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1.
《Limnologica》2021
The concern about emerging contaminants such as pharmaceuticals is growing, mainly due to the increased global consumption of synthetic chemicals and the potential risk to environmental and human health. Although developing countries may be hotspots of pharmaceutical pollution, the knowledge about the occurrence of pharmaceuticals is still limited and patchy. Brazil holds one of the largest freshwater volumes globally, yet, little is known about the occurrence of pharmaceuticals in reservoirs although they make up key water sources. The aim of this study was, therefore, to investigate micropollutant occurrence, mainly pharmaceuticals, in four freshwater reservoirs distributed in Brazil. Water samples were collected in the Curuá-Una (CUN, Amazon region), Chapéu D’Uvas (CDU, Atlantic Forest region), Funil (FUN, Atlantic Forest region), and Simplício (SIM, Atlantic Forest region) reservoirs. The occurrence of 28 different micropollutants, including 26 pharmaceuticals, was investigated with target analysis on a UHPLC-Orbitrap-MS/MS, and a non-target screening approach was performed on all water samples to identify the presence of additional contaminants. The highest micropollutant concentrations were observed in FUN and SIM, which are the reservoirs with the largest population size in the catchment. Only caffeine was detected in CDU and CUN, which are reservoirs less influenced by urbanization. Metformin was the pharmaceutical with the highest concentrations, reaching 2 191 ng L−1 in FUN. The non-target screening identified 125 chemicals, of which most were pharmaceuticals. The numbers of compounds identified and which were above the LOQ were higher in FUN and SIM, in agreement with results from the target analysis. Metformin is the compound with the highest risk to affect FUN reservoir negatively, based on calculated risk quotients. Considering that the reservoirs are used for multiple purposes, including water supply, irrigation, and aquaculture, it is important to continue investigating micropollutant occurrence to guarantee environmental and human health. 相似文献
2.
太湖地区农业源污染核算研究进展 总被引：6，自引：4，他引：2
太湖地区水体污染严重,控制太湖污染、改善太湖水质,对发挥太湖的综合服务功能,促进全流域经济可持续发展和社会稳定具有重要的战略意义.充分把握和核算太湖地区农业源污染排放量、入河量及其时空分布是落实太湖地区污染物科学减排从而进一步改善太湖水质的基础.本研究总结和概述了太湖地区农业源污染现有的核算方法、产排污参数、控制途径等,结合太湖地区农业源污染构成、排放与布局的复杂情况,提出综合运用各种核算研究方法,充分考虑各污染来源,确定农业源污染的产污量、排污量和入河量,并通过建立分期、分区、细分类型的农业源污染排放、入河参数,为科学确定农业源污染减排指标以及制定减排措施提供依据. 相似文献
3.
This study investigates the applicability of selected pharmaceutical compounds (e.g. sulfamethoxazole, carbamazepine, ibuprofen) as anthropogenic indicators for the interaction of surface water and groundwater in the hyporheic zone of an alluvial stream. Differences in transport behaviour and the resulting distribution of the pharmaceuticals in the riverine groundwater were evaluated. The investigated field site in the Grand Duchy of Luxembourg, Europe is represented by low permeable sediments and confined aquifer conditions. Water samples from single‐screen and multilevel observation wells installed in the riverbank at the field site were taken and analysed for selected pharmaceuticals and major ions for a period of 6 months. Surface water and groundwater levels were recorded to detect effluent and influent aquifer conditions. Nearly all pharmaceuticals that were detected in the stream were also found in the riverine groundwater. However, concentrations were significantly lower in groundwater than in surface water. A classification into mobile and sorbing/degradable pharmaceuticals based on their transport relevant properties was made and verified by the field data. Gradients with depth for some of these pharmaceuticals were documented and a more detailed understanding of the system stream/riverbank was obtained. It was demonstrated that the selected pharmaceutical compounds can be used as anthropogenic indicators at the investigated field site. However, not all compounds seem to be suitable indicators as their transport behaviour is not fully understood. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
4.
The pollution of groundwater and unsaturated zone rocks by oil products and PAH in urban areas 总被引：1，自引：0，他引：1
An approach to assessing the hazard of unsaturated zone rocks as a source of subsoil-water secondary pollution by oil products and PAH is considered based on environmental-geochemical studies of soils and rocks of the unsaturated zone, groundwater, and snow, which were carried out during the rehabilitation of the water environment of Lefortovskii Park (Moscow). The impact of the primary pollution sources is analyzed, and the formation of groundwater and rock pollution by oil products and PAH is considered. To assess the role of the unsaturated zone as a secondary source of pollution of surface and subsurface waters under the conditions of possible elimination of the primary sources, the transport of oil products (benzol and toluene) and PAH (pyrene) in unsaturated zone was simulated using WHI UnSat Suite Plus software package. 相似文献
5.
Dubai Creek is a tidal marine intrusion bisecting Dubai within the United Arab Emirates (UAE). The creek extends 14km inland from its opening into the Arabian Gulf, with a narrow lower creek channel leading to a lagoon section in the upper creek. The creek contains numerous sources of organic pollution including sewage outlet flows and boat waste. A survey of the creek was performed, assessing organic pollution, water properties, and the benthic macrofaunal community. The upper creek was heavily polluted with macrofauna communities commonly associated with organic pollution and eutrophication, while the lower creek contained low pollution and relatively healthy macrofauna communities. There is little net tidal flow of water within the creek and residence time in the lagoon is high, which may account for the high organic pollution levels. However, some evidence of the pollution effect moving into the lower creek was found. The results are considered in light of current and historic organic loading within the creek and future developments in the area. 相似文献
6.
Characteristics of distribution and transport of petroleum contaminants in fracture-karst water in Zibo Area, Shandong Province, China 总被引：8，自引：0，他引：8
Fracture-karst water is an important water resource for the water supply in North China. Petroleum contamination is one of
the most problematic types of the groundwater pollution. The characteristics of distribution and transport of the petroleum
contaminants in fracture-karst water are different from those in porous water. The flow velocity of fracture-karst water is
much faster than the velocity of porous water on an average. Therefore, contaminant transport in fracture-karst water is an
absolute advection-dominated problem. The plume of the petroleum contamination may extend to several kilometers from pollution
sources. It was not caused by the oil pool floating on the water table but by the oil components dissolved and scattered in
groundwater. The distribution of the petroleum contaminants over space are concentrated in the strong conductive zone on the
plane. On the vertical section the highest concentration of the oil contaminants appeared in the strata where the contamination
sources were located. The concentrations of the oil contaminants in wells changed greatly over time. Therefore, the curves
of concentration versus time fluctuated greatly. The reasons are as follows. (a) Fracture-karst water has a very great velocity.
(b) Local flow fields which were caused by pumping and stoppage in some wells changed frequently. (c) In fracture-karst aquifer
the transport channels are complicated. (d) Residual oil in vadose zone was leached after rainfall. It is of great practical
value for the control and remediation of petroleum contamination in fracture-karst aquifer to understand those characteristics. 相似文献
7.
A series of methods for assessing water body pollution by chemical characteristics are considered as applied to water bodies in the operation zone of mining plants. In some methods, the estimate of water body pollution may reflect regional features of waters, rather than their pollution. Evaluating the environmentally allowable concentrations of elements and their biogeochemical tolerance has shown those values to increase with increasing water body pollution, a fact that contradicts the essence of those characteristics. The most simple and universal is a procedure for evaluating water pollution index with the use of regional MACs, taking into account the geochemical background concentrations of the elements and their toxicity using as a criterion the value of MAC for water bodies used for fishery. 相似文献
8.
The non-point source pollution in livestock-breeding areas of the Heihe River basin in Yellow River 总被引：4，自引：0，他引：4
Hongguang Cheng Wei Ouyang Fanghua Hao Xiyan Ren Shengtian Yang 《Stochastic Environmental Research and Risk Assessment (SERRA)》2007,21(3):213-221
A GIS-based distributed soil and water assessment tools (SWAT) model was used to simulate the runoff, sediment yield and the
load of the non-point source pollution in the Heihe River basin, which is a tributary and main water supply source of the
Yellow River. It is a typical stockbreeding area, and its industry and agriculture are not well developed. The main pollution
source of the Heihe River was livestock related non-point source pollution. With GIS and remote sensing techniques, a database
of non-point source pollution in the Heihe River basin was established. The SWAT model was parameterized for this area. The
pollution load and transportation rules such as nitrogen were illustrated. After several years of hard work, the situations
of point source pollution were more and more accurate. This paper provided an effective way to assess and calculate the pollution
load in the wide agriculture area in China. With the help of historical data formulated parameters, the non-point source load
and the theory of pollution load distribution were illustrated about the Heihe River basin. In 2000, the soluble N load in this area was 1.06 × 106 kg. By the simulation, the main pollution sources were in the south east of the basin, where
the pasturing areas located in the south-east of Ruoergai County and in north of the Hongyuan County. 相似文献
9.
10.
太浦河是太湖流域重要跨省界河流,沿岸区域污染源众多,下游分布重要水源地,存在突发水污染潜在风险,迫切需要开展区域污染源潜在风险评估,为突发水污染事件的风险防控提供科学依据.本研究通过太浦河周边区域的污染源调研,明确污染源的空间分布与污染源强,确定评估区域的主要污染物（化学需氧量、氨氮、锑、重金属铬、油品、危险化学品）,综合考虑污染源、河流水文、沿岸社会经济等因素,筛选突发水污染潜在风险评估指标,构建评估指标体系,评估突发水污染事件的综合风险,识别太浦河周边区域的主要突发水污染潜在风险源.研究结果表明：太浦河周边区域的高突发水污染风险区呈现片状或斑块状分布,主要包括大型污水处理厂区域、大型工业企业区域、加油站和危险化学品仓库集中分布区、太浦河沿岸工业企业区域、水源地周边工业企业区域,总面积为22 km2,占太浦河污染源风险评估范围总面积的1.4%,是突发水污染事件防控的重点区域. 相似文献
11.
Ian Armstrong Stephen Higham Grant Hudson Troy Colley 《Marine pollution bulletin》1996,33(7-12):249-259
Since the commissioning of the three major deepwater outfalls in Sydney, there has been a dramatic improvement in general beach water quality at Sydney's ocean beaches. This has required the NSW Environment Protection Authority's Beachwatch Programme to shift from assessing the impacts of gross sewage pollution due to nearshore outfalls to more diffuse pollution from stormwater and sewer overflows.
The visual indicators of gross sewage pollution originally used by Beachwatch for the daily assessment of bacterial water quality are now of limited value. General linear models (with multiple effects) were constructed to identify the secondary indicators which best describe the levels of bacterial contamination due to stormwater pollution. Data from four representative Sydney beaches were modelled separately due to the site-specific effects of pollution sources and hydrodynamics. Factors which were built into the models and were known on the day of prediction were rain amount, presence of stormwater material, the maximum daily stormwater rating, drain or lagoon flows at the time of sampling, and the drain/lagoon bacterial concentration two days before sampling.
Results indicate that there is a general linear relationship between visual indicators and bacterial density; however, the reliability of the prediction on a daily basis is poor and rainfall alone as a predictor is equivalent to or better than visual assessment alone. The primary source of information for the preparation of Beachwatch daily pollution bulletins now is rainfall reports from a telemetered network of rain gauges along the coast. This is a more cost-effective approach and has allowed the reallocation of resources to address more directly the problem of stormwater pollution at higher risk beaches. 相似文献
12.
T. I. Moiseenko 《Water Resources》2010,37(6):773-795
The existing approaches to and methods for bioassessment of water quality are critically analyzed. The significance of the methodological approach under the concept of ecosystem “health” as the most integral numerical method for assessing pollution effects. Comparative analysis is given to the significance of criteria based on the state of individuals, populations, and communities. The results of practical testing of the methods developed for biological assessment of water quality for some water bodies are presented. Critical levels are established based on the construction of dose-effect dependences. The basic principles for limiting surface water pollution are formulated. 相似文献
13.
为了确定百花水库营养盐变化特征,选取百花水库5个监测点2014年1月-2018年7月共28个月份的水质实测数据,分析溶解氧、高锰酸盐指数、氨氮、总磷和总氮的年际变化特征.采用基于熵权法赋权的贝叶斯理论对5个监测点的水质综合状况进行评价,并结合水库的实际状况,从生态修复、工业污染源、沉积物中营养盐、水库季节性热分层及农业与生活污染源5个方面对其水质变化的影响因素进行分析.结果表明:2014-2018年水体环境波动较大;除总氮外,各污染指标浓度均有不同程度的下降;综合水质后验概率表明百花水库水质有逐渐变差的趋势;总氮和总磷治理应成为百花水库污染治理的主要方面;生态修复工程的开展和工业污染源的削减是百花水库水质转好的主要影响因素,农业与生活污染源的增加是百花水库水质转差的主要影响因素. 相似文献
14.
Geophysical methods can be applied to investigate the harmful effect of man's activities on the environment: the study of specific electrical resistivities and natural electric fields of filtrational origin makes it possible to control the penetration of exogenic pollutants into soil as well as desalinization and secondary salinization of soils; electrometric and seismometric methods allow to observe the groundwater level near water reservoirs thus evaluating the harmful effect of backing up natural groundwater flow; contrasting properties of bedrocks and rocks in a landslide body permit application of seismic and electrical prospecting methods. Observation of the changes in specific electrical resistivities with time on the slopes of quarries is an effective method of assessing slope stability and predicting landslide hazard. Mining activities, groundwater pumping, and oil extraction are the main causes of endogenic pollution of geological medium; surface and borehole geophysical methods make it possible to assess vertical and horizontal displacements of the interfaces between salty and fresh subterranean waters resulting from an extensive exploitation of water supply sources; activation of geodynamic processes associated with mining activities is determined from the data of ‘regime’ electrometric, seismometric, gravimetric, and inclinometric observations. Geophysical methods are applied widely for studying the intensification of physico-geological processes under the impact of man. A specific object of electrometric investigations is degradation of permafrost and intensification of karst processes in soluble rocks. The principal advantage of geophysical investigations lies in the possibility of creating high spatial and temporal density of observations permitting an extensive employment of statistical methods in the assessment of the impact of man on the geological medium. 相似文献
15.
Different approaches to studying hierarchical problems are compared with the use of a two-stage dynamic model of water quality control in the case of point pollution sources. Variations in pollutant concentrations in a watercourse are described by partial differential equations. The study embraces the cases of a single and multiple point pollution sources and different types of pollutants. 相似文献
16.
The role of bioassay in the pollution control system for water bodies is considered. Studies of the mechanisms of toxic impact of various chemical compounds on aquatic organisms were used to develop a bioindication method to give an integral estimate of water toxicity and determine some classes of chemical pollutants. The results of application of such methods to assessing water quality in Lake Ladoga are given. 相似文献
17.
定量解析污染源对水质影响的贡献是水环境精细化管理的重要基础。目前多通过水质和土地利用类型的关系以解析水体污染源的研究,忽略了空间尺度的差异性,引发景观配置不合理的后果。为此,本研究依据考虑空间尺度效应的污染源解析方法,基于异龙湖流域3条主要入湖河流的入湖口监测断面对雨季和旱季的水质数据进行研究。同时利用绝对主成分—多元线性回归模型(APCS-MLR)和bioenv分析揭示河道不同尺度缓冲区的土地利用变化对水质的影响并解析河流主要污染源。研究结果表明:(1)异龙湖主要入湖河流水质表现出季节性差异,旱季期间3条主要入湖河流的浊度、化学需氧量(CODCr)、氨氮(NH3-N)、总磷(TP)和总氮(TN)浓度平均值相比于雨季减幅分别为39.53%、39.93%、94.48%、38.29%和1.72%。其中,入湖河流水体中的TN在旱季和雨季的超标率分别为58%和74%,成为首要污染物;(2)在旱季,20 m缓冲区尺度内河流水质受耕地和裸地占比影响较大,随着空间尺度的扩大,至50～300 m缓冲区尺度时建设用地、林地及水体占比对水质的影响增加;在雨季,C... 相似文献
18.
随着社会经济和城市化进程的快速发展,湖泊水环境污染问题日益突出,加剧了湖泊原有功能的退化和丧失,因此污染治理成为了湖泊功能恢复和可持续发挥的必要条件,但如何实现污染精准溯源又是污染治理的重要前提。为此,本文以太湖流域滆湖为例,采用一种新兴技术——水质荧光指纹法开展湖泊污染溯源。于2021年累计采集滆湖周边70个农业、13个生活、3个企业排口的瞬时出水构建污染源荧光指纹库,连续12个月采集滆湖湖体8个样点水样分析水体荧光组分。通过平行因子分析共解析出4种污染源指纹和滆湖5种水体组分,经荧光相似度(塔克同余系数)分析进一步明确滆湖主要受到种植业面源、生活源和工业源的影响。此外,荧光强度与叶绿素a浓度和藻密度的强相关性表明藻类繁殖活动也会影响滆湖。从不同污染源对滆湖的时空影响特征来看,种植业面源主要在春、夏季影响西部、中部水域,生活源主要在夏、冬季影响西部、北部水域,工业源主要在特定月份(3 4月、10 12月)影响西部水域,藻类繁殖活动主要在夏季影响湖体。通过荧光组分与水质参数的时空相关性分析得到农业源和总磷、总氮,生活源和氨氮、有机物参数(BOD5、COD... 相似文献
19.
官厅水库水体营养状况分析 总被引：23，自引：4，他引：19
2001-2002年的调研结果显示,官厅水库为富营养型湖泊.初级生产力为浮游藻类与大型水生高等植物混合型.浮游藻类细胞密度为1126.54×104cells/L,其中蓝藻占53.4%,绿藻占32.1%.优势种为水华微囊藻(Microcystisflos-aquae)和铜绿微囊藻(M.aeruginosa).7-10月库区水体出现大面积的微囊藻水华.TN、TP分别为1.182mg/L和0.045mg/L,水体已达富营养.官厅水库TN和TP的质量浓度比大于7,Chla与TP存在显著的正相关.磷是水体中初级生产力增长的限制性营养盐.官厅水库的污染物主要来自点源,其次是面源和内源.应以点源为主进行综合防治,恢复其饮用水源地功能,以缓解北京市淡水资源的紧缺状态. 相似文献
20.
Methods of Hierarchical Control of Water Quality Taking into Account Manipulations of the Center and Countermoves of Enterprises 总被引：2，自引：1，他引：1
Methods of hierarchical control including manipulations of a Center and the countermove of enterprises are considered using as an example a dynamic two-level model of river water quality control in the presence of point pollution sources and in the absence of nonpoint sources. 相似文献