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1.
我国北方地区对流层中下层臭氧收支   总被引：1，自引：0，他引：1       下载免费PDF全文
为了揭示我国北方地区对流层中下层臭氧(O3) 的形成机理以及周边地区的污染输送对我国北方地区对流层中下层O3收支的影响, 在与外场观测数据比较分析的基础上, 利用全球化学输送模式(MOZART-2) 采用收支分析方法定量分析了影响我国北方地区对流层中下层O3的各个物理化学过程。结果表明:我国北方地区对流层下层O3最重要的来源是光化学生成作用, 约占总来源的58.3%(41.5 Tg), 光化学生成反应中HO2对于O3生成的贡献最大; 最大的汇是干沉降过程, 约占总汇的43.2%(26.2Tg); 水平净输送作用对我国北方地区对流层中下层O3收支的影响非常大, 在我国北方地区对流层下层, 41.6%左右的O3来自水平净输送, 随高度增加, 水平输送影响增大, 我国北方地区对流层中层大约81.5%的O3来自水平净输送。  相似文献   

2.
The Asian summer monsoon(ASM) anticyclone is a dominant feature of the circulation in the upper troposphere–lower stratosphere(UTLS) during boreal summer, which is found to have persistent maxima in carbon monoxide(CO). This enhancement is due to the upward transport of air with high CO from the planetary boundary layer(PBL), and confinement within the anticyclonic circulation. With rapid urbanization and industrialization, CO surface emissions are relatively high in the ASM region, especially in India and East China. To reveal the transport pathway of CO surface emissions over these two regions, and investigate the contribution of these to the CO distribution within the ASM anticyclone, a source sensitivity experiment was performed using the Weather Research and Forecasting(WRF) with chemistry model(WRFChem). According to the experiment results, the CO within the ASM anticyclone mostly comes from India, while the contribution from East China is insignificant. The result is mainly caused by the different transportation mechanisms. In India,CO transportation is primarily affected by convection. The surface air with high CO over India is directly transported to the upper troposphere, and then confined within the ASM anticyclone, leading to a maximum value in the UTLS region. The CO transportation over East China is affected by deep convection and large-scale circulation, resulting mainly in transportation to Korea, Japan, and the North Pacific Ocean, with little upward transport to the anticyclone, leading to a high CO value at215 h Pa over these regions.  相似文献   

3.
Climate changes induced by human activities have attracted a great amount of attention. With this, a coupling system of an atmospheric chemistry model and a climate model is greatly needed in China for better understanding the interaction between atmospheric chemical components and the climate. As the first step to realize this coupling goal, the three-dimensional global atmospheric chemistry transport model MOZART-2 (the global Model of Ozone and Related Chemical Tracers, version 2) coupled with CAM2 (the Community Atmosphere Model, version 2) is set up and the model results are compared against observations obtained in East Asia in order to evaluate the model performance. Comparison of simulated ozone mixing ratios with ground level observations at Minamitorishima and Ryori and with ozonesonde data at Naha and Tateno in Japan shows that the observed ozone concentrations can be reproduced reasonably well at Minamitorishima but they tend to be slightly overestimated in winter and autumn while underestimated a little in summer at Ryori. The model also captures the general features of surface CO seasonal variations quite well, while it underestimates CO levels at both Minamitorishima and Ryori. The underestimation is primarily associated with the emission inventory adopted in this study. Compared with the ozonesonde data, the simulated vertical gradient and magnitude of ozone can be reasonably well simulated with a little overestimation in winter, especially in the upper troposphere. The model also generally captures the seasonal, latitudinal and altitudinal variations in ozone concentration. Analysis indicates that the underestimation of tropopause height in February contributes to the overestimation of winter ozone in the upper and middle troposphere at Tateno.  相似文献   

4.
On the basis of original 2-D coupled model,36 species and 83 reactions about NMHCs areadded.By using this model,the budgets of ozone,carbon monoxide and methane in thetroposphere are analyzed.The results show that the amount of ozone transported from thestratosphere to the troposphere is about 1340 Tg/a,its producing rate in troposphere is about 1190Tg/a and the amount of ozone cleared by the dry deposition in troposphere is 1700Tg/a.Introposphere,the ozone is mainly produced at lower level in middle latitudes of the NorthernHemisphere and at upper levels in tropics.  相似文献   

5.
On the basis of original 2-D coupled model,36 species and 83 reactions about NMHCs are added.By using this model,the budgets of ozone,carbon monoxide and methane in the troposphere are analyzed.The results show that the amount of ozone transported from the stratosphere to the troposphere is about 1340 Tg/a,its producing rate in troposphere is about 1190 Tg/a and the amount of ozone cleared by the dry deposition in troposphere is 1700Tg/a.In troposphere,the ozone is mainly produced at lower level in middle latitudes of the Northern Hemisphere and at upper levels in tropics.  相似文献   

6.
By means of a three-dimensional meteorological model (MM5) and a chemical model,the distributions of tropospheric ozone and its precursors over China have been simulated in summer and winter time,16-18 August 1994 and 7-9 January 1995.The distribution of ozone over the Tibetan Plateau in summer time is deeply discussed.The simulated results indicate that thedistributions of surface ozone and NOx are in good agreement with observed results,and human activities and photochemical reactions are the main factors controlling the surface ozone and NOx concentrations.In addition,higher ozone concentrations are coincided with the air convergence,and the lower concentrations are related to the air divergence.In summer,over the Tibetan Plateau the strong flow convergence results in higher ozone concentrations in the lower troposphere:and the strong flow divergence results in lower ozone concentrations in the upper troposphere.In winter time ozone concentrations show large-scale characteristics controlled by westerly flow,and in the jet area they are lower than those outside the jet.  相似文献   

7.
末次冰期冰盛期中国地区水循环因子变化的模拟研究   总被引：2，自引：1，他引：1  
刘煜  李维亮  何金海  陈隆勋 《气象学报》2008,66(6):1005-1019
ISCCP卫星资料(1983—2006年)的结果显示:青藏高原地区是高云的高值中心;而以四川为中心直到同纬度的中国东南沿海地区是中云的高值区,同时,青藏高原地区是中云的低值中心。利用全球气候模式CCM3嵌套区域模式MM5模拟了现代和末次冰期冰盛期的气候。MM5模拟的结果与ISCCP的卫星资料对比表明:模拟结果再现了中国地区高云和中云分布的主要特征。这暗示云分布的气候特征可能主要由相对湿度决定。同时,通过MM5的结果与NCEP资料的对比也说明,模式可以较好地模拟水汽和温度的垂直分布。在此基础上,研究了末次冰期冰盛期水循环因子的变化。模拟结果显示:末次冰期冰盛期夏季对流层的温度降低,在对流层中上层存在温度降低的中心;而在冬季在南方的对流层中层存在降温中心,在北方的对流层中上层温度升高。大气中水汽含量与温度变化有很好的正相关,除了冬季北方对流层中上层水汽增加外,水汽含量一般降低,而且在近地层降低的最多,随高度增高水汽变化逐渐变小。但是,水汽的相对变化在对流层上层存在降低的高值中心。相对湿度存在变化,最大的变化超过15%,而且有增加,也有减少。在区域尺度相对湿度不是保守的。相对湿度变化与中云和低云的变化一致。在末次冰期冰盛期,中国地区高云量减少,除中国西南地区外,中云和低云量减少,低云量减少的最多。降水的变化与中云和低云的变化相对应,云量增加降水增加,云量减少降水也减少。从相对湿度和有效降水可以看到在西南地区末次冰期冰盛期变得潮湿,在夏季西北地区也变得潮湿。  相似文献   

8.
Using radiosonde and satellite observations, we investigated the trends of air temperature changes over the Tibetan Plateau （TP） in comparison with those over other regions in the same latitudes from 1979 to 2002. It is shown that Over the TP, the trends of air temperature changes in the upper troposphere to lower stratosphere were out of phase with those in the lower to middle troposphere. Air temperature decreased and a decreasing trend appeared in the upper troposphere to lower stratosphere. The amplitude of the annual or seasonal mean temperature decreases over the TP was larger than that over the whole globe. In the lower to middle troposphere over the TP, temperature increased, and the increasing trend was stronger than that over the non-plateau regions in the same latitudes in the eastern part of China. Meanwhile, an analysis of the satellite observed ozone data in the same period of 1979-2002 shows that over the TP, the total ozone amount declined in all seasons, and the ozone depleted the most compared with the situations in other regions in the same latitudes. It is proposed that the difference between the ozone depletion over the TP and that over other regions in the same latitudes may lead to the difference in air temperature changes. Because of the aggravated depletion of ozone over the TP, less （more） ultraviolet radiation was absorbed in the upper troposphere to lower stratosphere （lower to middle troposphere） over the TP, which favored a stronger cooling in the upper troposphere to lower stratosphere, and an intenser heating in the lower to middle troposphere over the TP. Therefore, the comparatively more depletion of ozone over the TP is possibly a reason for the difference between the air temperature changes over the TP and those over other regions in the same latitudes.  相似文献   

9.
Based on the International Satellite Cloud Climatology Project (ISCCP) data in 1983–2006,it is found that there is a high value center of high cloud amount over the Tibetan Plateau (TP),while there is a high value center of middle cloud amount over the Sichuan Basin extending to the coastal area of southeastern China along the same latitude,and a low one over the TP.The present day (PD) and Last Glacial Maximum (LGM) climates are simulated by using the NCAR Community Climate Model (CCM3) nested with a regio...  相似文献   

10.
张人禾  周顺武 《气象学报》2008,66(6):916-925
利用台站探空观测资料和卫星观测资料,分析了1979—2002年青藏高原上空温度的变化趋势。结果表明:高原地区上空平流层低层和对流层上层的温度与对流层中低层具有反相变化趋势。平流层低层和对流层上层降温,温度出现降低趋势,降温幅度无论是年平均还是季节平均都比全球平均降温幅度更大。高原上空对流层中低层增温,温度显示出增加的趋势,并且比同纬度中国东部非高原地区有更强的增温趋势。对1979—2002年卫星臭氧资料的分析表明,青藏高原上空臭氧总量在每个季节都呈现出明显的下降趋势,并且比同纬度带其他地区下降得更快。由于青藏高原上空臭氧有更大幅度的减少,造成高原平流层对太阳紫外辐射吸收比其他地区更少,使进入对流层的辐射更多,从而导致高原上空平流层低层和对流层上层降温比其他地区更强,而对流层中低层增温更大。因此,高原上空比其他地区更大幅度的臭氧总量减少可能是造成青藏高原上空与同纬度其他地区温度变化趋势差异的一个重要原因。  相似文献   

11.
Summary Analysis of ozonesonde data shows that in the lower troposphere above Hong Kong, there is a relative maximum with respect to height in all seasons except winter. In the upper troposphere, there is with respect to height a relative minimum in the seasonally averaged ozone mixing ratio in winter. Ozone mixing ratios in the upper troposphere in winter and spring can be significantly enhanced by stratospheric intrusions associated with the passage of cold fronts and upper cut-off lows.For Hong Kong, the seasonally averaged total ozone has the highest value in spring, and the lowest in winter. The seasonally averaged total tropospheric ozone also has the highest value in spring, but the lowest in summer. In a relative sense, total tropospheric ozone contributes most to the total ozone in spring and the least in summer.The phase of the total ozone anomaly above Hong Kong is influenced by the Quasi-Biennial Oscillation (QBO), with the positive anomaly associated with the easterly phase of QBO, and the negative anomaly the westerly phase.  相似文献   

12.
A 3-D chemical transport model (OSLO CTM2) is used to investigate the impact of the increase of NOx emission over China. The model is capable to reproduce basically the seasonal variation of surface NOx and ozone over eastern China. NOx emission data and observations reveal that NOx over eastern China increases quite quickly with the economic development of China. Model results indicate that NOx concentration over eastern China increasingly rises with the increase of NOx emission over China, and accelerates to increase in winter. When the NOx emission increases from 1995 to its double, the ratio of NO2/NOx abruptly drops in winter over northern China. Ozone at the surface decreases in winter with the continual enhancement of the NOx level over eastern China, but increases over southern China in summertime. It is noticeable that peak ozone over northern China increases in summer although mean ozone changes little. In summer, ozone increases in the free troposphere dominantly below 500 hPa.Moreover, the increases of total ozone over eastern China are proportional to the increases of NOx emission.In a word, the model results suggest that the relationship between NOx and ozone at the surface would change with NOx increase.  相似文献   

13.
基于2005、2006年夏季大气微波临边探测仪(MLS)探测的青藏高原上对流层-下平流层(UT/LS)一氧化碳(CO)和臭氧浓度数据,分析了其浓度的季节内变化特征并对可能机制进行了初步探讨。结果表明,青藏高原及其周边区域UT/LS是大气痕量成分的异常区,具有对流层特性的一氧化碳和具有平流层特性的臭氧在时间变化呈现出反位相变化特征;UT/LS大气成分的变化存在两个主要季节内振荡(ISO)周期,即10～20天和30～60天,但不同的高度上具有不同的表现特征,UT主要表现为10～20天的季节内振荡,而LS主要表现为30～60天的季节内振荡;这两个振荡周期分别和夏季对流活动以及南亚高压的季节内变化具有同位相特征,说明上述两个因子可能是影响该区域不同高度的大气痕量成分季节内振荡的两个主要动力过程。   相似文献   

14.
Total column ozone (TCO) over the Tibetan Plateau (TP) is lower than that over other regions at the same latitude, particularly in summer. This feature is known as the “TP ozone valley”. This study evaluates long-term changes in TCO and the ozone valley over the TP from 1984 to 2100 using Coupled Model Intercomparison Project Phase 6 (CMIP6). The TP ozone valley consists of two low centers, one is located in the upper troposphere and lower stratosphere (UTLS), and the other is in the middle and upper stratosphere. Overall, the CMIP6 models simulate the low ozone center in the UTLS well and capture the spatial characteristics and seasonal cycle of the TP ozone valley, with spatial correlation coefficients between the modeled TCO and the Multi Sensor Reanalysis version 2 (MSR2) TCO observations greater than 0.8 for all CMIP6 models. Further analysis reveals that models which use fully coupled and online stratospheric chemistry schemes simulate the anticorrelation between the 150 hPa geopotential height and zonal anomaly of TCO over the TP better than models without interactive chemistry schemes. This suggests that coupled chemical-radiative-dynamical processes play a key role in the simulation of the TP ozone valley. Most CMIP6 models underestimate the low center in the middle and upper stratosphere when compared with the Microwave Limb Sounder (MLS) observations. However, the bias in the middle and upper stratospheric ozone simulations has a marginal effect on the simulation of the TP ozone valley. Most CMIP6 models predict the TP ozone valley in summer will deepen in the future.  相似文献   

15.
利用东亚清洁背景站近地面臭氧观测资料,结合风场和降水资料,分析东亚各地区臭氧的多年季节变化特征,并探讨东亚太平洋地区臭氧的季节和年际变化与季风的关系以及影响近地层臭氧的主要因子。结果表明：东亚大部分地区与北半球背景站观测一致,近地层臭氧季节变化表现为春季最高、夏季最低的特征;但在东亚中纬度33～43°N,臭氧表现为夏季最高,而在东亚20°N以南地区臭氧则表现为冬末、春初最高。东亚太平洋沿岸近地面臭氧的季节变化主要受东亚冬、夏季风环流的季节变化控制。该地区不同纬度上春季峰值出现时间的差异与亚洲大陆春季不同时期污染物输送路径的差异有关。对东亚太平洋沿岸对流层顶附近位势涡度、高空急流和垂直环流季节变化的分析表明,冬春季可能是平流层向对流层输送的最强期,对近地面臭氧贡献最大。初夏至秋季（5-11月）,平流层向对流层输送较弱,对近地面臭氧贡献较小。东亚太平洋地区夏季风爆发的时间和强度以及季风环流型的年际差异是导致该地区春、夏季臭氧年际变化的主要原因;而季风降水和云带位置以及平流层一对流层交换是造成臭氧年际变化的其他原因。  相似文献   

16.
ＯｚｏｎｅＶｅｒｔｉｃａｌＰｒｏｆｉｌｅＣｈａｒａｃｔｅｒｉｓｔｉｃｓｏｖｅｒＱｉｎｇｈａｉＰｌａｔｅａｕＭｅａｓｕｒｅｄｂｙＥｌｅｃｔｒｏｃｈｅｍｉｃａｌＣｏｎｃｅｎｔｒａｔｉｏｎＣｅｌＯｚｏｎｅｓｏｎｄｅｓ①ＬｉｕＱｉｊｕｎ（刘奇俊），Ｚｈｅｎｇ...  相似文献   

17.
未来百年夏季青藏高原臭氧变化趋势及可能机制   总被引：1，自引：0，他引：1       下载免费PDF全文
利用全大气气候通用模式(WACCM3)对政府间气候变化专门委员会排放情景特别报告中2001年到2099年A1B、A2、B1三种排放情景进行了模拟,分析了三种排放情景下青藏高原地区未来百年臭氧总量在夏季(6—8月)的变化趋势及引起该变化的可能机制。结果表明:在三种排放情景下未来百年夏季高原区臭氧总量均呈现增长趋势,其中A2情景下臭氧增长最快,B1情景下增长最慢,但相对于同纬度其他地区,高原区的臭氧总量增长较慢,即高原区臭氧谷加深。高原区高空污染物的减少以及局域Hadley环流的减弱是未来高原区臭氧总量增加的原因;而南亚高压的增强,以及与之相对应的辐散增强则可能是高原区臭氧谷继续加深的原因。  相似文献   

18.
During the summer (8 June through 3 September) of 2008, 9 ozone profiles are examined from Dakar, Senegal (14.75°N, 17.49°W) to investigate ozone (O3) variability in the lower/middle troposphere during the pre-monsoon and monsoon periods. Results during June 2008 (pre-monsoon period) show a reduction in O3 concentrations, especially in the 850–700 hPa layer with Saharan Air Layer (SAL) events. However, O3 concentrations are increased in the 950–900 hPa layer where the peak of the inversion is found and presumably the highest dust concentrations. We also use the WRF-CHEM model to gain greater insights for observations of reduced O3 concentrations during the monsoon periods. In the transition period between 26 June and 2 July in the lower troposphere (925–600 hPa), a significant increase in O3 concentrations (10–20 ppb) occur which we suggest is caused by enhanced biogenic NOX emissions from Sahelian soils following rain events on 28 June and 1 July. The results suggest that during the pre-monsoon period ozone concentrations in the lower troposphere are controlled by the SAL, reducing ozone concentrations through heterogeneous chemical processes. At the base of the SAL we also find elevated levels of ozone, which we attribute to biogenic sources of NOX from Saharan dust that are released in the presence of moist conditions. Once the monsoon period commences, lower ozone concentrations are observed and modeled which we attribute to the dry deposition of ozone and episodes of ozone poor air that is horizontally transported into the Sahel from low latitudes by African Easterly Waves (AEWs).  相似文献   

19.
The ozone concentration near the earth's surface has been measured at some stations in the GDR for more than 30 yr using the wet chemical method. Even at rural stations the ozone data show a significant linear increase by about 1–3% yr–1. The ozone increase being stronger in summer than in winter is assumed to be due to photochemical ozone production from increasing anthropogenic emissions of trace gases that are transported over long distances. A weaker ozone increase by only about 0.2% per year was observed in the free troposphere (5.5 km) from balloon-soundings at Lindenberg within the period 1975–1984. If the ozone trends continue, the ozone concentration near the surface and its seasonal amplitude will have doubled around the turn of the century as compared to the mid-fifties.  相似文献   

20.
Growth in subsonic air traffic over the past 20 years has been dramatic, with an annual increase of }6.1% over the decade between 1978 and 1988. Furthermore, aircraft activities in the year 2000 are predicted to be double those of 1990, with a shift towards more high-flying, longhaul subsonics. Aircraft exhaust gases increase the amount of nitrogen oxides (NO x ) in the upper troposphere/lower stratosphere through injection at cruise altitudes. Given that NO x is instrumental in tropospheric ozone production and stratospheric ozone destruction, it is important to determine the influence of subsonic aircraft NO x emissions on levels of atmospheric ozone. This paper describes calculations designed to investigate the impact that subsonic aircraft may already have had on the atmosphere during the 1980s, run in a 2-D chemical-radiative-transport model. The results indicate a significant increase in upper tropospheric ozone over the decade arising from aircraft emissions. However, when comparing model results with observational data, certain discrepancies appear. Lower stratospheric ozone loss over the 1980s does not appear to be greatly altered by the inclusion of aircraft emissions in the model. However, given the trend in greater numbers of long-haul subsonic aircraft, this factor must be considered in any further calculations.  相似文献   

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