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云母对热塑化木材/马来酸酐接枝聚丙烯结构与性能的影响 总被引：1，自引：0，他引：1
云母是一种高形态化的薄片状硅酸铝矿物,是新型的工业化填料。通过苄基化法在相转移催化剂(PTC)的作用下可将木粉制备成热塑化木材(TPW),然后将热塑化木材、马来酸酐接枝聚丙烯按一定比例配料后,再分别与不同质量的云母共混挤出,制备成热塑化木材/马来酸酐接枝聚丙烯/云母复合材料(TPW/MAH-PP/Mi-ca)。利用扫描电子显微镜和广角X射线衍射仪来研究复合材料的冷淬断面及结晶行为,发现云母含量增加没有改变聚丙烯的结晶晶型,但降低其结晶度;研究材料的力学性能发现:在综合性能比较好的情况下,云母可有效地提高TPW/MAH-PP复合材料的拉伸强度近8%、弯曲强度25%~30%。 相似文献
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软黏土具有压缩性强、承载能力低的特点,实际工程中多用水泥作为固化剂对软黏土进行加固。云母是软黏土中较为常见的一种片状矿物,其含量和颗粒大小会影响水泥加固后的软黏土即水泥软黏土的强度。通过无侧限抗压强度试验和直接剪切试验研究云母含量及目数对水泥软黏土抗压强度及抗剪强度的影响,提出了云母含量、目数与水泥软黏土抗压强度、抗剪强度指标值之间的关系。试验中云母目数设定为10,20,40,80目共4个梯度,云母含量设定为0%、8%、16%、24%、32%共5个梯度。试验结果表明,云母含量的增加以及云母目数的减小会导致水泥软黏土无侧限抗压强度和抗剪强度的降低,且其对无侧限抗压强度的不利影响更为显著。含10目32%云母的水泥软黏土的强度减少量最大,此时无侧限抗压强度为0.33 MPa,是不含云母水泥软黏土的25.5%;黏聚力为76.5 kPa,比不含云母时减少了12.24 kPa;内摩擦角由不含云母时的23.71°降低至21.77°。云母自身的片状形态及其对水泥水解水化作用、离子交换作用的阻碍是造成水泥软黏土强度降低的主要原因。 相似文献
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本文采用高分子固化剂和聚丙烯纤维对砂土进行复合加固,通过对不同聚丙烯纤维含量、固化剂含量和干密度的重塑试样进行抗拉试验,测量试样破坏时的最大拉应力,对比不同试样抗拉强度的变化规律,并结合扫描电镜对复合加固机理进行较为深入的分析。试验结果表明,高分子固化剂和聚丙烯纤维的复合加固能够显著提高砂土的抗拉强度,纤维含量、固化剂含量和干密度对改良砂土的抗拉强度均具有较大的影响。当干密度和高分子固化剂含量一定时,砂土抗拉强度随纤维含量的增加逐渐增加,当固化剂含量为4%,干密度为1.5 g·cm-3时,纤维含量从0.2%到0.8%,抗拉强度从79.06 kPa增加到194.51 kPa;当干密度和纤维含量一定时,砂土抗拉强度随着高分子固化剂含量的增加而增加,当纤维含量为0.8%,干密度为1.5g·cm-3时,固化剂含量从1%到4%,抗拉强度从63.16 kPa增加到194.51 kPa;当高分子固化剂含量和纤维含量一定时,抗拉强度随着干密度的增加先增加后减小,在干密度为1.55 g·cm-3左右达到峰值。复合加固结合物理和化学加固的优点,通过纤维在颗粒间的相互作用力和固化剂在颗粒间的联结力,从而提高改良砂土的抗拉性能。本研究结果为进一步研究砂土复合加固及其工程应用提供一定的参考依据。 相似文献
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采用经铝酸酯偶联剂改性的伊利石粉做填料,对PVC进行了填充改性,采用熔融共混制备伊利石/PVC复合材料,并对复合材料的力学性能进行测试。研究表明,改性后的伊利石对软质PVC材料有明显的增强作用,其拉伸强度随着伊利石填充量增加先增大,后逐渐减小。填充量为6质量份时达到最大值15.01 MPa,较纯PVC提高30%,填充8质量份时拉伸强度开始下降但依然有18%的提升。随伊利石的添加量增大,复合材料的断裂伸长率比纯PVC低,其塑性下降。 相似文献
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为了提高普通乳化沥青混合料的路用性能,将乳化沥青与水性环氧树脂有机结合,得到一种新型复合材料——水性环氧乳化沥青。通过试验研究水性环氧树脂用量对混合料的力学强度、水稳定性以及温度稳定性的影响。结果表明：混合料的初期强度、后期强度以及高温稳定性随着水性环氧树脂用量的增加而提高,但其水稳定性和低温稳定性随着水性环氧树脂用量的增加先增大后减小,分别在水性环氧树脂用量为10%和15%时达到最佳提升效果。在实际工程应用中将水性环氧树脂用量控制在10%~15%之间。 相似文献
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多种矿物合理组合对工程塑料增强效果显著 总被引：3，自引：0，他引：3
硅灰石、滑石、绢云母与工程塑料ABS复合的系统实验表明：单一矿物参与复合时，矿物晶体产生的形态效应和结构效应对复合材料性能起主要影响作用，不同晶体形态和结构的矿物合理组合产生的协同效应对复合材料性能的影响作用更大。复合材料性能优于纯ABS，多矿物复合材料的性能最优，且复合体系的加工性能良好。 相似文献
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应用X射线衍射-扫描电镜-光学显微镜鉴定黑龙江石墨尾矿中的绢云母 总被引：2，自引：2，他引：0
石墨尾矿作为一类二次资源,当云母类矿物的含量在10%以上时,具有回收利用价值。黑龙江某地石墨尾矿中含有10%以上的云母类矿物,但其细度(500~800目)低于常规的云母矿,本文采用X射线衍射(XRD)分析矿物组成,再结合化学分析、扫描电镜-能谱、光学显微镜与纯矿物进行对比,由此鉴定云母类矿物种属。XRD研究初步表明石墨尾矿含有的云母族矿物属于白云母亚类或黑云母亚类。扫描电镜分析表明尾矿中的云母矿物与纯绢云母矿物均以片状和鳞片状为主要存在形态,而纯黑云母主要以片状形式存在。尾矿的Si O2含量为5%~13%,Al2O3含量为4%~8%,与纯绢云母接近。光学显微镜鉴定显示在正交偏光下石墨尾矿中的云母颜色和纯绢云母类似,而与纯黑云母截然不同。综合以上结果最终可确定该地石墨尾矿中的云母族矿物为白云母亚类中的绢云母。本研究为后续石墨尾矿的选矿工艺奠定了基础,也可应用于类似细度绢云母的鉴定。 相似文献
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Emily Keeble David I. Whiteside Michael J. Benton 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(2):99-119
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco. 相似文献
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The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts 总被引：4，自引：0，他引：4
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species. 相似文献
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Muriel Rocher Stéphane Baize Stéphane Jaillet Edward Marc Cushing Yannick Lozac&#x;h Francis Lemeille 《Comptes Rendus Geoscience》2003,335(8):701-708
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003). 相似文献
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正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level 相似文献
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正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7), 相似文献
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正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci- 相似文献
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正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli- 相似文献
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正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.) 相似文献
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正20142002 Wei Hualing(Institute of Geophysical and Geochemical Exploration,Chinese Academy of Geological Sciences,Langfang065000,China);Zhou Guohua Element Content and Mineral Compositions in Different Sizes of Soil in Tongling Area,Anhui Province(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(11),2013,p.1861 相似文献