaso Cáceres-Govea José Ramón Hernández-Santana Margaret Suárez-Muñoz Clara Melián-Rodríguez Mónica Rodríguez-Piña 《Environmental Geology》2008,55(2):247-267
Flows of different hierarchy, which travel through limestone, schist, sandstone and ultra-basic rocks, with ages from the
Paleocene to the Jurassic, at Sierra del Rosario, Pinar del Río, Cuba, were characterized. The waters were sampled from 1984
until 2004 and the data were statistically processed by means of chemical equilibrium and physico-chemical models, under a
flow system view of interpretation. Results demonstrate that the physico-chemical properties of the water are controlled by
water–rock interaction resulting from residence time since rainwater infiltrate and the path it follows to the discharge zone
and the type of aquifer material the different groundwater flows are in contact with. Geochemical indices allow the definition
of the different types of flow (local, intermediate, regional) to be characterized, permitting a further definition of the
different flow systems and rock type involved, as well as its use for water supply and medical use. The main geochemical processes
which control the chemical composition acquisitions mode are: congruent dissolution of calcite, dolomite, and halite; incongruent
dissolution of plagioclase and microcline minerals; pyrite oxidation, sulphate reduction, and silica dissolution at the surface
or silica precipitation at deep saturation and circulation zones. 相似文献
13.
六苴铜矿床是典型的陆相红层盆地砂岩型铜矿床, 具有明显的浅紫过渡带控矿与金属矿物分带特征, 砂岩粒间孔隙为金属矿物主要赋存空间。通过对赋矿砂岩层各岩性段的碎屑含量、颗粒分选性、胶结物特征、孔隙类型及孔隙度、渗透率等的统计与分析, 结果表明, 上白垩统马头山组六苴下亚段(K1ml1)的中细粒长石石英砂岩具有高碎屑含量、低分选系数、高孔渗系数等特征, 为有效的流体迁移通道。K1ml1砂岩层局部含丰富的有机质, 在中成岩阶段可演化为烃源岩, 形成富有机质的酸性-还原流体。该流体与碱性-氧化流体在砂岩透水通道中形成稳定对流, 在砂岩中可形成由紫到浅的铁质、钙镁质、钙硅质、硅质胶结的胶结物分带。在水-岩相互作用中, 酸性-还原流体起溶解砂岩早期的铁质、泥晶碳酸盐胶结物及还原硫酸盐的作用, 由此形成粒间孔隙并提供还原硫, 从而为矿质沉淀提供空间和硫源;碱性-氧化流体则提供铜离子并控制金属硫化物、碳酸盐胶结物的沉淀。生烃作用减弱时, 碱性-氧化流体越过稳定对流的平衡面, 使硅质胶结的浅色砂岩溶蚀, 形成溶蚀孔洞, 进一步提供容矿空间, 并导致金属矿物发生交代作用。砂岩各成岩阶段的水-岩相互作用是控制孔隙和胶结物生成及矿质沉淀的主要因素。 相似文献
14.
《Applied Geochemistry》2003,18(10):1555-1571
In the context of the proposed low- and intermediate-level radioactive waste repository at Wellenberg (Switzerland), calculations simulating the interaction between hyperalkaline solutions and a fractured marl, at 25 °C, have been performed. The aim of these calculations is to evaluate the possible effects of mineral dissolution and precipitation on porosity and permeability changes in such a fractured marl, and their impact on repository performance. Solute transport and chemical reaction are considered in both a high-permeability zone (fracture), where advection is important, and the wall rock, where diffusion is the dominant transport mechanism. The mineral reactions are promoted by the interaction between hyperalkaline solutions derived from the degradation of cement (a major component of the engineered barrier system in the repository) and the host rock. Both diffusive/dispersive and advective solute transport are taken into account in the calculations. Mineral reactions are described by kinetic rate laws. The fluid flow system under consideration is a two-dimensional porous medium (marl, 1% porosity), with a high-permeability zone simulating a fracture (10% porosity) crossing the domain. The dimensions of the domain are 6 m per 1 m, and the fracture width is 10 cm. The fluid flow field is updated during the course of the simulations. Permeabilities are updated according to Kozeny's equation. The composition of the solutions entering the domain is derived from modeling studies of the degradation of cement under the conditions at the proposed underground repository at Wellenberg. Two different cases have been considered in the calculations. These 2 cases are representative of 2 different stages in the process of degradation of cement (pH 13.5 and pH 12.5). In both cases, the flow velocity in the fracture diminishes with time, due to a decrease in porosity. This decrease in porosity is caused by the precipitation of calcite (replacement of dolomite by calcite) and other secondary minerals (brucite, sepiolite, analcime, natrolite, tobermorite). However, the decrease in porosity and flow velocity is much more pronounced in the lower pH case. The extent of the zone of mineral alteration along the fracture is also much more limited in the lower pH case. The reduction of porosity in the fractures would be highly beneficial for repository performance, since it would mean that the solutions coming from the repository and potentially carrying radionuclides in solution would have to flow through low-conductive rock before they would be able to get to higher-conductive features. The biggest uncertainty in the reaction rates used in the calculations arises from the surface areas of the primary minerals. Additional calculations making use of smaller surface areas have also been performed. The results show that the smaller surface areas (and therefore smaller reaction rates) result in a smaller reactivity of the system and smaller porosity changes. 相似文献
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成矿流体热场直接影响矿床的成矿作用.依据湘中盆地的水文地质特征, 以锡矿山锑矿床成矿流体为例, 利用热-重力驱动型流体运移模型, 选择具有代表性的龙山岳坪峰-锡矿山(AB)剖面, 研究大气年降水量的大小对成矿流体热场的影响.首先选取一个对比降水量1200 mm/a, 计算出区域的温度场分布, 然后分别取年平均大气降水量为600、1800和2400 mm/a与对比降水量的温度场进行对比, 得出2种温度场的差值图.模拟结果表明: 大气降水的水量大小对区域流场影响较大, 而对区域温度场的影响不大, 在不同降水量条件下, 其对温度的影响在5%~20%之间.研究结论认为, 大气降水量对成矿流体的热场影响不大. 相似文献
17.
湖南水口山矿田开放体系构造成矿动力学 总被引：8，自引：0，他引：8
湖南水口山矿田成矿作用受构造控制明显，主要与压剪性断裂作用有关。Ｈ、Ｏ、Ｃ、Ｓ、Ｐｂ同位素资料、断裂构造地球化学与矿床地球化学分析表明矿床形成于开放体系条件。开放体系下的（断裂）构造作用控制了矿田成矿元素的活化迁移与含矿流体的形成、流体的迁移、汇聚及矿液的沉淀与矿床的定位，文中分析了其动力学机理。最后建立了矿田的开放体系构造成矿动力学综合数学模型，对成矿过程进行了计算机模拟。 相似文献
18.
Ivo Colombo Giovanni M. Porta Paolo Ruffo Alberto Guadagnini 《Hydrogeology Journal》2017,25(2):385-403
This study illustrates a procedure conducive to a preliminary risk analysis of overpressure development in sedimentary basins characterized by alternating depositional events of sandstone and shale layers. The approach rests on two key elements: (1) forward modeling of fluid flow and compaction, and (2) application of a model-complexity reduction technique based on a generalized polynomial chaos expansion (gPCE). The forward model considers a one-dimensional vertical compaction processes. The gPCE model is then used in an inverse modeling context to obtain efficient model parameter estimation and uncertainty quantification. The methodology is applied to two field settings considered in previous literature works, i.e. the Venture Field (Scotian Shelf, Canada) and the Navarin Basin (Bering Sea, Alaska, USA), relying on available porosity and pressure information for model calibration. It is found that the best result is obtained when porosity and pressure data are considered jointly in the model calibration procedure. Uncertainty propagation from unknown input parameters to model outputs, such as pore pressure vertical distribution, is investigated and quantified. This modeling strategy enables one to quantify the relative importance of key phenomena governing the feedback between sediment compaction and fluid flow processes and driving the buildup of fluid overpressure in stratified sedimentary basins characterized by the presence of low-permeability layers. The results here illustrated (1) allow for diagnosis of the critical role played by the parameters of quantitative formulations linking porosity and permeability in compacted shales and (2) provide an explicit and detailed quantification of the effects of their uncertainty in field settings. 相似文献
19.
碳酸盐胶结物中氧碳同位素组成研究是分析成岩过程中流体-岩石相互作用的重要技术方法.综合运用岩石学、矿物学和地球化学方法，对辽河盆地西部凹陷沙河街组砂岩中碳酸盐胶结物的化学组成和碳酸盐胶结物及成岩流体同位素组成特征进行系统分析.研究表明，研究区碳酸盐岩主要为方解石和白云石，胶结物主要类型为嵌晶式胶结、孔隙式胶结、斑块状胶结和星点状胶结.碳、氧稳定同位素组成能有效地反映成岩-成矿流体及其他物质的来源，碳酸盐胶结物与现今浅层地下水氧同位素组成差异巨大而与变质水同位素组成具有相似性，反映了盆地演化过程中活动热流体对成岩作用的影响.包裹体的氢、氧同位素组成可表征成矿溶液的演化特征，砂岩碳酸盐胶结物包裹体更富集氢的轻同位素和氧的重同位素，表明发生了明显的“氧-18漂移”.碳酸盐胶结的成矿溶液表现出“受热雨水”的同位素组成特征，反映了深源活动热流体对成岩作用的影响. 相似文献
20.
四川乌斯河铅锌矿床是赋存于震旦系灯影组白云岩中的大型铅锌矿床.本次研究结合最新的野外地质现象发现该矿床除存在前人所强调的沉积成矿作用以外,热液成矿作用非常明显.对该矿床流体包裹体进行细致的岩相学、显微测温和激光拉曼研究,揭示成矿流体特征,并探讨成矿机制.研究结果显示该矿床包裹体类型较为单一,以气液两相为主,均一温度主要集中于120~260 ℃,平均盐度为10.0% NaCl eqv,压力为32~68 MPa,成矿流体为中-低温、中等盐度.激光拉曼测试显示包裹体气相成分含有CH4、H2S、C2H6、C2H2、N2和NH3,为多元共存的流体体系.在热驱动力下(120~260 ℃),流体混合作用提供了物质基础(SO42-)、催化剂(Mg2+)和还原剂(有机质、CH4和H2S)促使硫酸盐热化学还原反应(TSR)启动.TSR反应过程中流体pH发生变化,进一步促进了金属硫化物沉淀. 相似文献