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1.
To characterize the isotopic composition of organisms at the base of the food web and the controls on their variability, the concentration and δ13C isotopic composition of dissolved inorganic carbon (DIC) and plankton δ13C, δ15N, and δ34S were measured. The measurements were made during periods of high and low river flow in Apalachicola Bay, Florida, United States, over 3 yr. DIC concentration and δ13C values were related to salinity, indicating that conservative mixing of riverine and marine waters was responsible for the overall distributions. The usefulness of DIC δ13C data for characterizing the trophic processes within the estuary was dependent upon the residence time of water within the season. Plankton δ13C values varied from −22‰ to −30‰ and were directly related to estuarine DIC δ13C, offset by a factor of roughly −20‰. This offset factor varied with salinity. Values of δ34S in estuarine plankton (station means ranged from 11.4‰ to 13.1‰) were depleted relative to marine plankton (17.7±0.4‰) possibly due to the admixture of34S-depleted sedimentary sulfide with estuarine samples. Values of δ34S in plankton were not related to δ13C values of plankton and were only weakly correlated to the salinity of the water from which the plankton were collected, indicating that marine sulfate was the primary source of planktonic sulfur. Values of δ15N in plankton varied from 5.5‰ to 10.7‰ and appeared related to dominance of the sample by phytoplankton or zooplankton. Estuarine plankton was15N enriched relative to offshore plankton and estuarine sediment.  相似文献   

2.
The nitrogen and carbon stable isotope ratios (δ15N and δ13C) of the pygmy mussel,Xenostrobus securis, were determined for three estuaries with varying levels of catchment disturbance in northern New South Wales, Australia. The lower Manning River catchment supported the highest human population densities with 3% residential development and some livestock agriculture (41%); the Wallamba River catchment was mostly livestock agriculture (56%) while the Wallingat River catchment was mostly vegetated (79%). Mussels, estuarine particulate organic matter (POM), and livestock and human-derived waste were collected in two stages during the austral summers of 2001–2002 and 2002–2003 for dual carbon-nitrogen stable isotope analysis. The disturbed Manning and Wallamba River catchment mussels were enriched in15N by an average of 3.2‰ and 1.5‰, respectively, compared to the vegetated Wallingat River mussels. Mussel δ13C values ranged from −24.8‰ to −30.3‰ and showed an estuarine gradient becoming enriched with distance downstream within estuaries, but were unable to distinguish patterns in catchment disturbance between estuaries. The δ15N and δ13C values of POM showed a similar pattern to mussels, indicating a direct link between them within each estuary. A multiple regression model of mussel δ15N using the fractions of land used for livestock agriculture and residential development within 5 km zones from river networks to a distance equivalent to a tidal ellipse from sites explained 67% of the variation in mussel δ15N with 95% of the differences lying within 1.6‰ of observed values. Increasing fractions of land used for livestock agriculture depleted mussel δ15N values estimated by the regression equation, indicating the use of cow manure as a nutrient source with a value of 2.0‰. Increasing fractions of land used for residential development enriched estimated mussel δ15N, indicating the use of human-derived waste with a value of 20.8‰. Pygmy mussels are a useful long-term bio-indicator for the effects of anthropogenic catchment disturbance and nutrient enrichment in estuaries.  相似文献   

3.
Stable isotopic ratios of carbon and oxygen (δ13C and δ18O) from mollusk shells reflect the water quality characteristics of Florida Bay and can be used to characterize the great temporal variability of the bay. Values of δ18O are directly influenced by temperature and evaporation and may be related to salinity, δ13C values of δ13C are sensitive to organic and inorganic sources of carbon and are influenced by productivity. Analyses of eight mollusk species from five short-core localities across Florida Bay show large ranges in the values of δ13C and δ18O, and reflect the variation of the bay over decades. Samples from southwester Florida Bay have distinct δ13C values relative to samples collected in northeastern Florida Bay, and intermediate localities have intermediate values.13C values of δ13C grade from marine in the southwest bay to more estuarine in the northeast. Long cores (>1m), with excellent chronologies were analyzed from central and eastern Florida Bay. Preliminary analyses ofBrachiodontes exustus andTransenella spp. from the cores showed that both δ13C and δ18O changed during the first part of the twentieth century. After a century of relative stability during the 1800s, δ13C decreased between about 1910 and 1940, then stabilized at these new values for the next five decades. The magnitude of the reduction in δ13C values increased toward the northeast. Using a carbon budget model, reduced δ13C values are interpreted as resulting from decreased circulation in the bay, probably associated with decreased freshwater flow into the Bay. Mollusk shell δ18O values display several negative excursions during the 1800s, suggesting that the bay was less evaporitic than during the twentieth century. The isotope records indicate a fundamental change took place in Florida Bay circulation early in the twentieth century. The timing of the change links it to railroad building and early drainage efforts in South Florida rather than to flood control and water management measures initiated after World War II.  相似文献   

4.
Buzan et al. critique Turner’s (Estuaries and Coasts 29:345–352, 2006) analysis of the relationship between freshwater inflow and oyster productivity in the Gulf of Mexico, using 16 years of fisheries-independent data for Galveston Bay. They conclude that the catch-per-unit effort (CPUE; number h−1) of marketable oysters increase 1 to 2 years after years with increased freshwater inflows, and they express concerns that water supply managers may mis-apply the results of Turner (Estuaries and Coasts 29:345–352, 2006) to justify a reduced freshwater inflow to Galveston Bay. I find no relationship between the CPUE of oyster spat or marketable oyster density and the commercial harvest, but do find a strong inverse relationship between harvest and river discharge in Galveston Bay. There are three possible factors that may explain why the annual variations in the fisheries-independent data are not coherent with the annual variations in commercial harvest: variable levels of water quality, inconsistent fishing effort, and the fact that the fisheries-independent data are not prorated for the area of the reefs actually fished. I concur, completely, with the apprehension that reductions in freshwater inflow will be implemented without examining the full set of assumptions and consequences, and thereby compromise estuarine ecosystem quality, and perhaps permanently, before mistakes can be seen or reversed.  相似文献   

5.
Narragansett Bay has been heavily influenced by human activities for more than 200 years. In recent decades, it has been one of the more intensively fertilized estuaries in the USA, with most of the anthropogenic nutrient load originating from sewage treatment plants (STP). This will soon change as tertiary treatment upgrades reduce nitrogen (N) loads by about one third or more during the summer. Before these reductions take place, we sought to characterize the sewage N signature in primary (macroalgae) and secondary (the hard clam, Mercenaria mercenaria) producers in the bay using stable isotopes of N (δ15N) and carbon (δ13C). The δ15N signatures of the macroalgae show a clear gradient of approximately 4‰ from north to south, i.e., high to low point source loading. There is also evidence of a west to east gradient of heavy to light values of δ15N in the bay consistent with circulation patterns and residual flows. The Providence River Estuary, just north of Narragansett Bay proper, receives 85% of STP inputs to Narragansett Bay, and lower δ15N values in macroalgae there reflected preferential uptake of 14N in this heavily fertilized area. Differences in pH from N stimulated photosynthesis and related shifts in predominance of dissolved C species may control the observed δ13C signatures. Unlike the macroalgae, the clams were remarkably uniform in both δ15N (13.2 ± 0.54‰ SD) and δ13C (−16.76 ± 0.61‰ SD) throughout the bay, and the δ15N values were 2–5‰ heavier than in clams collected outside the bay. We suggest that this remarkable uniformity reflects a food source of anthropogenically heavy phytoplankton formed in the upper bay and supported by sewage derived N. We estimate that approximately half of the N in the clams throughout Narragansett Bay may be from anthropogenic sources.  相似文献   

6.
We measured seasonal effects of wastewater treatment plant (WTP) effluent on growth, survival, and accumulation of microbes in oysters near a major WTP in Mobile Bay, AL. Despite higher nutrients near the WTP, seasonal conditions rather than distance affected chlorophyll a concentration and oyster growth. In summer and fall, when oyster growth was higher, δ15N‰ in oysters near the WTP changed through time to reflect δ15N‰ in effluent (approx. −4‰). Microbial indicators (male-specific coliphage, fecal coliforms) were highest in oysters near the WTP in all seasons and correlated with δ15N‰ in fall and summer. Increased riverine discharge and slower acquisition of δ15N‰ likely confounded correlations in winter/spring. Although we did not detect gross ecological effects of wastewater exposure for oysters, data indicated wastewater-derived particles entered the local food web and accumulated in oysters. These data highlight the importance of using multiple indicators of wastewater exposure and considering both seasonal and spatial effects when defining wastewater influence on a system or species.  相似文献   

7.
The present study focused on detecting variations in trophic relationships among blue crab (Callinectes sapidus) consumers according to water quality along two estuaries in North Carolina. Stable isotope (δ15N and δ13C) analyses of particulate organic matter and bivalve(Rangia cuneata andCorbicula fluminea) food sources were examined in combination with an Isosource mixing model. Results suggest that blue crab δ13C values increased significantly with increasing salinity from upper to lower sites along the Neuse River estuary (NRE; R2 = 0.87, p < 0.01) and Alligator River estuary (R2 = 0.92, p < 0.01). There was a positive relationship between blue crab δ15N values and nitrate concentrations for the NRE (R2 = 0.48, p = 0.12). This study found that blue crab δ13C values increased with salinity from upper to lower regions along both estuaries. Results suggest that blue crab production may have used alternative food sources that were isotopically (δ13C) depleted, especially in the upper NRE, and enriched sources in the mid to lower regions of both estuaries. Consumers sampled from the upper NRE may be influenced by higher nitrogen input from urban land use and municipal wastewater.  相似文献   

8.
Increased frequency and severity of droughts, as well as growing human freshwater demands, in the Apalachicola-Chattahoochee-Flint River Basin are expected to lead to a long-term decrease in freshwater discharge to Apalachicola Bay (Florida). To date, no long-term studies have assessed how river discharge variability affects the Bay’s phytoplankton community. Here a 14-year time series was used to assess the influence of hydrologic variability on the biogeochemistry and phytoplankton biomass in Apalachicola Bay. Data were collected at 10 sites in the bay along the salinity gradient and include drought and storm periods. Riverine dissolved inorganic nitrogen and phosphate inputs were correlated to river discharge, but chlorophyll a (Chl a) was similar between periods of drought and average/above-average river discharge in most of the Bay. Results suggest that the potentially negative impact of decreased riverine nutrient input on Bay phytoplankton biomass is mitigated by the nutrient buffering capacity of the estuary. Additionally, increased light availability, longer residence time, and decreased grazing pressures may allow more Chl a biomass to accumulate during drought. In contrast to droughts, tropical cyclones and subsequent increases in river discharge increased flushing and reduced light penetration, leading to reduced Chl a in the Bay. Analysis of the time series revealed that Chl a concentrations in the Bay do not directly mirror the effect of riverine nutrient input, which is masked by multiple interacting mechanisms (i.e., nutrient loading and retention, grazing, flushing, light penetration) that need to be considered when projecting the response of Bay Chl a to changes in freshwater input.  相似文献   

9.
Alterations of hydrology are known to trigger changes in coastal ecosystems, such as the composition and abundances of local flora and fauna. It is less well known how these alterations lead to changes in nutrient and energy transfers in these systems. We used comparisons of stable isotope signatures (δ 13C, δ 15N, and δ 34S) in the tissues of conspecific plants and animals collected on each side of the Mobile Bay Causeway to determine the extent to which the causeway may have altered energy and nutrient exchange between the Mobile–Tensaw Delta and upper Mobile Bay. While the δ 13C signatures of most plants and animals varied irrespective of their location relative with causeway location, their δ 15N and δ 34S signatures were almost always more enriched south of the causeway, indicating significant alterations of trophic linkages within this estuarine food web. Dual isotope plots and mixing model analyses indicated that while terrestrial and floating plants were trophically important to consumers north of the causeway, submerged aquatic vegetation was more important to consumers south of the causeway. Although limited in spatial and temporal scale, our results preliminarily show that there are noteworthy differences in stable isotope signatures most likely due to the Mobile Bay Causeway altering energy and nutrient transference.  相似文献   

10.
The goals of this study were to quantify organic matter source utilization by consumers in the freshwater-dominated region (East Bay) of a high river flow estuary and compare the results to consumers in marine-influenced sites of the same estuary to understand how organic matter utilization by consumers may be changing along the salinity gradient. We used the results from these evaluations to establish the baseline against which we isotopically determined trophic level for consumers in East Bay. Average isotope values for consumers sampled in East Bay ranged from −20.1‰ to −24.8‰ for carbon and from 8.9‰ to 14.3‰ for sulfur. These values were well-constrained by the four identified sources: plankton, benthic organic matter, macroalgae, and terrestrial detritus. Application of a concentration-corrected mixing model resulted in contributions of benthic production and detrital sources (averaged over the food web) to East Bay consumers of 41% and 33%, respectively, with the remainder made up of plankton and benthic macroalage. While benthic organic matter was an important organic matter source for consumers at both sites, we found that the influence of terrestrial detritus varied significantly throughout the bay. Terrestrial detritus contributed only 18% of average total organic matter in organisms inhabiting marine-influenced sites. Although terrestrial detritus did contribute to all consumers examined, most fish species in Apalachicola Bay reflect a greater reliance on autochthonous sources. Our results suggest that, while terrestrial detritus does appear to be a major contributor to commercially important shellfish species (most notably oysters and penaeid shrimp), it is not the major source fueling the diversity of secondary production in Apalachicola Bay. Thus, production in Apalachicola Bay is highly dependent on riverine influx in two ways: (1) economically important bivalves and crustaceans are being fueled by terrestrial organic matter supplied by river flooding and (2) secondary and above consumer fish species are supported by in situ production which, in turn, is reliant on nutrients supplied by the Apalachicola River. These findings are significant in light of decisions regarding water usage and river flow restrictions in the Apalachicola-Chattahoochee-Flint drainage basin. The results of this study confirm that in situ estuarine organic matter is the dominant source supporting secondary production in this river-dominated estuary.  相似文献   

11.
 Tritium, 14C, δ13C, δ18O and δD measurements indicated as early as 1973 the existence of inflows of modern meteoric water to the Wapno salt mine in a Zechstein diapir. In spite of these early warnings, the continuation of improper exploitation led, in 1977, to sudden flooding of the mine followed by catastrophic land subsidence. The lesson learned from that catastrophe, as well as the results of isotope investigations performed in the Inowrocław salt mine, led to the decision to flood the mine artificially in order to avoid a similar land subsidence. The Kłodawa mine was not regarded to be in danger of flooding due to a thick clay cap. In fact, a large number of usually short-lasting water occurrences had the isotopic composition characteristic for evaporated ocean water. However, since 1956 an inflow has existed with δ18O and δD values close to that of pre-Quaternary saline waters and brines in the Mesozoic formations adjacent to the diapir. Two other inflows have recently occurred with the initial δ18O and δD values of modern waters. As a consequence, the mine is regarded to be in danger, and the exploitation of salt in the areas of inflows has been stopped. The Wieliczka mine, southern Poland, exploits Miocene salts overthrusted together with the Carpathian flysch from the south. The most dangerous and catastrophic inflows were caused by human errors. Isotope data show the water to be of glacial or Holocene age stored in Tertiary, slightly cemented rocks of low permeability, which neighbor the mine from the north. Owing to specific geology, the mine has survived for a long time, in spite of relatively large and long-lasting inflows. However, its existence is in permanent danger. Received: 7 March 1997 · Accepted: 17 November 1998  相似文献   

12.
The stable isotope compositions of sedimentary organic carbon and content of organic carbon for sediment cores recovered at two sites (sites 724C and 725C) during Ocean Drilling Program (ODP) Leg. 117 on the Oman continental margin are used to document variability of the monsoon winds for the past 350 ka. Although both sites have a mean δ13C value of -20.1‰, three zones depleted in13C are observable at site 724C during isotope stages 3, 8 and 10, while only one zone is recognizable at site 725C. Increased coastal upwelling during isotope stage 3 owing to intense SW monsoon winds resulted in higher concentration of CO2 in the water column causing the formation of organic matter that was depleted in13C. The other two zones deposited during oxygen isotope stages 8 and 10, which are also characterized by low values of organic carbon, nitrogen and C/N ratios, could be attributed to the dilution by terrestrial material derived from paleosol by transported by northwester lies. Because of utilization of13C enriched dissolved CO2 during the last glacial maximum Holocene sedimentary organic materials are depleted in13C relative to the the fomer. The content of residues organic carbon (ROC) is higher at site 724C (with an average of 2.3 ± 1.2%) relative to site 725C, which averages to 0.9 ± 0.4% probably because of differences in the degree of preservation. Organic material deposited at site 725C has undergone more degradation relative to site 724C as reflected by a systematic downcore decrease in13C resulting from a loss of13C enriched organic compounds. Owing to lack of good chronology at site 725C, a zone that is characterized by low δ13C values it could not be correlated with the other three zones observed at Site 724C.  相似文献   

13.
Seasonal variations in foliar stable carbon composition (δ13C) and nitrogen (N), phosphorus (P) and potassium (K) concentrations of Populus euphratica Olivier and Tamarix ramosissima Ledeb, as well as correlations between foliar δ13C values and N, P and K concentrations were studied in the Ejina oasis in the lower reaches of the Heihe River, northwestern China. Foliar δ13C values, and P and K concentrations significantly differed between species. Foliar δ13C signatures in T. ramosissima were significantly more enriched than those in P. euphratica, but P and K concentrations of P. euphratica were higher. The seasonal variations and patterns of these were similar. The total foliar δ13C values and N, P and K concentrations in both P. euphratica and T. ramosissima showed a descending trend. There were significantly positive correlations between foliar δ13C values and N and P concentration of both P. euphratica and T. ramosissima. For the relationship between foliar δ13C and K concentration, there appeared oppositely positive and negative correlations in P. euphratica and T. ramosissima, respectively, but they were not significant. The simple positive correlations of δ13C–P% and δ13C–N% suggested that N and P in P. euphratica and T. ramosissima behave in a similar manner. This study also showed that there were nutrient deficiencies; N and P nutriments were the co-limiting factors in P. euphratica, while it was P nutriment in T. ramosissima.  相似文献   

14.
The Kaoping (Taiwan) and Kapuas (Indonesia) Rivers differ in hydrological cycle, topography and landscape. These differences strengthen the use of 14C dating, lignin-derived phenols, δ13C values and C/N ratios to determine the sources and diagenesis of surface sedimentary organic carbon (OC) in both rivers. The Kapuas River is surrounded by forest, resulting in sedimentary OC with a 14C age between 600 and 740 years, Λ (total lignin expressed as mg/100 mg OC) values from 0.94 to 3.70, δ13C values from −27.87 to −30.00‰, C/N ratios from 6.7 to 30.8, %OC from 0.63 to 9.24% and vanillic acid to vanillin ratio, (Ad/Al)v, values from 0.73 to 2.09, all of which indicate the presence of recent plant-derived organic matter. The tributaries and three locations upstream of the Kaoping River are also surrounded by forests, resulting in Λ values (0.51–4.80), δ13C values (−23.85 to −27.08‰), C/N ratios (14.1–28.7), %OC (1.01–7.86%) and (Ad/Al)v values (0.86–1.88), which are indicative of a terrestrial signal. No lignin oxidation products were detected in the mainstream of the Kaoping River or its coastal zone, hence the surface sediments OC with a 14C age between 4,915 and 15,870 years, enriched δ13C values (−23.30 and −26.54‰), lower C/N ratios (6.0–17.5) and lower %OC (0.15–2.24%) likely represent old rock and soil material. Massive floods during typhoons most probably cause plant materials from the Kaoping River and its coastal zone to be transported into the deep sea.  相似文献   

15.
Oysters can create reefs that provide habitat for associated species resulting in elevated resident abundances, lower mortality rates, and increased growth and survivorship compared to other estuarine habitats. However, there is a need to quantify trophic relationships and transfer at created oyster reefs to provide a better understanding of their potential in creating suitable nekton habitat. Stable isotope analyses (δ13C and δ15N) were conducted to examine the organic matter sources and potential energy flow pathways at a created intertidal oyster (Crassostrea ariakensis; hereinafter, oyster) reef and adjacent salt marsh in the Yangtze River estuary, China. The δ13C values of most reef-associated species (22 of 37) were intermediate between those of suspended particle organic matter (POM) and benthic microalgae (BMI), indicating that both POM and BMI are the major organic matter sources at the created oyster reef. The sessile and motile macrofauna colonizing the reef make up the main prey of transient nekton (e.g., spotted sea bass, Asian paddle crab, and green mud crab), thus suggesting that the associated community was most important in supporting higher trophic levels as opposed to the direct dietary subsidy of oysters. The created oyster reef consistently supported higher trophic levels than the adjacent salt marsh habitat due to the dominance of secondary consumers. These results indicate that through the provision of habitat for associated species, created oyster reefs provide suitable habitat and support a higher average trophic level than adjacent salt marsh in the Yangtze River estuary.  相似文献   

16.
The stable carbon isotope (δ13C) and elemental C/N ratios in Total Organic Carbon (TOC) extracted from radiometrically dated cores from two Midwestern USA lakes were determined to investigate the factors that control these values in temperate lakes. The range of δ13C values (-26 to -32%) and C/N ratios (mean value ∼10.8) are typical of values reported for other temperate lake organic matter in this region. In the core from Lake Winnebago, Wisconsin, a negative correlation was seen between the TOC and δ13C, which can be interpreted in terms of a re-mixing and consumption of sedimented organic carbon along with rapid equilibration throughout the water column. No correlation was seen between the TOC and δ13C in the record from Ladd Lake, Ohio, implying that in this latter lake productivity alone was not a singular process controlling the isotope ratio. Here, it is suggested that equilibrium conditions are maintained such that the DIC of the water is never depleted of aqueous CO2 during high organic production and the resulting δ13C of the organic carbon lacks correlation with the TOC. Further, in this lake a fine resolution analysis was carried out which indicated a possible anthropogenic influence on the isotope ratio around times when human settlement (∼300 yrs ago) and enhanced agricultural practices (∼80 yrs ago) were significant. The study shows that carbon isotope studies are useful in paleolimnologic investigations.  相似文献   

17.
In this study, two sediment cores (~70 cm) were collected from separate mangrove forests straddling the Ba Lat Estuary, Red River of northern Vietnam, to examine the origins of sedimentary organic carbon (SOC) and reconstruct the paleoenvironment. In addition, mangrove leaves and particulate organic matter were collected and measured for δ13C to trace the origins of SOC. The cores were analyzed by high-resolution sections for δ13C, TOC, C/N ratios, sediment grain size, water content, and porosity, with values of δ13C, TOC, and C/N ratios ranging from −28.19 to −22.5‰, 2.14–30.94 mg/g, and 10.29–18.32, respectively. The δ13C and TOC relationship indicated that there were some small residual effects of diagenetic processes on TOC and δ13C values in mangrove sediments. However, the shifts of δ13C and C/N ratios from the bottom to the surface sediment of the cores explained the change in organic matter sources, with values of C/N > 12 and δ13C < −25‰, and C/N < 12 and δ13C > −25‰ indicated terrestrial (e.g., mangrove litter) and marine phytoplankton sources, respectively. The covarying δ13C, C/N ratios, and sediment grain sizes during the past 100 years in sediment cores showed that the paleoenvironment may be reconstructed into three environments (subtidal, tidal flat, and intertidal mangrove). General trends in δ13C and C/N followed a gradual increase in the C/N ratio and a concomitant decrease in δ13C from the subtidal, through to tidal flat, and to the intertidal mangrove. δ13C and C/N ratios are therefore effective in measuring the continuum of environmental change in mangrove ecosystem.  相似文献   

18.
Stable isotope ratios of carbon and sulfur were used to assess organic matter utilization of numerically abundant consumers present in Apalachicola Bay, FL, USA. These results were used to infer nitrogen isotopic enrichment of organic matter sources in an effort to establish baseline δ 15N enrichment for trophic evaluations. We compared results from concentration-independent and concentration-dependent mixing models and found that the two methods resulted in widely different conclusions about the importance of organic matter sources that varied ninefold in sulfur concentrations. Nitrogen isotopic enrichment was used to determine relative trophic positions of consumer organisms. Source elemental concentrations of nitrogen were also considered in the calculation of relative trophic levels in a concentration-dependent approach. Concentration-independent and concentration-dependent methods of calculating trophic results were compared. While relative trophic levels of individual species varied continuously from approximately 1.7 to 3.5, comparisons of trophic level among consumers indicated four possible trophic groupings. Filter feeders (mussels and oysters) made up the lowest trophic tier while teleost fishes made up the highest trophic tier. Invertebrates sampled were assigned intermediate nondiscrete trophic levels. Because δ 15N values of important organic matter sources in the system were similar, the concentration-independent and concentration-dependent methods did not result in significantly different conclusions about trophic level for any of the consumers examined. However, a comparison of the two methods applied to a hypothetical case found that differences in base δ 15N values ranging approximately 4‰ resulted in significantly different trophic-level assignments when comparing the concentration-dependent and concentration-independent methods of trophic-level calculations. Our results confirm that consideration of the elemental concentrations of the base organisms is an important factor in determining source contributions and may affect trophic-level calculations in systems with a sufficient range of base nitrogen enrichment. However, this result depended on the relative isotopic signatures of the chosen sources and their elemental concentrations and should be considered individually for each system.  相似文献   

19.
A continuous high-resolution (monthly) record of stable isotopes (δ13C and δ18O) in a well-laminated freshwater travertine deposited at Baishuitai, SW China from May 1998 to November 2001 was presented. The travertine exhibits clear annual bands with coupled brown/white color laminations. Throughout field investigation, it was found that the thin (1.5–2.2 mm), brown porous lamina was formed in the monsoonal rainy season from April to September, whereas the thick (5–8 mm), dense white lamina was formed in the dry season from October to March. The comparisons of lamina thickness and stable isotope signals in the travertine with the meteorological records allow us to constrain the relevant geochemical processes in the travertine formation under different climate conditions and to relate climate variables to their physicochemical proxies in the travertine record. Sympathetic variations in lamina thickness, δ13C and δ18O along the sampled profile reflect changes in hydrogeochemistry, showing that thin lamina and low δ13C and δ18O values occur in warm and rainy seasons. The decreased amount of calcite precipitation and low δ13C values during the warm and rainy seasons is caused by dilution of overland flow after rainfall. The low δ18O values are believed to be related to the rainfall amount effect in subtropical monsoonal regions. This process is thought to be markedly subdued whenever the amount of rainfall is lower than a given threshold. Accordingly, distinct minima in lamina thickness, δ13C and δ18O are interpreted to reflect events with above-average rainfall, possibly heavy floods, and vice versa. This study demonstrates the potential of freshwater travertine to provide valuable information on seasonal or even monthly rainfall variations.  相似文献   

20.
 Late Proterozoic to Cambrian carbonate rocks from Lone Mountain, west central Nevada, record multiple post-depositional events including: (1) diagenesis, (2) Mesozoic regional metamorphism, (3) Late Cretaceous contact metamorphism, related to the emplacement of the Lone Mountain granitic pluton and (4) Tertiary hydrothermal alteration associated with extension, uplift and intrusion of silicic porphyry and lamprophyre dikes. Essentially pure calcite and dolomite marbles have stable isotopic compositions that can be divided into two groups, one with positive δ13C values from+3.1 to +1.4 ‰ (PDB) and high δ18O values from +21.5 to +15.8 ‰ (SMOW), and the other with negative δ13C values from –3.3 to –3.6‰ and low δ18O values from +16.9 to +11.1‰. Marbles also contain minor amounts of quartz, muscovite and phlogopite. Brown and blue luminescent, clear, smooth textured quartz grains from orange luminescent calcite marbles have high δ18O values from +23.9 to +18.1‰, while brown luminescent, opaque, rough textured quartz grains from red luminescent dolomite marbles typically have low δ18O values from +2.0 to +9.3‰. The δ18O values of muscovite and phlogopite from marbles are typical of micas in metamorphic rocks, with values between +10.4 and +14.4‰, whereas mica δD values are very depleted, varying from −102 to −156‰. No significant lowering of the δ18O values of Lone Mountain carbonates is inferred to have occurred during metamorphism as a result of devolatilization reactions because of the essentially pure nature of the marbles. Bright luminescence along the edges of fractures, quartz cements and quartz overgrowths in dolomite marbles, low δD values of micas, negative δ13C values and low δ18O values of calcite and dolomite, and depleted δ18O values of quartz from dolomite marbles all indicate that meteoric fluids interacted with Lone Mountain marbles during the Tertiary. Partial oxygen isotopic exchange between calcite and low 18O meteoric fluids lowered the δ18O values of calcite, resulting in uniform quartz-calcite fractionations that define an apparent pseudoisotherm. These quartz-calcite fractionations significantly underestimate both the temperature of metamorphism and the temperature of post-metamorphic alteration. Partial oxygen isotopic exchange between quartz and meteoric fluids also resulted in 18O depletion of quartz from dolomite marbles. This partial exchange was facilitated by an increase in the surface area of the quartz as a result of its dissolution by meteoric fluids. The negative δ13C values in carbonates result from the oxidation of organic material by meteoric fluids following metamorphism. Stable isotopic data from Lone Mountain marbles are consistent with the extensive circulation of meteoric hydrothermal fluids throughout western Nevada in Tertiary time. Received: 1 February 1994/Accepted: 12 September 1995  相似文献   

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