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1.
Palaeomagnetic measurements were carried out on low-grade metamorphic carbonates, of Mesozoic age from the Shiar area (85.1°E, 28.6°N) of the Tethyan Himalaya (TH) in north central Nepal. Two characteristic remanence components carried by pyrrhotite (ChRM1) and magnetite (ChRM2) could be identified by their unblocking temperature spectra of 270–340 and 430–580°C, respectively. Fold tests are not significant, due to the uniform bedding of all sites. However, according to results from other areas of the TH, the pyrrhotite component has been probably acquired as a secondary (p)TRM during exhumation and cooling; thus the age of remanence acquisition can be related to the last cooling event (25–17 Ma in the surrounding areas). The inclination of the magnetite component matches the value expected from the Indian APWP. This may the primary origin of the ChRM2.Pyrrhotite site-mean directions show a small-circle distribution, with a best fit parallel to the N–S direction. Backtilting to the expected inclination (Iexp) by intersection of the remanence small-circle with the small-circle of constant Iexp yields a clockwise block rotation of 30–35° with respect to the Indian Plate. Characteristics of the pyrrhotite component (small-circle distribution of site-means, secondary origin, (p)TRM with unblocking temperatures below about 300°C), allow the interpretation of the chronologic order of the thermo-tectonic history: (i) an earlier main folding phase at elevated temperatures; (ii) a later event of cooling through about 300°C coinciding with the acquisition of ChRM1; (iii) clockwise block rotations with respect to the Indian Plate and (iv) long-wave folding as the youngest tectonic event.  相似文献   

2.
E.Schill    E.Appel    P.Gautam  WT  ”BX 《地学前缘》2000,(Z1)
TERTIARY BLOCK ROTATIONS AND PYRRHOTITE/ MAGNETITE GEOTHERMOMETRY IN THE TETHYAN HIMALAYA(SHIAR KHOLA,CENTRAL NEPAL)1　AppelE ,M櫣ｌｌｅｒＲ ,WidderRW .PalaeomagneticresultsfromtheTibetanSedimentarySeriesoftheManangarea (northcentralnepal) [J].GeophysJInt ,1991,10 4:2 5 5～ 2 6 6 . 2　AppelE ,PatzeltA ,ChoukerC .SecondarypalaeoremanenceofTethyansedimentsfromtheZanskarRange (NWHimalaya)[J].GeophysJInt,1995 ,12 2 :2 2 7～ 2 42 . 3　B…  相似文献   

3.
E.Schill    E.Appel    O.Zeh    V.Singh   《地学前缘》2000,(Z1)
BLOCK ROTATIONS AT THE NORTHERN EDGE OF INDIA (SPITI,N-INDIA) AND THEIR CONTINUATION TO THE EAST (MALARI, N-INDIA)-REGIONAL SIGNIFICANCE FOR THE TECTONIC DEVELOPMENT OF THE TETHYAN HIMALAYAS1　AppelE ,MuellerR ,WidderRW .GeophysJInt ,1991,10 4:2 5 5～ 2 6 6 . 2　AppelE ,PatzeltA ,ChoukerC .GeophysJInt ,1995 ,12 2 :2 2 7～ 2 42 . 3　BagatiTN .J .Himal.Geol,1990 ,(1) :35～ 47. 4　BesseJ ,CourtillotV .JGeop…  相似文献   

4.
Clay‐rich basins have undergone varying degrees of magnetic transformation during burial, affecting their ability to retain accurate records of Earth's dynamic magnetic field. We propose to bracket the magnetite‐out and pyrrhotite‐in temperatures in shales and slates from Taiwan and the Pyrenees by using a combination of low‐temperature magnetic transitions and geothermometers. For Tburial < 340°C, the magnetic assemblage is dominated by magnetite. Gradually with increasing burial temperature, the concentration of magnetite decreases to a few ppmv. We observe the magnetite‐out isograd at Tburial ~350°C. At Tburial >60°C and Tburial >340°C respectively, fine‐grained and coarse‐grained pyrrhotite develop. In the course of burial, a clay‐rich basin gradually loses its capability to retain a record of Earth's magnetic field. It is only during basin uplift, that coarse pyrrhotite might acquire a thermo remanent magnetization. Our results point out therefore highly contrasted magnetic properties and palaeomagnetic records between deeply buried basins and exhumed ones.  相似文献   

5.
In the Himalayan chain the collision of India into Eurasia has produced some of the most complex crustal interactions along the Himalayan–Alpine Orogen. In NW Bhutan, middle to late Miocene deformation has been partitioned between conjugate strike-slip faulting, E–W extension along the Yadong-Gulu graben and kilometre-scale folding. To better understand the late deformation stages and their implications for the evolution of the eastern Himalayas, the palaeomagnetism in the erosional remnant of the Tethyan Himalayan rocks outcropping in NW Bhutan has been studied. Their position to the south of the trace of the inner South Tibetan Detachment, to the south of the Tibetan Plateau offers a unique possibility to study the Tertiary rotation of the Himalayas. Pyrrhotite is the carrier of the characteristic magnetisation based on 270–325 °C unblocking temperatures. The age of the remanence is ca. 13 Ma indicated by illite 40K/40Ar cooling ages and a negative fold test. Small circle intersection method applied to the pyrrhotite components shows a ca. 32° clockwise rotation with respect to stable India since 13 Ma. We suggest that this clockwise rotation is related to strain partitioning between NE-directed shortening, sinistral-slip along the Lingshi fault, and east–west extension. This represents a field-based explanation and a minimum onset age for present-day eastward motion of the upper-crust of SE-Tibet and NE-Himalayas.  相似文献   

6.
A palaeomagnetic study has been carried out in the Tethyan Himalaya (TH; the northern margin of Greater India). Twenty-six palaeomagnetic sites have been sampled in Triassic low-grade metasediments of western Dolpo. Two remanent components have been identified. A pyrrhotite component, characterized by unblocking temperatures of 270–335 °C, yields an in situ mean direction of D=191.7°, I=−30.9° (k=29.5, α95=5.7°, N=23 sites). The component fails the fold test at the 99% confidence level (kin situ/kbed=6.9) and is therefore of postfolding origin. For reason of the low metamorphic grade, this pyrrhotite magnetization is believed to be of thermo-chemical origin. Geochronological data and inclination matching indicate an acquisition age around 35 Ma. The second remanence component has higher unblocking temperatures (>400 °C and up to 500–580 °C range) and resides in magnetite. A positive fold test and comparison with expected Triassic palaeomagnetic directions suggest a primary origin.The postfolding character of the pyrrhotite component, and its interpreted age of remanence acquisition, implies that the main Himalayan folding is older than 35 Ma in the western Dolpo area. This study also suggests that the second metamorphic event (Neo-Himalayan) was more significant in the Dolpo area than the first (Eo-Himalayan) one.A clockwise rotation of 10–15° is inferred from the pyrrhotite component, which is compatible with oroclinal bending and/or rotational underthrusting models. This rotation is also supported by the magnetite component, indicating that no rotation of the Tethyan Himalaya relative to India took place before 35 Ma.  相似文献   

7.
Four distinct components of natural remanent magnetization were isolated from a single site in welded tuffs in the Upper Cretaceous Kisin Group of the Sikhote Alin mountain range, Russia. In order to contribute toward a basis for an interpretation of multicomponent magnetization, rock magnetic experiments were performed on the welded tuffs. All four magnetization components essentially reside in magnetite. The lowest-temperature component up to 300 °C (component A: D=349.3°, I=60.9°, α95=7.3°, N=7) is a present day viscous magnetization. The third-removed component (component C: D=41.4°, I=51.8°, α95=3.5°, N=8), isolated over the temperature range of 450–560 °C, is a primary remanence. The second- and fourth-demagnetized components (component B: D=174.7°, I=−53.1°, α95=21.2°, N=3 and component D: D=188.1°, I=−64.5°, α95=4.0°, N=8, respectively) are secondary magnetizations related to a thermal event in Sikhote Alin between 66 and 51 Ma. Components B and D were acquired through different remagnetization processes. Component B is ascribed to a thermoviscous remanent magnetization carried by single-domain magnetite, and component D is a chemical remanent magnetization.  相似文献   

8.
Dependences of magnetic susceptibility (MS) on the temperature of natural iron sulfide samples (pyrite, marcasite, greigite, chalcopyrite, arsenopyrite, pyrrhotite) from the deposits of northeastern Russia were studied. The thermal MS curves for pyrite and marcasite are the same: On heating, MS increases at 420–450 °C, and unstable magnetite (maghemite) and monoclinic pyrrhotite with a well-defined Hopkinson peak are produced. In oxygen-free media with carbon or nitrogen, magnetite formation is weak, whereas pyrrhotite generation is more significant. The heating curves for chalcopyrite are similar to those for pyrite. They show an increase in MS at the same temperatures (420–450 °C). However, stable magnetite is produced, whereas monoclinic pyrrhotite is absent. In contrast to that in pyrite, marcasite, and chalcopyrite, magnetite formation in arsenopyrite begins at > 500 °C. Arsenopyrite cooling is accompanied by the formation of magnetite (S-rich arsenopyrite) or maghemite (As-rich arsenopyrite) with a dramatic increase in MS. Arsenopyrite with an increased S content is characterized by insignificant pyrrhotite formation. Greigite is marked by a decrease in MS on the heating curves at 360–420 °C with the formation of unstable cation-deficient magnetite.Monoclinic pyrrhotite is characterized by a decrease in MS at ～ 320 °C, and hexagonal pyrrhotite, by a transition to a ferrimagnetic state at 210–260 °C. The addition of organic matter to monoclinic pyrrhotite stimulates the formation of hexagonal pyrrhotite, which transforms back into monoclinic pyrrhotite on repeated heating. The oxidation products of sulfides (greigite, chalcopyrite) show an increase in MS at 240–250 °C owing to lepidocrocite.  相似文献   

9.
Palaeomagnetic, rock magnetic and magnetic fabric results are presented for a Carboniferous (Visean to Westphalian) succession of felsic, mainly ignimbritic, volcanic and volcaniclastic rocks from the Rocky Creek Block of the northern Tamworth Belt, southern New England Orogen. Detailed thermal demagnetisation of 734 samples from 64 sites show three groups of magnetic components with low (<300°C), intermediate (300–600°C) and high (500–680°C) unblocking temperature ranges. Well‐defined primary magnetisations have been determined for 28 sites with evidence of four overprint phases. The overprints arise from a mid‐Tertiary weathering event (or possibly recent viscous origin), and from fluid movements associated with the Late Cretaceous opening of the Tasman Sea, thrusting during the Middle Triassic main phase of the Hunter‐Bowen Orogeny, and latest Carboniferous — Early Permian formation of the Bowen‐Gunnedah‐Sydney Basin system. Rock magnetic tests establish that the primary magnetisation carriers in the volcanic rocks are mainly magnetite (predominantly single domain, or pseudo‐single domain, and little or no multidomain) and hematite. Optimal magnetic cleaning is achieved at high to very high temperatures, with subtle, but systematic, directional and statistical differences between primary components derived from the mainly hematite fraction and pseudo‐components derived from the mainly magnetite fraction. The 28 primary magnetisation results are presented as six mean‐site results, summarised below and representing 25 sites, and three single‐site results. Fold tests could be applied to five mean‐site results. These are all positive, but one of these results may represent a secondary magnetisation. The primary magnetisation results define a Visean to Westphalian pole path. This long pole path indi cates extensive latitudinal and rotational movement for the Rocky Creek Block, and potentially for the New England Orogen, as follows: (i) Yuendoo Rhyolite Member (Caroda Formation, Visean) pole 235.8°E, 27.7°S, ED95 = 9.0°, n = 3; (ii) Peri Rhyolite Member/Boomi Rhyolite Member (Clifden Formation, Namurian, 318.0 ± 3.4 Ma) pole 177.4°E, 63.4°S, ED95 = 5.2°, n = 3; (iii) tuffaceous beds above Boomi Rhyolite Member (Clifden Formation?, Namurian) pole 162.2°E, 59.1°S, ED95 = 10.2°, n = 3; ((iv) upper Clifden Formation/lower Rocky Creek Conglomerate (Namurian/Westphalian) pole 95.3°E, 49.6°S, ED95 = 8.1°, n = 3 (possible overprint)); (v) Rocky Creek Conglomerate (Westphalian) pole 136.5°E, 57.6°S, ED95 = 5.3°, n = 5; (vi) Lark Hill Formation (Westphalian) pole 127.0°E, 50.4°S, ED95 = 4.8°, n = 8.  相似文献   

10.
Spinels, Fe–Ti oxide minerals, apatites, and carbonates hosted in ophiolitic serpentinites and metagabbros of Gabal Garf (southern ED) and Wadi Hammariya (central ED) of Egypt are discussed. Microscopic and electron probe studies on these minerals are made to evaluate their textural and compositional variations. Alteration of chromites led to form ferritchromite and magnetite; rutile–magnetite intergrowths and martite are common in serpentinites. Fine trillis exsolution of ilmenite–magnetite and ilmenite–hematite and intergrowth of rutile–magnetite and ilmenite–sphene are recorded. Composite intergrowth grains of titanomagnetite–ilmenite trellis lamellae are common in metagabbros. The formation of ilmenite trellis and lamellae in magnetite and titanomagnetite indicate an oxidation process due to excess of oxygen contained in titanomagnetite; trapped and external oxidizing agents. This indicates the high P H2O and oxygen fugacity of the parental magma. The sulfides minerals include pyrrhotite, pyrite and chalcopyrite. Based on the chemical characteristics, the Fe–Ti oxide from the ophiolitic metagabbros in both areas corresponds to ilmenite. The patites from the metagabbros are identified as fluor-apatite. Carbonates are represented by dolomites in serpentinites and calcite in metagabbros. Spinel crystals in serpentinites are homogenous or zoned with unaltered cores of Al-spinel to ferritchromit and Cr-magnetite toward the altered rims. Compared to cores, the metamorphic rims are enriched in Cr# (0.87–1.00 vs. 0.83–0.86 for rims and cores, respectively) and impoverished in Mg# (0.26–0.48 vs. 0.56–0.67) due to Mg–Fe and Al (Cr)–Fe3+ exchange with the surrounding silicates during regional metamorphism rather than serpentinization process. The Fe–Ti oxides have been formed under temperature of ~800 °C for ilmenite. Al-spinels equilibrated below 500–550 °C, while the altered spinel rims correspond to metamorphism around 500–600 °C. Geochemical evidence of the podiform Al-spinels suggest a greenschist up to lower amphibolite facies metamorphism (at 500–600 °C), which is isofacial with the host rocks. Al-spinel cores do not appear to have re-equilibrated completely with the metamorphic spinel rims and surrounding silicates, suggesting relic magmatic composition unaffected by metamorphism. The composition of Al-spinel grains suggest an ophiolitic origin and derivation by crystallization of boninitic magma that belonging to a supra-subduction setting could form either in forearcs during an incipient stage of subduction initiation or in back-arc basins.  相似文献   

11.
Physical property measurements provide a critical link between geological observations and geophysical measurements and modelling. To enhance the reliability of gravity and magnetic modelling in the Yilgarn Craton's Agnew–Wiluna Greenstone Belt, mass and magnetic properties were analysed on 157 new rock samples and combined with an existing corporate database of field measurements. The new samples include sulfide ore, serpentinised and olivine-bearing ultramafic host-rocks, granitoid, and felsic and mafic volcanic and volcaniclastic country rock. Synthesis of the data provides a useful resource for future geophysical modelling in the region. Several rock types in the region have sufficiently distinct physical properties that a discriminant diagram is proposed to facilitate a basic classification of rock types based on physical properties. However, the accumulation of emplacement, metamorphic, hydrothermal and structural processes has complicated the physical properties of the rocks by imposing duplicate and sometimes opposing physical property trends. The data confirm that massive sulfide and ultramafic rocks have the most distinctive mass and magnetic properties but with variability imposed by their complex history. Sulfide content imposes the strongest control on densities, but can only be identified when comprising >10 vol% of the rock. The pyrrhotite-rich Ni-sulfide assemblages generally have similar magnetic properties to the host ultramafic rocks, but can have much lower susceptibilities where the thermal history of the rocks has favoured development of hexagonal pyrrhotite over monoclinic pyrrhotite. In ultramafic rocks that contain <10 vol% sulfides, density and susceptibility are primarily controlled by serpentinisation, with olivine breaking down to serpentine and magnetite in the presence of water. Serpentinisation dramatically lowered densities and increased susceptibilities, but had limited influence on the intensity of remanent magnetisation. All ultramafic rocks contain multidomain magnetite, and most contain low coercivity grains prone to overprinting by in situ viscous remanent magnetisation or drilling-induced isothermal remanent magnetisation during extraction. Despite the low coercivities, Koenigsberger ratios of 1–20 are observed indicating that viscous remanent magnetisation aligned parallel to the present Earth field must be considered in any magnetic modelling. It is also noted that coarser-grained intrusive varieties of all rock types (e.g. granite, gabbro) show remanent magnetisation intensities 1–2 orders of magnitude greater than their extrusive equivalents (felsic and basaltic volcanics).  相似文献   

12.
The Shevaroy Hills of northern Tamil Nadu, southern India, expose the highest-grade granulites of a prograde amphibolite facies to granulite facies deep-crustal section of Late Archaean age. These highly oxidized quartzofeldspathic garnet charnockites generally show minor high-TiO2 biotite and amphibole as the only hydrous minerals and are greatly depleted in the incompatible elements Rb and Th. Peak metamorphic temperatures (garnet–orthopyroxene) and pressures (garnet–orthopyroxene–plagioclase–quartz) are near 750 °C and 8 kbar, respectively. Pervasive veinlets of K-feldspar exist throughout dominant plagioclase in each sample and show clean contact with orthopyroxene. They are suggested to have been produced by a low H2O activity, migrating fluid phase under granulite facies conditions, most likely a concentrated chloride/carbonate brine with high alkali mobility accompanied by an immiscible CO2-rich fluid. Silicate, oxide and sulphide mineral assemblages record high oxygen fugacity. Pyroxenes in the felsic rocks have high Mg/(Mg+Fe) (0.5–0.7). The major oxide mineral is ilmenite with up to 60 mole per cent exsolved hematite. Utilizing three independent oxygen barometers (ferrosilite–magnetite–quartz, ferrosilite–hematite–quartz and magnetite–hematite) in conjunction with garnet–orthopyroxene exchange temperatures, samples with XIlmHm>0.1 yield a consistent oxygen fugacity about two log units above fayalite stability. Less oxidized samples (XIlmHm<0.1) show some scatter with indications of having equilibrated under more reducing conditions. Temperature-f (O2 ) arrays result in self consistent conditions ranging from 660 °C and 10?16 bar to 820 °C and 10?11.5 bar. These trends are confirmed by calculations based on the assemblage clinopyroxene–orthopyroxene–magnetite–ilmenite using the QUIlF program. In the most oxidized granulite samples (XIlmHm>0.4) pyrite is the dominant sulphide and pyrrhotite is absent. Pyrite grains in these samples have marginal alteration to magnetite along the rims, signifying a high-temperature oxidation event. Moderately oxidized samples (0.1no coexisting magnetite. Chalcopyrite is a common accessory mineral of pyrite and pyrrhotite in all the samples. Textures in some samples suggest that it formed as an exsolution product from pyrrhotite. Extensive vein networks of magnetite and pyrite, associated principally with the pyroxene and amphibole, give evidence for a pervasive, highly oxidizing fluid phase. Thermodynamic analysis of the assemblage pyrrhotite, pyrite and magnetite yields consistent high oxidation states at 700–800 °C and 8 kbar. The oxygen fugacity in our most oxidized pyrrhotite-bearing sample is 10?12.65 bar at 770 °C. There are strong indications that the Shevaroy Hills granulites recrystallized in the presence of an alkali-rich, low H2O-activity fluid, probably a concentrated brine. It cannot be demonstrated at present whether the high oxidation states were set by initially oxidized protoliths or effected by the postulated fluids. The high correspondence of maximally Rb-depleted samples with the highest recorded oxidation states suggests that the Rb depletion event coincided with the oxidation event, probably during breakdown of biotite to orthopyroxene+K-feldspar. We speculate that these alterations were effected by exhalations from deep-seated alkali basalts, which provided both heat and high oxygen fugacity, low aH2O fluids. It will be of interest to determine whether greatly Rb-depleted granulites in other Precambrian terranes show similar highly-oxidizing signatures.  相似文献   

13.
The article deals with phase relations in the KFeS2–Fe–S system studied by the dry synthesis method in the range of 300–600 °C and at a pressure of 1 bar. At the temperature below 513?±?3 °C, pyrite coexists with rasvumite and there are pyrite–rasvumite–KFeS2 and pyrite–rasvumite–pyrrhotite equilibria established. Above 513?±?3 °C pyrite and rasvumite react to form KFeS2 and pyrrhotite, limiting the pyrite–rasvumite association to temperatures below this in nature. The experiments also outline the compositional stability range of the copper-free analog of murunskite (K x Fe2?yS2) and suggest that mineral called bartonite is not stable in the Cl-free system, at least at atmospheric pressure and the temperature in the experiments. Chlorbartonite could be easily produced after adding KCl in the experiment. Possible parageneses in the quaternary K–Fe–S–Cl system were described based on the data obtained in this research and found in the previous studies. The factors affecting the formation of potassium–iron sulfides in nature were discussed.  相似文献   

14.
Oxygen fugacities have been estimated for a wide distribution of samples from the granulite facies terrane (region C) of the Bamble Sector, SE Norway using both the titaniferous magnetite–ilmenite and orthopyroxene–titaniferous magnetite–quartz oxygen barometers. These oxygen fugacities are estimated using temperatures calculated from the titaniferous magnetite–ilmenite thermometer of Ghiorso and Sack (1991) and are both internally consistent with each other as well with the thermometer. In samples for which the estimated temperature is high, the two oxygen barometers show good agreement whereas agreement is poor for low temperature samples. In these low temperature samples, oxygen fugacities estimated from titaniferous magnetite–ilmenite are considerably less than those estimated from orthopyroxene–titaniferous magnetite–quartz. An increase in this discrepancy with decrease in temperature appears to reflect preferential resetting of the hematite component in the ilmenite grains without significant alteration of the more numerous titaniferous magnetite grains. This is due, in part, to greater re-equilibration of the ilmenite grains during retrograde interoxide resetting between the ilmenite grains and the titaniferous magnetite grains. The mean temperature for the non-reset samples, 791?±?17?°C (1σ), is in good agreement with temperatures obtained from garnet–orthopyroxene KD exchange thermometry in the same region, 785–795?°C (1σ) (Harlov 1992, 2000a). Most non-reset oxygen fugacities range from log10?f?O2=?14 to ?11.8 or approximately 0.5–1.5?log units above quartz–fayalite–magnetite at 7.5?kbar. Both these temperatures and the range of oxygen fugacities are in good agreement with those estimated using the titaniferous magnetite–ilmenite thermometer/oxygen barometer of Andersen et?al. (1991). The QUIlP equilibrium (quartz–ulvöspinel–ilmenite–pyroxene) is used to project self-consistent equilibrium temperatures and oxygen fugacities for samples reset due to hematite loss from the ilmenite grains. These projected temperatures and oxygen fugacities agree reasonably well with the non-reset samples. The mean projected QUIlP temperature is 823?±?6?°C (1σ). This result supports the conclusion that low titaniferous magnetite–ilmenite temperatures (down to 489?°C) and accompanying low oxygen fugacities are the result of hematite loss from the ilmenite grains. Non-reset oxygen fugacities lie approximately 1.5?log10 units above the upper graphite stability curve indicating that the stable C–O–H fluid phase interacting with these gneisses, whether regionally or locally, was CO2. This is borne out by the presence of numerous CO2-rich fluid inclusions in these rocks.  相似文献   

15.
Jurassic to Cretaceous red sandstones were sampled at 33 sites from the Khlong Min and Lam Thap formations of the Trang Syncline (7.6°N, 99.6°E), the Peninsular Thailand. Rock magnetic experiments generally revealed hematite as a carrier of natural remanent magnetization. Stepwise thermal demagnetization isolates remanent components with unblocking temperatures of 620–690 °C. An easterly deflected declination (D = 31.1°, I = 12.2°, α95 = 13.9°, N = 9, in stratigraphic coordinates) is observed as pre-folding remanent magnetization from North Trang Syncline, whereas westerly deflected declination (D = 342.8°, I = 22.3°, α95 = 12.7°, N = 13 in geographic coordinates) appears in the post-folding remanent magnetization from West Trang Syncline. These observations suggest an occurrence of two opposite tectonic rotations in the Trang area, which as a part of Thai–Malay Peninsula received clockwise rotation after Jurassic together with Shan-Thai and Indochina blocks. Between the Late Cretaceous and Middle Miocene, this area as a part of southern Sundaland Block experienced up to 24.5° ± 11.5° counter-clockwise rotation with respect to South China Block. This post-Cretaceous tectonic rotation in Trang area is considered as a part of large scale counter-clockwise rotation experienced by the southern Sundaland Block (including the Peninsular Malaysia, Borneo and south Sulawesi areas) as a result of Australian Plate collision with southeast Asia. Within the framework of Sundaland Block, the northern boundary of counter-clockwise rotated zone lies between the Trang area and the Khorat Basin.  相似文献   

16.
A detailed paleomagnetic and rock-magnetic investigation spanning loess L7 to paleosol S8 has been carried out at the Baoji and Xifeng sections. Results of anisotropy of magnetic susceptibility confirm that the studied loess–paleosol sediments retain primary sedimentary fabrics. Stepwise thermal demagnetization shows that two well-defined magnetization components can be isolated from both loess and paleosol specimens. A low-temperature component, isolated between 100°C and 200°C, is consistent with the present geomagnetic field direction, and a high-temperature component, isolated between 200–300°C and 620–680°C, includes clearly normal and reversed polarities. Isothermal remanent magnetization and thermomagnetic analyses indicate that characteristic remanent magnetization is mainly carried by magnetite and hematite. The Day plot, together with the stratigraphic variations of rock-magnetic parameters, shows that the uniformity of magnetic mineralogy and grain size fulfills the criteria for relative paleointensity (RPI) studies. RPI records have been constructed using natural remanent magnetization (NRM) intensity after thermal demagnetization at 300°C normalized by low-frequency magnetic susceptibility (NRM300/χ). The results show that the RPI record from the Baoji section, where pedogenesis is quite weak, is compatible with the stacked PISO-1500 paleointensity record, suggesting that it might reflect the paleointensity variation of the geomagnetic field. The RPI record from the Xifeng section, where pedogenesis is rather strong, indicates a clear dissimilarity with the stacked PISO-1500 paleointensity record, implying that it does not reflect the paleointensity variation of the geomagnetic field. Our new results show that the NRM300/χ from the strongly pedogenetic paleosols does not completely eliminate the pedogenetic (climatic) influence, so it might be unsuitable for a reliable paleointensity study.  相似文献   

17.
The cocrystallization coefficient of Mn and Fe (DMn/Fe) in magnetite crystals is determined in hydrothermal-growth experiments with internal sampling at 450 and 500 °C and 100 MPa (1 kbar). It is weakly dependent on temperature in the studied PT-region and is constant over a wide range of Mn/Fe values. This permits using the magnetite composition as an indicator of Mn/Fe in the fluid under equilibrium: (Mn/Fe)aq ≈ 100 (Mn/Fe)mt. Since Mn is often a macrocomponent of the fluid and a microcomponent of magnetite, local analysis of fluid inclusions for Mn might help to determine Fe even in iron minerals. This will permit evaluation of the contents of other ore metals if the DMe/Fe values are known. For fine crystals (< 0.1–0.2 mm) with low contents of Mn (< 0.01–0.02%), it is necessary to take into account the fractionation of Mn into the surficial nonautonomous phase, in which its content can reach several percent. Comparison of these data with earlier data on the distribution of Mn in the system magnetite–pyrite–pyrrhotite–greenockite–hydrothermal solution shows that DMn/Fe remains constant in the presence of sulfur and sulfides. Precipitation of magnetite, in which Mn is a compatible admixture, cannot affect radically Mn/Fe in the solution because of the low DMn/Fe value. This effect is still more unlikely for pyrrhotite and pyrite, in which Mn is an incompatible admixture. The most probable mechanism of Mn fractionation into the solid phase is crystallization of FeOOH at lower temperatures. This is indirectly supported by the strong fractionation of Mn into the nonautonomous oxyhydroxide phase on the surface of magnetite crystals. The necessity of a more rigorous validation of “the new Fe/Mn geothermometer for hydrothermal systems” is substantiated.  相似文献   

18.
The Mascot–Jefferson City (M-JC) Mississippi Valley-type (MVT) deposits are in the Valley and Ridge province of the Appalachian orogen in East Tennessee. They have been a major source of zinc for the USA but their age is uncertain and thus their genesis controversial. About 10 specimens from each of 37 sites have been analysed paleomagnetically using alternating field and thermal step demagnetisation methods and saturation isothermal remanence methods. The sites sample limestones, dolostones, breccia clasts and sphalerite–dolomite MVT mineralisation from mines in the Lower Ordovician Kingsport and Mascot formations of the Knox Group. The characteristic remanent magnetisation (ChRM) is carried by magnetite in the limestones, by both magnetite and pyrrhotite in the dolostones and by pyrrhotite preferentially to magnetite in the mineralisation. Mineralized sites have a more intense ChRM than non-mineralised, indicating that the mineralising and magnetisation event are coeval. Paleomagnetic breccia tests on clasts at the three sites are negative, indicating that their ChRM is post-depositional remagnetisation, and a paleomagnetic fold test is negative, indicating that the ChRM is a remagnetisation, and a post-dates peak Alleghanian deformation. The unit mean ChRM direction for the: (a) limestones gives a paleopole at 129°E, 12°N (dp=18°, dm=26°, N=3), indicating diagenesis formed a secondary chemical remanent magnetisation during the Late Ordovician–Early Silurian; (b) dolomitic limestones and dolostone host rocks gives a paleopole at 125.3°E, 31.9°N (dp=5.3°, dm=9.4°, N=7), recording regional dolomitisation at 334±14 Ma (1σ); and (c) MVT mineralisation gives a paleopole at 128.7°E, 34.0°N (dp=2.4°, dm=4.4°, N=25), showing that it acquired its primary chemical remanence at 316±8 Ma (1σ). The mineralisation is interpreted to have formed from hydrothermal fluid flow, either gravity or tectonically driven, after peak Alleghanian deformation in eastern Tennessee with regional dolomitisation of the host rocks occurring as part of a continuum during the 20 Ma prior to and during peak deformation.  相似文献   

19.
In the design of hydrothermal solubility studies it is important that the system be completely defined chemically. If the solubilities of minerals containing m metallic elements are to be determined in hydrothermal NaCl solutions, the phase rule requires that a total of m + 6 independent intensive parameters be controlled or measured in order to determine completely the system.In this study the solubility of the univariant assemblage pyrite + pyrrhotite + magnetite has been determined in vapor saturated hydrothermal solutions from 200 to 350°C for NaCl concentrations ranging from 0.0 to 5.0 molal. At any temperature, oxygen and sulfur fugacities were buffered by the chosen assemblage. System pH was determined from excess CO2 partial pressures and computed ionic equilibria. Equilibrium constants were calculated by regression analysis of solubility data. The results show that more than 10 ppm of each mineral can dissolve in typical hydrothermal solutions under geologically realistic conditions. Solubilities were best represented by the species Fe2+ and FeCl+ at 200 and 250°C; Fe2+, FeCl+ and FeCl20 at 300°C; and Fe2+ and FeCl20 at 350°C. Ore deposition would occur by lowering temperature, diluting chloride concentration, or by raising pH through wall rock alteration reactions.  相似文献   

20.
The crystallization sequence of a basaltic andesite from Bezymianny Volcano, Kamchatka, Russia, was simulated experimentally at 100 and 700 MPa at various water activities (aH2O) to investigate the compositional evolution of residual liquids. The temperature (T) range of the experiments was 950–1,150 °C, aH2O varied between 0.1 and 1, and the log of oxygen fugacity (fO2) varied between quartz–fayalite–magnetite (QFM) and QFM + 4.1. The comparison of the experimentally produced liquids and natural samples was used to constrain the pressure (P)–T–aH2O–fO2 conditions of the Bezymianny parental magma in the intra-crustal magma plumbing system. The phase equilibria constraints suggest that parental basaltic andesite magmas should contain ~2–2.5 wt% H2O; they can be stored in upper crustal levels at a depth of ~15 km, and at this depth they start to crystallize at ~1,110 °C. The subsequent chemical evolution of this parental magma most probably proceeded as decompressional crystallization occurred during magma ascent. The final depths at which crystallization products accumulated prior to eruption are not well constrained experimentally but should not be shallower than 3–4 km because amphibole is present in natural magmas (>150 MPa). Thus, the major volume of Bezymianny andesites was produced in a mid-crustal magma chamber as a result of decompressional crystallization of parental basaltic andesites, accompanied by mixing with silicic products from the earlier stages of magma fractionation. In addition, these processes are complicated by the release of volatiles due to magma degassing, which occurs at various stages during magma ascent.  相似文献   

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