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1.
Spatial regression models were used to predict yields (kg?ha?1?yr?1) of nitrogen (N) and phosphorus (P) discharged from catchments throughout New Zealand under natural and current conditions. The models were derived using loads (kg?yr?1) of TN, NO3-N, TP and DRP calculated for 592 river water quality monitoring sites. Anthropogenic increases in yields above natural levels were associated with the proportions of catchments occupied by the intensive agricultural land cover and were unevenly distributed across regions. Anthropogenic increases in national loads of TN, NO3-N, TP and DRP exported to the ocean were 74%, 159%, 48% and 18%, respectively. Increases in loads exported to the ocean varied considerably at smaller scales, with catchments having significant load increases between 4- and 26-fold for N and 6- to 9-fold for P. Predictions of yields and loads reported here have utility in the development of strategies to manage nutrients.  相似文献   

2.
Water quality of a lowland stream in a New Zealand dairy farming catchment   总被引：3，自引：2，他引：1  
A small stream in a predominantly dairying catchment in the Waikato region of New Zealand was monitored for 2 years at three sites. Total nitrogen (TN) concentrations were up to 7.09 g m‐3 in winter, with the bulk comprising nitrate nitrogen (NO‐ 3‐N). During summer NO‐ 3‐N was near zero and TN mostly comprised organic nitrogen. Maximum concentrations of total phosphorus (TP) and dissolved reactive phosphorus (DRP) were 1.64 and 0.555 g m‐3, respectively, and peaks coincided with spring and autumn applications of phosphorus fertiliser. Ammoniacal nitrogen concentrations exceeded 1 g m‐3 on several occasions and mean concentrations at the three sites were 0.165–0.272 g m‐3. Faecal coliform and enterococci bacteria concentrations were 64–26000 and 7–23000 cfu per 100 ml, respectively. Specific yields of TN and NO‐ 3‐N (35.3 and 30.7 kg ha yr‐1, respectively) were much greater than any previously reported for New Zealand pasture catchments, whereas TP and DRP yields (1.16 and 0.54 kg ha yr‐1, respectively) were more in accord with other studies. Greater use of land treatment of liquid wastes will reduce stream inputs of faecal organisms, NH4‐N and P.  相似文献   

3.
The annual loads of nutrients (TOxN equal to nitrate+nitrite; ammonium, phosphate, silicate) to all the estuaries on the mainland of the United Kingdom were estimated from data on water flow through gauging stations at the tidal limits of estuaries, and from concentration measurements under the Harmonised Monitoring Scheme of nutrient concentrations in water samples from these stations. The annual loads of nutrients showed distinct regional variations, with estuaries along the west coast of Wales and northern Scotland having much smaller loads than those along the east coast of England. The largest nitrogen loads were of TOxN, and ammonium loads were usually small in comparison. The Severn, Mersey, Humber and Thames had the highest loads, although these were small in relation to the larger continental European estuaries. Loads of TOxN per unit of catchment area were surprisingly constant (about 105 moles N km−2 y−1). The nutrient loads showed that most U.K. catchments were influenced by human activity, the majority being in the ‘ moderately influenced ’ category. Nutrient loads were also normalized for the area of each estuary, as a measure of the relative influence of nutrients on the receiving estuaries. The ratios of N:P, N:Si and P:Si in the annual loads suggested that most estuaries were likely to be, if anything, P limited rather than N or Si limited. However, crude annual loads may conceal significant seasonal variations.The spring maximum chlorophylla concentrations in coastal waters adjacent to each estuary were significantly correlated with the log total annual loads of TOxN, ammonium and phosphate (but not silicate) for each estuary, providing a direct link between a measure of the degree of biological response in coastal waters and the nutrient load through the estuaries. There were no significant correlations between spring maximum chlorophyll a concentrations and either catchment-normalized or estuary-normalized nutrient loads. There was significant correlation between catchment area-normalized loads of phosphate and an urbanization index for the catchments, but not with the catchment area-normalized loads of the other nutrients.  相似文献   

4.
OVERSEER is used in New Zealand to estimate nutrient losses from farmland, but does not quantify subsequent movement through the catchment, or attenuation. This paper uses the ROTAN model, based on the Scandinavian HBV-N model, to route nitrogen losses from 1900–2015 to Lake Rotorua where groundwater age ranges from 14 to 170 years. ROTAN conceptualises three delivery pathways (quickflow, groundwater and streamflow) with different attenuation. When calibrated to measured stream and groundwater concentrations, several combinations of attenuation gave equally good fits largely because of sparse and uncertain input and calibration data. Nevertheless, lake N loads were predicted for current land use (754?±?39?t y?1) and with proposed N loss reductions (431?±?26?t y?1). Probabilities were also calculated that the reductions are more (12%–18%) or less (82%–88%) than required to meet the target lake N load (405?t y?1). ROTAN shows promise for calculating nitrogen movement in catchments dominated by groundwater where there is limited data.  相似文献   

5.
Geochemical estimates of N2 fixation in the North Atlantic often serve as a foundation for estimating global marine diazotrophy. Yet despite being well-studied, estimations of nitrogen fixation rates in this basin vary widely. Here we investigate the variability in published estimates of excess nitrogen accumulation rates in the main thermocline of the subtropical North Atlantic, testing the assumptions and choices made in the analyses. Employing one of these previously described methods, modified here with improved estimates of excess N spatial gradients and ventilation rates of the main thermocline, we determine a total excess N accumulation rate of 7.8 ± 1.7 × 1011 mol N yr− 1. Contributions to excess N development include atmospheric deposition of high N:P nutrients (adding excess N at a rate of 3.0 ± 0.9 × 1011 mol N yr− 1 for  38% of the total), high N:P dissolved organic matter advected into and mineralized in the main thermocline (adding excess N at 2.2 ± 1.1 × 1011 mol N yr− 1 for  28% of the total), and, calculated by mass balance of the excess N field, N2 fixation (adding excess N at 2.6 ± 2.2 × 1011 mol N yr− 1 for  33% of the total). Assuming an N:P of 40 and this rate of excess N accumulation due to the process, N2 fixation in the North Atlantic subtropical gyre is estimated at  4 × 1011 mol N yr− 1. This relatively low rate of N2 fixation suggests that i) the rate of N2 fixation in the North Atlantic is greatly overestimated in some previous analyses, ii) the main thermocline is not the primary repository of N fixed by diazotrophs, and/or iii) the N:P ratio of exported diazotrophic organic matter is much lower than generally assumed. It is this last possibility, and our uncertainty in the N:P ratios of exported material supporting excess N development, that greatly lessens our confidence in geochemical measures of N2 fixation.  相似文献   

6.
Abstract

Growth rates of five species of surf clam were estimated on the Kapiti Coast, southern North Island, New Zealand. Length‐frequencies of sequential population samples were analysed by the computer program, MULTIFAN. Incremental growth of marked individuals was analysed by the computer program, GROTAG. The von Bertalanffy growth parameters k and L 8 estimated by MULTIFAN for Spisula aequilatera (Deshayes in Reeve, 1854) were 0.80 yr?1 and 52.1 mm; for Mactra murchisoni Deshayes in Reeve, 1854 were 0.60 yr?1 and 72.3 mm; and for M. discors Gray, 1837 were 0.35 yr?1 and 60.1 mm. MULTIFAN could not model growth of Paphies donacina (Spengler, 1793) and Dosinia anus (Philippi, 1848) from the population samples. The growth parameters estimated by GROTAG for D. anus were 0.53 yr?1 and 53.0 mm and for M. murchisoni 1.84 yr?1 and 72.4 mm. The growth rates of P. donacina, S. aequilatera, and M. discors were estimated for the size range of their incremental growth data and the estimates are usable for this limited size range only. Growth rates of each species varied with depth in the surf zone in the same way in the North and the South Island. The growth rate of two species was faster in the South Island and asymptotic size of all species was greater in the South Island.  相似文献   

7.
The metal load into sediments and the change in the sedimentary environment of Osaka Bay in the Seto Inland Sea have been studied through geochemical analysis of core sediments, using both Pb-210 dating and a selective chemical leaching technique. Analytical results from a 6-m core of sediment show that copper and zinc pollution started in the late 1800's and the present enrichment ratios of copper and zinc, relative to background levels (20 mg kg–1 for Cu and 94 mg kg–1 for Zn), are 2.8 and 4.1, respectively. The present anthropogenic copper and zinc loads into Osaka Bay sediments, are 47 and 368 ton yr–1, while natural copper and zinc loads are 40 and 186 ton yr–1, respectively. Osaka Bay sediment at the present day is considered to be seriously polluted by zinc, now. The vertical profiles of copper and zinc in four successively separated fractions (10% acetic acid soluble fraction: F-HAC, 0.1M hydrochloric acid-soluble fraction: F-HCl, hydrogen peroxide-soluble fraction: F-H2O2 and hydrofluoric acid-soluble fraction: F-HF) from the core sediments indicate that enrichments of copper and zinc in the upper layer of the sediment are dependent on increases in the metal contents of the F-HAC, F-HCl and F-H2O2 fractions. Copper in F-HAC, and zinc in F-HAC and F-HCl, seem to be of anthropogenic origin.Results of sequential studies of the whole Seto Inland Sea can be summarized as follows: At the present time, the sedimentary loads of copper and zinc over the whole Seto Inland Sea area are 630 and 3,500 ton yr–1, respectively, while the natural and anthropogenic loads are 320 and 310 ton yr–1 for copper and 1,800 and 1,700 ton yr–1 for zinc, respectively.  相似文献   

8.
ABSTRACT

SedNetNZ is used to model the effect of erosion control undertaken under the Sustainable Land Use Initiative (SLUI) and predict the effect of climate change on sediment load in the Manawatū–Whanganui region. Sediment load in 2004 is estimated at 13.4?Mt?yr?1; by 2018, ≈5000?km2 of land had farm plans implemented and annual sediment load reduced by 6.2% of the 2004 load. If SLUI stops at the 2018 level of implementation, by 2038 it is predicted to achieve a 15.7% reduction in annual sediment load. If SLUI continues to implement farm plans, 7949?km2 of land will be treated by 2043 and annual sediment load could be reduced by a further 14.7%. Climate change is predicted to substantially increase sediment loads. By 2043 annual sediment load for the region is predicted to increase, compared to 2004, by between 8.3 and 23.7%. However, this can largely be offset by SLUI works. By 2090 an annual sediment load increase of between 53 and 224% due to climate change is predicted. The results suggest climate warming may dominate changes in sediment load in the future.  相似文献   

9.
Abstract

Nitrate runoff from pastoral fanning is of concern because it contributes to lake eutrophication. Surface flow in wetlands is a measure of the runoff likely to experience nitrate attenuation. This study assessed the potential of small headwater wetlands to reduce catchment nitrate loads by quantifying the proportion of total runoff that occurred as surface flow at the outlet of wetlands. Surface flow can be measured from wetlands in side valleys (valley wetlands) with well defined flow channels, but not in those parallel to the stream (riparian wetlands) with distributed flow. This study, from November 2004 to June 2008: (1) measured the mean specific flow yield (mm yr?1) at the outlet of 6 wetlands; (2) classified wetlands into 3 types based on hydrology; (3) mapped and classified all wetlands in the catchment; and (4) calculated the area‐weighted mean specific yield of wetlands for the whole catchment. The 6.6 km2 study catchment at Taupo, North Island, New Zealand, was predominantly pasture on volcanic soils where flows were baseflow dominated. Riparian and valley wetlands occupied 5% of catchment area. Type 1 wetlands flowed continuously, were dominated by baseflow (81–83%), and had a mean annual yield (± SE) of 167 ± 46 mm (34% of stream yield). Type 2 wetlands dried up during droughts and type 3 wetlands dried up each summer. Both latter types had a low baseflow component (20%) and a yield of 66±18 mm (13% of stream yield). In one tributary, gaugings over 4 days in summer during a wet year indicated that 27% of streamflow originated from wetlands. For the catchment as a whole, wetland baseflow accounted for 11± 4% of mean annual streamflow and wetland quickflow another 8 ± 2%, although these percentages are likely underestimates because seepages occurred downslope from measurement points. Although riparian and valley wetlands occupied only 5% of the catchment area, they could potentially have attenuated nitrogen in 11–19% of runoff. Other catchments may have different hydrology and wetland nitrate attenuation, and the methods outlined here could be used to quantify these differences.  相似文献   

10.
 Recent sediment accumulation rates are 18–230 mg cm-2 yr-1 (0.02–0.2 cm yr-1) based on excess 210Pb activity profiles in the southwestern part of the East Sea (Sea of Japan). Assuming no mixing beneath surface mixed layers, 210Pb-derived sediment accumulation rates are 18–32 mg cm-2 yr-1 in the northern part of the Yamato Ridge and the Ulleung Basin, 29–136 mg cm-2 yr-1 in the Korea Plateau, and 230 mg cm-2 yr-1 in the southern shelf. These values generally agree with long-term sedimentation rates estimated from dated ash layers. Received: 6 October 1995 / Revision received: 31 May 1996  相似文献   

11.
Concentrations of total carbonate, alkalinity and dissolved oxygen were obtained near the 1973 GEOSECS stations in the North Pacific subpolar region north of 40°N along 175°E between 1993 and 1994. A difference of excess CO2 content between the GEOSECS and our expeditions was estimated. The maximum difference in water column inventory of excess CO2 has increased by about 280 gC m–2 above 2000 m depth which apparently means an uptake of excess CO2 taken from air to sea during the last two decades. An averaged value of the annual flux of excess CO2 at 75–1000 m depth was 8.63±2.01 gC m–2yr–1 in the North Pacific subpolar region. By introducing the annual flux of excess CO2 into a two-box model for the North Pacific subpolar region, a penetration factor of excess CO2 from air to sea was obtained to be 1.08×10–2 gC m–3ppm–1 in the North Pacific subpolar region. Based on this factor, the surface concentration of excess CO2 in the North Pacific subpolar region was estimated to be 68 mole I–1, suggesting that the North Pacific subpolar region absorbed atmospheric excess CO2 more than the saturated concentration of excess CO2. Total amount of excess CO2 taken from the North Pacific subpolar region by 1993 was estimated to be 36.2×1015 gC, which was equal to about one tenth of that released by human activities after the preindustrial era.  相似文献   

12.
Sedimentation rates in ten sediment cores from Hiroshima Bay in the Seto Inland Sea of Japan were determined with the |2210|0Pb technique, and heavy metals were analyzed. The sedimentation rates vary from 0.18 to 0.33 g cm|2-2|0 yr|2-1|0. The highest sedimentation rates were observed in the northern part of the bay at the mouth of Ota River, while lower sedimentation rates not more than 0.20 g cm−2 yr−1 were observed at stations close to narrow water-ways, or where water depth was shallow. The contents of copper and zinc in the sediment cores began to increase around 1930 as a result of increased human activity, and have remained almost unchanged since 1970 possibly because of regulation of pollutant discharge. The natural background values of copper and zinc in the sediment of this bay range from 16 to 27 mgkg−1 and 70 to 105 mg kg−1, respectively. The total amounts of anthropogenic copper and zinc deposited in the sediments since about 1930 are estimated to be 0.5–2.7 ton km−2 and 2.2–14.5 ton km−2, respectively. At the present-day, the anthropogenic loads of copper and zinc to the sediments of the whole bay are 26 ton yr−1 and 183 ton yr−1, and these values constitute 39% and 48% of the total sedimentary loads at the present-day, respectively.  相似文献   

13.
ABSTRACT

National assessments have highlighted that urban streams have some of the poorest water quality in New Zealand, yet there has been no analysis focussing on these streams. In this study we defined urban streams as >15% catchment urban land cover and used monitoring data to assess several indicators of water quality including dissolved metals, nutrients, bacteria and the macroinvertebrate community index. We investigated associations between the indicators and urban land cover, imperviousness and geographic location. Water quality was highly variable, within and between monitored sites; and invariably poor when compared to water quality criteria. Dissolved zinc was positively related to the proportion of urban land cover and imperviousness in the upstream catchment. There were significant differences in ammoniacal-N, nitrate-N, turbidity, MCI, dissolved zinc and E. coli between geographic locations. The analysis indicates that if urban development continues in its current form, increases in urban land cover around New Zealand can be expected to result in further declines in water quality and a reduced likelihood that water quality objectives will be achieved at impacted locations.  相似文献   

14.
Application of a simple model describing regional variations in the contents of manganese and associated minor metals in deep-sea sediments suggests that solid manganese phases are being removed from the <0.5 μm fraction of seawater at ～1–7 · 1012g yr?1 in excess of the rate of stream-supplied manganese. This flux is consistent with: (1) the relative rates of sediment accumulation in the Atlantic and Pacific Oceans; (2) the contrast between the oceanic residence time of manganese calculated from stream-supply data (14 · 103 yr) and from the flux of manganese precipitating in marine sediments or as manganese nodules (0.38–2.4 · 103 yr); (3) the surplus mass of manganese revealed by geochemical balance calculations (22.9 · 102g). On this basis excess manganese is accumulating in deep-sea sediments at 0.2–2.0 · 10?6 g cm?2yr?1. Manganese supplied to the upper layers of marine sediments by diagenesis has been evaluated with the aid of vertical advection—diffusion—reaction models. The calculated diagenetic flux of manganese at the sediment surface in a near-shore environment is in agreement with the known accretion rate of manganese deposits (1.7 · 10?2 g cm?2 10?3 yr?1) and the regionally variable flux over the area assessed is consistent with the presence or absence of manganese nodules at or near the water-sediment interface. The diagenetic flux at the surface of deep-sea sediments has been calculated at 0.7 · 10?4 g cm?2 10?3 yr?1 when the upper, oxic, zone of the sediment is ～20 cm thick. A limiting factor on the in situ production flux of dissolved manganese in deep-sea sediments appears to be the availability of reducing agents for manganese dissolution rather than the rate of downward transport of manganese-rich sediment to a reaction boundary where dissolution takes place. Various estimates of the rate of upward-migrating manganese suggest that manganese precipitates in the oxic zone with a rate constant of ～10?7 sec?1 with the result that diagenetic processes cannot supply the flux of excess manganese through more than ～0.25 m of oxic sediment. However, estimates of the flux of manganese to the oceans by submarine volcanic processes (0.79–1.1 · 1012g yr?1) are similar to the surplus mass of manganese detected by geochemical balance calculations (0.7 · 1012g yr?1). If submarine hydrothermal solutions provide only 10% of this excess then their computed discharge rate (39 g cm?2 yr?1) and residence time in the upper layer of oceanic crust (130,000 yr) agree well with these parameters for continental thermal springs.  相似文献   

15.
A 1-D coupled physical-biogeochemical model is used to study the seasonal cycles of silicon and nitrogen in two High Nutrient Low Chlorophyll (HNLC) systems, the Antarctic Circumpolar Current (ACC) and the North Pacific Ocean, and a mesotrophic system, the North Atlantic Ocean. The biological model consists of nine compartments (diatoms, nano-flagellates, microzooplankton, mesozooplankton, two types of detritus, nitrate, ammonium and silicic acid) forced by irradiance, temperature, mixing and deep nitrate and silicic acid concentrations. At all sites, nanophytoplankton standing crop variations are low, in spite of variations in primary production, because of a “top–down” control by microzooplankton. Although nanophytoplankton sustain more than 60% of the annual primary production in these areas, their contribution to the export production does not exceed 1% of the total. The differences in the seasonal plankton cycle among these regions come mainly from differences in the dynamics of large phytoplankton (here diatoms). In the ACC, the chlorophyll maximum remains <1.5 mg m−3, as an unfavourable light/mixing regime and a likely trace-metal limitation keep diatoms from blooming. In the northeast Pacific, trace-metal limitation seems to keep diatoms from blooming throughout the year. In both these systems, light or iron limitations induce high Si/N uptake ratios. Incidentally these high Si/N uptake ratios lead to a net excess of silicic acid utilization over nitrate, and to a subsequent silicic acid limitation during the summertime. In the North Atlantic, under favourable light/mixing regime and nutrient-replete conditions at the onset of the growing period, diatoms outburst and sustain a bloom >3.5 mg Chl-a m−3. Thereafter, mesozooplankton grazing pressure and silicic acid limitation induce the collapse of the chlorophyll maximum and the persistence of lower chlorophyll concentrations in summer. Although the ACC and the North Pacific show HNLC features, they support a high biogenic silica production (1.9 and 1.07 mol Si m−2 yr−1) and export flux (0.79 and 0.61 mol Si m−2 yr−1), compared to the North Atlantic (production: 0.23 mol Si m−2 yr−1, export: 0.12 mol Si m−2 yr−1). The differences in Si production and export between the HNLC systems and the mesotrophic North Atlantic come from both higher Si concentrations and Si/N uptake ratios in the HNLC areas compared to the North Atlantic. Also, the low dissolution rate of biogenic silica compared to nitrogen degradation rate, and the inhibition of nitrate uptake by ammonium, reinforce the net excess of silicic acid utilization over nitrate. As a result, the model also illustrates the efficiency of the silica pump for the three sites: about 50% of the biogenic silica synthesized in the euphotic layer is exported out of the first 100 m, while only 4–11% of the particulate organic nitrogen escapes recycling in the surface layer.  相似文献   

16.
Fish farming impact on the seasonal biomass, carbon and nutrient (nitrogen and phosphorus) balance of the endemic Mediterranean seagrass Posidonia oceanica was assessed in the Aegean Sea (Greece) in order to detect changes in magnitude and fate of seagrass production and nutrient incorporation with organic loading of the meadows. Phosphorus concentration in the leaves, rhizomes and roots was enhanced under the cages throughout the study. Standing biomass was diminished by 64% and carbon, nitrogen and phosphorus standing stock by 64%, 61% and 48%, respectively, under the cages in relation to those at the control. Seagrass production decreased by 68% and element (C, N, P) incorporation by 67%, 58% and 58%, respectively, under the cages. Leaf shedding was reduced by 81% and loss of elements (C, N, and P) through shedding by 82%, 74% and 72%, respectively, under the cages. Leaf and element (C, N, P) residual loss rate, accounting for grazing and mechanical breakage of leaves, was decreased by 79%, 85%, 100% and 96%, respectively, at the control station. At the control station, 13.98 g C m?2 yr?1, 1.91 g N m?2 yr?1 and 0.05 g P m?2 yr?1 were produced in excess of export and loss. In contrast, under the cages 12.69 g C m?2 yr?1, 0.31 g N m?2 yr?1 and 0.04 g P m?2 yr?1 were released from the meadow. Organic loading due to fish farm discharges transformed the seagrass meadow under the cages from a typical sink to a source of organic carbon and nutrients.  相似文献   

17.
In the Hiuchi-Nada area of the Seto Inland Sea, Japan, sedimentation rates were determined with the Pb-210 technique, and heavy metals in sediments were also analyzed. Sediments were collected in twelve short sediment cores and a long sediment core, using 1-m and 6-m gravity corers.The sedimentation rates vary from 0.14 to 0.31 g cm–2yr–1. The highest sedimentation rate was observed in the central part of the area, while lower sedimentation rates were observed in the eastern part.In Hiuchi-Nada, a remarkable increase in copper and zinc contents is noticeable as early as the 1800's. Over the past 240 years a copper smelter at the south-western side of this area has been causing serious pollution of the sediment. Now, anthropogenic copper and zinc loads into the sediment are 123 and 376 ton yr–1 compared to natural copper and zinc loads of 82 and 401 ton yr–1, respectively. The highest level of copper and zinc pollution was observed in the 1960's, when the relative enrichments above background values (copper; 19 and zinc; 93 mg kg–1) were 5.5 and 2.8, respectively.  相似文献   

18.
Data from the first systematic survey of inorganic carbon parameters on a global scale, the GEOSECS program, are compared with those collected during WOCE/JGOFS to study the changes in carbon and other geochemical properties, and anthropogenic CO2 increase in the Atlantic Ocean from the 1970s to the early 1990s. This first data-based estimate of CO2 increase over this period was accomplished by adjusting the GEOSECS data set to be consistent with recent high-quality carbon data. Multiple Linear Regression (MLR) and extended Multiple Linear Regression (eMLR) analyses to these carbon data are applied by regressing DIC with potential temperature, salinity, AOU, silica, and PO4 in three latitudinal regions for the western and eastern basins in the Atlantic Ocean. The results from MLR (and eMLR provided in parentheses) indicate that the mean anthropogenic CO2 uptake rate in the western basin is 0.70 (0.53) mol m?2 yr?1 for the region north of 15°N; 0.53 (0.36) mol m?2 yr?1 for the equatorial region between 15°N and 15°S; and 0.83 (0.35) mol m?2 yr?1 in the South Atlantic south of 15°S. For the eastern basin an estimate of 0.57 (0.45) mol m?2 yr?1 is obtained for the equatorial region, and 0.28 (0.34) mol m?2 yr?1 for the South Atlantic south of 15°S. The results of using eMLR are systematically lower than those from MLR method in the western basin. The anthropogenic CO2 increase is also estimated in the upper thermocline from salinity normalized DIC after correction for AOU along the isopycnal surfaces. For these depths the results are consistent with the CO2 uptake rates derived from both MLR and eMLR methods.  相似文献   

19.
In the Suo-Nada area of the Seto Inland Sea, Japan, sedimentation rates and the sedimentary record of anthropogenic metal loads were determined by combining the Pb-210 dating technique with heavy metal analysis of the sediments. The sedimentation rates vary from 0.11 to 0.27 g cm–2 yr–1. Lower sedimentation rates were observed in the eastern part of the basin which is characterized by a bottom with sand and gravel, and fast tidal currents.Anthropogenic and natural loads of copper and zinc into the sediments are 34 and 326, and 65 and 375 ton yr–1, respectively. The anthropogenic loads are fairly low compared with those of the other main areas of sediment accumulation in the Seto Inland Sea. The highest level of zinc and copper pollution was observed in the western part of the basin because of waste discharge from an old and big ironworks outside basin since the early 1900's.  相似文献   

20.
Nitrite is chemically stable but photochemically unstable in seawater. The net disappearance rate in abiotic low-nitrate seawater exposed to sunlight is ～ 10% per day. The primary products are the free radicals NO and OH. Quantitative aspects of the kinetics and secondary product formation are discussed in terms of a fourteen-step reaction scheme. Possible pathways explaining the results are suggested but not unequivocally identified.The rate of reaction in various marine environments is estimated from cruise data and extrapolations to vary between 0.2–60·10?3 moles m?2yr?1, with a suggested global average for comparison purposes of 1–10·103 moles m?2yr?1.These results confirm and quantify our previous suggestion that nitrite photolysis represents a source of OH radical in seawater. The reaction rate is large enough that significant impacts on the geochemical cycles of dissolved organic carbon and nitrogen and heavy metals may plausibly result. Effects on marine biota and atmospheric trace gas composition are also possible. However, specific reactions coupling the nitrite system to other processes have not yet been identified or demonstrated empirically.  相似文献   

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