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1.
Natural Resources Research - Nano-particles can localize at oil–water (O/W) interface, reduce residual oil saturation, increase the viscosity of brine and decrease the viscosity of crude oil...  相似文献   

2.
In an earlier report, changes in bitumen prices at Hardesty, Alberta, Canada, were modeled as the responses to changes in monthly prices of Hardesty light/medium crude oil for the period 2000–2006 with a simple error correction econometric model. This note re-examines that price relationship for the period 2009–2014. Over the period 2006–2014, there was also rapid growth in North American light oil production from low-permeability carbonate, sandstone, and shale reservoirs. During that period, Canadian raw bitumen production grew by more than 12% per year and there was significant geographical diversification in its markets. Results of the statistical analysis showed that the change in the dynamic relationships between bitumen prices and Hardesty light oil prices probably reflected, in part, the maturation of bitumen markets and closer integration with North American light oil markets. The analysis also examines the dynamic relationships between bitumen prices and West Texas Intermediate and Brent international benchmark crude oil prices. Ideally, if bitumen prices are found to be closely related to a widely traded benchmark crude oil, the benchmark crude oil price forecasts could be used as a basis for predicting bitumen prices. However, neither of international benchmark crude oils tested had high explanatory power.  相似文献   

3.
Wettability plays a pivotal role in oil recovery processes in reservoirs owing to the fact that it has a direct impact on the proportion of oil recovery. Reservoir rocks are a complex of a variety of mineral types, and each mineral may have a different wettability. Typically most aquifer materials such as quartz, carbonate, and dolomite are water-wet prior to oil migration. Some oil recovery processes are designed to alter the wetting preference of the oil formation to be more oil-wet. There are three techniques used in the laboratory for the characterization of the capillary pressure properties of core samples: mercury injection, centrifuge, and porous plate. This article provides an in-depth review of wettability. It also entails a case study from one of the Iranian carbonate reservoirs and measurements, which have been carried out for selected samples to clarify the nature of the wettability of reservoir rock. Samples were chosen from three wells of oil field which is composed of limestones and dolomites, rarely inter-bedded by shales, and their wettability was measured by Amott–Harvey method, which is one of the main methods for measuring wettability. After cleaning and drying the samples, measurements were carried out. According to the results, it can be said that the range of Amott–Harvey index for these samples is between ?0.48 and ?0.8. In Amott–Harvey method, if IAH varies from ?1 to ?0.3, the rock is oil-wet. Therefore, it can be concluded that the reservoir is oil-wet.  相似文献   

4.
During the last quarter-century, global demand for energy has increased by more than 60%, and a similar increase is anticipated to occur by 2030 (Raymond, Deming, & Nichols, 2007). In the U.S., oil and gas development is projected to continue across western states within sage-grouse habitat. Greater sage-grouse, recently a candidate species for protection under the Endangered Species Act (ESA), have well documented negative responses to oil and gas disturbance. In this study, we create spatially-explicit oil and gas future development scenarios, baseline and high, and link them to sage-grouse population and habitat maps to quantify future exposure risk within Western Association of Fish and Wildlife Agencies (WAFWA) sage-grouse management zones (MZ) I and II. We then analyze recent land use decisions from the Bureau of Land Management (BLM) along with enacted policy from the State of Wyoming to estimate how these management actions might minimize the exposure risk of sage-grouse to oil and gas development into the future. Our results show that BLM and Wyoming conservation plans could reduce the exposure of sage-grouse to oil and gas development from 15-27% to 11–17% (31–37% reduction) in MZ I and from 15-27% to 5–9% (64–68% reduction) in MZ II. Our estimates of exposure to future oil and gas development, and conservation measures designed to ameliorate those threats, represent the upper and lower extents of potential impacts within scenarios. Our work demonstrates how spatial modeling and GIS visualization can be used by managers to assess likely outcomes of conservation decisions.  相似文献   

5.
Zhang  Chengli  Hu  Bozhou  Wang  Peng  Fu  Xiaofei  Song  Guoliang  Liu  Haoliang 《Natural Resources Research》2020,29(3):2191-2207
Natural Resources Research - Alkali–surfactant–polymer (ASP)-produced effluent contains polymer, alkali and surfactant, and it has higher content of suspended oil droplets and suspended...  相似文献   

6.

Oil from the Oligocene oil sands of the Lower Ganchaigou Formation in the Northern Qaidam Basin and the related asphaltenes was analyzed using bulk and organic geochemical methods to assess the organic matter source input, thermal maturity, paleo-environmental conditions, kerogen type, hydrocarbon quality, and the correlation between this oil and its potential source rock in the basin. The extracted oil samples are characterized by very high contents of saturated hydrocarbons (average 62.76%), low contents of aromatic hydrocarbons (average 16.11%), and moderate amounts of nitrogen–sulfur–oxygen or resin compounds (average 21.57%), suggesting that the fluid petroleum extracted from the Oligocene oil sands is of high quality. However, a variety of biomarker parameters obtained from the hydrocarbon fractions (saturated and aromatic) indicate that the extracted oil was generated from source rocks with a wide range of thermal maturity conditions, ranging from the early to peak oil window stages, which are generally consistent with the biomarker maturity parameters, vitrinite reflectance (approximately 0.6%), and Tmax values of the Middle Jurassic carbonaceous mudstones and organic-rich mudstone source rocks of the Dameigou Formation, as reported in the literature. These findings suggest that the studied oil is derived from Dameigou Formation source rocks. Furthermore, the source- and environment-related biomarker parameters of the studied oil are characterized by relatively high pristane/phytane ratios, the presence of tricyclic terpanes, low abundances of C27 regular steranes, low C27/C29 regular sterane ratios, and very low sterane/hopane ratios. These data suggest that the oil was generated from source rocks containing plankton/land plant matter that was mainly deposited in a lacustrine environment and preserved under sub-oxic to oxic conditions, and the data also indicate a potential relationship between the studied oil and the associated potential source rocks. The distribution of pristane, phytane, tricyclic terpanes, regular steranes and hopane shows an affinity with the studied Oligocene Lower Ganchaigou Formation oil to previously published Dameigou Formation source rocks. In support of this finding, the pyrolysis–gas chromatography results of the analyzed oil asphaltene indicate that the oil was primarily derived from type II organic matter, which is also consistent with the organic matter of the Middle Jurassic source rocks. Thus, the Middle Jurassic carbonaceous mudstones and organic rock mudstones of the Dameigou Formation could be significantly contributing source rocks to the Oligocene Lower Ganchaigou Formation oil sand and other oil reservoirs in the Northern Qaidam Basin.

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7.
This paper traces the energy transitions in Indonesia: from woodfuels to coal, spanning the period from the establishment of Dutch colonial rule to the 1950s; and from coal to oil, spanning the period from the 1950s to the oil crisis of 1973–1974. It then examines the role of oil in the energy mix of Indonesia, and discusses the reasons — high rates of domestic oil products consumption; the importance of oil as a foreign exchange earner — for the country to move away from oil dependency to alternative forms of energy to meet her domestic needs.  相似文献   

8.
Tian  Yapeng  Ju  Binshan  Wang  Xudong  Wang  Hongya  Hu  Jie  Huang  Yingsong  Liu  Nannan  Dong  Yintao 《Natural Resources Research》2021,30(5):3533-3549

The phase behavior of fluid is essential for predicting ultimate oil recovery and determining optimal production parameters. The pore size in shale porous media is nanopore, which causes different phase behaviors of fluid in unconventional reservoirs. Nanopores in shale media can be regard as semipermeable membrane to filter heavy components (sieving effect) in shale oil, which leads to the different distributions of fluid components and different phase behaviors. In addition, the phase behavior of fluid in nanopores can be significantly altered by large capillary pressure. In this paper, the phase behavior of fluid in shale reservoirs is investigated by a new two-phase flash algorithm considering sieving effect and capillary pressure. Firstly, membrane efficiency and capillary pressure are introduced to establish a thermodynamic equilibrium model that is solved by Rachford–Rice flash calculation and Newton–Raphson method. The capillary pressures in different pore sizes are calculated by the Young–Laplace equation. Then, the influences of sieving effect and capillary pressure on phase behavior are analyzed. The results indicate that capillary pressure can suppress the bubble point pressure of fluid in nanopores. The distributions of fluid components are different in various parts of shale media. In the unfiltered part, density and viscosity of fluid are higher. Finally, it is found that the membrane efficiency can be improved by CO2 injection. The minimum miscibility pressure for shale oil–CO2 system is also studied. The developed model provides a better understanding of the phase behavior of fluid in shale oil reservoirs.

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9.
An analysis is made of the oil pollution of the Ob river waters using a long-term (1993–2013) hydrochemical monitoring of oil fields in Khanty-Mansi Autonomous Okrug. Contents of oil hydrocarbons (OHC) were determined in 4277 samples from the main Ob channel, and in 7076 samples from its anabranches by using infrared spectrometry. An increase in MAC (0.05 mg/dm3) was observed in 28% of the samples from the main channel, and in 32% from the anabranches. The total percentage of samples with an extremely high (> 50 MAC) and high (30–50 MAC) pollution level made up 0.3% of the samples for the anabranches, and 0.1% for the main channel. Maximum pollution was revealed in the eastern part of Okrug, from its eastern boundary to the mouth of the Trom’egan river which is associated with a considerable number of accidents on the pipelines within the Nizhnevartovskii district. The upper and lower quantiles in the most polluted anabranches, Pasl and Bagras, are 0.03–01.7 and 0.032–0.16 mg/dm3, respectively, whereas in the main Ob channel they vary from 0.022 to 0.065 mg/dm3 (0.4–1.2 MAC). The methods of geoinformatics and mathematical statistics were used to assess a dependence of OHC on the number of pollution sources (well clusters, and the area of oil spills) in zones at different distances from the river channels. By calculating the Spearman correlation coefficients, it was shown that OHC contents are dependent mainly on the number of wells, and on the area of oil spills located at less than 2 km from the channels.  相似文献   

10.
The objective of this research is to simulate the impact of well operation conditions on wax precipitation in an oil sample, and to predict the wax-free well flowrate. Laboratory studies help producers to protect oil wells from potential problems. The maximum rise of simulated well operation conditions to in situ oil recovery leads to oilfield practice. The methods used for testing of oil sample were microscopy under high pressure with grain size analysis and light-scattering technique, which were conducted using laboratory equipment suited for investigations of reservoir fluids in conditions close to oilfield conditions. Experiments with modeling of temperature and pressure drop rates, flow velocity, and flow through time from downhole to wellhead were carried out. These experiments resulted in modeling of the relationship between functional pressure and wax appearance temperature (WAT), which is properly consistent with the Clapeyron–Clausius equation in a range of well operation conditions. Experimental simulation of well thermobaric operation conditions also resulted in definition of potential wax formation area in the tubing. Research data showed that WAT declines with increase in flow velocity and temperature, and pressure drop rates. Calculations demonstrated that an increase in flow velocity by 0.04 m/sec (equivalent to a well flowrate of 20 m3 per day) leads to a decrease in wax formation depth of up to approximately 200 meters. Guidelines for slowdown of asphaltene–resin–paraffin particles formation in the well by chemical treatment are made.  相似文献   

11.
Liu  Shumin  Li  Xuelong  Wang  Dengke  Zhang  Dongming 《Natural Resources Research》2021,30(2):1467-1480
Natural Resources Research - Liquid nitrogen freeze–thaw has been used in oil, shale gas and coalbed methane exploitation as an efficient fracturing technology. This paper aimed to study the...  相似文献   

12.
Most states levy severance taxes on the value of natural resources when they are severed or extracted from the ground or subsurface. In Louisiana, severance tax on oil and gas production contributes to the majority of mineral revenue in the state, and over the last decade, has ranged between $400 million and $1.1 billion, or between 5 and 9% of annual state revenue. The purpose of this article is to develop a forecast model for severance tax revenue to better understand the severance tax regime and to assist in state budgeting and planning purposes. We couple an oil and gas production model with empirical relationships describing historical severance tax receipts to perform the forecast. We demonstrate that oil production correlations are robust, but that in recent years, unconventional gas production from the Haynesville shale has led to a significant departure from historic trends. We estimate that cumulative oil and gas severance tax revenues during 2011–2015 will range from $1.0 to $2.1 billion for oil and $1.3–$1.9 billion for gas. Louisiana is transforming into a gas-producing state, and more attention needs to be paid to tax design and the impact of exemptions on future severance revenue receipts.  相似文献   

13.
Mapping and correlation of 2D seismic reflection data define the overall subsurface structure of the East Gobi basin (EGB), and reflect Jurassic–Cretaceous intracontinental rift evolution through deposition of at least five distinct stratigraphic sequences. Three major northeast–southwest‐trending fault zones divide the basin, including the North Zuunbayan (NZB) fault zone, a major strike‐slip fault separating the Unegt and Zuunbayan subbasins. The left‐lateral NZB fault cuts and deforms post‐rift strata, implying some post‐middle‐Cretaceous movement. This fault likely also had an earlier history, based on its apparent role as a basin‐bounding normal or transtensional fault controlling deposition of the Jurassic–Cretaceous synrift sequence, in addition to radiometric data suggesting a Late Triassic (206–209 Ma) age of deformation at the Tavan Har locality. Deposits of the Unegt subbasin record an early history of basin subsidence beginning ～155 Ma, with deposition of the Upper Jurassic Sharilyn and Lower Cretaceous Tsagantsav Formations (synrift sequences 1–3). Continued Lower Cretaceous synrift deposition is best recorded by thick deposits of the Zuunbayan Formation in the Zuunbayan subbasin, including newly defined synrift sequences 4–5. Geohistory modelling supports an extensional origin for the EGB, and preliminary thermal maturation studies suggest that a history of variable, moderately high heat flow characterized the Jurassic–Cretaceous rift period. These models predict early to peak oil window conditions for Type 1 or Type 2 kerogen source units in the Upper Tsagantsav/Lower Zuunbayan Formations (Synrift Sequences 3–4). Higher levels of maturity could be generated from distal depocentres with greater overburden accumulation, and this could also account for the observed difference in maturity between oil samples from the Tsagan Els and Zuunbayan fields.  相似文献   

14.
Louisiana receives royalty revenue when minerals are produced on state-owned lands and water bottoms, federal properties within the state, and offshore fields underlying federal and state jurisdiction within 3–6 nautical miles from the coastline. Royalty revenue on oil and gas production has averaged $465 million per year and has contributed 3–7% of the state general revenue over the past decade. The purpose of this article is to develop a royalty revenue forecast model to assist in state budgeting and planning purposes. Producing fields are evaluated within a probabilistic framework to capture the uncertainty associated with future capital outlays and operational changes, and a discovery model is used to generate production from fields expected to be discovered in the future. The forecasts are combined with commodity price scenarios and royalty rate assumptions to generate a royalty revenue outlook for the state. We estimate that cumulative royalty revenue during 2012–2017 will range from $704 million to $1,408 million for oil production and from $286 million to $1,145 million for gas production for commodity prices of 60–120 $/bbl and 2–8 $/Mcf. At $80/bbl and $4/Mcf, cumulative royalty receipts from 2012 to 2017 are estimated at $1,510 million.  相似文献   

15.
Rapeseed is one of the major oil crops in China and it is very sensitive to climate change. The Yangtze River Basin is the main rapeseed production area in China. Therefore, a better understanding of the impact of climate change on rapeseed production in the basin is of both scientific and practical importance to Chinese oil industry and food security. In this study, based on climate data from 5 General Circulation Models (GCMs) with 4 representative concentration pathways (RCPs) in 2011–2040 (2020s), 2041–2070 (2050s) and 2071–2100 (2080s), we assessed the changes in rapeseed production potential between the baseline climatology of 1981–2010 and the future climatology of the 2020s, 2050s, and 2080s, respectively. The key modelling tool – the AEZ model – was updated and validated based on the observation records of 10 representative sites in the basin. Our simulations revealed that: (1) the uncertainty of the impact of climate change on rapeseed production increases with time; (2) in the middle of this century (2050s), total rapeseed production would increase significantly; (3) the average production potential increase in the 2050s for the upper, middle and lower reaches of the Yangtze River Basin is 0.939, 1.639 and 0.339 million tons respectively; (4) areas showing most significant increases in production include southern Shaanxi, central and eastern Hubei, northern Hunan, central Anhui and eastern Jiangsu.  相似文献   

16.
Since oil and gas are non-renewable resources, it is important to identify the extent to which they have been depleted. Such information will contribute to the formulation and evaluation of appropriate sustainable development policies. This paper provides an assessment of the changes in the availability of oil and gas resources in Malaysia by first compiling the physical balance sheet for the period 2000–2007, and then assessing the monetary balance sheets for the said resource by using the Net Present Value method. Our findings show serious reduction in the value of oil reserves from 2001 to 2005, due to changes in crude oil prices, and thereafter the depletion rates decreased. In the context of sustainable development planning, albeit in the weak sustainability sense, it will be important to ascertain if sufficient reinvestments of the estimated resource rents in related or alternative capitals are being attempted by Malaysia. For the study period, the cumulative resource rents were to the tune of RM61 billion. Through a depletion or resource rents policy, the estimated quantum may guide the identification of a reinvestment threshold (after considering needed capital investment for future development of the industry) in light of ensuring the future productive capacity of the economy at the time when the resource is exhausted.  相似文献   

17.
Encouraged by the initial success of the Cape Hoskins oil palm scheme, the national government developed two more oil palm schemes, one at Bialla in New Britain, and the other at Popondetta in the Northern Province. The three schemes are organised on the same basis: a nucleus estate surrounded by a large number of smallholdings. It is estimated that these three schemes will earn about forty million kina by 1987–88; this will represent more than ten per cent of the total Papua New Guinea agricultural exports, a remarkable achievement in the space of twenty years. However, the success of the industry may depend on the performance of the smallholders, and already, there are signs that this sector of the industry is experiencing some problems.  相似文献   

18.
Fine‐grained Palaeogene–early Neogene strata of the South Caspian basin, specifically the Oligocene–Lower Miocene Maikop Series, are responsible for the bulk of hydrocarbon generation in the region. Despite the magnitude of oil and gas currently attributed to the source interval offshore, geochemical evaluation of 376 outcrop samples from the northern edge of the Kura basin (onshore eastern Azerbaijan) indicates that depositional conditions in these proximal strata along the basin margins were dominantly oxic to mildly suboxic/anoxic throughout three major depositional stages: the Palaeocene–Eocene, Oligocene–early Middle Miocene and late Middle–Late Miocene. Palaeocene–Eocene samples have low average total organic carbon (TOC) values (0.3%), with higher total inorganic carbon (TIC) values (average=2.6%), extremely low sulphur content (0.2%) and relatively high detrital input as indicated by Fe/Al and Ti/Al ratios. C–S–Fe associations, along with relatively lower concentrations of redox‐sensitive trace elements (e.g. V, Ni, Mo, U) indicate dominantly oxic environments of deposition during much of the Palaeocene–Eocene. A pronounced geochemical shift occurred near the Eocene–Oligocene boundary, and continued through the Early Miocene. Specifically, this interval is characterized by a distinct increase in TOC (ranging from 0.1 to 6.3% with an average of 1.5%), C–S–Fe associations that reveal an abrupt relative increase of carbon and sulphur with respect to iron‐dominated Palaeocene–Eocene samples, and higher concentrations of redox‐sensitive trace metals. These changes suggest that a shift away from unrestricted marine conditions and towards more variable salinity conditions occurred coincident with the initial collision of the Arabian plate and partial closure of the Paratethys ocean. Despite periodic basin restriction, the majority of Upper Eocene–Lower Miocene strata in the northern Kura basin record oxic to slightly dysoxic conditions.  相似文献   

19.
We utilized carbonate clumped isotope thermometry to explore the thermal history of the Delaware Basin, West Texas, USA. Carbonate wellbore cuttings from five oil/gas wells across the basin yielded clumped isotope temperatures (T(Δ47)) ranging from 27°C to 307°C, interpreted to reflect a combination of initial precipitation/recrystallization temperature and solid-state C-O bond reordering during burial. Dolomite samples generally record lower apparent T(Δ47)s than calcite, reflecting greater resistance to reordering in dolomite. In all five wells, clumped isotope temperatures exceed modern downhole temperature measurements, indicating higher heat flow in the past. Using modelled burial curves based on sedimentological history, we created unique time-temperature histories by linearly applying a geothermal gradient. Applying two different thermal history reordering models, we modelled the extent of solid-state C–O bond reordering to iteratively find the time-averaged best-fit geothermal gradients for each of the five wells. Results of this modelling suggest that the shallower, southwestern portion of the study area experienced higher geothermal gradients throughout the sediment history (~45°C/km) than did the deeper, southeastern portion (~32°C/km), with the northern portion experiencing intermediate geothermal gradients (~35–38°C/km). This trend is in agreement with the observed gas/oil ratios of the Delaware Basin, increasing from east to west. Furthermore, our clumped isotope temperatures agree well with previously published vitrinite reflectance data, confirming previous observations and demonstrating the utility of carbonate clumped isotope thermometry to reconstruct basin thermal histories.  相似文献   

20.
复杂网络理论下世界原油贸易空间格局演进研究   总被引：15，自引：3，他引：12  
程淑佳  王肇钧 《地理科学》2011,31(11):1342-1348
依据世界原油贸易数据,以复杂网络理论为基础,结合地理学的区域分析方法,勾勒出世界原油贸易空间结构,并比较了区域间节点、出、入度及权重值的差异。利用熵值分析了网络的均质性,并对世界原油贸易空间结构进行了模拟。研究表明:①尽管世界原油贸易空间格局的节点增幅不大,但随时间推移,节点的度与权重值大幅增加,即世界原油贸易范围及效应在逐渐加大;②通过对节点、出、入度及权重值的比较,揭示了不同区域在世界原油贸易空间格局中的职能差异;③结构熵、权重熵的测定与世界原油贸易空间格局的模拟均表明世界原油贸易空间格局网络的有序性,世界原油空间格局是非均质的。多元化不等于均质化,贸易主体要依据各自所面临的客观环境选择适合区域合作伙伴,才能更好的落实多元化进口策略,切实解决可能面临的石油供给危机。  相似文献   

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