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1.
《Chemie der Erde / Geochemistry》2016,76(1):49-62
Geochemical maps can provide us with much information on geology, earth surface processes and anthropogenic pressure and are valuable tools for ore prospecting and land management. Stream sediments represent an integral of the various possible sources of sediments upstream from the sampling point therefore there can be multiple signal sources but generally the prevailing signal source is the one related to bedrock geology. Stream sediments collected from active second-order channels including singular geological units, were selected in order to determine the geochemical characteristics of each unit. The aim of this study was to analyze their potential for using them to integrate geological interpretation and produce a geologically-oriented geochemical map. From the 770 samples collected for a regional geochemical mapping program, we selected 149 samples whose catchment basin included only one of the members recognized within the Marnoso-arenacea formation. This middle–upper Miocene (Langhian–Tortonian) turbiditic unit forms the backbone of the Romagna Apennines and has been subdivided into 14 members according to age and lithostratigraphic criteria. The results indicate that there are marked differences in the composition of the members of the Marnoso arenecea formation which indicate the provenance of the sediment and the palaeogeographic evolution of the units. By means of univariate and multivariate statistical analyses (Factor analyzes) two main types of sediment compositions are identified: Tortonian members are characterized by sialic coarse grain-sediments while the Langhian–Serravallian members are richer in carbonate fraction, slightly enriched in a mafic contribution. This study elaborated the geochemical data from a geological point of view by integrating the information available in literature to spatially extend the interpretation based on limited site observation as for petrographic studies. In general, the geochemical map based on a geological unit could be a useful tool for carrying out the geological reconstruction of a complex area. 相似文献
2.
《Applied Geochemistry》2006,21(9):1482-1497
Population statistics for As concentrations in rocks, sediments and ground water differ by geology and land use features in the New England region, USA. Significant sources of As in the surficial environment include both natural weathering of rocks and anthropogenic sources such as arsenical pesticides that were commonly applied to apple, blueberry and potato crops during the first half of the 20th century in the region. The variation of As in bedrock ground water wells has a strong positive correlation with geologic features at the geologic province, lithology group, and bedrock map unit levels. The variation of As in bedrock ground water wells also has a positive correlation with elevated stream sediment and rock As chemistry. Elevated As concentrations in bedrock wells do not correlate with past agricultural areas that used arsenical pesticides on crops. Stream sediments, which integrate both natural and anthropogenic sources, have a strong positive correlation of As concentrations with rock chemistry, geologic provinces and ground water chemistry, and a weaker positive correlation with past agricultural land use. Although correlation is not sufficient to demonstrate cause-and-effect, the statistics favor rock-based As as the dominant regional source of the element in stream sediments and ground water in New England. The distribution of bedrock geology features at the geologic province, lithology group and map unit level closely correlate with areas of elevated As in ground water, stream sediments, and rocks. 相似文献
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《Applied Geochemistry》2003,18(2):283-309
International agreements (e.g. OSPAR) on the release of hazardous substances into the marine environment and environmental assessments of shelf seas require that concentrations and bioavailability of metals from anthropogenic sources can be distinguished from those originating as a result of natural geological processes. The development of a methodology for distinguishing between anthropogenic and natural sources of metals entering the Irish Sea through river inputs is described. The geochemistry of stream, river and estuarine sediments has been used to identify background geochemical signatures, related to geology, and modifications to these signatures by anthropogenic activities. The British Geological Survey (BGS) geochemical database, based on stream sediments from 1 to 2 km2 catchments, was used to derive the background signatures. Where mining activity was present, the impact on the signature was estimated by comparison with the geochemistry of sediments from a geologically similar, but mining free, area. River sediment samples taken upstream and downstream of major towns were used respectively to test the validity of using stream sediments to estimate the chemistry of the major river sediment and to provide an indication of the anthropogenic impact related to urban and industrial development. The geochemistry of estuarine sediments from surface samples and cores was then compared with river and offshore sediment chemistry to assess the importance of riverine inputs to the Irish Sea. Studies were undertaken in the Solway, Ribble, Wyre and Mersey estuaries. The results verify that catchment averages of stream sediments and major river samples have comparable chemistry where anthropogenic influences are small. Major urban and industrial (including mining) development causes easily recognised departures from the natural multi-element geochemical signature in river sediment samples downstream of the development and enhanced metal levels are observed in sediments from estuaries with industrial catchments. Stream sediment chemistry coupled with limited river and estuarine sampling provides a cost-effective means of identifying anthropogenic metal inputs to the marine environment. Investigations of field and laboratory protocols to characterise biological impact (bioaccumulation) of metals in sediments of the Irish Sea and its estuaries show that useful assessments can be made by a combination of surveys with bioindicator species such as clams Scrobicularia plana, selective sediment measurements that mimic the ‘biologically available’ fractions, and laboratory (mesocosm) studies. 相似文献
4.
The Austrian portion of the Bohemian Massif is a Precambrian terrane composed mostly of highly metamorphosed rocks intruded by a series of granitoids that are petrographically similar. Rocks are exposed poorly and the subtle variations in rock type are difficult to map in the field. A detailed geochemical survey of stream sediments in this region has been conducted and included as part of the Geochemischer Atlas der Republik Österreich,and the variations in stream sediment composition may help refine the geological interpretation. In an earlier study, multivariate analysis of variance (MANOVA) was applied to the stream-sediment data in order to minimize unwanted sampling variation and emphasize relationships between stream sediments and rock types in sample catchment areas. The estimated coefficients were used successfully to correct for the sampling effects throughout most of the region, but also introduced an overcorrection in some areas that seems to result from consistent but subtle differences in composition of specific rock types. By expanding the model to include an additional factor reflecting the presence of a major tectonic unit, the Rohrbach block, the overcorrection is removed. This iterative process simultaneously refines both the geochemical map by removing extraneous variation and the geological map by suggesting a more detailed classification of rock types. 相似文献
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描述岩石粘弹性固体性质的开尔文模型 总被引：1，自引：0，他引：1
大多数固体材料都具有弹性,但真实的固体却极少严格遵从弹性的虎克定律。这些固体材料的变形往往有对时间的依赖性,这种性质是流变学研究的内容。岩石是自然界最普遍的固体,它的力学性质在通常条件下可用虎克定律作精确的描述,而在漫长的地质过程中,岩石的流变特征就逐渐显现出来。地质作用越缓慢,岩石对变形时间的依赖性越明显。为精确描述岩石在地质过程的力学性质,流变学方法被引入地质学。笔者已经介绍过描述"牛顿流体"的马克斯威尔流变模型,文中介绍描述粘弹性固体的开尔文流变模型。和马克斯威尔模型一样,开尔文模型也是流变学的基本模型,它是由一个弹性元件和一个阻尼元件并联而成。文中给出开尔文模型的本构关系和地质应用的简介。 相似文献
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Lake sediments are integrators of watershed wide environmental information that includes bedrock geology, glacial overburden, vegetation, hydrology and land use. Lake sediments were collected from an area covering approximately 13,600 km2 from the Gowganda and Temagami regions to determine the geochemical background conditions representing different bedrock types. For the entire dataset, the median value for arsenic in lake sediment was 2.6 mg/kg, well within the prescribed limits indicating that the Canadian national objective for arsenic in sediments for the protection of aquatic life (17 mg/kg). Overall, the vast majority of lake sediment samples (97.2%) were below the 17 mg/kg Canadian objective for the protection of aquatic life, however, catchments with Nipissing Diabase had the highest background levels for arsenic (10 mg/kg) with some lakes ranging up to 30 mg/kg. The major geological controls influencing changes in lake sediment geochemistry were determined using random forest classification and principal component analysis (PCA). Random forest classification was able to identify which geological province the samples were derived from and the dominant rock types in the sample catchment with respectable accuracy. PCA revealed strong spatial relationships between lake sediment geochemistry and bedrock geology, particularly a strong relationship between Nipissing Diabase in the watershed of the lake and the cobalt-type mineralization indicator elements in the lake sediment including naturally higher levels of arsenic. Within the samples that exceeded regulatory standards, over half the samples that exceeded the regulatory objectives were located in watersheds that contained Nipissing Diabase in their catchment. This study demonstrates that unique geochemical assemblages can be associated with specific geological areas which is of interest to exploration geologists, for target generation and prospecting, and to environmental policy makers, for site-specific restoration targets. 相似文献
10.
利用R型因子分析方法对胶东半岛乳山寨幅1∶5万水系沉积物测量数据进行了分析,提取出7个具有代表性的因子,绘制出地球化学分区图,并讨论了各分区的地质地球化学特征;将研究区内水系沉积物样本所体现的全部地球化学统计信息在一幅图中以区块的形式得以反映,通过对其判读分析各类分区特定的地质地球化学特征,同时结合圈定的综合异常,进一步缩小了找矿靶区,可为矿产勘查工作指明方向。 相似文献
11.
A. S. Basaham A. M. Gheith A. A. A. Khawfany R. Sharma N. H. Hashimi 《Arabian Journal of Geosciences》2014,7(3):951-970
Sediment characteristics are the indicators of the intensity and geological history of the processes active in an area. Their association with different geomorphic features also signifies the present day conditions of deposition. In this study, variations in sediment characteristics associated with different geomorphic features, such as the coastal zone, two islands and a lagoon in the Al-Lith area of central-west coast of Saudi Arabia have been analysed. Whereas, the detrital sediments (sand?+?mud) are common (61–87 %) in most of the subunits of the coastal zone; the nondetrital (carbonate rich) sediments are more common (54–95 %) on the two islands as well as the lagoon; indicating distinct sources of sediments in these regions. The variation of sediment texture between sand and sandy silt in most geomorphic units, also shows that they are exposed to high-energy conditions, whereas occurrence of heavy minerals in small proportions (<7 %) indicates limited inputs from land-based igneous and metamorphic rocks. Sediment mean size vs. standard deviation shows that the sediment characteristics of a geomorphic unit (e.g. beach or sand bar) on the coast and on the island are different owing to different processes responsible for their formation. 相似文献
12.
P.N. Ranasinghe G.W.A.R Fernando C.B. Dissanayake M.S. Rupasinghe D.L. Witter 《Journal of Geochemical Exploration》2009,103(2-3):97-114
Stream sediment geochemistry is extensively used in mineral exploration and environmental studies. However, quantitative assessments of the effectiveness of stream sediment geochemistry for describing upstream lithologies are rare, especially in high-grade metamorphic terrains. This study statistically evaluates whether stream sediment geochemistry can aid in recognizing variations in upstream geology in several high-grade metamorphic lithotectonic units having different metamorphic and tectonic histories, including the Highland Complex, Vijayan Complex, Wanni Complex, and Kadugannawa Complex of Sri Lanka. For this study, concentrations of 21 elements were measured in 2080 stream sediment samples collected from the Walawe River, Maha Oya, Gala Oya basins located on above lithotectonic units and Uma Oya, Belihul Oya, Badulu Oya basins situated adjacent to each other on the Highland Complex. These rivers flow across dry, intermediate and wet zones of Sri Lanka, with river courses having both slope (> 20°) and flat (< 20°) areas. Elemental concentrations, averaged over each river basin, show patterns of enrichment and depletion which may relate to localized mineralization conditions, local lithological changes, anthropogenic activities and environmental factors such as local variations in climate and morphology among river basins. Comparison of element concentrations in sediments from the four different lithotectonic units shows that enrichment – depletion patterns can be partly related to rock geochemistry of the associated lithotectonic unit. However, climate and basin morphology also seem to play an important role. Results of Kruskal–Wallis H tests show that both major and trace element levels in sediments from the four different lithotectonic units, as well as from adjacent Uma Oya, Badulu Oya and Belihul Oya basins, are significantly different. Discriminant function analysis appropriately classifies sediments into the four different lithotectonic units with an accuracy of 91.9%. This method also classifies sediments into river basins which share common lithology being situated adjacent to each other in the same lithotectonic unit with an accuracy of 89.5%. This strongly suggests that stream sediment geochemistry is capable of describing the upstream regional scale as well as local scale lithological changes at a great accuracy in complex high-grade metamorphic terrains. In both cases use of channel slope and basin climatic zone as additional variables does not significantly increase overall or individual accuracy in classification. 相似文献
13.
新疆哈拉奇地区地球化学分区特征及地质意义 总被引：1，自引：0，他引：1
水系沉积物测量是勘查地球化学一种重要方法。随着勘查地球化学的深入发展,有关地球化学异常圈定的方法已成为人们关注的焦点。采用R型因子分析方法,对哈拉奇地区水系沉积物测量所取得的数据进行统计处理,提取了具有代表性的5种因子组合类型,同时以因子得分为综合指标,绘制了因子得分等值线图并制作了元素组合分区图。通过综合分析,地球化学分区图反映了不同地段中以相应的元素组合类型为主的地球化学异常及地质成因信息,同时与主要控矿因素的空间分布比较一致,为研究区地质找矿提供新方向。 相似文献
14.
Geological and anthropogenic influences on sediment metal composition in the upper Paracatu River Basin, Brazil 总被引：1，自引：1，他引：0
Daniel Santos Mulholland Geraldo Resende Boaventura Daniel Ferreira Araújo 《Environmental Earth Sciences》2012,67(5):1307-1317
This work reports a geochemical study of sediments from the upper Paracatu River Basin. The objective is to define the influences of Au, Zn, and Pb mineral deposits and mining activities on the sediment metal sources, distribution, and accretion. The samples were analyzed using ICP/OES, AAS, and XRD techniques and were treated with principal components analysis and the geo-accumulation index. The main geochemical processes that control the sediment composition are pyrite oxidation, muscovite weathering, carbonate dissolution, and the erosion of oxisols enriched with Zn and Pb. The upper Rico Stream has high Al, Fe, Cu, Cr, Co, and Mn concentrations due erosion of oxisols and pyrite oxidation and muscovite alteration present in the parental rock. The artisanal alluvial gold mining increased the primary rock-minerals?? weathering and Hg sediment concentration. The lower Escuro River and Santa Catarina Stream are enriched with Zn and Pb due the erosion of metal-rich soils formed over galena, sphalerite, calamine, and willemite mineral deposits located upstream. Elements such as Ca, Mg, and Ba have low concentrations throughout the sampled area due the high solubility of these metals-bearing minerals. The dispersion of metals is limited by the basin geomorphology and their affinity to silt-clayey minerals and Fe and Mn oxides and hydroxides in circumneutral pH waters. 相似文献
15.
Shift in detrital sedimentation in the eastern Bay of Bengal during the late Quaternary 总被引：1，自引：0，他引：1
C. Prakash Babu J. N. Pattan K. Dutta N. Basavaiah G. V. Ravi Prasad D. K. Ray P. Govil 《Journal of Earth System Science》2010,119(3):285-295
Down-core variations of granulometric, geochemical and mineral magnetism of a 70-cm long sediment core retrieved from the eastern Bay of Bengal abyssal region were studied to understand sedimentation pattern and sediment provenance during the last ～12 kyr BP. Based on down-core physical and elemental variations, three units were identified: unit 3 (70–43 cm) is a ～30 cm thick clayey silt organic carbon-rich (0.5–0.92%) turbidite probably delivered by the Brahmaputra River during the late Quaternary period. Units 2 (43–24 cm) and 1 (24–0 cm) represent enhanced and reduced supply of coarse-grained detrital sediments from the Ganges River during early and late Holocene period, respectively. Increased terrigenous supply dilutes calcium carbonate (CaCO3) and biogenic elements (P, Ba and Cu) in units 3 and 2. On the contrary, a reduction in detrital input enhances CaCO3 and biogenic elements in unit 1. Lithogenic elements (Ti, Al, K and Rb) and shale-normalized REE patterns in all three units suggest terrigenous source. The shift in provenance from the Brahmaputra to the Ganges derived sediments is evident by a sharp increase in sediment grain size, increased concentration and grain size assemblages of magnetic minerals, lithogenic elements concentration and Lan/Ybn ratio. This study highlights terrigenous dilution on biogenic sedimentation in the eastern Bay of Bengal sediments. 相似文献
16.
Di Zhou 《Journal of Geochemical Exploration》1985,24(2):207-222
Conventional analyses of exploration geochemical data assume that the background is a constant or slowly changing value, equivalent to a plane or a smoothly curved surface. However, it is better to regard the geochemical background as a rugged surface, varying with changes in geology and environment. This rugged surface can be estimated from observed geological, geochemical and environmental properties by using multivariate statistics.A method of background adjustment was developed and applied to groundwater and stream sediment reconnaissance data collected from the Hot Springs Quadrangle, South Dakota, as part of the National Uranium Resource Evaluation (NURE) program. Source-rock lithology appears to be a dominant factor controlling the chemical composition of groundwater or stream sediments. The most efficacious adjustment procedure is to regress uranium concentration on selected geochemical and environmental variables for each lithologic unit, and then to delineate anomalies by a common threshold set as a multiple of the standard deviation of the combined residuals. Robust versions of regression and RQ-mode principal components analysis techniques were used rather than ordinary techniques to guard against distortion caused by outliers Anomalies delineated by this background adjustment procedure correspond with uranium prospects much better than do anomalies delineated by conventional procedures. The procedure should be applicable to geochemical exploration at different scales for other metals. 相似文献
17.
Interpolated geochemical maps contain problems of sample catchments and vacant sample areas. However, the resemblance of these
maps with regional geological maps implies that there are strong correlations between them. A conceptual model of the geological
units from multivariate chemical elements is constructed by decision tree technique. The reproducibility of the geological
map with the conceptual model is about 80% in the Chungbuk province map of Korea. Statistical uncertainties indicate that
rock units could be predicted reasonably well by decision tree if the geological map polygon is big enough. Misinterpreted
points are due to interpolation problems between samples from adjacent rock units and from different sample catchments. In
the Chungbuk example, the latter is less significant. The size of the map polygon is one of the most critical factors, and
a polygon size greater than 50 km2 is reliable for such analyses for the Chungbuk example. Combined lithologies in a single mapping unit are not critically
affected by decision tree prediction. 相似文献
18.
因子分析结果受样品数量的影响，同一件样品的因子计量也随之发生变化，使传统因子计量方法在地球化学数据处理中的应用受到一定的限制。因子计量模型法综合了因子计量的优点和利用模型找矿的思路，通过选定的某一典型地质单元计算因子计量系数矩阵，建立因子计量模型，用模型类比未知区。该方法使因子计量图的地球化学意义更加明确，并且可节省重新处理数据的工作量。因子计量模型方法和传统因子计量方法应用于某地区1：20万水系沉积物地球化学数据处理，因子计量模型法得出的地球化学异常规律性更为明显，更好地反映了区域地质构造与异常的关联性，有利于异常的解释和评价。 相似文献
19.
This work presents the stratigraphy and facies analysis of an interval of about 2500 m in the Langhian and Serravallian stratigraphic succession of the foredeep turbidites of the Marnoso‐arenacea Formation. A high‐resolution stratigraphic analysis was performed by measuring seven stratigraphic logs between the Sillaro and Marecchia lines (60 km apart) for a total thickness of about 6700 m. The data suggest that the stratigraphy and depositional setting of the studied interval was influenced by syndepositional structural deformations. The studied stratigraphic succession has been subdivided into five informal stratigraphic units on the basis of how structurally controlled topographic highs and depocentres, a consequence of thrust propagation, change over time. These physiographic changes of the foredeep basin have also been reconstructed through the progressive appearance and disappearance of thrust‐related mass‐transport complexes and of five bed types interpreted as being related to structurally controlled basin morphology. Apart from Bouma‐like Type‐4 beds, Type‐1 tripartite beds, characterized by an internal slurry unit, tend to increase especially in structurally controlled stratigraphic units where intrabasinal topographic highs and depocentres with slope changes favour both mud erosion and decelerations. Type‐2 beds, with an internal slump‐type chaotic unit, characterize the basal boundary of structurally controlled stratigraphic units and are interpreted as indicating tectonic uplift. Type‐3 beds are contained‐reflected beds that indicate different degrees of basin confinement, while Type‐5 are thin and fine‐grained beds deposited by dilute reflected turbulent flows able to rise up the topographic highs. The vertical and lateral distribution of these beds has been used to understand the synsedimentary structural control of the studied stratigraphic succession, represented in the Marnoso‐arenacea Formation by subtle topographic highs and depocentres created by thrust‐propagation folds and emplacements of large mass‐transport complexes. 相似文献
20.
Geochemical characteristics of fine and coarse fractions of sediments in the Yarlung Zangbo River Basin (southern Tibet,China) 总被引：1，自引：0，他引：1
Shisong Du Yongqiu Wu Lihua Tan Wenmin Huang Chengzhi Hao 《Environmental Earth Sciences》2018,77(9):337
Tracing sources of aeolian sediment is key to reconstructing earth surface processes in arid areas and interpreting the paleoenvironmental significance of aeolian sequences. However, the difference of geochemical characteristics between different fractions of sediments in the Yarlung Zangbo River Basin (YZRB) is still unclear, so we want to identify which fraction of sediments is more suitable for tracing sediment sources. Considering the long distance between different wide valleys in the YZRB, we wonder whether there is any difference between these wide valleys in terms of geochemical characteristics of sediments. Forty-three surface sediment samples in the YZRB are collected, and the grain-size distributions and the major-element composition for 37 samples and the trace and rare earth element composition for the coarse (75–500 μm) and fine (<?75 μm) fractions of all samples are determined. The results reveal the following: (1) the fine fractions of the deposits contain more environmental information, suggesting that the fine fractions cannot be directly compared between different climate zones for provenance identification and that appropriate coarse fractions, based on the grain-size distribution of the targeted sediments, are more ideal for tracing sediment sources; and (2) geochemical characteristics of various sediment types show spatial heterogeneity. The coarse and fine fractions of the loose sediment samples can be divided into two regional groups based on geochemical characteristics: the Maquanhe zone in the upper reach, the Xigaze, Shannan and Mainling zone in the middle reach, which is consistent with the geological background of the YZRB; (3) aeolian deposits in the YZRB are a local origin and predominantly derived from the adjacent loose sediments, and fluvial sediments in the upper reach contribute little to the aeolian sands in the middle reach. 相似文献