共查询到20条相似文献，搜索用时 187 毫秒
1.
热液体系氢、氧同位素分馏机制及其地质意义 总被引：9，自引：0，他引：9
探讨了热液体系氢、氧同位素地球化学行为及其与水/岩交换同位素分馏的内在关系。有效W/R值是除温度条件外,另一控制蚀变岩石和热液水氢、氧同位素组成变化的因素。此外还根据数个矿区成矿热液水和蚀变岩石氢、氧同位素组成及变化特征对水/岩交换和W/R值的应用及地质意义展开讨论。最后提出热液体系中大气降水和岩浆热液水氢、氧同位素组成演化模式简图。 相似文献
2.
在分析下庄铀矿田成矿地质背景的基础上，根据包体水氢、氧同位素组成和水－岩相互作用原理对该矿田成矿热液的水源进行了详细探讨。其结果表明，下庄铀成矿热液的氢、氧同位素组成δ１８Ｏ＝＋６．９０‰～－９．８０‰（ＳＭＯＷ）、δＤ＝－３０‰～－８５‰（ＳＭＯＷ）位于已发生氧漂移的大气降水同位素组成范围。水－岩同位素交换后，岩石的δ１８Ｏ值明显降低，显示出与岩石相互作用的古地下水具有相当低的δ１８Ｏ值。不同水－岩比值条件下同位素交换结果证明下庄成矿古水热系统具有比较充足的水源，大气降水与岩石交换后热液的δ１８Ｏ计算（－８．２６‰～＋１．５３‰）与成矿期热液的δ１８Ｏ值（－６．５４‰～＋１．４３‰）相吻合。证据表明下庄铀矿田成矿热液的水源主要来自大气降水。 相似文献
3.
在分析下庄铀矿田成矿地质背景的基础上，根据包体水氢、氧同位素组成和水－岩相互作用原理对该矿田成矿热液的水源进行了详细探讨。其结果表明，下庄铀成矿热液的氢、氧同位素组成δ＾１８Ｏ＝＋６．９０‰－９．８０‰（ＳＭＯＷ）、δＯ＝－３０－８５‰（ＳＭＯＷ）位于已发生氧漂移的大气降水同位素组成范围。水－岩同位素交换后，岩石的δ＾１８Ｏ值明显降低，显著出与岩石相互作用的古地下水具有相当低的δ＾１８Ｏ值。不同水 相似文献
4.
相山铀矿田水—岩氢,氧同位素交换的实验研究 总被引：3，自引：0，他引：3
为了研究相山铀矿田的水－岩氢、氧稳定同位素交换作用及其对水溶液和岩石氢、氧稳定同位素组成的影响，为探讨矿床成因提供实验依据，笔者进行了相山铀成矿古水热系统中水－岩氢、氧同位素交换实验。实验结果表明，在水热系统中水－岩之间可以发重 氧同位素交换作用，致使岩石的δ＾１８Ｏ值下降，水的δ＾１８Ｏ值升高，即发生“氧－１８飘移”。热水溶液的δＤ值相对稳定，但与含有较多含氢矿物（云母等）的岩石作用时，δＤ值可 相似文献
5.
本文以西华山钨矿为例,介绍了用水/岩交换氢氧同位素地球化学行为特征,判定热液矿床成矿介质水的性质、来源及各种水/岩交换初始参数的确定方法;阐述了经水/岩交换后成矿热液水与其初始水之间氢氧同位素组成的差异;指出要慎重使用混合水成矿的观点来解释矿床成因. 相似文献
6.
德兴斑岩铜矿成矿热液来源及其演化——花岗闪长斑岩的氧同位素制约 总被引：8，自引：0，他引：8
作者研究了德兴铜厂花岗闪长斑岩的氧同位素组成特征在垂直方向上的变化规律,及蚀变作用对花岗闪长斑岩全岩和单矿物氧同位素组成的影响。结果表明,从地表到深部,花岗闪长斑岩全岩和长石单矿物的δ＾１８Ｏ值总体上有逐渐降低的趋势,反映花岗闪长斑岩受到已演化的大气降水水－岩氧同位素交换作用的影响。水－岩交换作用对花岗闪长斑岩氧同位素组成的影响在浅部和深部是不同的,这主要受控于水－岩交换温度和交换水的初始氧同位素组成等因素。石英的氧同位素组成及变化特征不同于全岩和长石,其值与岩石的蚀变作用有关从花岗闪长斑岩的氧同位煮组成及其变化规律可以推论,由大气降水演化为德兴斑岩铜矿成矿热液是可能的。 相似文献
7.
西秦岭南亚带的拉尔玛金成矿带,由拉尔玛、邛莫金矿床和牙相金矿点组成。矿床（点）赋存于寒武系太阳顶群碳质硅岩和碳质板岩组成的硅岩建造中,受地层、岩性、岩相和构造控制十分明显,对其所表现出来的层控性质为众所公认。通过对各金矿床（点）流体氢、氧同位素组成研究之后,作者得出成矿流体乃大气降水的结论。大气降水补给的地下热液在环流过程中,促使硅岩建造中的成矿物质发生活化、迁移和再聚集,并最终导致工业矿床的形成。水－岩体系氢、氧同位素交换演化曲线表明,矿质沉淀时,成矿流体曾发生过沸腾作用。 相似文献
8.
热液体系水-岩作用过程中的氧氢同位素行为 总被引：5，自引：0，他引：5
陈振胜 《大地构造与成矿学》1997,21(1):51-61
论述水-岩作用过程氧氢同位素地球化学行为特征。列举西华山钨矿、台上金矿、白乃庙金矿和额仁陶勒盖银矿的水-岩体系氧（氢）同位素组成特征。论证了开放体系单阶段和二阶段水-岩反应中氧同位素行为接近于封闭体系氧同位素交换演变轨迹，具有成因指示意义，但不具定量意义。探讨了大气降水热液矿床矿体产出位置与氧同位素组成之间关系。本文还指出开放体系中氢同位素动力分馏行为控因复杂，主要由于1H相对富集于各种含氢气体中逃逸出热液体系，使热液体系氢同位素地球化学行为偏离理论演化轨迹，因此氢同位素组成的成因指示意义远不如氧同位素。 相似文献
9.
中国东部大陆浅成热液矿床的H、O同位素地球化学 总被引：1，自引：0，他引：1
浅成热液矿床属于古地热系统。中国东部大陆边缘29个浅成热液矿床的H、O同位素组成特征证实，成矿流体源自当地大气降水。水-岩相互作用同位素交换模拟计算结果表明，浅成热液矿床形成期间水/岩比通常是高的。 相似文献
10.
对青城子铅-锌矿床矿体和围岩的氧、碳、铅、硫同位素系统研究表明,成矿物质初始来源主要是海底火山喷发沉积提供。含矿岩系遭受了变质作用和热液改造作用。从矿床东区→西区,从下部地层→上部地层,碳酸盐岩的氧、碳同位素组成作有规律地递变。印支-燕山期的构造岩浆活动对成矿有一定影响。氧同位素研究表明花岗岩为基底地层深部重熔的S型花岗岩,它提供了部分成矿物质。氧同位素交换水/岩值计算表明,成矿溶液以大气降水为主,混有少量岩浆水。因此,笔者认为该矿床为一沉积-变质-热液叠加改造型层控铅-锌矿床。 相似文献
11.
The Cangyuan Pb-Zn-Ag polymetallic deposit is located in the Baoshan Block, southern Sanjiang Orogen. The orebodies are hosted in low-grade metamorphic rocks and skarn in contact with Cenozoic granitic rocks. Studies on fluid inclusions (FIs) of the deposit indicate that the ore-forming fluids are CO2-bearing, NaCl-H2O. The initial fluids evolved from high temperatures (462–498 °C) and high salinities (54.5–58.4 wt% NaCl equiv) during the skarn stage into mesothermal (260–397 °C) and low salinities (1.2–9.5 wt% NaCl equiv) during the sulfide stage. The oxygen and hydrogen isotopic compositions (δ18OH2O: 2.7–8.8‰; δD: −82 to −120‰) suggest that the ore-forming fluids are mixture of magmatic fluids and meteoric water. Sulfur isotopic compositions of the sulfides yield δ34S values of −2.3 to 3.2‰; lead isotopic compositions of ore sulfides are similar to those of granitic rocks, indicating that the sulfur and ore-metals are derived from the granitic magma. We propose that the Cangyuan Pb-Zn-Ag deposit formed from magmatic hydrothermal fluids. These Cenozoic deposits situated in the west of Lanping-Changdu Basin share many similarities with the Cangyuan in isotopic compositions, including the Laochang, Lanuoma and Jinman deposits. This reveals that the Cenozoic granites could have contributed to Pb-Zn-Cu mineralization in the Sanjiang region despite the abundance of Cenozoic Pb-Zn deposits in the region, such as the Jingding Pb-Zn deposit, that is thought to be of basin brine origin. 相似文献
12.
通过矿床地质特征、流体包裹体及氧、氢稳定同位素的研究,认为马家窑金矿属再平衡岩浆热液矿床,金青顶和十里铺金矿属大气降水热液矿床。马家窑金矿石英的δD、δ18O值高,变化小,比较稳定;蚀变岩石的δ18O在磺向上由围岩向矿脉逐渐升高。金青顶和十里铺金矿石英的δD、δ18O值低、变化大;蚀变岩石的δ18O值由地表向深部逐渐降低。开展金矿的氮稳定同泣素研究,在国内尚数首次。马家窑金矿36Ar在温度300℃以下相对含量不到10%,金青顶和十里铺金矿36Ar则达90%以上,表明前者以岩浆成因40Ar为代表,后者则以大气氩36Ar为代表,进而表明马家窑金矿是再平衡岩浆热液成因,金青顶和十里辅金矿是大气降水热液成因。示踪结果与H、O同位素一致,表明氩同位素在示踪成矿热液、矿床成因研究方面是一种较为有效的手段。 相似文献
13.
河南桐柏老湾金矿床的成矿作用是在变基性火山碎屑沉积岩为矿源层的背景上演化的。本文根据矿床氢氧同位素研究,认为矿床的热液成矿期成矿流体为大气降水和老湾花岗岩岩浆水的混合,成矿Ⅰ阶段和Ⅱ阶段以岩浆水为主,成矿Ⅲ阶段以大气降水为主,但在成矿Ⅱ阶段大气降水已占有很大的比例。氦同位素分析表明,在老湾金矿形成过程中有地幔流体加入,且从成矿Ⅱ阶段至Ⅲ阶段,由于大气降水比例增大,其与地幔流体的混合导致成矿流体的3He/4He比值不断减小。 相似文献
14.
内蒙古金厂沟梁金矿床稳定同位素组成和矿床成因讨论 总被引：7，自引：0，他引：7
稳定同位素的研究对于分析矿床成因、阐明成矿物质来源等具有重要意义。金厂沟梁金矿成矿流体的同位素组成与本区变质岩、岩浆岩的同位素组成具有非常密切的关系,成矿流体的H、O、C、S同位素特征继承了本区变质岩、岩浆岩的H、O、C、S同位素特征,它们的δ18O、δD、δ13C、δ34S值具有相似的变化范围,其同位素的变化规律表明变质岩是本区成矿物质的母岩。本区岩浆构造活动频繁,为成矿物质活化提供了动力条件。成矿模式为本区太古宙变质岩经过多次活化,使成矿物质逐步聚集,到了燕山晚期,岩浆期后热液活动将成矿物质带到构造有利部位聚集形成了金矿床,因此,该矿床属重熔岩浆热液型矿床。 相似文献
15.
The Liziyuan gold deposit, situated on the south side of the Shangdan suture zone, West Qinling Orogen, occurs in metamorphic volcanic rocks(greenschist facies) of the early Paleozoic Liziyuan Group and in Indosinian Tianzishan monzogranite. Orebodies in the Liziyuan gold field are controlled by the ductile-brittle shear zone, and by thrusting nappe faults related to the Indosinian orogeny. In detail, this paper analyzed the geological characteristics of the Liziyuan gold field, and the Pb isotopes of the Lziyuan host rocks, granitoids(Tianzishan monzogranite and Jiancaowan syenite porphyry), sulfides, and auriferous quartz veins by multiple-collector inductively coupled plasma mass spectrometry(MC-ICPMS). In addition, previous data on the sulfur, hydrogen, and oxygen isotopes were employed to discuss the possible sources of the ore-forming fluids and materials, and to further understand the tectonic setting of the Liziyuan gold deposit. The sulfides and their host rocks(Lziyuan Group), Tianzishan monzogranite and Jiancaowan syenite porphyry, and auriferous quartz veins have similar Pb isotopic compositions.Zartman's plumbotectonic model diagram shows that most of the data for the deposit fall near the orogenic Pb evolutionary curve or within the area between the orogenic and mantle Pb evolutionary curves. In the△β-△γ diagram, which genetically classifies the lead isotopes, most of the data fall within the range of the subduction-zone lead mixed with upper crust and mantle. This indicates that a complex source of the ore lead formed in the orogenic environment. The δ~(34)S values of the sulfides range from 3.90 to 8.50‰(average6.80‰), with a pronounced mode at 5.00‰-8.00‰. These values are consistent with that of orogenic gold deposits worldwide, indicating that the sulfur sourced mainly from reduced metamorphic fluids. The isotopic hydrogen and oxygen compositions support a predominantly metamorphic origin of the oreforming fluids, with possible mixing of minor magmatic fluids, but the late stage was dominated by meteoric water. The characteristics of the Liziyuan gold deposit formed in the Indosinian orogenic environment of the Qinling Orogen are consistent with those of orogenic gold deposits found worldwide. 相似文献
16.
《Ore Geology Reviews》2009,35(4):597-609
The magma–ore deposit relationship of most low-sulfidation epithermal ore deposits is still unclear, partly because many stable isotopic studies of such deposits have indicated the predominance of meteoric waters within hydrothermal fluids. However, it is certainly true that hydrothermal systems are ultimately driven by magmatic intrusions, and epithermal gold deposits might therefore be produced by magmatic activity even in deposits having has no obvious links to a magma. We re-examine the genesis of two typical low-sulfidation epithermal gold deposits, the Kushikino and Hishikari deposits, using structural simulations and isotope data.Many epithermal gold deposits including the Kushikino and Hishikari deposits have been discovered in Kyushu, southwestern Japan. The Kushikino deposit comprises fissure-filling veins within Neogene andesitic volcanics that overlie unconformably Cretaceous sedimentary basement. The veins consist of gold- and silver-bearing quartz and calcite with minor amounts of adularia, sericite and sulfides. Although carbon and oxygen isotopic data for the veins indicate a meteoric origin of the ore fluid, finite element simulations suggest that the vein system might have formed in direct response to magma intrusion. In particular, geophysical data suggest that intruding magma has uplifted the basement rocks, thereby producing fractures and veins and a positive Bouguer anomaly, and providing the heat necessary to drive an ore-forming hydrothermal system.The second component of this study has been to investigate the nature and evolution of the Kushikino and Hishikari epithermal systems. Isotope data document the geochemical evolution of the hydrothermal fluids. We conclude that the existence of sedimentary basement rocks at depth might have affected the strontium and carbon isotopic ratios of the Kushikino and Hishikari ore fluids. The 87Sr/86Sr ratios and δ13C–δ18O trend reveal that major ore veins in the Hishikari deposit can be distinguished from shallow barren veins. It was suggested isotopically that fluids responsible for the barren veins in nearby shallow and barren circulation systems were only controlled by the shallow host rocks. Such multi-isotope systematics provide a powerful tool with which to determine the center of hydrothermal activity and thereby document the evolution of hydrothermal fluids. 相似文献
17.
The Chandmani Uul deposit is located in Dornogovi province, Southeastern Mongolia. Iron oxide ores are hosted in the andesitic rocks of the Shar Zeeg Formation of Neoproterozoic to Lower‐Cambrian age. Middle‐ to Upper‐Cambrian bodies of granitic rocks have intruded into the host rocks in the western and southern regions of the deposit. The wall rocks around the iron oxide ore bodies were hydrothermally altered to form potassic, epidote, and sericite–chlorite alteration zones, and calcite and quartz veinlets are ubiquitous in the late stage. Since granitic rocks also underwent potassic alteration, the activity of the granitic rocks must have a genetic relation to the ore deposit. The ore mineral assemblage is dominated by iron oxides such as mushketovite, euhedral magnetite with concentric and/or oscillatory zoning textures, and cauliflower magnetite. Lesser amounts of chalcopyrite and pyrite accompany the iron oxides. Among all these products, mushketovite is dominant and is distributed throughout the deposit. Meanwhile, euhedral magnetite appears in limited amounts at relatively shallow levels in the deposit. By contrast, cauliflower magnetite appears locally in the deeper parts of the deposit, and is associated with green‐colored garnet and calcite. Sulfide minerals are ubiquitously associated with these iron oxides. The oxygen isotope (δ18O) values of all types of magnetite, quartz, and epidote were found to be ?5.9 to ?2.8‰, 10.5 to 14.9‰, and 3.6 to 6.6‰, respectively. The δ18O values of quartz–magnetite pairs suggest an equilibrium isotopic temperature near 300°C. The calculated values of δ18O for the water responsible for magnetite ranged from 2 to 10‰. All the data obtained in this study suggest that the iron oxide deposit at the Chandmani Uul is a typical iron oxide–copper–gold deposit, and that this deposit was formed at an intermediate depth with potassic and sericite–chlorite alteration zones under the oxidized conditions of a hematite‐stable environment. The δ18O range estimated implies that the ore‐forming fluid was supplied by a crystallizing granodioritic magma exsolving fluids at depth with a significant contribution of meteoric water. 相似文献
18.
19.
西秦岭大水金矿的花岗岩成矿作用特征 总被引：14，自引：4，他引：14
西秦岭大水金矿是西秦岭造山带南缘三叠系浅海相碳酸盐岩中新近发现的一类独特的特大型金矿床。矿区侵入岩属花岗岩大类 ,δ <4,ASI >1,属中性—中偏基性过铝质钙碱系列岩石 ,具深源浅成的特征。岩石化学成分δ τ图解以及稀土元素的w(Rb) w (Yb +Nb)和w(Rb) w(Yb +Ta)图解显示其属造山带同碰撞构造环境。金矿石的碳、氢、氧、硅同位素测试结果显示成矿物质来源于深部。矿石为轻稀土富集型 ,配分模式与岩浆岩接近。全岩K Ar同位素年龄表明格尔括合岩体为 190 0～ 190 5Ma ,矿化脉岩为 182 6～ 184 7Ma ,说明成岩与成矿具同源性但主成矿期滞后于脉岩的形成。花岗岩的成矿作用主要体现为 :( 1)沟通深部矿源场和成矿场 ;( 2 )岩浆高热能和岩浆水参与成矿流体的循环 ;( 3)花岗岩的就位机制为“气球膨胀”式 ,并通过就位扩容压缩围岩产生的张性断裂构造控制金矿体的产出。 相似文献
20.
内蒙古甲乌拉大型Pb-Zn-Ag矿床稳定同位素地球化学研究 总被引：2，自引：0，他引：2
内蒙古甲乌拉银多金属矿床位于大兴安岭成矿带北段,为近年来发现的大型银铅锌多金属矿床。矿床矿体分布完全受到断裂构造的控制,金属矿物组成主要为方铅矿、闪锌矿、黄铜矿、黄铁矿、磁黄铁矿、毒砂、辉钼矿及磁铁矿等。文中重点分析了矿床的硫、氢、氧、碳和铅稳定同位素地球化学特征。研究结果表明：金属硫化物δ34S集中为1.37‰~4.10‰,平均为3.10‰(n=13),极差为2.73‰;石英和方解石δ18Owater的变化范围较大(-18.96‰~+1.08‰) (n=9),均值为-11.36‰;δDV SMOW的变化范围比较集中(-133.6‰~-103.4‰) (n=9);27件样品的铅同位素组成为：206Pb/204Pb=18.228 3~18.758 7、207Pb/204Pb=15.457~15.880和208Pb/204Pb=37.841~39.049,矿床的铅组成基本为正常的放射性成因铅;方解石δ13CV PDB变化范围为-5.2‰~-8.4‰,平均为-6.8‰(n=2)。矿石硫化物的硫同位素及方解石的碳同位素均指示成矿物质可能来源于深部的岩浆活动;石英和方解石的氢氧同位素组成表明成矿流体早期以岩浆流体为主,成矿晚期加入了大量加热补给的大气降水;铅同位素组成表明成矿流体中铅的来源主要为幔源,矿床形成过程中混入少量的壳源铅。矿床稳定同位素组成显示成矿流体主要来源于深部的岩浆热液,特别与燕山晚期的火山次火山热液有较为密切的联系,在流体演化过程中大气降水的加入对矿床成矿元素的聚集和沉淀也起到有利作用。成矿作用的发生是在一种总硫浓度比较低、中等氧化环境、相对开放的非平衡体系中进行的。矿床形成的地球动力学背景为一种岩石圈大规模快速减薄的过程。甲乌拉大型Pb Zn Ag矿床的成因类型属于火山次火山热液脉状银多金属矿床。 相似文献