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1.
矿物3CaO·3Al_2O_3·BaSO_4形成过程研究 总被引：1，自引：0，他引：1
ｅｏｒｅａｎｕ等［１］研究ＣａＯＡｌ２Ｏ３Ｍｘ（ＳＯ４）Ｙ［Ｍ＝Ｍｇ２＋、Ｓｒ２＋、Ｂａ２＋、Ｚｎ２＋、Ｆｅ２＋、Ｆｅ３＋、Ａｌ３］系统中,形成类似于矿物３ＣａＯ·３Ａｌ２Ｏ３·ＣａＳＯ４（硫铝酸钙）的可能性时,报道合成了新矿物３ＣａＯ·３Ａｌ２Ｏ３·ＢａＳＯ４（简写为３ＣＡ·ＢａＳＯ４）;部分学者［２,３］研究过它的胶凝性能等。在有关文献中,研究者制备研究用纯矿物的煅烧条件、获得样品的矿相组成不尽相同。如文献［１］在温度１４００℃保温２４０ｍｉｎ,制备的样品包括铝酸钙（ＣａＯ·Ａｌ２Ｏ３… 相似文献
2.
硅灰石是一种钙的偏硅酸盐类矿物,化学分子式为Ｃａ［ＳｉＯ３］,含４８－３％ＣａＯ和５１－７％的ＳｉＯ２。天然硅灰石常呈白至灰白色,玻璃到珍珠光泽,密度２－７８～２－９１ｇｃｍ３,硬度为４－５～５,通常为针状、放射状、纤维状集合体,甚至微小颗粒仍保持纤维状结构［１］。由于硅灰石具有特殊的纤维状结构及优良的物理、化学性质,使其在工业生产中有广泛的应用,如陶瓷、塑料、橡胶、冶金铸造、磨料、焊条、玻璃、矿棉、水泥、造纸、石棉代用品等［２,３］。随着研究的深入,对硅灰石在非陶瓷方面（造纸、涂料、塑料、石… 相似文献
3.
胶东台上金矿成矿机制模拟实验研究 总被引：2，自引：0，他引：2
模拟实验研究表明，台上金矿床的成矿机制为：胶东群地层重熔形成滦家河花岗岩岩浆时，初始浆为几乎均匀的熔体相；随着结晶成岩作用的进行，由于局部岩浆结晶分异作用，产生富Ｋ＾＋，Ｎａ＾２＾＋，Ｃａ＾２＾＋，Ｍｇ＾２＾＋，Ｆ＾－，Ｃｌ＾－，Ｓ＾２＾－，ＣＯ３＾２＾－及挥发份ＣＯ２，ＣＯ，Ｈ２Ｏ等的流体相，并不断从已结晶矿物及残熔体中，以［Ａｕ（ＨＳ）２］＾－，［Ａｕ（ＨＳ）Ｓ］＾２＾－，ＡｕＣｌ４］＾－等络 相似文献
4.
铁水预处理用鱼雷罐、铁水罐的炉衬多为Ａｌ２Ｏ３ＳｉＣＣ砖,随着铁水脱硫量的加大,耐火材料的侵蚀也较严重。而现在由于市场需要钢水中的磷含量要求较低,脱磷处理过程中由于国外多采用氧化铁系脱磷剂,氧化亚铁对石墨的氧化很大,对炉衬侵蚀也大,这就要求对Ａｌ２Ｏ３ＳｉＣＣ砖的性能进行改进以适宜工艺需要。国内对脱磷的研究较少,实际生产对铁水进行脱磷处理的厂家也很少。为探讨脱硫、磷剂对耐火材料的影响,本文对不同脱硫、磷剂侵蚀Ａｌ２Ｏ３ＳｉＣＣ砖后的残砖的显微结构进行了分析,探讨了铝碳化硅碳砖的侵蚀原… 相似文献
5.
本文用强功率四圆单晶衍射仪精确地修正了独居石和磷钇矿的晶体结构。独居石［Ｍｏｎａｚｉｔｅ－（Ｃｅ），ＣｅＰＯ４］属单斜晶系，ａ＝６．７８４３（１７），ｂ＝６．９８９１（１２），ｃ＝６．４５９２（１０），β＝１０３．６２６（１６）°，Ｚ＝４，空间群为Ｐ２１／ｎ。使用１１０６个［Ｆ≥３σ（Ｆ）］的独立衍射点，经多轮最小二乘法修正后，最终获得偏离因子Ｒ＝０．０６０。独居石的结构由孤立的［ＰＯ４］四面体构成，Ｃｅ位于［ＰＯ４］四面体包围之中，Ｃｅ的配位数为９，独居石的Ｃｅ—Ｏ平均键长为２．５５２，Ｐ—Ｏ平均键长为１．５２８。磷钇矿（Ｘｅｎｏｔｉｍｅ，ＹＰＯ４）属四方晶系，其晶格常数为：ａ＝６．８７９１（２４），ｃ＝６．０１４７（１９），Ｚ＝４，空间群为Ｉ４Ｉ／ａｍｄ（Ｎｏ．１４１）。使用１４２个［Ｆ≥３σ（Ｆ）］的独立衍射点，经多轮最小二乘法修正后，最终获得偏离因子Ｒ为０．０４８３。磷和氧形成四面体配位，其Ｐ—Ｏ平均键长为１．５４３；稀土钇与氧原子相连构成八次配位，其Ｙ—Ｏ平均键长为２．３３３。 相似文献
6.
7.
361铀矿床热液地球化学特征及成矿物理化学条件 总被引：4，自引：1，他引：4
文章研究了３６１矿床热液地球化学特征，并进行了热力学模拟计算，认为矿床热液是大气降水与深源流体混合而成。深源流体是与基性岩脉同源的富含Ｎａ＾＋，Ｃｌ＾－和ＣＯ２等挥发组分的流体，它沿深大断裂上升，对地壳表层的大气降水加热、混合。混合热液运移时把花岗岩中的活化铀浸出，并主要以［ＵＯ２（ＣＯ３）３］＾４－，［ＵＯ２（ＣＯ３）２·２Ｈ２Ｏ］＾２－和ＵＯ＾２＋２等形式迁移至断裂附近的破碎部位富集成矿。 相似文献
8.
二氧化碳—水体系的拉曼光谱研究 总被引：1，自引：1，他引：0
研究了使用石英管熔融封闭法分别在酸性、中性以及碱性条件下,采用ＣａＣＯ３或Ｎａ２ＣＯ３与ＨＣｌ反应制备不同浓度的ＣＯ２标准系列,并对气相、液相中的ＣＯ２进行拉曼光谱研究,得出了定量分析气相ＣＯ２所遵循的规律,即ＣＯ２的浓度与拉曼位移（１３８８．９ｃｍ－１）强度呈线性相关,为定量分析流体包裹体中ＣＯ２的含量奠定了基础。 相似文献
9.
在熔融的２ＰｂＯ．Ｂ２Ｏ３中（９７４Ｋ）,用滴溶量热法测定了２９８Ｋ下由组分Ｋ２ＣＯ３和ＣａＣＯ３形成的复碳酸盐Ｋ２Ｃａ（ＣＯ３）２（它有胶方解石和碳钾钙石两种多型）和Ｋ２Ｃａ２（ＣＯ３）３为－７．２±５．８ｋＪ／ｍｏｌ。同时推算出了复碳酸盐生砀熵变ΔＳｔ。假定具有序结构的胶方解石的ΔＳｔ＝０,则碳钾钙石的生成熵为４０．９±５．１Ｊ／ｍｏｌ．Ｋ,Ｋ２Ｃａ２（ＣＯ３）３为３９．４±７．３Ｊ／ｍｏｌ． 相似文献
10.
东川式铜矿地球化学研究 总被引：2，自引：0，他引：2
东川式铜矿赋矿围岩落雪组白云岩的常量元素投影点在Ａｌ２Ｏ３──ＳｉＯ２──（ＣａＯ＋ＭｇＯ）图解、ｌｇ（ＳｉＯ２／Ａｌ２Ｏ３）──ｌｇ［（ＣａＯ＋ＮａＯ）／Ｋ２Ｏ］图解和（ａｌ─ａｌｋ）──Ｃ图解上有一些非正常沉积的特点，并与红海现代热水化学沉积物有相似的特征。黄铜矿Ｃｏ／Ｎｉ值及落雪组白云岩微量元素在Ｃｏ＋Ｎｉ─Ａｓ＋Ｃｕ＋Ｍｏ＋ｐｂ＋Ｖ＋Ｚｎ图解上也反映出热水沉积特征。稀土元素研究成果表明落雪组是热水沉积与正常沉积相混合的产物。包裹体研究后认为成矿热水属Ｎａ＋（Ｃａ２＋、Ｍｇ２＋）─ＨＣＯ－３─Ｃｌ－型，并含ＣＯ、Ｈ２Ｏ（气）、ＣＯ２、ＣＨ４等气相组分，成矿温度１１０─２１４℃，成矿深度３─１５０ｍ。硫、碳、氧和氢的同位素反映了这四种组分多来自海水，成矿热水主要是下渗对流循环而受加热的海水及部分建造水。结合地质研究成果，本文提出“热水微裂隙喷溢沉积成矿”的新认识，即海水下渗，受裂谷高热流加热，萃取流经围岩中的硅质及矿质在还原环境中，沿落雪期尚未彻底固结沉积物中的微裂隙间断式喷溢沉积成矿。 相似文献
11.
Chemical diffusion profiles in molten CaO---Al2O3---SiO2 have been measured over a large range of compositions at 1500°C and l GPa. The diffusion profiles have been inverted for effective binary diffusion coefficients (EBDCs) and for the chemical diffusion matrix. The EBDCs are shown to depend strongly on both composition and direction of diffusion in composition space. The dependence of EBDCs on direction in composition space, which for the system studied here can be as large as a factor of seven, severely limits the applicability of EBDCs to interdiffusion in any direction other than the one used to derive the EBDCs.
The chemical diffusion matrix for molten CaO---Al2O3---SiO2 was determined using diffusion profiles from two or three mutually orthogonal diffusion couples in the ternary composition space. All features of the diffusion profiles shown in this work can be reproduced by representing the chemical fluxes in the three-component system as a linear combination of concentration gradients via a 2 × 2 diffusion matrix. Chemical diffusion in molten CaO---Al2O3---SiO2 shows clear evidence of strong diffusive coupling among the components. This can be seen in the uphill diffusion profiles of components that were initially uniform, in the fact that the apparent rate of diffusion of some components is a strong function of direction in composition space, and most quantitatively in the magnitude of off-diagonal elements of the diffusion matrix relative to the magnitude of the diagonal elements. SiO2 for example, is found to be strongly coupled with CaO in relatively silicic melts, whereas Al2O3 is strongly coupled with CaO in less silicic melts. Furthermore, the coupling of CaO with either Al2O3 or Si02 reverses sign between more and less polymerized compositions. Interdiffusion profiles in natural melts have numerous features that suggest similar coupling between Al2O3 and CaO and between SiO2 and CaO. 相似文献
12.
An inversion of SiO2 and MgO volatility occurs during high-temperature melt evaporation in the CaO–MgO–Al2O3–SiO2 (CMAS) system. This results in that SiO2, which is usually more volatile than MgO, becomes less volatile during the evaporation of melts enriched in the refractory oxides CaO and Al2O3. The volatility inversion is adequately explained within the theory of acid–base interaction of silicate melt components developed by D.S. Korzhinskii. The compositions of high-Al2O3 and SiO2-poor glasses (known as HASP glasses) from the lunar regolith show a systematic decrease in MgO/SiO2 with increasing CaO content, which is a direct consequence of the influence of acid–base effects. 相似文献
13.
Stability of phengite and biotite in eclogite is discussed using petrological data of natural eclogites, and the observational data are examined by thermodynamic calculations. Generally, phengite is a major K phase in natural eclogite and is stable in wide range of bulk composition. However, in eclogites from several localities of the Caledonides, biotite occurs as a stable eclogite-facies mineral, and is often associated with orthopyroxene. Bulk compositions of such biotite- or orthopyroxene-bearing eclogites are compared with those of eclogites from the Dabie–Sulu region, China, where phengite is a major K phase in eclogite. The biotite- or orthopyroxene-bearing eclogites from the Western Gneiss Region of the Caledonides are rich in MgO (10–15 wt%) and relatively poor in CaO (7–8 wt%) and Al2O3 (12–16 wt%). The CaO/MgO ratios of the biotite- or orthopyroxene-bearing eclogites are clearly lower than those of eclogites from the Dabie–Sulu region, indicating that MgO-rich and CaO-poor environments should be important for stabilizing of biotite and orthopyroxene in eclogite. Biotite-bearing eclogite from the North-East Greenland Eclogite Province is rich in MgO (≈16 wt%) and CaO (≈15.5 wt%) and extremely poor in Al2O3 (≈8 wt%). To stabilize biotite in eclogite, Al2O3-poor environments are also important. Bulk compositions of these biotite- or orthopyroxene-bearing eclogites are similar to picrite basaltic compositions. To examine these observational data, thermodynamic calculations were carried out in a seven-component system KH2O1.5–Na2O–CaO–FeO–MgO–Al2O3–SiO2, which includes garnet, kyanite, phengite, biotite, quartz, omphacite, orthopyroxene and olivine in conjunction with mass-balance calculations. Firstly, calculations were performed on the average bulk composition of eclogites from the Dabie–Sulu region to lherzolite (KLB-1). The calculation results confirmed that phengite should be stable in eclogite with 'ordinary' basaltic composition, whereas biotite and orthopyroxene should be stable in picrite basaltic compositions (e.g. MgO >11.0 wt%, CaO <9.8 wt%, Al2O3 <15.2 wt% at 700 °C, 2.5 GPa). Further calculations in basaltic system confirmed that increase of MgO content and decrease of CaO and Al2O3 contents were important to stabilize biotite and orthopyroxene in eclogite. Thus, mineral assemblage in picrite basalt system should be completely different from that in normal basaltic system. 相似文献
14.
Chromium as Cr3+ substitutes for octahedrally coordinated Alin upper-mantle minerals, thereby reducing the activity of Al2O3in the system and hence the concentration of Al2O3 in partialmelts. The effect of Cr2O3 on melt compositions multiply saturatedwith the spinel lherzolite phase assemblage has been quantifiedin the system CaO–MgO–Al2O3–SiO2–Cr2O3at 1·1 GPa as a function of 100 Cr/(Cr + Al) in the spinel(Cr#sp). The decrease of Al2O3 in the melt with increasing Cr#spis accompanied by increasing MgO and SiO2, whereas CaO remainsalmost constant. Consequently, the CaO/Al2O3 ratio of the meltincreases with Cr#sp, and the melt becomes richer in normativediopside, hypersthene and quartz. The effect may explain certainmantle melts with unusually high CaO/Al2O3 ratios. The concentrationof Cr2O3 in the melt remains low even at high Cr#sp, which meansthat the strong effect of Cr2O3 on partial melting equilibriais not readily apparent from its concentration in the melt itself.The existence of a highly refractory major component such asCr2O3 nullifies simplified conclusions from the ‘inverseapproach’ in the experimental study of basalt petrogenesis,as there is insufficient information in the composition of thepartial melt to reconstruct the conditions of melting. KEY WORDS: basalt petrogenesis; partial melting; reversal experiment; spinel lherzolite; system CMAS–Cr2O3; CaO/Al2O3 of melt; effect of Cr2O3 相似文献
15.
走廊过渡带石羊硐岩基南坝杂岩体含有大量的闪长质包体,作者在原1∶5万区域地质填图资料的基础上,再次开展了该杂岩体内的包体和寄主岩的岩石学、主量及微量元素地球化学研究工作,确定南坝杂岩体的包体具火成结构,包体与寄主岩存在地球化学差异、但同时二者主量元素、微量元素在比值-比值协变图中呈双曲线或直线变异关系,在共分母比值-比值成分变异图中则呈直线变异特点,反映了壳幔混源的特征;根据杂岩体内强烈的塑性构造变形及杂岩体主要岩性在R1-R2图解及微量元素洋脊花岗岩标准化图解上的判别结果,确定该杂岩体属同碰撞花岗岩,与祁连地体与阿拉善地体的碰撞有关,是碰撞晚期构造机制转化阶段的产物,而与二地体碰撞有关的底侵作用是走廊过渡带地壳生长的重要因素之一。 相似文献
16.
用MgO=8％标准化后,中国东部中-新生代玄武质火山岩表现为高Al2O3／TiO2、SiO2,低CaO／Al2O3的特征;新生代玄武质火山岩表现为低SiO2和低Al2O3／TiO2;高Fe8.0、Na8.0、CaO／Al2O3的特征。与区域软流圈地慢上涌和岩石圈伸展构造环境下形成的桂东南钾玄质岩石的高Fe8.0、低Na8.0和CaO／Al2O3值有明显的差异。中国东部中一新生代玄武质火山岩主量元素的特征,可能反映了与桂东南钾玄质岩石不同的形成环境。而中、新生代玄武质火山岩主量元素特征上的差异反映了岩浆来源区的变化。 相似文献
17.
Electron-probe microanalysis of a series of garnets in metapelitic rocks of the chloritoid staurolite, kyanite and sillimanite metamorphic zones, eastern area of the Sierra de Guadarrama, Sistema Central, Spain, manifest the well-known cryptozonation commonly observed in these minerals, with MgO and FeO increasing and MnO and CaO decreasing from the center to the outer rim of the crystals.The differences in composition of the garnets, from one metamorphic zone to another, is mainly a result of small differences in composition of the host-rock, since: (1) the amounts of MnO in the garnet are controlled by the amounts of SiO2, Al2O3 and FeO present in the host-rock; and (2) the percentages of MnO and MgO of the parent-rock influence in some way the concentration of CaO in the garnet, and those of MnO, Al2O3 and CaO influence the concentration of FeO. Nevertheless, the amount of FeO in the garnet is finally controlled, due to the diadochy, by the concentration of MnO + CaO in this mineral. 相似文献
18.
目前,岩浆岩的超基性、基性、中性、酸性的分类均根据SiO2的含量,但这种单一含量判别标准并不严谨,含量经常与分类不完全对应。使用TraceElem 1.0软件对各种岩浆岩进行逐步判别分析、聚类分析和对应分析研究,据此认为超基性岩由MgO和FeO组成的因子确定,基性岩则由P2O5、Fe2O3、TiO2、CaO、MnO组成的因子确定,中性岩由Na2O和Al2O3组成的因子确定,酸性岩由K2O和SiO2组成的因子确定。岩浆岩的分类宜以SiO2为主、以MgO和CaO为辅,尤其要引入MgO。在SiO2含量相同的情况下,MgO、CaO含量越高,基性程度越强。基于这一分析结果,提出一种新的酸度指数（ADI)计算方法,即ADI=w(SiO2)-0.75w(MgO)-0.23w(CaO),ADI<38.0%为超基性岩,在38.0%～52.0%之间为基性岩,在52.0%～62.5%之间为中性岩,>62.5%为酸性岩。 相似文献
19.
When melts of Ca–Al inclusions in chondrites, which are dominated by the oxides SiO2, MgO, CaO, and Al2O3, evaporate at high temperatures, the SiO2 and MgO fugacities are inverted: SiO2, which is more volatile than MgO, becomes less volatile when melts rich in refractory CaO and Al2O3 evaporate. This fugacity inversion can be realistically explained within the framework of D.S. Korzhinskii’s theory of acid–base interaction between components in silicate melts. According to this theory, an increase in CaO concentration in the melt increases its basicity, and this, in turn, increases the activity (and hence, also fugacity) of MgO and decreases those of SiO2. In the real compositions of the Ca–Al inclusions in chondrites, the MgO/SiO2 ratio systematically decreases with an increase in the CaO concentration under the effect of acid–base interaction. 相似文献
20.
Because of major differences in both bulk chemical composition and silicate mineralogy between metabasalts and metaperidotites, valid comparison of the degree or intensity of carbonate alteration cannot be made in terms of weight per cent CO2. Molar CO2/CaO is preferred as an index of the intensity of carbonate alteration in metabasalts; molar CO2/CaO in carbonatized metabasalts is independent of CaO/MgO and only mildly sensitive to bulk composition and to the proportions of tremolite and clinozoisite. Molar CO2/CaO reflect the proportions of calcite and dolomite in metabasalts and the proportions of dolomite and magnesite in metaperidotites. However, neither molar CO2/CaO nor the proportions of dolomite and magnesite are reliable measures of carbonate alteration in metaperidotites of variable composition because both are strongly dependent on MgO/CaO in the whole rock. The preferred alteration index in metaperidotites is m CO2/m (CaO + MgO + FeO), which represents the proportion of total relevant cations that exist in carbonate form. An empirical equation relating molar CO2/CaO in metabasalts (x) and MCO2/m(CaO+MgO+FeO) in metaperidotites (y) is: y=0.16+0.30 x. 相似文献