共查询到20条相似文献，搜索用时 46 毫秒
1.
Measurements of the magnetic fields by the electron reflection method in the neighborhood of the long structural rille Rima Sirsalis show that a magnetic field of strength ? 100 nT (100 γ) is present over a region on the order of 10 km in width and at least 300 km long. The center of the magnetized region closely parallels and is centered on the rille. The linear magnetization feature extends at least to latitude 8°S, 60 km beyond the place where the rille disappears at the edge of Oceanus Procellarum. This extension is coincident with the extrapolation of the rille based on photographs. However, the magnetization is much weaker or entirely absent at 5°S and has vanished at 0° latitude. These results suggest that the rille is indeed a structural feature and has associated with it magnetization, either in the form of intrusive, magnetized rock, or else in the form of a gap in an otherwise more or less uniformly magnetized layer of rock of large extent in two dimensions. Furthermore, the rille structure evidently is present for some distance beneath the lava flows of the Oceanus Procellarum basin. 相似文献
2.
Apollo 15 and 16 subsatellite measurements of lunar surface magnetic fields by the electron reflection method are summarized. Patches of strong surface fields ranging from less than ° to tens of degrees in size are found distributed over the lunar surface, but in general no obvious correlation is observed between field anomalies and surface geology. In lunar mare regions a positive statistical correlation is found between the surface field strength and the geologic age of the surface as determined from crater erosion studies. However, there is a lack of correlation of surface field with impact craters in the mare, implying that mare do not have a strong large-scale uniform magnetization as might be expected from an ancient lunar dynamo. This lack of correlation also indicates that mare impact processes do not generate strong magnetization coherent over ～ 10 km scale size. In the lunar highlands fields of >100 nT are found in a region of order 10 km wide and >300 km long centered on and paralleling the long linear rille, Rima Sirsalis. These fields imply that the rille has a strong magnetization (>5 × 10 ?6 gauss cm 3 gm ?1 associated with it, either in the form of intrusive, magnetized rock or as a gap in a uniformly magnetic layer of rock. However, a survey of seven lunar farside magnetic anomalies observed by the Apollo 16 subsatellite suggests a correlation with inner ejecta material from large impact basins. The implications of these results for the origin of lunar magnetism are discussed. 相似文献
3.
Properties of lunar crustal magnetization thus far deduced from Apollo subsatellite magnetometer data are reviewed using two of the most accurate presently available magnetic anomaly maps — one covering a portion of the lunar near side and the other a part of the far side. The largest single anomaly found within the region of coverage on the near-side map correlates exactly with a conspicuous, light-colored marking in western Oceanus Procellarum called Reiner Gamma. This feature is interpreted as an unusual deposit of ejecta from secondary craters of the large nearby primary impact crater Cavalerius. An age for Cavalerius (and, by implication, for Reiner Gamma) of 3.2 ± 0.2 × 109 y is estimated. The main (30 × 60 km) Reiner Gamma deposit is nearly uniformly magnetized in a single direction, with a minimum mean magnetization intensity of 7 × 10−2 G cm3/g (assuming a density of 3 g/cm3), or about 700 times the stable magnetization component of the most magnetic returned samples. Additional medium-amplitude anomalies exist over the Fra Mauro Formation (Imbrium basin ejecta emplaced 3.9 × 109 y ago) where it has not been flooded by mare basalt flows, but are nearly absent over the maria and over the craters Copernicus, Kepler, and Reiner and their encircling ejecta mantles. The mean altitude of the far-side anomaly gap is much higher than that of the near-side map and the surface geology is more complex, so individual anomaly sources have not yet been identified. However, it is clear that a concentration of especially strong sources exists in the vicinity of the craters Van de Graaff and Aitken. Numerical modeling of the associated fields reveals that the source locations do not correspond with the larger primary impact craters of the region and, by analogy with Reiner Gamma, may be less conspicuous secondary crater ejecta deposits. The reason for a special concentration of strong sources in the Van de Graaff-Aitken region is unknown, but may be indirectly related to the existence of strongly modified crustal terrain which also occurs in the same region. The inferred directions of magnetization for the several sources of the largest anomalies are highly inclined with respect to one another, but are generally depleted in the north-south direction. The north-south depletion of magnetization intensity appears to continue across the far-side within the region of coverage. The mechanism of magnetization and the origin of the magnetizing field remain unresolved, but the uniformity with which the Reiner Gamma deposit is apparently magnetized, and the north-south depletion of magnetization intensity across a substantial portion of the far side, seem to require the existence of an ambient field, perhaps of global or larger extent. The very different inferred directions of magnetization possessed by nearly adjacent sources of the Van de Graaff-Aitken anomalies, and the depletion in their north-south component of magnetization, do not favor an internally generated dipolar field oriented parallel to the present spin axis. A variably oriented interplanetary magnetizing field that was intrinsically strong or locally amplified by unknown surface processes is least inconsistent with the data. 相似文献
4.
North-seeking bacteria (NSB) with 1 μm diameters migrate to the S pole only. They were applied to identify the S pole determination on a polished surface of magnetite-rich pyroxenite whose natural remanent magnetization (NRM) intensity was 5.64 × 10 −3 Am 2 kg −1. The microscopic observations were performed under dark-field illumination in a controlled magnetic field to 10 μT. The NSB formed clusters on limited areas of magnetite grains and scattered over the whole magnetite grains. The NRM decreased to 1.02 × 10−5 Am2 kg−1 by alternating field (AF) demagnetization to 60 mT but no clusters appeared, while small populations of the NSB scattered on each grain. These scattered bacteria may gather toward the S pole resulting from magnetic domain walls. When the sample acquired saturation isothermal remanent magnetization (SIRM) to 1 T, the NSB formed dense clusters at the opposite side to the applied field direction on the many grains as expected. This evidence indicated that the NSB can be useful micro-organisms for the determination of fine magnetic structures. Some grains also had NSB clusters at the edge of the grains toward the field direction or did not exhibit any clusters. The complicated distribution of the clusters (the S poles) may be explained by shape anisotropy of the magnetic grains. 相似文献
5.
Chemical diffusion of four rare-earth elements (La, Nd, Dy and Yb) has been measured in natural calcite under anhydrous conditions, using rare-earth carbonate powders as the source of diffusants. Experiments were run in sealed silica capsules along with finely ground calcite to ensure stability of the single-crystal samples during diffusion anneals. Rutherford backscattering spectroscopy (RBS) was used to measure diffusion profiles. The following Arrhenius relations were obtained over the temperature range 600–850°C: DLa =2.6×10 −14 exp(−147±14 kJ mol −1/ RT) m 2 s −1, DNd =2.4×10 −14 exp(−150±13 kJ mol −1/ RT) m 2 s −1, DDy =2.9×10 −14 exp(−145±25 kJ mol −1/ RT) m 2 s −1, DYb =3.9×10 −12 exp(−186±23 kJ mol −1/ RT) m 2 s −1. In contrast to previous findings for refractory silicates (e.g. zircon), differences in transport rates among the REE are not pronounced over the range of temperature conditions investigated in this study. Diffusion of the REE is significantly slower than diffusion of the divalent cations Sr and Pb and slower than transport of Ca and C at temperatures above 650°C. Fine-scale zoning and isotopic and REE chemical signatures may be retained in calcites under many conditions if diffusion is the dominant process affecting alteration. 相似文献
6.
In 1996, long-term sealed-hole hydrological observatories with subseafloor temperature and pressure sensors were installed in four cased holes drilled by the Ocean Drilling Program into sedimented young oceanic crust east of the Juan de Fuca Ridge. Data recovered over a year later showed that all four holes displayed temperature profiles indicative of vertical fluid flow immediately prior to their being sealed. Warm water was being produced from basement in two cases, and cool ocean bottom water was being drawn into basement at the others. Linear flow rates of 60–200 m/h were estimated from the perturbation of the temperature profiles relative to undisturbed geothermal gradients at the sites. The pressure differentials driving the flow were also measured at the time of the observatory installations, allowing estimates of permeabilities of the upper crustal sections penetrated by the holes. Estimated permeabilities vary systematically with age, ranging from about 10 −10 m 2 in the youngest site (0.9 Ma) to 10 −12 m 2 in the oldest site (3.6 Ma), confirming an apparent reduction of permeability with age determined with packer experiments at three of the same sites. Combined with other estimates of permeabilities in the same holes using methods with different scales of investigation, the new permeability estimates also provide evidence for a significant scale dependence of permeability in the upper oceanic crust. 相似文献
7.
The impact of domestic sewage effluent (SE) on the dynamics of phytoplankton assemblages from Bedford Basin was evaluated in the laboratory. Phytoplankton production and chlorophyll a increased proportionally with SE enrichment. Phytoplankton species composition also changed. The potentially harmful diatoms, Pseudonitzschia spp., present initially in small numbers (600 cells 1 −1) in Bedford Basin seawater, and became dominant (3–5×10 6 cells 1 −1) when the seawater was enriched with 0.5–5% untreated SE. With higher proportions of SE, other harmful species such as Fragilaria spp. and Euglena spp. became dominant (7−15×10 6 and 2.2×10 4 cells 1 −1, respectively). Treatment of SE with UV light or activated charcoal seems to favour growth of benign species, such as Chaetoceros socialis, Skeletonema costatum and Thalassiosira spp., but not harmful species such as Pseudonitzschia spp. Further research on UV treatment of domestic sewage is recommended. 相似文献
8.
In 1989, in a hydrological research programme within a deacidification project in the Gårdsjön area in southwest Sweden, flow paths and residence times of soil water and groundwater in microcatchments were examined to support the interpretation of the hydrochemical changes. Saturated hydraulic conductivity and soil water retention were analysed on more than 100 cylinder samples. The catchments have shallow sandy-silty till soil with a mean depth in the main catchment of 43 cm. Porosity of the mineral soil in the main catchment was high and ranged from 38 to 85%. The samples from the B-horizon had generally higher porosity. Porosity and the content of organic matter were correlated. The soil water retention was relatively high at all tensions, likely owing to the high content of organic matter. Dissolved organic substances were most probably transported from the shallow soil on the steep sides of the catchment down to the valley where it precipitated. The high porosities could be a consequence of long-term weathering, provided that the organic substances present have increased the leaching of the weathering products. Measured values of saturated hydraulic conductivity were close to log-normally distributed with a mean for all samples of 3 × 10 −5 m s −1. There was a significant increase in conductivity toward the ground surface with the mean conductivity of the samples in the uppermost 10 cm of the mineral soil of 4 × 10 −5 m s −1, which was about 13 times higher than the conductivity of 3 × 10 −6 m s −1 at 1 m depth. From the relationship between runoff at the catchment outlet and groundwater levels, the conductivity was estimated to be 15–200 times higher in the upper soil layer than in the deeper ones. In one profile, 44–64% of the yearly lateral flow was estimated to occur above 30 cm depth. The conductivity was correlated with the content of drainable water, which indicated the importance of the largest pores for the saturated hydraulic conductivity. 相似文献
9.
A new method is described for estimating: (a) the meridional electric current density, jθ, (b) the vertical growth rate of the zonal magnetic field, ∂ Bφ/∂ r, or its scale-height, Bφ/∂ Bφ/∂ r) and (c) the vertical growth rate of the vertical current density, ∂ jr/∂ r, at a few isolated points on the top surface of the Earth's core from observations of the internal geomagnetic field at the Earth's surface. The theoretical technique rests on combining unaccelerated, gravitationally-driven Boussinesq fluid dynamics of the core with frozen-flux electromagnetism, the mantle being treated as a spherically symmetric insulator. Insertion into this theory of main field models for epochs 1965, 1975 leads to preliminary values for these quantities of magnitude: (a) jθ 1 A/m2, (b) ∂Bφ/∂r 10−6 T/m or Bφ/(∂Bφ/∂r) 10 m, (c) ∂jr/∂r 10−6 A/m3. Some geophysical implications of these estimates are discussed. 相似文献
10.
Noble gases were extracted in steps from grain size fractions of microdiamonds ( < 100 μm) from the Kokchetav Massif, Northern Kazakhstan, by pyrolysis and combustion. The concentration of 4He in the diamonds proper (liberated by combustion) shows a 1/ r dependence on grain size. For grain diameters > 15 μm the concentration also decreases with the combustion step. Both results are clear evidence that 4He has been implanted into the diamonds from -decaying elements in the surrounding matrix. The saturation concentration of 4He(5.6 × 10 −4 cm 3 STP/g) is among the very highest observed in any terrestrial diamonds. Fission xenon from the spontaneous fission of 238U accompanies the radiogenic 4He; the 136Xe f/ 4He ratio of (2.5 ± 0.3) × 10 −9 agrees well with the production ratio of 2.3 × 10 −9 expected in a reservoir where Th/U 3.3. Radiogenic 40Ar is predominantly ( > 90%) set free upon combustion; it also resides in the diamonds and appears to have been incorporated into the diamonds upon their formation. 3He, on the other hand is mainly released during pyrolysis and hence is apparently carried by ‘contaminants’. The concentration in the diamonds proper is of the order of 4 × 10−12 cm3 STP/g, with a 3He/4He ratio of 1 × 10−8. Excess 21Ne, similarly, appears to be present in contaminants as well as in diamonds proper. These two nuclides in the contaminants must have a nucleogenic origin, but it is difficult to explain their high concentrations. 相似文献
11.
This research ( 1) characterized the effects of sublethal cupric ion activities on the grazing behavior of two estuarine copepods ( Acartia tonsa, Acartia hudsonica) and one nearshore, neritic copepod ( Temora longicornis) and ( 2) compared the sensitivity of short-term sublethal behavioral assays with that of longer-term acute toxicity tests. A nitrilotriacetate-trace-metal-ion buffer system at 27‰. S was used to quantify and control the free cupric ion activity. Acute toxicity tests were used to determine the mortality of A. tonsa and T. longicornis over 72 h within the approximate cupric ion activity range of 10 −13 to 10 −9.5 M. 24 h survival was not affected within the approximate cupric ion activity range of 10 −13 to 10 −9.7 M, the range used for subsequent grazing activity experiments after 24 h exposure to Cu. Grazing activity was significantly diminished at cupric ion activities of ≈ 10 −10 M for A. tonsa and T. longicornis, and at ≈ 10 −11 M for A. hudsonica. A hormetic pattern of response in feeding activity was observed with A. tonsa and T. longicornis. Grazing activity was found to be a sensitive measure of sublethal Cu stress compared with the acute toxicity tests. Grazing activity was affected at environmentally relevant cupric ion activities. 相似文献
12.
The formation and development of a salt plume (salinity up to 800 mg Cl 1 −1) in the inner part of the Coastal Plain aquifer of Israel is analyzed. Massive groundwater exploitation during the 1950s caused a large drop in the water level and formation of a hydrologic depression in the Be'er Toviyya-Kefar Warburg area. The depression reached a maximal depth during the late 1960s; thereafter a reduction in the rate of pumpage led to restoration of water levels and shallowing of the depression, until its complete disappearance towards the end of the 1980s. A spot of high salinity first appeared in 1956, following a deep drawdown in the water levels. This saline plume has been continuously expanding with increasing salinity concentrations (200–800 mg Cl 1 −1) in its center. The average rate of radial expansion was about 50 m year −1. The expansion and salinization did not cease as the depression disappeared. Rather, equalization of water levels in wells situated within the plume area with those of situated along its margins resulted in the salinization of the latter within a period of 1 year. Mass balances for water and chloride contents were made for the period 1967–1990. Taking into consideration the storage change, pumpage, natural replenishment and artificial recharge, the lateral inflow to the depression is estimated as 60 × 106 m3. Upon addition of the chloride balance, and taking into consideration the chloride concentrations of the surrounding fresh water and the apparent possible end-member of the saline source (based on geochemical considerations), the saline inflow is estimated as (40–60) × 106 m3. These estimates indicate that a large amount of saline water penetrated into the aquifer, of about half of the natural replenishment of the study area, with an estimated salinity of 1900–2700 mg Cl 1−1. It is suggested that the salt plume was formed as a result of a drop in water level combined with a flow of underlying saline water bodies from deeper strata. The chemical composition of the groundwater points to the existence of two saline water bodies of Ca-chloride composition and a marine Br/Cl ratio: (1) saline water with low Na/Cl (0.6), So4/Cl, and B/Cl ratio; (2) saline water with higher Na/Cl (> 0.6), So4/Cl, and B/Cl ratios. These chemical compositions resemble Ca-chloride saline waters found in other locations in the Coastal Plain aquifer and in underlying formations. The saline water bodies may occur in either pockets at the bottom of the aquifer or lumachelle and sandstone layers of high hydraulic conductivity in underlying sediments. 相似文献
13.
The barge Florida spilled No. 2 fuel oil into Buzzards Bay, Massachusetts on 29 September 1969. Sediments from five of the original stations were sampled in August 1989 and analysed for fuel oil hydrocarbons. Two subtidal and one intertidal marsh station showed no evidence of fuel oil. One subtidal mud core had traces of biodegraded fuel oil at 10–15 cm. One marsh core contained 10 −6 g g −1 dry wt of weathered and biodegraded fuel oil aromatic hydrocarbons and cycloalkanes at 5–10 cm with lesser concentrations at 0–5 and 10–15 cm. Although present in trace concentrations, these hydrocarbons appear to be slightly inducing cytochrome P4501A in marsh fish ( Fundulus heteroclitus). 相似文献
14.
We have developed techniques to determine 238U, 234U and 232Th concentrations in seawater by isotope dilution mass spectrometry. U measurements are made using a 233U 236U double spike to correct for instrumental fractionation. Measurements on uranium standards demonstrate that 234U/ 238U ratios can be measured accurately and reproducibly. 234U/ 238U can be measured routinely to ± 5‰ (2σ) for a sample of 5 × 10 9 atoms of 234U (3 × 10 −8 g of total U, 10 ml of seawater). Data acquisition time is 1 hour. The small sample size, high precision and short data acquisition time are superior to-counting techniques. 238U is measured to ± 2‰ (2σ) for a sample of 8 × 10 12 atoms of 238U ( 3 × 10 −9 g of U, 1 ml of seawater). 232Th is measured to ± 20‰ with 3 × 10 11232Th atoms (10 −10 g 232Th, 1 1 of seawater). This small sample size will greatly facilitate investigation of the 232Th concentration in the oceans. Using these techniques, we have measured 238U, 234U and 232Th in vertical profiles of unfiltered, acidified seawater from the Atlantic and 238U and 234U in vertical profiles from the Pacific. Determinations of 234U/ 238U at depths ranging from 0 to 4900 m in the Atlantic (7°44′N, 40°43′W) and the Pacific (14°41′N, 160°01′W) Oceans are the same within experimental error (± 5‰,2σ). The average of these 234U/ 238U measurements is 144 ± 2‰ (2σ) higher than the equilibrium ratio of 5.472 × 10 −5. U concentrations, normalized to 35‰ salinity, range from 3.162 to 3.281 ng/g, a range of 3.8%. The average concentration of the Pacific samples (31°4′N, 159°1′W) is 1% higher than that of the Atlantic (7°44′N, 40°43′W and 31°49′N, 64°6′W). 232Th concentrations from an Atlantic profile range from 0.092 to 0.145 pg/g. The observed constancy of the 234U/ 238U ratio is consistent with the predicted range of 234U/ 238U using a simple two-☐ model and the residence time of deep water in the ocean determined from 14C. The variation in salinity-normalized U concentrations suggests that U may be much more reactive in the marine environment than previously thought. 相似文献
15.
Variations in some physical, chemical, and nutrient conditions were investigated at Turkwel Gorge Reservoir and its inflowing river, Suam between 1994 and 1995. Seasonal changes in inflow volume had the greatest impact on the reservoir and river conditions investigated. A wide fluctuation in inflow volume combined with a regulated outflow independent of season resulted in a draw down of over 10 m in each year. Flood inflows during the wet season resulted in the lowest values of Secchi depth (range, 0.09–2.16 m), electrical conductivity (EC, range = 140–200 mS cm −1) and total alkalinity (TA, range = 75–111 mg l −1) while the highest values were measured during the dry season. A functional relation between EC and TA (TA = 0.529 mg l −1, EC: R 2 = 0.876) suggests a predominance of carbonates among the anions. Vertical profiles of temperature and dissolved oxygen (DO) revealed that the reservoir is monomictic with a wide variation in the depth of the daily mixed layer. High values of pH (range = 6.7–8.9) and DO (range = 4.9–9.2 mg l −1) were associated with periods of peak phytoplankton photosynthesis while the lowest values followed reservoir mixing. Peak total nitrogen (TN, range = 119–526 μg l −1) and total phosphorus (TP, range = 8.9–71.6 μg l −1) levels during the wet season resulted from increased river loading. Values of dissolved reactive silica (DRS, range = 0.41–9.77 mg l −1) showed a wet season decline which was related to diatom depletion during the wet season. Annual reservoir areal loading rates of 27.38, 10.90 and 408.5 mg m −2 were computed for TN, TP and DRS respectively based on estimates of inflowing river loads in 1994. At the inflowing river Suam, low levels of EC (range = 107–210 μS cm−1) and TA (range = 62–125 mg l−1) occurred during the wet season while the highest levels occurred shortly before the river dried up. The first flood water at the resumption of river inflow in March was characterized by very low levels of DO (range = 1.8–8.2 mg l−1) and high levels of TN (range = 205–3354 μg l−1) and TP (102–1259 μg l−1). River pII (6.9–7.7) and DRs (range = 9.01–19.93 mg l−1) varied irregularly throughout the year. 相似文献
16.
Levels of bacterial indicators of pollution are related with marine salinity and turbidity at both high tide (HT) and low tide (LT). The salinity varied from values around 26.9 ppm at the LT and 28.6 ppm at the high tide but affected total and faecal coliform (FC) estimates. Salinity readings of 25–30 ppm produced microbial counts below 10 −2 MPN/100 ml total coliforms (TCs) whereas salinity of 15–22 ppm produced a TC level of 4.6×10 −4 MPN/100 ml. Turbidity peaks in the samples are accompanied by peaks of microbial contamination of the seawater indicating that the contamination is normally deposited at the marine sediment rather than in the water column. In fact, samples collected under heavy stormy weather, in which the water agitation resulted in turbidity values up to 68.3 NTU, produced maximum microbial counts. 相似文献
17.
We have observed natural remanent magnetizations (NRM), ranging from 10 −3 to 10 −5 Gauss cm 3/g, at least two orders of magnitude greater than 10 −7, the noise level of our spinner magnetometer, in the carbonaceous chondrites, Orgueil, Cold Bokkeveld, Nogoya and Mighei. Preliminary alternating field demagnetization of two samples of Orgueil showed a moderate sized stable component of 10 −4 Gauss cm 3/g. Microscopic study reveals that a grey spinel oxide, Ni-Fe and an Fe sulphide are the principal opaque minerals in both Cold Bokkeveld and Orgueil; the oxide phase predominates in both, while the Ni-Fe is more visible in the former. Coercive force determinations in Orgueil and Cold Bokkeveld indicate single domain particles as the NRM carrier. These meteorites are suitable for the determination of the magnetic field intensity in the primary solar nebula. 相似文献
18.
The diffusion of the dynamo-generated magnetic field into the electrically conducting inner core of the Earth may provide an explanation for several problematic aspects of long-term geomagnetic field behavior. We present a simple model which illustrates how an induced magnetization in the inner core which changes on diffusive timescales can provide a biasing field which could produce the observed anomalies in the time-averaged field and polarity reversals. The Earth's inner core exhibits an anisotropy in seismic velocities which can be explained by a preferred orientation of a polycrystalline aggregate of hexagonal close-packed (hcp) iron, an elastically anisotropic phase. Room temperature analogs of hcp iron also exhibit a strong anisotropy of magnetic susceptibility, ranging from 15 to 40% anisotropy. At inner core conditions the magnetic susceptibility of hcp iron is estimated to be between 10 −4 and 10 −3 SI. We speculate here that the anisotropy in magnetic susceptibility in the inner core could produce the observed anomalies in the time-averaged paleomagnetic field, polarity asymmetry, and recurring transitional virtual geomagnetic pole (VGP) positions. 相似文献
19.
To examine nitrate persistence, detailed geochemical profiling, using core-squeezed water and piezometer samples, was carried out at five sites in southern Ontario where groundwater is moving downward in silt-rich aquitard sediments at rates of 16 to more than 20 cm year −1. Elevated levels of NO 3−-N (5–50 mg 1 −1) that occur in the shallow groundwater as a result of agricultural activity, were found to be consistently attenuated, generally to very low levels (< 0.05 mg 1 −1-N), at the ‘redoxcline’, the horizon marking the boundary between the surficial weathered (brown) sediments and the underlying unweathered (grey) sediments. Tritium dating suggests that groundwater at the redoxcline depths (3–5 m) was recharged between 1970 and 1980, thus the N03 depletion appears to result from biodegradation reactions since no major landuse changes have occurred during this period. The close association of the nitrate depletion zones with the redoxcline, where, in particular, sediment sulphur contents increase abruptly, and where also porewater SO 42− levels increase, suggests that the dominant attenuation reaction is autotrophic denitrification using reduced sulphur compounds present in the unweathered sediment as the electron donor. Mass balance calculations suggest that the increase in the downward rate of migration of the redoxcline, owing to added sulphur consumption from NO 3− contamination, is only about 1 mm year −1 at these sites. Review of the literature indicates that most silt- and clay-rich sediments have S contents in the same range, or higher, than those investigated here, thus, in most cases where aquifers are overlain by several metres or more of unweathered confining sediments, it is likely that a high degree of protection is afforded from surficial NO 3− contamination. 相似文献
20.
238U, 232Th, 230Th and 226Ra abundances have been measured in six samples of recent Hawaiian basalt by high precision mass spectrometry, in an attempt to compare the melting process in plumes and at spreading ridges. The data reveal a very small range in ( 230Th/ 238U) activity ratio up to a maximum value of 1.02 ± 0.01, and ( 226Ra/ 230Th) activity ratios which lie between 1.10 ± 0.015 and 1.19 ± 0.02. UTh and RaTh abundances are linearly correlated demonstrating that the disequilibria predate crystallisation and differentiation. Using recently published estimates for the bulk partition coefficients of U and Th, the results are consistent with melting rates > 10 −3 kg m −3 a −1 at porosities < 10 −3 for dynamic fractional melting in the garnet stability field. 相似文献
|
