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1.
Current estimations of gas exchange between the ocean and the atmosphere are based on the concepts about diffusive gas transfer across the interface and about a stationary character of the processes; however, under a strong wind, these concepts are invalid. Transfer equations for gas constitutents of the air are incorporated into a numerical model of a nonstationary upper layer of the ocean. These equations contain the source function—gas transfer by bubbles, which becomes noticeable even at a wind speed of 8–10 m/s. The fluxes of oxygen and CO2 are calculated at a specified wind speed, dependences of these fluxes on the wind speed are constructed, and estimates for the average annual fluxes are obtained for several areas of the Gulf Stream and Kuroshio. A substantial change in the difference of the air-water gas contents under a strong wind, caused by the turbulent exchange growth and appreciably affecting the gas exchange, is noted. The influence of the carbonate system of seawater on the CO2 transfer during a storm is estimated. The results obtained are compared to the estimates based on the traditional approach.  相似文献   

2.
Direct measurements of the air-sea CO2 flux by the eddy covariance technique were carried out in the equatorial Indian Ocean. The turbulent flux observation system was installed at the top of the foremast of the R/V MIRAI, thus minimizing dynamical and thermal effects of the ship body. During the turbulent flux runs around the two stations, the vessel was steered into the wind at constant speed. The power spectra of the temperature or water vapor density fluctuations followed the Kolmogorov −5/3 power law, although that of the CO2 density fluctuation showed white noise in the high frequency range. However, the cospectrum of the vertical wind velocity and CO2 density was well matched with those of the vertical velocity and temperature or water vapor density in this frequency range, and the CO2 white noise did not influence the CO2 flux. The raw CO2 fluxes due to the turbulent transport showed a sink from the air to the ocean, and had almost the same value as the source CO2 fluxes due to the mean vertical flow, corrected by the sensible and latent heat fluxes (called the Webb correction). The total CO2 fluxes including the Webb correction terms showed a source from the ocean to the air, and were larger than the bulk CO2 fluxes estimated using the gas transfer velocity by mass balance techniques.  相似文献   

3.
A global ocean carbon cycle model based on the ocean general circulation model POP and the improved biogeochemical model OCMIP-2 is employed to simulate carbon cycle processes under the historically observed atmospheric CO 2 concentration and different future scenarios (called Rep- resentative Concentration Pathways, or RCPs). The RCPs in this paper follow the design of Inter- governmental Panel on Climate Change (IPCC) for the Fifth Assessment Report (AR5). The model results show that the ocean absorbs CO 2 from atmosphere and the absorbability will continue in the 21st century under the four RCPs. The net air-sea CO 2 flux increased during the historical time and reached 1.87 Pg/a (calculated by carbon) in 2005; however, it would reach peak and then decrease in the 21st century. The ocean absorbs CO 2 mainly in the mid latitude, and releases CO 2 in the equator area. However, in the Antarctic Circumpolar Current (ACC) area the ocean would change from source to sink under the rising CO 2 concentration, including RCP4.5, RCP6.0, and RCP8.5. In 2100, the anthropogenic carbon would be transported to the 40 S in the Atlantic Ocean by the North Atlantic Deep Water (NADW), and also be transported to the north by the Antarctic Bottom Water (AABW) along the Antarctic continent in the Atlantic and Pacific oceans. The ocean pH value is also simulated by the model. The pH decreased by 0.1 after the industrial revolution, and would continue to decrease in the 21st century. For the highest concentration sce- nario of RCP8.5, the global averaged pH would decrease by 0.43 to reach 7.73 due to the absorption of CO 2 from atmosphere.  相似文献   

4.
The climate model of intermediate complexity developed at the Oboukhov Institute of Atmospheric Physics, Russian Academy of Sciences (IAP RAS CM), has been supplemented by a zero-dimensional carbon cycle model. With the carbon dioxide emissions prescribed for the second half of the 19th century and for the 20th century, the model satisfactorily reproduces characteristics of the carbon cycle over this period. However, with continued anthropogenic CO2 emissions (SRES scenarios A1B, A2, B1, and B2), the climate-carbon cycle feedback in the model leads to an additional atmospheric CO2 increase (in comparison with the case where the influence of climate changes on the carbon exchange between the atmosphere and the underlying surface is disregarded). This additional increase is varied in the range 67–90 ppmv depending on the scenario and is mainly due to the dynamics of soil carbon storage. The climate-carbon cycle feedback parameter varies nonmonotonically with time. Positions of its extremes separate characteristic periods of the change in the intensity of anthropogenic emissions and of climate variations. By the end of the 21st century, depending on the emission scenario, the carbon dioxide concentration is expected to increase to 615–875 ppmv and the global temperature will rise by 2.4–3.4 K relative to the preindustrial value. In the 20th–21st centuries, a general growth of the buildup of carbon dioxide in the atmosphere and ocean and its reduction in terrestrial ecosystems can be expected. In general, by the end of the 21st century, the more aggressive emission scenarios are characterized by a smaller climate-carbon cycle feedback parameter, a lower sensitivity of climate to a single increase in the atmospheric concentration of carbon dioxide, a larger fraction of anthropogenic emissions stored in the atmosphere and the ocean, and a smaller fraction of emissions in terrestrial ecosystems.  相似文献   

5.
Carbon dioxide flux techniques performed during GasEx-98   总被引：2，自引：0，他引：2  
A comprehensive study of air–sea interactions focused on improving the quantification of CO2 fluxes and gas transfer velocities was performed within a large open ocean CO2 sink region in the North Atlantic. This study, GasEx-98, included shipboard measurements of direct covariance CO2 fluxes, atmospheric CO2 profiles, atmospheric DMS profiles, water column mass balances of CO2, and measurements of deliberate SF6–3He tracers, along with air–sea momentum, heat, and water vapor fluxes. The large air–sea differences in partial pressure of CO2 caused by a springtime algal bloom provided high signals for accurate CO2 flux measurements. Measurements were performed over a wind speed range of 1–16 m s−1 during the three-week process study. This first comparison between the novel air-side and more conventional water column measurements of air–sea gas transfer show a general agreement between independent air–sea gas flux techniques. These new advances in open ocean air–sea gas flux measurements demonstrate the progress in the ability to quantify air–sea CO2 fluxes on short time scales. This capability will help improve the understanding of processes controlling the air–sea fluxes, which in turn will improve our ability to make regional and global CO2 flux estimates.  相似文献   

6.
The ocean captures a large part of the anthropogenic carbon dioxide emitted to the atmosphere. As a result of the increase in CO2 partial pressure the ocean pH is lowered as compared to pre-industrial times and a further decline is expected. Ocean acidification has been proposed to pose a major threat for marine organisms, particularly shell-forming and calcifying organisms. Here we show, on the basis of meta-analysis of available experimental assessments, differences in organism responses to elevated pCO2 and propose that marine biota may be more resistant to ocean acidification than expected. Calcification is most sensitive to ocean acidification while it is questionable if marine functional diversity is impacted significantly along the ranges of acidification predicted for the 21st century. Active biological processes and small-scale temporal and spatial variability in ocean pH may render marine biota far more resistant to ocean acidification than hitherto believed.  相似文献   

7.
Results from twin control simulations of the preindustrial CO2 gas exchange (natural flux of CO2) between the ocean and the atmosphere are presented here using the NASA-GISS climate model, in which the same atmospheric component (modelE2) is coupled to two different ocean models, the Russell ocean model and HYCOM. Both incarnations of the GISS climate model are also coupled to the same ocean biogeochemistry module (NOBM) which estimates prognostic distributions for biotic and abiotic fields that influence the air–sea flux of CO2. Model intercomparison is carried out at equilibrium conditions and model differences are contrasted with biases from present day climatologies. Although the models agree on the spatial patterns of the air–sea flux of CO2, they disagree on the strength of the North Atlantic and Southern Ocean sinks mainly because of kinematic (winds) and chemistry (pCO2) differences rather than thermodynamic (SST) ones. Biology/chemistry dissimilarities in the models stem from the different parameterizations of advective and diffusive processes, such as overturning, mixing and horizontal tracer advection and to a lesser degree from parameterizations of biogeochemical processes such as gravitational settling and sinking. The global meridional overturning circulation illustrates much of the different behavior of the biological pump in the two models, together with differences in mixed layer depth which are responsible for different SST, DIC and nutrient distributions in the two models and consequently different atmospheric feedbacks (in the wind, net heat and freshwater fluxes into the ocean).  相似文献   

8.
Over a period of 5 days between August 12 and 17, 2005, we performed a gas exchange experiment using the dual tracer method in a tidal coastal ocean located off the southern coast of Korea. The gas exchange rate was determined from temporal changes in the ratio of3He to SF6 measured daily in the surface mixed layer. The measured gas exchange rate (k CO 2), normalized to a Schmidt number of 600 for CO2 in fresh water at 20°C, was approximately 5.0 cm h-1 at a mean wind speed of 3.9 m s-1 during the study period. This value is significantly less than those obtained from floating chamber-based experiments performed previously in estuarine environments, but is similar in magnitude to values obtained using the dual tracer method in river and tidal coastal waters and values predicted on the basis of the relationship between the gas exchange rate and wind speed (Wanninkhof 1992), which is generally applicable to the open ocean. Our result is also consistent with the relationship of Raymond and Cole (2001), which was derived from experiments carried out in estuarine environments using222Rn and chlorofluorocarbons along with measurements undertaken in the Hudson River, Canada, using SF6 and3He. Our results indicate that tidal action in a microtidal region did not discernibly enhance the measuredk CO 2 value.  相似文献   

9.
The global distributions of the air-sea CO2 transfer velocity and flux are retrieved from TOPEX/Poseidon and Jason altimeter data from October 1992 to December 2009 using a combined algorithm. The 17 a average global, area-weighted, Schmidt number-corrected mean gas transfer velocity is 21.26 cm/h, and the full exploration of the uncertainty of this estimate awaits further data. The average total CO2 flux （calculated by carbon） from atmosphere to ocean during the 17 a was 2.58 Pg/a. The highest transfer velocity is in the circumpolar current area, because of constant high wind speeds and currents there. This results in strong CO2 fluxes. CO2 fluxes are strong but opposite direction in the equatorial east Pacific Ocean, because the air-sea CO2 partial pressure difference is the largest in the global cceans. The results differ from the previous studies calculated using the wind speed. It is demonstrated that the air-sea transfer velocity is very important for estimating air-sea CO2 flux. It is critical to have an accurate estimation for improving calculation of CO2 flux within climate change studies.  相似文献   

10.
A 3D coupled biogeochemical–hydrodynamic model (MIRO-CO2&CO) is implemented in the English Channel (ECH) and the Southern Bight of the North Sea (SBNS) to estimate the present-day spatio-temporal distribution of air–sea CO2 fluxes, surface water partial pressure of CO2 (pCO2) and other components of the carbonate system (pH, saturation state of calcite (Ωca) and of aragonite (Ωar)), and the main drivers of their variability. Over the 1994–2004 period, air–sea CO2 fluxes show significant inter-annual variability, with oscillations between net annual CO2 sinks and sources. The inter-annual variability of air–sea CO2 fluxes simulated in the SBNS is controlled primarily by river loads and changes of biological activities (net autotrophy in spring and early summer, and net heterotrophy in winter and autumn), while in areas less influenced by river inputs such as the ECH, the inter-annual variations of air–sea CO2 fluxes are mainly due to changes in sea surface temperature and in near-surface wind strength and direction. In the ECH, the decrease of pH, of Ωca and of Ωar follows the one expected from the increase of atmospheric CO2 (ocean acidification), but the decrease of these quantities in the SBNS during the considered time period is faster than the one expected from ocean acidification alone. This seems to be related to a general pattern of decreasing nutrient river loads and net ecosystem production (NEP) in the SBNS. Annually, the combined effect of carbon and nutrient loads leads to an increase of the sink of CO2 in the ECH and the SBNS, but the impact of the river loads varies spatially and is stronger in river plumes and nearshore waters than in offshore waters. The impact of organic and inorganic carbon (C) inputs is mainly confined to the coast and generates a source of CO2 to the atmosphere and low pH, of Ωca and of Ωar values in estuarine plumes, while the impact of nutrient loads, highest than the effect of C inputs in coastal nearshore waters, also propagates offshore and, by stimulating primary production, drives a sink of atmospheric CO2 and higher values of pH, of Ωca and of Ωar.  相似文献   

11.
Diurnal changes in seawater temperature affect the amount of air–sea gas exchange taking place through changes in solubility and buoyancy-driven nocturnal convection, which enhances the gas transfer velocity. We use a combination of in situ and satellite derived radiometric measurements and a modified version of the General Ocean Turbulence Model (GOTM), which includes the National Oceanic and Atmospheric Administration Coupled-Ocean Atmospheric Response Experiment (NOAA-COARE) air–sea gas transfer parameterization, to investigate heat and carbon dioxide exchange over the diurnal cycle in the Tropical Atlantic. A new term based on a water-side convective velocity scale (w*w) is included, to improve parameterization of convectively driven gas transfer. Meteorological data from the PIRATA mooring located at 10°S10°W in the Tropical Atlantic are used, in conjunction with cloud cover estimates from Meteosat-7, to calculate fluxes of longwave, latent and sensible heat along with a heat budget and temperature profiles during February 2002. Twin model experiments, representing idealistic and realistic conditions, reveal that over daily time scales the additional contribution to gas exchange from convective overturning is important. Increases in transfer velocity of up to 20% are observed during times of strong insolation and low wind speeds (<6 m s−1); the greatest enhancement from w*w to the CO2 flux occurs when diurnal warming is large. Hence, air–sea fluxes of CO2 calculated using simple parameterizations underestimate the contribution from convective processes. The results support the need for parameterizations of gas transfer that are based on more than wind speed alone and include information about the heat budget.  相似文献   

12.
海-气CO2通量估算模型中参数的可靠性是决定模型可靠性的重要因素, 也决定了模型估算结果的可靠性, 因此开展海-气CO2通量计算模型中误差传递规律与敏感性分析, 对模型参数端元因子的误差控制, 提高模型预测精度和降低不确定性十分重要。但由于模型中参数众多, 且各种参数间彼此相互影响, 使得误差传递过程与敏感性分析十分复杂困难。本文在海-气界面CO2通量观测建模过程详细分析的基础上, 以海-气界面CO2分压差的经典通量计算模型为基础, 以实测数据通量计算过程为例, 针对模型中的参数变量, 在假设参数变量的误差正态分布的前提下, 利用Monte Carlo手段分析各参数变量的误差在模型中的传递规律, 并将单因子扰动试验法用于海-气界面CO2通量建模的参数敏感性分析。模拟和分析结果表明:CO2通量计算过程中误差经模型传递后的分布规律存在正态分布、指数分布等多种形式;气体交换系数对通量计算结果的敏感性最大, 通量估算中的风速和表层海水温度是必须进行精度控制的关键参数。  相似文献   

13.
It is not clear whether global warming will favour or reduce global ocean phytoplankton productivity in coastal areas. Moreover, the relative contributions made by natural and/or anthropogenic factors to possible changes in phytoplankton productivity are not clear. As the relationship between primary production and alongshore wind forcing is well established for the Eastern Boundary Current (EBC) ecosystems, our aim is to determine whether the changes experienced over the last five decades (1958–2007) in atmospheric CO2 and solar activity have been able to affect the wind regime and water column stability in the most biologically productive upwelling areas of California, Canary, Humboldt and Benguela. We approached the work by statistically studying the effect of solar activity and atmospheric CO2 on surface alongshore wind stress and on water column stability. There was an increasing trend in wind stress and water column stability in all the upwelling areas over the period studied (with the single exception of stability in the California EBC system). The analysis of detrended series evidenced significant relationships between atmospheric CO2 concentration and wind stress and water column stability in the coastal upwelling areas investigated. In addition, wind stress and stability data were found to be consistent, with negative linear relationships between wind stress and CO2 in most of the sites in the Benguela, Canary and Humboldt regions associated, as expected, to positive relationships when water column stability is used as regressand. The results of the present study suggest that greenhouse gas forcing, independent of its well known general increasing trend, was able to decrease wind stress intensity and increase water column stability for the period 1958 to present in most of the sites of the four Eastern Boundary Ecosystems studied, with the one exception of the California region. Conversely, the impact of solar activity appeared to be quite low compared to the greenhouse gas forcing.  相似文献   

14.
《Oceanologica Acta》1999,22(5):499-515
Water column pCO2 and air-sea CO2 fluxes were studied during an 18-month period (May 1994–September 1995) in a coastal embayment affected by upwelling, located in the northwestern Iberian Peninsula (Ria de Vigo and adjacent shelf). Overall, the region acted as a net annual atmospheric CO2 sink, with magnitude ranging from 0.54 mgC m−2d−1 in the Ria estuary to 22 mgC m−2d−1 offshore. During moderate upwelling and upwelling relaxation conditions the sampling area was a sink for atmospheric CO2. By contrast, during winter conditions and during intense upwelling the flux reversed towards the atmosphere. The relative influence of physical and biological processes on pCO2 was evaluated using two different approaches: firstly, statistical analysis of physico-chemical correlations, and secondly, a thermodynamic analysis in the oceanic CO2 system. Both methods yielded consistent results, showing that the main processes controlling seasonal and spatial pCO2 variability were the production and remineralization of organic matter, explaining ca. 70 % of the total variability. In the inner part of the embayment, air-sea CO2 exchange was mainly modulated by CO2 partial pressure gradient, whereas in the adjacent shelf, wind speed largely contributed to CO2 fluxes between the ocean and the atmosphere.  相似文献   

15.
The SOLAS air-sea gas exchange experiment (SAGE) was a multiple-objective study investigating gas-transfer processes and the influence of iron fertilisation on biologically driven gas exchange in high-nitrate low-silicic acid low-chlorophyll (HNLSiLC) Sub-Antarctic waters characteristic of the expansive subpolar zone of the southern oceans. This paper provides a general introduction and summary of the main experimental findings. The release site was selected from a pre-voyage desktop study of environmental parameters to be in the south-west Bounty Trough (46.5°S 172.5°E) to the south-east of New Zealand and the experiment was conducted between mid-March and mid-April 2004. In common with other mesoscale iron addition experiments (FeAX’s), SAGE was designed as a Lagrangian study, quantifying key biological and physical drivers influencing the air-sea gas exchange processes of CO2, DMS and other biogenic gases associated with an iron-induced phytoplankton bloom. A dual tracer SF6/3He release enabled quantification of both the lateral evolution of a labelled volume (patch) of ocean and the air-sea tracer exchange at tenths of kilometer scale, in conjunction with the iron fertilisation. Estimates from the dual-tracer experiment found a quadratic dependency of the gas exchange coefficient on windspeed that is widely applicable and describe air-sea gas exchange in strong wind regimes. Within the patch, local and micrometeorological gas exchange process studies (100 m scale) and physical variables such as near-surface turbulence, temperature microstructure at the interface, wave properties and windspeed were quantified to further assist the development of gas exchange models for high-wind environments.There was a significant increase in the photosynthetic competence (Fv/Fm) of resident phytoplankton within the first day following iron addition, but in contrast to other FeAX’s, rates of net primary production and column-integrated chlorophyll a concentrations had only doubled relative to the unfertilised surrounding waters by the end of the experiment. After 15 days and four iron additions totalling 1.1 ton Fe2+, this was a very modest response compared to other mesoscale iron enrichment experiments. An investigation of the factors limiting bloom development considered co-limitation by light and other nutrients, the phytoplankton seed-stock and grazing regulation. Whilst incident light levels and the initial Si:N ratio were the lowest recorded in all FeAXs to date, there was only a small seed-stock of diatoms (less than 1% of biomass) and the main response to iron addition was by the picophytoplankton. A high rate of dilution of the fertilised patch relative to phytoplankton growth rate, the greater than expected depth of the surface mixed layer and microzooplankton grazing were all considered as factors that prevented significant biomass accumulation. In line with the limited response, the enhanced biological draw-down of pCO2 was small and masked by a general increase in pCO2 due to mixing with higher pCO2 waters. The DMS precursor DMSP was kept in check through grazing activity and in contrast to most FeAX’s dissolved dimethylsulfide (DMS) concentration declined through the experiment. SAGE is an important low-end member in the range of responses to iron addition in FeAX’s. In the context of iron fertilisation as a geoengineering tool for atmospheric CO2 removal, SAGE has clearly demonstrated that a significant proportion of the low iron ocean may not produce a phytoplankton bloom in response to iron addition.  相似文献   

16.
Comprehensive sea surface surveys of the partial pressure of carbon dioxide (pCO2) have been made in the upwelling system of the coastal (0–200 km from shore) southeastern tropical Pacific since 2004. The shipboard data have been supplemented by mooring and drifter based observations. Air–sea flux estimates were made by combining satellite derived wind fields with the direct sea surface pCO2 measurements. While there was considerable spatial heterogeneity, there was a significant flux of CO2 from the ocean to the atmosphere during all survey periods in the region between 4° and 20° south latitude. During periods of strong upwelling the average flux out of the ocean exceeded 10 moles of CO2 per square meter per year. During periods of weaker upwelling and high productivity the CO2 evasion rate was near 2.5 mol/m2/yr. The average annual fluxes exceed 5 mol/m2/yr. These findings are in sharp contrast to results obtained in mid-latitude upwelling systems along the west coast of North America where the average air–sea CO2 flux is low and can often be from the atmosphere into the ocean. In the Peruvian upwelling system there are several likely factors that contribute to sea surface pCO2 levels that are well above those of the atmosphere in spite of elevated primary productivity: (1) the upwelling source waters contain little pre-formed nitrate and are affected by denitrification, (2) iron limitation of primary production enhanced by offshore upwelling driven by the curl of the wind stress and (3) rapid sea surface warming. The combined carbon, nutrient and oxygen dynamics of this region make it a candidate site for studies of global change.  相似文献   

17.
The oceanic biogeochemical fluxes in the North Pacific, especially its northwestern part, are discussed to prove their importance on a global scale. First, the air-sea exchange processes of chemical substances are considered quantitatively. The topics discussed are sea salt particles transported to land, sporadic transport of soil dust to the ocean and its role in the marine ecosystem, the larger gas transfer velocity of CO2 indicating the effect of bubbles, and DMS and greenhouse gases other than CO2. Next, chemical tracers are utilized to reveal the water circulation systems in the region, which are the Pacific Deep Water including its vertical eddy diffusivity, the North Pacific Intermediate Water and the Japan Sea Deep Water. Thirdly, the particulate transport process of chemical substances through the water column is clarified by analyzing the distribution of insoluble radionuclides and the results obtained from sediment trap experiments. Fourthly, the northern North Pacific is characterized by stating the site decomposing organic matter and Si playing a key role in the marine ecosystem. Both are induced by the upwelled Pacific Deep Water. Fifthly, the oceanic CO2 system related to global warming is presented by clarifying the distribution of anthropogenic CO2 in the western North Pacific, and roles of the upwelled Pacific Deep Water and the continental shelf zone in the absorption of atmospheric CO2. Finally, Mn and other chemical substances in sediments are discussed as recorders of the early diagenesis and indicators of low biological productivity during glacial ages in the northwestern North Pacific. It is concluded that the western North Pacific is characterized mainly by the Pacific Deep Water bringing nutrients to the northern North Pacific, located at the exit of the global deep water circulation and, therefore, the region plays a key role in the global biogeochemical fluxes. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

18.
A new deep-sea laser Raman spectrometer (DORISS—Deep Ocean Raman In Situ Spectrometer) is used to observe the preferential dissolution of CO2 into seawater from a 50%–50% CO2–N2 gas mixture in a set of experiments that test a proposed method of CO2 sequestration in the deep ocean. In a first set of experiments performed at 300 m depth, an open-bottomed 1000 cm3 cube was used to contain the gas mixture; and in a second set of experiments a 2.5 cm3 funnel was used to hold a bubble of the gas mixture in front of the sampling optic. By observing the changing ratios of the CO2 and N2 Raman bands we were able to determine the gas flux and the mass transfer coefficient at 300 m depth and compare them to theoretical calculations for air–sea gas exchange. Although each experiment had a different configuration, comparable results were obtained. As expected, the ratio of CO2 to N2 drops off at an exponential rate as CO2 is preferentially dissolved in seawater. In fitting the data with theoretical gas flux calculations, the boundary layer thickness was determined to be  42 μm for the gas cube, and  165 μm for the gas funnel reflecting different boundary layer turbulence. The mass transfer coefficients for CO2 are kL = 2.82 × 10− 5 m/s for the gas cube experiment, and kL = 7.98 × 10− 6 m/s for the gas funnel experiment.  相似文献   

19.
The seasonal variability of the carbon dioxide (CO2) system in the Southern Ocean, south of 50°S, is analysed from observations obtained in January and August 2000 during OISO cruises conducted in the Indian Antarctic sector. In the seasonal ice zone, SIZ (south of 58°S), surface ocean CO2 concentrations are well below equilibrium during austral summer. During this season, when sea-ice is not obstructing gas exchange at the air–sea interface, the oceanic CO2 sink ranges from −2 to −4 mmol/m2/d in the SIZ. In the permanent open ocean zone, POOZ (50–58°S), surface oceanic fugacity fCO2 increases from summer to winter. The seasonal fCO2 variations (from 10 to 30 μatm) are relatively low compared to seasonal amplitudes observed in the subtropics or the subantarctic zones. However, these variations in the POOZ are large enough to cross the atmospheric level from summer to winter. Therefore, this region is neither a permanent CO2 sink nor a permanent CO2 source. In the POOZ, air–sea CO2 fluxes calculated from observations are about −1.1 mmol/m2/d in January (a small sink) and 2.5 mmol/m2/d in August (a source). These estimates obtained for only two periods of the year need to be extrapolated on a monthly scale in order to calculate an integrated air–sea CO2 flux on an annual basis. For doing this, we use a biogeochemical model that creates annual cycles for nitrate, inorganic carbon, total alkalinity and fCO2. The changing pattern of ocean CO2 summer sink and winter source is well reproduced by the model. It is controlled mainly by the balance between summer primary production and winter deep vertical mixing. In the POOZ, the annual air–sea CO2 flux is about −0.5 mol/m2/yr, which is small compared to previous estimates based on oceanic observations but comparable to the small CO2 sink deduced from atmospheric inverse methods. For reducing the uncertainties attached to the global ocean CO2 sink south of the Polar Front the regional results presented here should be synthetized with historical and new observations, especially during winter, in other sectors of the Southern Ocean.  相似文献   

20.
The influence of the spatial heterogeneity of vegetation cover and topography on CO2 fluxes in the atmospheric surface layer is estimated using a two-dimensional (2D) hydrodynamic model of turbulent exchange. A ~4.5-km-long profile that crossed a hilly area with a mosaic vegetation cover in Tula region was selected for model experiments. During the first experiment, a wind field and vertical fluxes were calculated by the 2D model for the entire selected profile with respect to the horizontal heterogeneity of the vegetation cover and surface topography. In the second experiment, the profile was considered an assemblage of elementary independent homogeneous segments; for each of them, vertical fluxes were calculated by the 2D model with the assumption of ‘zero’ horizontal advection, i.e., the required functions are independent of the horizontal coordinates. The influences of any boundary effects that appear at the interface between the different vegetation communities and at topographical irregularities on the turbulent regime are ignored in this case. For the profile selected, ignoring the horizontal advection, disturbances in the wind field that appeared at surface topography irregularities, and boundaries between different vegetation communities can lead to a 26% underestimation of the total CО2 absorption by the ground surface on a clear sunny day under summer weather conditions.  相似文献   

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