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1.
The atomic fractions Mg/(Mg + Fe) and the Mg-Fe distribution coefficient $$K_{{\text{D}}{\text{.Mg - Fe}}}^{{\text{Ca - am - Cum}}} \left( { = \tfrac{{[{\text{Mg/Fe]}}_{{\text{Ca - am}}} }}{{{\text{[Mg/Fe]}}_{{\text{Cum}}} }}} \right)$$ are calculated for 31 metamorphic cummingtonite-hornblende pairs. Data on 21 pairs are taken from the litterature, and new electron microprobe analyses and structural formulae are presented of nine pairs from Tydal, Sör-Tröndelag, Norway, and of one pair from Cooma, N.S.W., Australia (cf. Kisch, 1969). The electron microprobe methods used are described, particularly the use of mineral standards, and the variation of the mass absorption in substitution series. The hornblendes from the Tydal pairs are markedly pargasitic in composition, and contain minor proportions of the cummingtonite “molecule”. The Mg-Fe distributions in the cummingtonite-hornblende pairs — as plotted on a [Mg/(Mg + Fe)]Ca-am vs. [Mg/(Mg + Fe)]Cum diagram (Fig. 3) — differ significantly from the Mg-Fe distribution curve for cummingtonite-actinolite pairs from Quebec (Mueller, 1961). Whereas the actinolites have markedly higher Mg/Fe ratios than the co-existing cummingtonites (K D.Mg-Fe Ca-am-Cum ≈ 1.5–2.0), the cummingtonite-hornblende pairs diverge towards lower values from the distribution coefficient. In most of the metamorphic cummingtonite-hornblende pairs — including the nine pairs from Tydal — the Mg/Fe ratio of the hornblende is lower than in the co-existing cummingtonite, i.e K D.Mg-Fe Ca-am-Cum <1. A relation appears to exist between the Mg-Fe distribution and the Al content of the calcic amphibole phase. This is believed to be due to the non-random distribution of AlY among the octahedral lattice sites: in hornblende AlVI enters the M 1+M3 positions, in which Mg is preferred over Fe, rather than M 2, in which Fe is preferred (Ghose, 1965). Since the cummingtonites remain Al-poor, the over-all Mg/Fe ratio in the hornblende is reduced relative to the co-existing cummingtonite as a result. The variations of the Mg-Fe distribution in the cummingtonite-hornblende pairs can also be related directly to the presence and composition of the plagioclase and other Al-rich phases in the metamorphic mineral assemblage. In any range of Mg/Fe ratios, the cummingtonite-hornblende pairs associated with oligoclase have lower distribution coefficients (0.61–0.81; 12 pairs) than those associated with calcic plagioclase or plagioclase-free assemblages (0.97 to 1.89; 6 pairs); the pairs associated with andesine have intermediate Mg-Fe distributions (0.74–1.15; 6 pairs).  相似文献   

2.
Three new sets of mineral and rock chemical data on basic granulites confirm the trends in compositional relationships, with respect to magnesium and iron, among hornblende, orthopyroxene and calcic pyroxene advanced by Sen (1970) and Ray and Sen (1970). Analysing the interrelationships among magnesium-iron distribution coefficients between hornblende-orthopyroxene and hornblende-calcic pyroxene, tetrahedral aluminium contents of hornblendes, and temperature of equilibration, it can be shown that equilibrium temperatures are higher with the Mg/(Mg+Fe) ratios of hornblendes increasing. An application of these relations to ferromagnesian phases of some garnet-bearing basic granulites points to formation of garnets in response to decreasing temperature.  相似文献   

3.
Hornblende-orthopyroxene-calcic pyroxene-plagioclase (andesine-labradorite) — magnetite-ilmenite±quartz assemblages are evidently the most common granulite facies representatives of basic rocks throughout the world, and they must represent a variance of more than one. Ramberg (1948) invoked an additional degree of freedom arising out of unequal fractionation of Mg and Fe in the ferromagnesian silicates in such rocks. This is examined in detail on the basis of chemical data on twentytwo hornblende-orthopyroxenecalcic pyroxene triads, half of them from the type charnockite area near Madras.Theoretical consideration of a magnesium-iron distribution model shows that in quartz-bearing hornblende pyroxene granulites, the Mg/Mg+Fe ratios of hornblende, orthopyroxene and calcic pyroxene are uniquely determined by temperature at constant pressure. But these assemblages contain quartz rarely and Mg-Fe distribution among the three can be best described by three exchange equilibria where, at constant temperature, there is a fixed relation between the Mg/Mg+Fe ratios of the minerals. Among these, the exchange equilibria between hornblende-orthopyroxene and hornblende-calcic pyroxene appear to be interdependent; however, they are known to be significantly modified by varying tetrahedral aluminium contents of hornblendes. Comparison of molecular Mg/(Mg+Fe) ratios of hornblendes and parent rocks strongly points to an absence of Mg-Fe compositional variance in the total system, a petrologically important corollary being that the hornblendes in these rocks are highly unlikely to be secondary after pyroxenes. The general variance of the assemblages is also discussed.  相似文献   

4.
Equilibria in the Sirf (Silica-Ilmenite-Rutile-Ferrosilite) system: $${\text{SiO}}_{\text{2}} + ({\text{Mg,Fe}}){\text{TiO}}_{\text{3}} {\text{ + (Mg,Fe)SiO}}_{\text{3}} $$ have been calibrated in the range 800–1100° C and 12–26 kbar using a piston-cylinder apparatus to assess the potential of the equilibria for geobarometry in granulite facies assemblages that lack garnet. Thermodynamic calculations indicate that the two end-member equilibria involving quartz + geikielite = rutile + enstatite, and quartz + ilmenite = rutile + ferrosilite, are metastable. We therefore reversed equilibria over the compositional range Fs40–70, using Ag80Pd20 capsules with \(f_{{\text{O}}_{\text{2}} } \) buffered at or near iron-wüstite. Ilmenite compositions coexisting with orthopyroxene are \(X_{{\text{MgTiO}}_{\text{3}} }^{{\text{Ilm}}} \) of 0.06 to 0.15 and \(X_{{\text{Fe}}_{\text{2}} {\text{O}}_{\text{3}} }^{{\text{Ilm}}} \) of 0.00 to 0.01, corresponding toK D values of 13.3, 10.2, 9.0 and 8.0 (±0.5) at 800, 900, 1000 and 1100° C, respectively, whereK D =(XMg/XFe)Opx/(XMg/XFe)Ilm. Pressures have been calculated using equilibria in the Sirf system for granulites from the Grenville Province of Ontario and for granulite facies xenoliths from central Mexico. Pressures are consistent with other well-calibrated geobarometers for orthopyroxeneilmenite pairs from two Mexican samples in which oxide textures appear to represent equilibrium. Geologically unreasonable pressures are obtained, however, where oxide textures are complex. Application of data from this study on the equilibrium distribution of iron and magnesium between ilmenite and orthopyroxene suggests that some ilmenite in deep crustal xenoliths is not equilibrated with coexisting pyroxene, while assemblages from exposed granulite terranes have reequilibrated during retrogression. The Sirf equilibria are sensitive to small changes in composition and may be used for determination of activity/composition (a/X) relations of orthopyroxene if an ilmenite model is specified. A symmetric regular solution model has been used for orthopyroxene in conjunction with activity models for ilmenite available from the literature to calculatea/X relations in orthopyroxene of intermediate composition. Data from this study indicate that FeSiO3?MgSiO3 orthopyroxene exhibits small, positive deviations from ideality over the range 800–1100°C.  相似文献   

5.
Feldspathic hornblende granulites from Doubtful Sound, New Zealand with the assemblage plagioclase+hornblende+clinopyroxene+orthopy-roxene +oxide+apatite are criss-crossed by a network of garnetiferous anorthosite veins and pegmatites. The feldspathic gneiss in contact with anorthosite has a reaction zone containing the assemblage plagioclase +garnet+clinopyroxene+quartz+rutile+apatite. The garnet forms distinctive coronas around clinopyroxene. The origin of these rocks is discussed in the light of mineral and whole rock chemical analyses and published experimental work.It is thought that under conditions leading up to 750 °C, 8 kb load pressure and 5 kb H2O pressure, partial melting occured in feldspathic hornblende granulites. The melt migrated into extensional fractures and eventually crystallised as anorthosite pegmatites and veins. The gneisses adjacent to the pegmatites from which the melt was extracted changed composition slightly, by the loss of H2O and Na2O, so that plagioclase reacted simultaneously with hornblende, orthopyroxene, and oxide to form garnet, clinopyroxene, quartz and rutile.  相似文献   

6.
The partitioning of Fe and Mg between garnet and aluminous orthopyroxene has been experimentally investigated in the pressure-temperature range 5–30 kbar and 800–1,200° C in the FeO-MgO-Al2O3-SiO2 (FMAS) and CaO-FeO-MgO-Al2O3-SiO2 (CFMAS) systems. Within the errors of the experimental data, orthopyroxene can be regarded as macroscopically ideal. The effects of Calcium on Fe-Mg partitioning between garnet and orthopyroxene can be attributed to non-ideal Ca-Mg interactions in the garnet, described by the interaction term:W CaMg ga -W CaFe ga =1,400±500 cal/mol site. Reduction of the experimental data, combined with molar volume data for the end-member phases, permits the calibration of a geothermometer which is applicable to garnet peridotites and granulites: $$T(^\circ C) = \left\{ {\frac{{3,740 + 1,400X_{gr}^{ga} + 22.86P(kb)}}{{R\ln K_D + 1.96}}} \right\} - 273$$ with $$K_D = {{\left\{ {\frac{{Fe}}{{Mg}}} \right\}^{ga} } \mathord{\left/ {\vphantom {{\left\{ {\frac{{Fe}}{{Mg}}} \right\}^{ga} } {\left\{ {\frac{{Fe}}{{Mg}}} \right\}}}} \right. \kern-\nulldelimiterspace} {\left\{ {\frac{{Fe}}{{Mg}}} \right\}}}$$ and $$X_{gr}^{ga} = (Ca/Ca + Mg + Fe)^{ga} .$$ The accuracy and precision of this geothermometer are limited by largerelative errors in the experimental and natural-rock data and by the modest absolute variation inK D with temperature. Nevertheless, the geothermometer is shown to yield reasonable temperature estimates for a variety of natural samples.  相似文献   

7.
A deep-level crustal section of the Cretaceous Kohistan arc is exposed in the northern part of the Jijal complex. The occurrence of mafic to ultramafic granulite-facies rocks exhibits the nature and metamorphic evolution of the lower crust. Mafic granulites are divided into two rock types: two-pyroxene granulite (orthopyroxene+clinopyroxene+plagioclase±quartz [1]); and garnet–clinopyroxene granulite (garnet+clinopyroxene+plagioclase+quartz [2]). Two-pyroxene granulite occurs in the northeastern part of the Jijal complex as a relict host rock of garnet–clinopyroxene granulite, where the orthopyroxene-rich host is transected by elongated patches and bands of garnet–clinopyroxene granulite. Garnet–clinopyroxene granulite, together with two-pyroxene granulite, has been partly replaced by amphibolite (hornblende±garnet+plagioclase+quartz [3]). The garnet-bearing assemblage [2] is expressed by a compression–dehydration reaction: hornblende+orthopyroxene+plagioclase=garnet+clinopyroxene+quartz+H2O↑. Subsequent amphibolitization to form the assemblage [3] is expressed by two hydration reactions: garnet+clinopyroxene+plagioclase+H2O=hornblende+quartz and plagioclase+hornblende+H2O=zoisite+chlorite+quartz. The mafic granulites include pod- and lens-shaped bodies of ultramafic granulites which consist of garnet hornblendite (garnet+hornblende+clinopyroxene [4]) associated with garnet clinopyroxenite, garnetite, and hornblendite. Field relation and comparisons in modal–chemical compositions between the mafic and ultramafic granulites indicate that the ultramafic granulites were originally intrusive rocks which dissected the protoliths of the mafic granulites and then have been metamorphosed simultaneously with the formation of garnet–clinopyroxene granulite. The results combined with isotopic ages reported elsewhere give the following tectonic constraints: (1) crustal thickening through the development of the Kohistan arc and the subsequent Kohistan–Asia collision caused the high-pressure granulite-facies metamorphism in the Jijal complex; (2) local amphibolitization of the mafic granulites occurred after the collision.  相似文献   

8.
几种镁铁矿物平衡共生的成分标志   总被引：3，自引：0，他引：3  
阎月华 《地质科学》1997,32(3):267-274
本文以晋冀内蒙边界地区变质岩中主要镁铁质造岩矿物辉石,闪石为例,阐明镁铁矿物平衡共生的一条普遍规律,即平衡共生的正辉石,钙闪石之间有相同的镁铁比,其分配系数等于或接近于1.引用冀东,吉南,泰山和南极凯西站等地的实例,论证了此规律同时存在于黑云母与钙闪石,黑云母与正辉石之间,也存在于辉长岩和花岗岩等岩浆岩的橄榄石和正辉石,角闪石与黑云母等矿物对之间。这是判断镁铁矿物是否平衡的成分标志。  相似文献   

9.
The effect of temperature, pressure, and dissolved H2O in the melt on the Fe2+–Mg exchange coefficient between orthopyroxene and rhyolite melt was investigated with a series of H2O fluid-saturated phase-equilibrium experiments. Experiments were conducted in a rapid-quench cold-seal pressure vessel over a temperature and pressure range of 785–850 °C and 80–185 MPa, respectively. Oxygen fugacity was buffered with the solid Ni–NiO assemblage in a double-capsule assembly. These experiments, when combined with H2O-undersaturated experiments in the literature, show that \( ^{{{\text{Fe}}^{2 + } {-}{\text{Mg}}}} K_{\text{D}} \) between orthopyroxene and rhyolite liquid increases strongly (from 0.23 to 0.54) as a function of dissolved water in the melt (from 2.7 to 5.6 wt%). There is no detectable effect of temperature or pressure over an interval of 65 °C and 100 MPa, respectively, on the Fe2+–Mg exchange coefficient values. The data show that Fe-rich orthopyroxene is favored at high water contents, whereas Mg-rich orthopyroxene crystallizes at low water contents. It is proposed that the effect of dissolved water in the melt on the composition of orthopyroxene is analogous to its effect on the composition of plagioclase. In the latter case, dissolved hydroxyl groups preferentially complex with Na+ relative to Ca2+, which reduces the activity of the albite component, leading to a more anorthite-rich (calcic) plagioclase. Similarly, it is proposed that dissolved hydroxyl groups preferentially complex with Mg2+ relative to Fe2+, thus lowering the activity of the enstatite component, leading to a more Fe-rich orthopyroxene at high water contents in the melt. The experimental results presented in this study show that reversely zoned pyroxene (i.e., Mg-rich rims) in silicic magmas may be a result of H2O degassing and not necessarily the result of mixing with a more mafic magma.  相似文献   

10.
Assessment of groundwater quality is essential to ensure sustainable use of it for drinking, agricultural, and industrial purposes. The chemical quality of groundwater of Gaya region has been studied in detail in this work to delineate the potable groundwater zones. A total of 30 groundwater samples and 2 surface water samples were collected in and around Gaya district of Bihar. The major cations follow the trend: Ca2+?>?Mg2+?>?Na+?>?K+. The domination of calcium ions in the groundwater is due to weathering of rocks. The K+ ranged between 0.2 and 47.95 ppm, suggesting its abundance the below desired limit; but some samples were found to be above permissible limit. K+ weathering of potash silicate and the use of potash fertilizer could be the source. The major anions abundance followed the order HCO 3 ? ?>?Cl??>?SO 4 2? ?>?NO 3 ? ?>?PO 4 3? . Dissolution of carbonates and reaction of silicates with carbonic acid accounts for the addition of HCO 3 ? to the groundwater and oxidation of sulphite may be the source of SO 4 2? . Principal component analysis was utilized to reflect those chemical data with the greatest correlation and seven major principal components (PCs) representing >80 % of cumulative variance were able to interpret the most information contained in the data. PC1, PC2 and PC3 reflect the hydrogeochemical processes like mineral dissolution, weathering and anthropogenic sources. PC4, PC5, PC6 and PC7 show monotonic, random and independent relationships.  相似文献   

11.
The voluminous Pleistocene—Recent Taupo rhyolites typically contain phenocrysts of plagioclase (oligoclase-labradorite), quartz, titanomagnetite, ilmenite, and ferromagnesian silicates. Ferromagnesian assemblages correlate with well defined Fe-Ti oxide equilibration temperature ranges and allow the rhyolites to be subdivided as follows: (1) Cummingtonite (c)—calcic hornblende (hb)—orthopyroxene (opx); 725–755°C, (2) Hb-opx, 750–825°C, (3) Biotite-hb-(c-opx), 720–765°C, (4) Opx-clinopyroxene (cpx), 860–915°C, (5) Fe olivine-opx-cpx, one sample with temperature of 900°C. Plagioclase and orthopyroxene phenocryst compositions typically exhibit a range of composition up to ～20 mol.%. Calculated average phenocryst equilibration pressures (P total) range between 0.5–4.9 kb, and average 2.2 kb (～7–8 km depth), indicating upper crustal crystallization. These calculations are very sensitive to variations in phenocryst composition. Calculated \(/_{{\text{H}}_2 {\text{O}}} \) for the amphibole and biotite-bearing rhyolites indicate phenocryst equilibration under \(P_{{\text{H}}_2 {\text{O}}} \simeq P_{{\text{total}}} \) , with \(X_{{\text{H}}_2 {\text{O}}} \) ～0.17–0.24 (5–8 wt. %). The precipitation of cummingtonite is thus temperature dependent, the upper limit being close to 760°C. Eruptive mechanisms of the lavas, pumices, and ash-flow deposits are evidently not primarily controlled by temperature, P total, \(P_{{\text{H}}_2 {\text{O}}} \) , or crystal content of the magmas, and explanations must lie in kinetic and fluid dynamic behavior of the magmas. For the Taupo rhyolites, it is suggested that the critical size of a magma body (i.e. Rayleigh number) is a controlling factor in that it will influence the convective regime; fully turbulent convection is deduced to have occurred within the larger magma bodies. One consequence is intense vesiculation, prior to eruption, within the uppermost zones of these magma chambers, and the voluminous pumice deposits are believed to emanate from such chambers. Oscillatory compositional zoning within pyroxene phenocrysts is consistent with magma convection.  相似文献   

12.
Garnet growth in high‐pressure, mafic garnet granulites formed by dehydration melting of hornblende‐gabbronorite protoliths in the Jijal complex (Kohistan palaeo‐island arc complex, north Pakistan) was investigated through a microstructural EBSD‐SEM and HRTEM study. Composite samples preserve a sharp transition in which the low‐pressure precursor is replaced by garnet through a millimetre‐sized reaction front. A magmatic foliation in the gabbronorite is defined by mafic‐rich layering, with an associated magmatic lineation defined by the shape‐preferred orientation (SPO) of mafic clusters composed of orthopyroxene (Opx), clinopyroxene (Cpx), amphibole (Amp) and oxides. The shape of the reaction front is convoluted and oblique to the magmatic layering. Opx, Amp and, to a lesser extent, Cpx show a strong lattice‐preferred orientation (LPO) characterized by an alignment of [001] axes parallel to the magmatic lineation in the precursor hornblende‐gabbronorite. Product garnet (Grt) also displays a strong LPO. Two of the four 〈111〉 axes are within the magmatic foliation plane and the density maximum is subparallel to the precursor magmatic lineation. The crystallographic relationship 〈111〉Grt // [001]Opx,Cpx,Amp deduced from the LPO was confirmed by TEM observations. The sharp and discontinuous modal and compositional variations observed at the reaction front attest to the kinetic inhibition of prograde solid‐state reactions predicted by equilibrium‐phase diagrams. The P–T field for the equilibration of Jijal garnet granulites shows that the reaction affinities are 5–10 kJ mol.?1 for the Grt‐in reaction and 0–5 kJ mol.?1 for the Opx‐out reaction. Petrographic and textural observations indicate that garnet first nucleated on amphibole at the rims of mafic clusters; this topotactic replacement resulted in a strong LPO of garnet. Once the amphibole was consumed in the reaction, the parallelism of [001] axes of the mafic‐phase reactants favoured the growth of garnet crystals with similar orientations over a pyroxene substrate. These aggregates eventually sintered into single‐crystal garnet. In the absence of deformation, the orientation of mafic precursor phases conditioned the nucleation site and the crystallographic orientation of garnet because of topotaxial transformation reactions and homoepitaxial growth of garnet during the formation of high‐pressure, mafic garnet‐granulite after low‐pressure mafic protoliths.  相似文献   

13.
Experimental data combined with data from natural rocks have been used to calibrate a geothermometer based on the distribution of Fe2+ and Mg between coexisting garnets and phengites. The pressure effect on the K D -value appears to be considerable. The calculated thermometer is expressed as $$T(K) = \frac{{3685 + 77.1P(kb)}}{{InK_D + 3.52}}.$$ The use of this \(K_{D_{(FeO/MgO)} }^{ga + ph}\) geothermometer on eclogites with low Fe2O3 content, gives P-T values which are in good accordance with those obtained by other methods. The problems that arise when Fe3+ is present in larger amounts, are discussed.  相似文献   

14.
Lithian ferrian enstatite with Li2O = 1.39 wt% and Fe2O3 7.54 wt% was synthesised in the (MgO–Li2O–FeO–SiO2–H2O) system at P = 0.3 GPa, T = 1,000°C, fO2 = +2 Pbca, and a = 18.2113(7), b = 8.8172(3), c = 5.2050(2) Å, V = 835.79(9) Å3. The composition of the orthopyroxene was determined combining EMP, LA-ICP-MS and single-crystal XRD analysis, yielding the unit formula M2(Mg0.59Fe 0.21 2+ Li0.20) M1(Mg0.74Fe 0.20 3+ Fe 0.06 2+ ) Si2O6. Structure refinements done on crystals obtained from synthesis runs with variable Mg-content show that the orthopyroxene is virtually constant in composition and hence in structure, whereas coexisting clinopyroxenes occurring both as individual grains or thin rims around the orthopyroxene crystals have variable amounts of Li, Fe3+ and Mg contents. Structure refinement shows that Li is ordered at the M2 site and Fe3+ is ordered at the M1 site of the orthopyroxene, whereas Mg (and Fe2+) distributes over both octahedral sites. The main geometrical variations observed for Li-rich samples are actually due to the presence of Fe3+, which affects significantly the geometry of the M1 site; changes in the geometry of the M2 site due to the lower coordination of Li are likely to affect both the degree and the kinetics of the non-convergent Fe2+-Mg ordering process in octahedral sites.  相似文献   

15.
 The Middle Miocene Tobe hornfels in the Sanbagawa metamorphic belt, western Shikoku, southwest Japan, is characterized by an abnormally steep metamorphic gradient compared with other hornfelses associated with intrusive bodies. The basic hornfels, originally Sanbagawa greenschist rocks, is divided into the following three metamorphic zones: plagioclase, hornblende, and orthopyroxene. The plagioclase zone is defined by the appearance of calcic plagioclase, the hornblende zone by the assemblage of hornblende+calcic plagioclase+quartz, and the orthopyroxene zone is characterized by the assemblage of orthopyroxene + clinopyroxene + plagioclase + quartz. Calcic amphibole compositions change from actinolite to hornblende as a result of the continuous reactions during prograde metamorphism. Petrographical and thermometric studies indicate a metamorphic temperature range of 300–475°C for the plagioclase zone, 475–680°C for the hornblende zone, and 680–730°C for the orthopyroxene zone. The temperature gradient based on petrological studies is approximately 5°C/m, which is unusually high. Geological and petrological studies demonstrate that the hornfelses were formed by the focusing of high-temperature fluids through zones of relatively high fracture permeability. The steep thermal gradient in the Tobe hornfels body is consistent with a large fluid flux, greater than 8.3 × 10–7 m3 m–2S–1, over the relatively short duration of metamorphism, approximately 100 years. Received: 10 October 1995 / Accepted: 28 May 1996  相似文献   

16.
The Fuping Complex and the adjoining Wutai and Hengshan Complexes are located in the central zone of the North China craton. The dominant rock types in the Fuping Complex are high‐grade tonalitic–trondhjemitic–granodioritic (TTG) gneisses, with minor amounts of mafic granulites, syntectonic granitic rocks and supracrustal rocks. The petrological evidence from the mafic granulites indicates three stages of metamorphic evolution. The M1 stage is represented by garnet porphyroblasts and matrix plagioclase, quartz, orthopyroxene, clinopyroxene and hornblende. Orthopyroxene+plagioclase symplectites and clinopyroxene+plagioclase±orthopyroxene coronas formed in response to decompression during M2 following the peak metamorphism at M1. Hornblende+plagioclase symplectites formed as a result of further isobaric cooling and retrograde metamorphism during M3. The P–T estimates using TWQ thermobarometry are: 900–950 °C and 8.0–8.5 kbar for the peak assemblage (M1), based on the core compositions of garnet, matrix pyroxene and plagioclase; 700–800 °C and 6.0–7.0 kbar for the pyroxene+plagioclase symplectites or coronas (M2); and 550–650 °C and 5.3–6.3 kbar for the hornblende+plagioclase symplectites (M3), based on garnet rim and corresponding symplectic mineral compositions. These P–T estimates define a clockwise P–T path involving near‐isothermal decompression for the Fuping Complex, similar to the P–T path estimated for the metapelitic gneisses. The inferred P–T path suggests that the Fuping Complex underwent initial crustal thickening, subsequent exhumation, and finally cooling and retrogression. This tectonothermal path is similar to P–T paths inferred for the Wutai and Hengshan Complexes and other tectonic units in the central zone of the North China craton, but different from anti‐clockwise P–T paths estimated for the basement rocks in the eastern and western zones of the craton. Based on lithological, structural, metamorphic and geochronological data, the eastern and western zones of the craton are considered to represent two different Archean to Paleoproterozoic continental blocks that amalgamated along the central zone at the end of Paleoproterozoic. The P–T paths of the Fuping Complex and other tectonic units in the central zone record the collision between the eastern and western zones that led to the final assembly of the North China craton at c. 1800 Ma.  相似文献   

17.
Some mafic granulites in the Sanggan area of the northern Trans‐North China Orogen (TNCO) have a relatively simple mineralogy with low energy grain shapes that are compatible with an assumption of equilibrium, but the rock‐forming minerals show variations in composition that create challenges for thermobarometry. The mafic granulites, which occur as apparently disrupted dyke‐like bodies in tonalite–trondhjemite–granodiorite gneisses, are divided into two types based on petrography and chemical composition. Type 1 mafic granulites are fine‐ to medium‐grained with an equilibrated texture and an assemblage of plagioclase+clinopyroxene+garnet+magnetite+ilmenite and sometimes minor hornblende±orthopyroxene. Type 2 mafic granulites are coarse‐grained and hornblende bearing with a peak assemblage of garnet+clinopyroxene+plagioclase+hornblende and variably developed coronae and symplectites of plagioclase+hornblende+orthopyroxene partially replacing porphyroblastic garnet±clinopyroxene. SIMS U–Pb dating of metamorphic zircon from two type 1 mafic granulites yields metamorphic ages of c. 1.84 and 1.83 Ga, consistent with published ages of the type 2 mafic granulites. Based on phase equilibrium modelling, we use the common overlap of P–T fields defined by the mineral assemblage limits, and the mole proportion and composition isopleths of different minerals in each sample to quantify the metamorphic conditions. For type 1 granulites, overlap of the mineral proportion and composition fields for each of three samples yields similar P–T conditions of 710–880°C at 0.57–0.79 GPa, 820–850°C at 0.59–0.63 GPa and 800–860°C at 0.59–0.68 GPa. For the type 2 granulites, overlaying the peak assemblage fields for three samples yields common P–T conditions of 870–890°C at 1.1–1.2 GPa. For the retrograde assemblage, overlap of the mineral proportion and composition fields for each sample yields similar P–T conditions of 820–840°C at 0.85–0.88 GPa, 860–880°C at 0.83–0.86 GPa and 880–930°C at 0.89–0.95 GPa. The P–T conditions appear distinct between the two types of mafic granulite, with the mineralogically simple type 1 mafic granulites recording the lowest pressures. However, there are significant uncertainties associated with these results. For the granulites, there are uncertainties related to the determination of modes and composition of the equilibration volume, particularly estimation of O and H2O contents, and in the phase equilibrium modelling there are uncertainties that propagate through the calculation of mole proportions and mineral compositions. The compound uncertainties on pressure and temperature for high‐T granulites are large and the results of our study show that it may be unwise to rely on P–T conditions determined from the simple intersection of calculated mineral composition isopleths alone. Since the samples in this study are from a limited area—a few hundred square metres—we infer that they record a single P–T path involving both decompression and cooling. However, there is no evidence of the high‐P granulite facies event at 1.93–1.90 Ga that is recorded elsewhere in the TNCO, which suggests that the precursor basic dykes were emplaced late during the assembly of the North China Craton.  相似文献   

18.
Absorption bands are determined in polarized optical spectra of vivianite Fe3(PO4)2·8H2O, recorded at room and low temperatures. These bands are caused by spin-allowed d-d transitions in structurally nonequivalent Fe A 2+ (～11000 cm-1 (γ-polarization) (and) ～12000 cm-1 (β-polarization)) (and) Fe B 2+ (～8400 cm-1 (γ, α-polarization) and ～11200 cm-1 (α-polarization)) ions. A charge transfer band (CTB) Fe B 2+ +Fe B 3+ →Fe B 2+ +Fe B 2+ (～15000 cm-1) also determined, has polarizing features giving evidence of a change in the Fe B 2+ -Fe B 3+ bond direction, when compared with Fe B 2+ -Fe B 2+ . Bands of exchange-coupled Fe3+-Fe3+ pairs (～19400, ～20400, ～21300 and ～21700 cm-1) which appear on oxidation of Fe2+ in paired Fe B octahedra are also characterized.  相似文献   

19.
The Eastern Ghats Frontal Thrust (EGFT) demarcates the boundary between the Archaean/Paleoproterozoic cratonic rocks to the west, and the Meso/Neoproterozoic granulites of the Eastern Ghats Mobile Belt (EGMB) to the east. At Jeypore (Orissa, India), mafic schists and granites of the cratonic domain document a spatial increase in the metamorphic grade from greenschist facies (garnet, clinozoisite – absent varieties) in the foreland to amphibolite facies (clinozoisite- and garnet-bearing variants) progressively closer to the EGFT. Across the EGFT, the enderbite–charnockite gneisses and mafic granulites of EGMB preserves a high-grade granulite facies history; amphibolite facies overprinting in the enderbite–charnockite gneisses at the cratonic fringe is restricted to multi-layered growth of progressively Al, Ti – poor hornblende at the expense of pyroxene and plagioclase. In associated mafic granulites, the granulite facies gneissic layering is truncated by sub-centimeter wide shear bands defined by synkinematic hornblende + quartz intergrowth, with post-kinematic garnet stabilized at the expense of hornblende and plagioclase. Proximal to the contact, these granulites of the Eastern Ghats rocks are intruded by dolerite dykes. In the metadolerites, the igneous assemblage of pyroxene–plagioclase is replaced by intergrown hornblende + quartz ± calcite that define the thrust-related fabric and are in turn mantled by coronal garnet overgrowth, while scapolite is stabilized at the expense of recrystallized plagioclase and calcite. Petrogenetic grid considerations and thermobarometry of the metamorphic assemblages in metadolerites intrusive into granulites and mafic schists within the craton confirm that the rocks across the EGFT experienced prograde heating (Tmax value ∼650–700 °C at P ∼ 6–8 kbar) along the prograde arm of a seemingly clockwise P–T path. Since the dolerites were emplaced post-dating the granulite facies metamorphism, the prograde heating is correlated with renewed metamorphism of the granulites proximal to the EGFT. A review of available age data from rocks neighboring the EGFT suggests that the prograde heating of the cratonic granites and the re-heating of the Eastern Ghats granulites are Pan – African in age. The re-heating may relate to an Early Paleozoic Pan-Gondwanic crustal amalgamation of older terrains or reactivation along an old suture.  相似文献   

20.
Oxygen isotope geothermometry of coexisting minerals from five mafic granulites does not reflect the peak temperature of metamorphism as determined by other methods. Exchange of 18O between phases during slow cooling has (a) lowered the δ 18O of clinopyroxene relative to orthopyroxene in the presence of hornblende, (b) raised the δ 18O of quartz in a manner which is partly dependent on quartz abundance, and (c) lowered the δ 18O of plagioclase in some rocks.  相似文献   

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