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1.
Lateral inflows control the spatial distribution of river discharge, and understanding their patterns is fundamental for accurately modelling instream flows and travel time distributions necessary for evaluating impacts of climate change on aquatic habitat suitability, river energy budgets, and fate of dissolved organic carbon. Yet, little is known about the spatial distribution of lateral inflows in Arctic rivers given the lack of gauging stations. With a network of stream gauging and meteorological stations within the Kuparuk River watershed in northern Alaska, we estimated precipitation and lateral inflows for nine subcatchments from 1 July to 4 August,2013, 2014, and 2015. Total precipitation, lateral inflows, runoff ratios (area-normalized lateral inflow divided by precipitation), percent contribution to total basin discharge, and lateral inflow per river kilometre were estimated for each watershed for relatively dry, moderate, or wet summers. The results show substantial variability between years and subcatchments. Total basin lateral inflow depths ranged 24-fold in response to a threefold change in rainfall between dry and wet years, whereas within-basin lateral inflows varied fivefold from the coastal plain to the foothills. General spatial trends in lateral inflows were consistent with previous studies and mean summer precipitation patterns. However, the spatially distributed nature of these estimates revealed that reaches in the vicinity of a spring-fed surficial ice feature do not follow general spatial trends and that the coastal plain, which is typically considered to produce minimal runoff, showed potential to contribute to total river discharge. These findings are used to provide a spatially distributed understanding of lateral inflows and identify watershed characteristics that influence hydrologic responses.  相似文献   

2.
River regulation and river training have been performed for various purposes and negative effects have been shown in numerous cases. In some cases the negative effects are so serious that humans have to consider to "renaturalize" the regulated rivers. Only by using the strategy of integrated river management the diverse river uses and natural fluvial processes and ecological systems may be harmonized. Based on analysis of case studies and data collected from literatures this paper presents the concept of integrated river management and four principles of river training. The integrated river management comprises: 1) taking the watershed, upper stream basin including the tributaries, middle and lower reaches and the estuary as an integrated entity in the planning, design and management; and 2) mitigating or controlling the negative impacts on hydrology, erosion and sedimentation, fluvial processes, land use and river use, environment and ecology while in achieving economic benefit from water resources development, flood safety management and hydropower exploitation. River training and management should be in accordance with the four principles: 1) extending the duration of river water flowing on the continent, which may be achieved by extending the river course or reducing the flow velocity; 2) controlling various patterns of erosions and reducing the sediment transportation in the rivers; 3) increasing the diversity of habitat and enhancing the connectivity between the river and riparian waters; and 4) restoring natural landscapes.  相似文献   

3.
Nonpoint sources of nitrogen (N) and other nutrients are a major source of water pollution within the Chesapeake Bay watershed and other basins around the world. Human activities associated with agricultural practices can account for a large percentage of N loadings delivered to streams and rivers. This work aims to improve understanding of N transport from groundwater to surface waters, quantifying the principal hydrological processes driving water and N fluxes into and out of a headwater agricultural stream reach. The study site is a 175-m stream reach in a heavily cultivated 40-ha watershed in east-central Pennsylvania. This subwatershed is underlain by fractured shale bedrock, and receives most of its baseflow from groundwater, either by diffuse matrix discharge through the streambed or by localized discharge through riparian seeps. Samples of stream, seep, and shallow groundwater were collected approximately monthly under steady hydrologic conditions in 2017. Calculated matrix flow from hydraulic head and conductivity measurements paired with differential stream gauging was used to solve for the riparian seep flux using a mass balance approach. Riparian seep fluxes ranged from 45 to 217 m3/d, transporting 0.6–4.2 kg N d−1 of nitrate-N from the fractured bedrock aquifer to the stream. Hydrochemical data suggest that the stream is mainly disconnected from the underlying aquifer and that seeps supply essentially all water and N to the system. Seeps are likely sourced with N in nearby agricultural fields and accelerated through the system with shorter residence times than shallow groundwater. Water isotope data reinforced this notion. This study underscores the importance of agriculture as a source of N to ground and surface waters. Identifying source areas that are causing groundwater enrichment of N and seep areas where N discharges to streams is beneficial for developing N pollution mitigation strategies and implementing management practices that aim to reduce nutrient loads to the Chesapeake Bay.  相似文献   

4.
At watershed extents, our understanding of river form, process and function is largely based on locally intensive mapping of river reaches, or on spatially extensive but low density data scattered throughout a watershed (e.g. cross sections). The net effect has been to characterize streams as discontinuous systems. Recent advances in optical remote sensing of rivers indicate that it should now be possible to generate accurate and continuous maps of in‐stream habitats, depths, algae, wood, stream power and other features at sub‐meter resolutions across entire watersheds so long as the water is clear and the aerial view is unobstructed. Such maps would transform river science and management by providing improved data, better models and explanation, and enhanced applications. Obstacles to achieving this vision include variations in optics associated with shadows, water clarity, variable substrates and target–sun angle geometry. Logistical obstacles are primarily due to the reliance of existing ground validation procedures on time‐of‐flight field measurements, which are impossible to accomplish at watershed extents, particularly in large and difficult to access river basins. Philosophical issues must also be addressed that relate to the expectations around accuracy assessment, the need for and utility of physically based models to evaluate remote sensing results and the ethics of revealing information about river resources at fine spatial resolutions. Despite these obstacles and issues, catchment extent remote river mapping is now feasible, as is demonstrated by a proof‐of‐concept example for the Nueces River, Texas, and examples of how different image types (radar, lidar, thermal) could be merged with optical imagery. The greatest obstacle to development and implementation of more remote sensing, catchment scale ‘river observatories’ is the absence of broadly based funding initiatives to support collaborative research by multiple investigators in different river settings. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

5.
Surface water oxygen and hydrogen isotopic values are commonly used as proxies of precipitation isotopic values to track modern hydrologic processes while proxies of water isotopic values preserved in lake and river sediments are used for paleoclimate and paleoaltimetry studies. Previous work has been able to explain variability in USA river‐water and meteoric‐precipitation oxygen isotope variability with geographic variables. These studies show that in the western United States, river‐water isotopic values are depleted relative to precipitation values. In comparison, the controls on lake‐water isotopic values are not well constrained. It has been documented that western United States lake‐water input values, unlike river water, reflect the monthly weighted mean isotopic value of precipitation. To understand the differing controls on lake‐ and river‐water isotopic values in the western United States, we examine the seasonal distribution of precipitation, evaporation and snowmelt across a range of seasonality regimes. We generate new predictive equations based on easily measured factors for western United States lake‐water, which are able to explain 69–63% of the variability in lake‐water hydrogen and oxygen isotopic values. In addition to the geographic factors that can explain river and precipitation values, lake‐water isotopic values need factors related to local hydrologic and climatic characteristics to explain variability. Study results suggest that the spring snowmelt runs off the landscape via rivers and streams, depleting river and stream‐water isotopic values. By contrast, lakes receive seasonal contributions of precipitation in proportion to the seasonal fraction of total annual precipitation within their watershed. Climate change may alter the ratio of snow to rain fall, affecting water resource partitioning between rivers and lakes and by implication of groundwater. Paleolimnological studies must account for the multiple drivers of water isotopic values; likewise, studies based on the isotopic composition of fossil material need to distinguish between species that are associated with rivers versus lakes. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

6.
流域水系自动提取的方法和应用   总被引:31,自引:3,他引:28  
李昌峰  冯学智  赵锐 《湖泊科学》2003,15(3):205-212
讨论由栅格数字高程模型(DEM)自动提取流域水系的原理和方法,并以西苕溪中上游流域为研究区进行了河网生成实验. 研究表明:在山地丘陵区和平均地形坡度不小于3°的区域,所生成河网具有很高的可靠性. 为了解决在平均地形坡度小于3°的平坦区域河网生成中产生的虚拟河网与自然水系偏差较大的问题,提出了利用主干河道和平原水系数字化作为约束条件的生成河网的方法,取得了与实际情况比较接近的结果,从而使水文要素的模拟更具有实际意义.  相似文献   

7.
如何表达流域复杂的系统结构是实现流域信息与模型集成,构建流域决策支持系统需要研究的首要问题.在分析现有流域数据库存在问题的基础上,以太湖流域西南部的西苕溪流域为研究区,采用面向对象的Geodatabase地理数据技术,通过分析流域系统的组成要素及过程,提出面向流域水文、水质应用需求的数据库信息组织体系;应用Arcgis的Archydro水文分析模块,基于国家基础地理数据库中的数字地形提取流域要素信息,构建了包括河流流线、集水区出水口、监测台站位置、湖库出口等要素的完整水文网络,并分析水文网络要素上下游关系,对流域集水区与河流的水力联系进行表达;通过分析流域监测台站空间信息、监测项目、时间序列的信息特征,设计Geodatabase的表结构和连接类,实现流域空间特征与状态序列的一体化表达,研究可以为流域数据库建设及流域决策支持系统信息平台构建提供一些技术参考.  相似文献   

8.
Most terrestrial allochthonous organic matter enters river networks through headwater streams during high flow events. In headwaters, allochthonous inputs are substantial and variable, but become less important in streams and rivers with larger watersheds. As allochthonous dissolved organic matter (DOM) moves downstream, the proportion of less aromatic organic matter with autochthonous characteristics increases. How environmental factors converge to control this transformation of DOM at a continental scale is less certain. We hypothesized that the amount of time water has spent travelling through surface waters of inland systems (streams, rivers, lakes, and reservoirs) is correlated to DOM composition. To test this hypothesis, we used established river network scaling relationships to predict relative river network flow-weighted travel time (FWTT) of water for 60 stream and river sites across the contiguous United States (3090 discrete samples over 10 water years). We estimated lentic contribution to travel times with upstream in-network lake and reservoir volume. DOM composition was quantified using ultraviolet and visible absorption and fluorescence spectroscopy. A combination of FWTT and lake and reservoir volume was the best overall predictor of DOM composition among models that also incorporated discharge, specific discharge, watershed area, and upstream channel length. DOM spectral slope ratio (R2 = 0.77) and Freshness Index (R2 = 0.78) increased and specific ultraviolet absorbance at 254 nm (R2 = 0.68) and Humification Index (R2 = 0.44) decreased across sites as a function of FWTT and upstream lake volume. This indicates autochthonous-like DOM becomes continually more dominant in waters with greater FWTT. We assert that river FWTT can be used as a metric of the continuum of DOM composition from headwaters to rivers. The nature of the changes to DOM composition detected suggest this continuum is driven by a combination of photo-oxidation, biological processes, hydrologically varying terrestrial subsidies, and aged groundwater inputs.  相似文献   

9.
针对当前城市化所引起水系衰减、河流连通受阻以及由此所引起洪涝与水环境的问题,以秦淮河中、下游为例,选取1979和2006年两期流域遥感影像,分析了城市化影响下的下垫面变化特征;选取1980s和2009年的地形图对河流水系进行提取,借鉴景观生态学中河流廊道空间结构分析方法,通过不同时期水系分级,探讨了城市化对水系结构及其连通性的影响.结果表明:(1)城市化使得2006年城镇用地面积相比1979年增加84.54 km2,增加了9倍多,大量林草地、耕地以及水域转变成城镇用地;(2)河流长度在过去的30年里减少了41%,河道主干化趋势明显;河流发育呈现由多元到单一、由复杂到简单的趋势;(3)连通性参数连接率、实际结合度分别由原来的1.28、0.43下降到0.79、0.26,河流的连通性呈下降趋势.该研究将为城市化地区河流水系保护提供支持与参考.  相似文献   

10.
11.
Contemporary watershed management practices can reflect oversimplifications of relationships between anthropogenic pressures and resource degradation. Remediation and restoration efforts often focus on recent land use practices as the primary driver of hydrologic regime changes. We present a case study that serves as an example to the scientific and watershed management communities of the lasting influences of historic land use practices and natural physical processes on a stream in the central United States listed as impaired by the federal government. Abnormal spatiotemporal streamflow relationships, determined by means of an experimental watershed study, alerted the authors to possible sink/source behavior in the upper‐watershed. Subsequent research uncovered archival evidence of coal mining, which may provide at least partial explanation. Additional investigation identified hydrologic processes associated with natural landscape evolution, noted by early‐20th‐century researchers, which are considered in the context of the current water quality and flow regime. Despite best‐intended management practices, regulatory agencies, scientists, and local decision makers have not accounted for such practices and processes, instead relying on recent development as the proximate cause of designated impairment. We present argumentation that historic land use (coal mining) and landscape processes comprise cumulative yet unconsidered legacy effects that contribute systemically to the observed hydrologic regime of the watershed. Results hold important implications for contemporary watershed management, and support rethinking the case‐by‐case appropriateness of federal and state water impairment listings, and the achievability of restoration efforts in many developing watersheds.  相似文献   

12.
Long-term experimental watershed studies have significantly influenced our global understanding of hydrological processes. The discovery and characterization of how stream water quantity and quality respond to a changing environment (e.g. land-use change, acidic deposition) has only been possible due to the establishment of catchments devoted to long-term study. One such catchment is the Fernow Experimental Forest (FEF) located in the headwaters of the Appalachian Mountains in West Virginia, a region that provides essential freshwater ecosystem services to eastern and mid-western United States communities. Established in 1934, the FEF is among the earliest experimental watershed studies in the Eastern United States that continues to address emergent challenges to forest ecosystems, including climate change and other threats to forest health. This data note describes available data and presents some findings from more than 50 years of hydrologic research at the FEF. During the first few decades, research at the FEF focused on the relationship between forest management and hydrological processes—especially those related to the overall water balance. Later, research included the examination of interactions between hydrology and soil erosion, biogeochemistry, N-saturation, and acid deposition. Hydro-climatologic and water quality datasets from long-term measurements and data from short-duration studies are publicly available to provide new insights and foster collaborations that will continue to advance our understanding of hydrology in forested headwater catchments. As a result of its rich history of research and abundance of long-term data, the FEF is positioned to continue to advance understanding of forest ecosystems in a time of unprecedented change.  相似文献   

13.
Dividing rivers into homogeneous reaches is key for river processes and watershed management. In contrast to downstream fluvially dominated rivers, upstream debris-flow dominated torrents have steeper channel slopes and smaller valley width/depth ratios. Investigating transition reaches between torrents and fluvially dominated rivers, not only explores the structure of the landscape, but also contributes to hazard management. This study proposed a valley morphology index combining two variables, channel slope and valley width/depth ratio, to determine transition reaches between torrents and rivers. The methodology was applied to 41 mountain streams in Taiwan using a Geographic Information System (GIS)-based topographic analysis. Plots of valley width/depth ratio versus channel slope were used to determine boundary values of the valley morphology index (Iv) separating torrents from rivers. The plots showed that about 80% of the river basins present “L-shaped” curves, which indicate sharp decreases in slope for upstream sections and dramatic increases of valley width/depth ratio for downstream sections. Results further demonstrated an average value of Iv 0.0047 across the study sites. Spatial comparison between geographic regions indicated that transition reaches in eastern rivers tend to occur lower in the drainage basin due, in part, to higher terrain. Local factors, such as tributary confluences and landslides promote the transition from torrents to fluvially dominated rivers. Satellite images verified that the approach correctly identified transition reaches, suggesting that it may provide a useful reference for river management.  相似文献   

14.
Urbanization threatens headwater stream ecosystems globally. Watershed restoration practices, such as infiltration‐based stormwater management, are implemented to mitigate the detrimental effects of urbanization on aquatic ecosystems. However, their effectiveness for restoring hydrologic processes and watershed storage remains poorly understood. Our study used a comparative hydrology approach to quantify the effects of urban watershed restoration on watershed hydrologic function in headwater streams within the Coastal Plain of Maryland, USA. We selected 11 headwater streams that spanned an urbanization–restoration gradient (4 forested, 4 urban‐degraded, and 3 urban‐degraded) to evaluate changes in watershed hydrologic function from both urbanization and watershed restoration. Discrete discharge and continuous, high‐frequency rainfall‐stage monitoring were conducted in each watershed. These datasets were used to develop 6 hydrologic metrics describing changes in watershed storage, flowpath connectivity, or the resultant stream flow regime. The hydrological effects of urbanization were clearly observed in all metrics, but only 1 of the 3 restored watersheds exhibited partially restored hydrologic function. At this site, a larger minimum runoff threshold was observed relative to the urban‐degraded watersheds, suggesting enhanced infiltration of stormwater runoff within the restoration structure. However, baseflow in the stream draining this watershed remained low compared to the forested reference streams, suggesting that enhanced infiltration of stormwater runoff did not recharge subsurface storage zones contributing to stream baseflow. The highly variable responses among the 3 restored watersheds were likely due to the spatial heterogeneity of urban development, including the level of impervious cover and extent of the storm sewer network. This study yielded important knowledge on how restoration strategies, such as infiltration‐based stormwater management, modulated—or failed to modulate—hydrological processes affected by urbanization, which will help improve the design of future urban watershed management strategies. More broadly, we highlighted a multimetric approach that can be used to monitor the restoration of headwater stream ecosystems in disturbed landscapes.  相似文献   

15.
Watershed disturbances caused by land use/land cover(LU/LC) change, intensive forestry practices, and other forms of watershed disturbance are known to negatively affect water quality, if best management practices(BMPs) are not present. Disturbances near or around headwaters where BMPs are absent or are inadequate may impact downstream water quality and stream ecology regardless of the presence of downstream BMPs. In this study, the recovery of two small forest-dominated watersheds(Ww and Ew) in Auburn, Alabama, USA, was monitored 6-years after a partial clearcut was done. The streamside management zone(SMZ) in Ww was also partially harvested shortly after the partial clearcut to improve its sediment trapping effectiveness over the long-term. The hydrology and sediment transport in these watersheds were expected to stabilize over this period, however, new disturbances in the headwaters of both watersheds changed the watershed dynamics. Streamflow and sediment load were examined over a15-month period from February 2014 to May 2015. The clearcut in Ww and Ew, and the partially harvested SMZ in Ww seemed to have recovered; however, substantial amount of sediment load were measured across all monitoring sites in both watersheds as a result of upstream disturbances. This study emphasizes the necessity of watershed management as a whole, and the importance of BMP applications within the entire watershed. It also highlights the fact that watershed management and BMP implementation is a dynamic process, thus, strategies and techniques need to be continuously adapted in response to environmental changes.  相似文献   

16.
A key aspect of large river basins partially neglected in large‐scale hydrological models is river hydrodynamics. Large‐scale hydrologic models normally simulate river hydrodynamics using simplified models that do not represent aspects such as backwater effects and flood inundation, key factors for some of the largest rivers of the world, such as the Amazon. In a previous paper, we have described a large‐scale hydrodynamic approach resultant from an improvement of the MGB‐IPH hydrological model. It uses full Saint Venant equations, a simple storage model for flood inundation and GIS‐based algorithms to extract model parameters from digital elevation models. In the present paper, we evaluate this model in the Solimões River basin. Discharge results were validated using 18 stream gauges showing that the model is accurate. It represents the large delay and attenuation of flood waves in the Solimões basin, while simplified models, represented here by Muskingum Cunge, provide hydrographs are wrongly noisy and in advance. Validation against 35 stream gauges shows that the model is able to simulate observed water levels with accuracy, representing their amplitude of variation and timing. The model performs better in large rivers, and errors concentrate in small rivers possibly due to uncertainty in river geometry. The validation of flood extent results using remote sensing estimates also shows that the model accuracy is comparable to other flood inundation modelling studies. Results show that (i) river‐floodplain water exchange and storage, and (ii) backwater effects play an important role for the Amazon River basin hydrodynamics. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

17.
Concentration–discharge (C-Q) relationships are an effective tool for identifying watershed biogeochemical source and transport dynamics over short and long timescales. We examined stormflow C-Q, hysteresis, and flushing patterns of total suspended sediment (TSS) and soluble reactive phosphorus (SRP) in two stream reaches of a severely impaired agricultural watershed in northeastern Wisconsin, USA. The upper watershed reach—draining a relatively flat, row crop-dominated contributing area—showed predominantly anti-clockwise TSS hysteresis during storms, suggesting that particulate materials were mobilized more from distal upland sources than near- and in-channel areas. In contrast, the incised lower watershed reach produced strong TSS flushing responses on the rising limb of storm hydrographs and clockwise hysteresis, signalling rapid mobilization of near- and in-channel materials with increasing event flows. C-Q relationships for SRP showed complex patterns in both the upper and lower reaches, demonstrating largely non-linear chemodynamic C-Q behaviour during events. As with TSS, anti-clockwise SRP hysteresis in the upper reach suggested a delay in the hydrologic connectivity between SRP sources and the stream, with highly variable SRP concentrations during some events. A broad range of clockwise, anti-clockwise, and complex SRP hysteresis patterns occurred in the lower watershed, possibly influenced by in-channel legacy P stores and connection to tile drainage networks in the lower watershed area. Total suspended sediment and SRP responses were also strongly related to precipitation event characteristics including antecedent precipitation, recovery period, and precipitation intensity, highlighting the complexity of stormflow sediment and phosphorus responses in this severely impaired agricultural stream.  相似文献   

18.
The South Saskatchewan River Basin of southern Alberta drains the transboundary central Rocky Mountains region and provides the focus for irrigation agriculture in Canada. Following extensive development, two tributaries, the Oldman and Bow rivers, were closed for further water allocations, whereas the Red Deer River (RDR) remains open. The RDR basin is at the northern limit of the North American Great Plains and may be suitable for agricultural expansion with a warming climate. To consider irrigation development and ecological impacts, it is important to understand the regional hydrologic consequences of climate change. To analyse historic trends that could extend into the future, we developed century‐long discharge records for the RDR, by coordinating data across hydrometric gauges, estimating annual flows from seasonal records, and undertaking flow naturalization to compensate for river regulation. Analyses indicated some coordination with the Pacific decadal oscillation and slight decline in summer and annual flows from 1912 to 2016 (?0.13%/year, Sen's slope). Another forecasting approach involved regional downscaling from the global circulation models, CGCMI‐A, ECHAM4, HadCM3, and NCAR‐CCM3. These projected slight flow decreases from the mountain headwaters versus increases from the foothills and boreal regions, resulting in a slight increase in overall river flows (+0.1%/year). Prior projections from these and other global circulation models ranged from slight decrease to slight increase, and the average projection of ?0.05%/year approached the empirical trend. Assessments of other rivers draining the central and northern Rocky Mountains revealed a geographic transition in flow patterns over the past century. Flows from the rivers in Southern Alberta declined (around ?0.15%/year), in contrast to increasing flows in north‐eastern British Columbia and the Yukon. The RDR watershed approaches this transition, and this study thus revealed regional differentiation in the hydrological consequences from climate change.  相似文献   

19.
Groundwater discharges in the western Canadian oil sands region impact river water quality. Mapping groundwater discharges to rivers in the oil sands region is important to target water quality monitoring efforts and to ensure injected wastewater and steam remain sequestered rather than eventually resurfacing. Saline springs composed of Pleistocene‐aged glacial meltwater exist in the region, but their spatial distribution has not been mapped comprehensively. Here we show that formation waters discharge into 3 major rivers as they flow through the Athabasca Oil Sands Region adjacent to many active oil sands projects. These discharges increase river chloride concentrations from river headwaters to downstream reaches by factors of ~23 in the Christina River, ~4 in the Clearwater River, and ~5 in the Athabasca River. Our survey provides further evidence for the substantial impact of formation water discharges on river water quality, even though they comprise less than ~2% of total streamflow. Geochemical evidence supporting formation water discharges as the leading control on river salinity include increases in river chloride concentrations, Na/(Na + Ca) ratios, Cl/(Cl + SO4) ratios and decreases in 87Sr/86Sr ratios; each mixing trend is consistent with saline groundwater discharges sourced from Cretaceous or Devonian aquifers. These regional subsurface‐to‐surface connections signify that injected wastewater or steam may potentially resurface in the future, emphasizing the critical importance of mapping groundwater flow paths to understand present‐day streamflow quality and to predict the potential for injected fluids to resurface.  相似文献   

20.
Pre‐ and post‐remediation data sets are used herein to assess the effectiveness of remedial measures implemented in the headwaters of the Mineral Creek watershed, where contamination from hard rock mining has led to elevated metal concentrations and acidic pH. Collection of pre‐ and post‐remediation data sets generally followed the synoptic mass balance approach, in which numerous stream and inflow locations are sampled for the constituents of interest and estimates of streamflow are determined by tracer dilution. The comparison of pre‐ and post‐remediation data sets is confounded by hydrologic effects and the effects of temporal variation. Hydrologic effects arise due to the relatively wet conditions that preceded the collection of pre‐remediation data, and the relatively dry conditions associated with the post‐remediation data set. This difference leads to a dilution effect in the upper part of the study reach, where pre‐remediation concentrations were diluted by rainfall, and a source area effect in the lower part of the study reach, where a smaller portion of the watershed may have been contributing constituent mass during the drier post‐remediation period. A second confounding factor, temporal variability, violates the steady‐state assumption that underlies the synoptic mass balance approach, leading to false identification of constituent sources and sinks. Despite these complications, remedial actions completed in the Mineral Creek headwaters appear to have led to improvements in stream water quality, as post‐remediation profiles of instream load are consistently lower than the pre‐remediation profiles over the entire study reach for six of the eight constituents considered (aluminium, arsenic, cadmium, copper, iron, and zinc). Concentrations of aluminium, cadmium, copper, lead, and zinc remain above chronic aquatic‐life standards, however, and additional remedial actions may be needed. Future implementations of the synoptic mass balance approach should be preceded by an assessment of temporal variability, and modifications to the synoptic sampling protocol should be made if necessary. Published in 2009 by John Wiley & Sons, Ltd.  相似文献   

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