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1.
Ignimbrites from the central North Island consist mainly of glass or its devitrified product (70–95%); their phenocryst mineralogy is varied and includes plag., hyp., ti-mag., ilm., aug., hblende, biot., san., qtz, ol., with accessory apatite, zircon and pyrrhotite. The Fe-Mg minerals can be used to divide the ignimbrites into four groups with hyp.+aug. reflecting high quench temperatures and biot.+hblende +hyp.+aug., low quench temperatures. Oxygen fugacities lie above the QMF buffer curve and even in ignimbrites with low crystal contents the solid phases apparently buffered fO2. Some ignimbrites contain the assemblage actinolite, gedrite, magnetite and hematite, reflecting post-eruption oxidation. The mineralogy also allows estimation of using pyrrhotite and thence , . The assemblage biotite-sanidine can be used to estimate and thence . Water fugacity is calculated in a variety of ways using both biotite and hornblende as well as the combining reaction . It is high and approaches P total in most ignimbrites (~4kb) but is lower in unwelded pumice breccias. Comparison of temperature estimates using mineral geothermometers for the various phenocryst phases suggests that the ignimbrite magmas showed temperature differences of 60–100 °C and pressure differences of several kilobars. Individual magma chambers therefore, would have extended over several kilometres vertically. The chemical potential of water may have been constant through the magma.  相似文献   

2.
Near-liquidus melting experiments were performed on a high-K latite at fO2's ranging from iron-wustite-graphite (IWG) to nickel-nickel oxide (NNO) in the presence of a C-O-H fluid phase. Clinopyroxene is a liquidus phase under all conditions. At IWG , the liquidus at 10 kb is about 1,150° C but is depressed to 1,025° C at NNO and . Phlogopite and apatite are near-liquidus phases, with apatite crystallizing first at pressures below 10 kb. Phlogopite is a liquidus phase only at NNO and high . Under all conditions the high-K latites show a large crystallization interval with phlogopite becoming the dominant crystalline phase with decreasing temperature. Increasing fO2 affects phlogopite crystallization but the liquidus temperature is essentially a function of . The chemical compositions of the near-liquidus phases support formation of the high-K latites under oxidizing conditions (NNO or higher) and high . It is concluded from the temperature of the H2O-saturated liquidus at 10 kb, the groundmass: crystal ratio and presence of chilled latite margins around some xenoliths that the Camp Creek high-K latite magma passed thru the lower crust at temperatures of 1,000° C or more.  相似文献   

3.
The mineralogy and petrology of volcanic and plutonic rocks from the island of Grenada are described. The volcanic rocks include basanitoids, alkalic and subalkalic basalts, andesites and dacites. Phenocryst phases in the basanitoids and basalts are olivine (Fo90–71), zoned calcic augite, spinel ranging from ferrian pleonaste through chromite to titaniferous magnetite, and plagioclase. Some of the basalts contain pargasitic amphibole. Andesites and dacites generally contain hypersthene and augite, and one pigeonite-hypersthene-augite-bearing andesite was found. Apatite commonly occurs as a phenocryst in the andesites and dacites and quartz is present in some dacites as well as being a possible xenocryst in both alkalic and subalkalic basalts. Plutonic cumulates found as ejected fragments in tuffs and ashes are composed of variable proportions of olivine, magnetite, calcic augite, amphibole and plagioclase. One peridotitic (ol-cpx-opx) fragment was found but spinel or garnet peridotitis are absent. Despite the alkalic nature of the association, calcalkalic characteristics such as calcic plagioclase, restricted Feenrichment in coexisting pyroxenes and generally low TiO2 content relative to oceanic suites are present in Grenada. Estimates of conditions of equilibration of the basanitoids with potential upper mantle materials using the results of high-pressure experiments are compared with estimates from thermodynamic data. Equating and basanitoid with hypothetical garnet peridotite assemblages gives a pressure and temperature of equilibration in the region of 35–38 kbar and 1550–1625 ° K. Experimental results are not supportive of these estimates.  相似文献   

4.
Near-liquidus phase relationships of a spinel lherzolite-bearing olivine melilitite from Tasmania were investigated over a P, T range with varying , , and . At 30 kb under MH-buffered conditions, systematic changes of liquidus phases occur with increasing ( = CO2/CO2 +H2O+olivine melilitite). Olivine is the liquidus phase in the presence of H2O alone and is joined by clinopyroxene at low . Increasing eliminates olivine and clinopyroxene becomes the only liquidus phase. Further addition of CO2 brings garnet+orthopyroxene onto the liquidus together with clinopyroxene, which disappears with even higher CO2. The same systematic changes appear to hold at higher and lower pressures also, only that the phase boundaries are shifted to different . The field with olivine- +clinopyroxene becomes stable to higher with lower pressure and approaches most closely the field with garnet+orthopyroxene+clinopyroxene at about 27 kb, 1160 °C, 0.08 and 0.2 (i.e., 6–7% CO2+ 7–8% H2O). Olivine does not coexist with garnet+orthopyroxene+clinopyroxene under these MH-buffered conditions. Lower oxygen fugacities do not increase the stability of olivine to higher and do not change the phase relationships and liquidus temperatures drastically. Thus, it is inferred that olivine melilitite 2927 originates as a 5% melt (inferred from K2 O and P2O5 content) from a pyrolite source at about 27kb, 1160 dg with about 6–7% CO2 and 7–8% H2O dissolved in the melt. The highly undersaturated character of the melt and the inability to find olivine together with garnet and orthopyroxene on the liquidus (in spite of the close approach of the respective liquidus fields) can be explained by reaction relationships of olivine and clinopyroxene with orthopyroxene, garnet and melt in the presence of CO2.  相似文献   

5.
This work reports new data on phenocryst composition and carbonate-silicate equilibria in the volcanic rocks of kamafugitic affinity in the Toro-Ankole Province (East African rift zone). Inclusions of primary carbonates (calcite and dolomite) were found in olivines from ugandite and mafurite of the Bunyaruguru volcanic field. The initial compositions of melt inclusions in olivine from the ugandite were calculated from microprobe analyses and correspond to carbonatites. The find of barite and dolomite-barite inclusions in the olivine from the mafurite indicates that the melt contained sulfate sulfur, which is typical of oxidizing conditions. The calculation of the olivine-spinel equilibrium (T-$ f_{O_2 } $ f_{O_2 } ) showed that crystallization of phenocrysts in mafurite occurred at oxygen fugacities above the NNO buffer (ΔQFM ∼ 2.5) in a wide temperature range (1230–750°C).  相似文献   

6.
The reaction chlorite+muscovite=staurolite+biotite+quartz+vapor has been experimentally determined and reversible equilibrium has been demonstrated. At an oxygen fugacity corresponding to that of the FMQ buffer and using a starting mixture with a Mg/Mg+Fe ratio of 0.4, the equilibrium conditions of the reaction are 565±15°C at 7 kb and 540±15°C at 4 kb. The preliminary maximum stability of staurolite in the presence of quartz, muscovite, and biotite has been established at the following conditions: 675±15°C at 5.5 kb and 575±15°C at 2 kb. The results of both investigations are in good agreement with other experimental data and with petrographical observations. Furthermore, equilibria between minerals in medium-grade pelitic rocks are deduced from theoretical considerations and the effect of T, P solid, , on some dehydration reactions is discussed.  相似文献   

7.
The positions of the liquidi and the near-liquidus phases of olivine-melilitite+CO2 have been determined under MH-buffered and furnace-buffered conditions up to 40 kb. It is found that CO2 alone lowers the liquidus compared to dry conditions, yet its influence is minor compared to H2O. The major role of CO2 is to favour the growth of orthopyroxene and garnet over that of olivine at least at high pressures. CO2-contents of glasses from experiments just above the liquidus (MH-buffered) were determined as 5.1 % at 10kb; 7.5 % at 20kb, 9.3 % at 30kb and 10–11 % (estimated) at 40 kb. Experiments on (pyrolite –40 % olivine)+H2O+CO2 show that CO2 occurs under mantle conditions as carbonate under subsolidus conditions and dissolved in a melt above the solidus. At 30kb, the solidus lies between 1,000 ° C and 1,050 ° C for vapour-saturated conditions, at and at .  相似文献   

8.
The nature of the near-liquidus phases for a mantle-derived olivine melilitite composition have been determined at high pressure under dry conditions and with various water contents. Olivine and clinopyroxene occur on or near the liquidus and there are no conditions where orthopyroxene crystallizes in equilibrium with the olivine melilitite. We have determined the effect on the liquidus temperature and liquidus phases of substituting CO2 for H2O on a mole for mole basis at 30 kb, using olivine melilitite + 20 wt% H2O at = 0 and = (CO2)/(H2+CO2) (mole fraction) = 0.25, 0.5, 0.75 and 1.0 (i.e. olivine melilitite + 38 wt% CO2). Experiments were buffered by the MH or NNO buffers. At 30 kb, CO2 is only slightly less soluble than water for <0.5 as judged by the slight increase in liquidus temperature on mole-for-mole substitution of CO2 for H2O and at 30 kb, 1200° C, = = 0.5 the olivine melilitite contains 8.8 wt% H2O and 21 wt% CO2 in solution. For 1 the CO2 saturated liquidus is depressed 70 ° C below the anhydrous liquidus and the magma dissolves approx. 17% CO2 at 30kb, 1400 ° C, 1, 0. Infrared spectra of quenched glasses have absorption bands characteristic of CO 3 = and OH- molecules and no evidence for HCO 3 - . The effect of CO 3 = molecules dissolved in the olivine melilitite at high pressure is to suppress the near-liquidus crystallization of olivine and clinopyroxene and bring orthopyroxene and garnet on to the liquidus. We infer that olivine melilitite magmas may be derived by equilibrium partial melting (<5%) of pyrolite at 30 kb, 1150–1200 ° C, provided that both H2O and CO2 are present in the source region in minor amounts. Preferred conditions are 0< <0.5, 0.5< <1, and at low oxygen fugacities (相似文献   

9.
Experimental Petrology of a Highly Potassic Magma   总被引：3，自引：0，他引：3  
The melting behaviour of a highly potassic biotite mafuriteof the Central African olivine leucitite kindred has been studiedexperimentally as a function of pressure (to 30kb) temperature,and water content (0%, 5%, 15%, 25%, and 40% H2O). Olivine isthe liquidus phase up to 30 kb for all water contents studiedexcept for anhydrous (clinopyroxene on the liquidus) and 15%H2O (phlogopite on the liquidus) conditions. Analyses of phasescrystallizing from the biotite mafurite show that pressure hasvery little effect on the composition of clinopyroxene whichis extremely calcium-rich, and low in Al2O3 and TiO2 for allconditions investigated. Phlogopite has low TiO2 content andtitanphlogopite cannot be a refractory phase in the upper mantlecausing Ti-depletion in partial melts in equilibrium with titanphlogopite.There are apparently no conditions where the extremely potassicbiotite mafurite could be a partial melt from pyrolite but derivationfrom an olivine+clinopyroxene+phlogopite+ilmenite assemblageoccurring as ‘enriched’ patches in the upper mantle,is possible. Liquids in equilibrium with phlogopite as a residualphase at 30 kb would be olivine nephelinites with approximately5% K2O, Na2O/K2O 1 and TiO2 > 5+. Crystal elutriation withtransported residual phlogopite reacting (phlogopite+liquid1 olivine+liquid 2) at lower pressures provides a mechanismfor K-enrichment and generating Na2O/K2O < 1.  相似文献   

10.
Microphenocrystic pyrrhotites were observed in the glassy groundmass of two dacite rocks from Satsuma-Iwojima, southwest Kyushu, Japan. It suggests that the dacite magma was saturated with respect to pyrrhotite at the time of eruption, and thus the sulfur contents in the groundmass can be taken as the solubility of sulfur in the dacite magma. The solubility of sulfur in the dacite rocks thus calculated is 65 to 72 ppm sulfur at the estimated conditions of T=900±50°C, and atm.  相似文献   

11.
Trace element analyses of 1-atm and high-pressure experiments show that in komatiite and peridotite, the olivine (OL)/liquid (L) distribution coefficient for Al2O3 ( ) increases with pressure and temperature. Olivine in equilibrium with liquid accepts as much as 0.2 wt% Al2O3 in solution at 6 GPa. Convergence to equilibrium compositions at this high level is shown by cation diffusion of Al into synthetic forsterite crystals of low-Al contents in the presence of melt. Convergence to low-Al equilibrium compositions at lower P and T is shown by diffusion of Al out of synthetic forsterite with high initial Al content. Isobaric and isothermal experimental data subsets reveal that temperature and pressure variations both have real effects on . Variation in silicate melt composition has no detectable effect on within the limited range of experimentally investigated mixtures. Least-squares regression for 24 experiments, using komatiite and peridotite, performed at 1 atm to 6 GPa and 1300 to 1960°C, gives the best fit equation: Increase in with increasingly higher-pressure melting is consistent with incorporation of a spinel-like component of low molar volume into olivine, although other substitutions possibly involving more complex coupling cannot be ruled out. High P-T ultrabasic melting residues, if pristine, may be recognized by the high calculated from microprobe analyses of Al2O3 concentrations in residual olivines and estimated Al2O3 concentration in the last liquid removed. In general the low levels of Al in natural olivine from mantle xenoliths suggest that pristine residues are rarely recovered.  相似文献   

12.
The interbedding of pelite and calc-schist in part of the contact aureole of a Devonian (biotite K-Ar age 346±4 Ma) granite pluton that straddles the Quebec-Vermont border offers an opportunity to compare metamorphic conditions prevailing in both rock types, and to test for internal consistency among several different geothermometers and geobarometers.Microprobe analyses and recent thermodynamic data are used with simple activity-composition models to estimate P-T-X fluid conditions near the sillimanite zone. Calculations yield the following results: P=2 to 3 kb, and T =400° to 600° C in the inner one kilometre of the aureole; was around 0.8. Estimates are based on the calc-silicate isobaric invariant assemblages tremolite-K-feldspar-plagioclase-clinozoisite-phlogopite-calcite-quartz and diopside-tremolite-plagiolase-clinozoisite-calcite-quartz, and the paragonite-andalusite-sillimanite-albite-quartz equilibrium. The solid-solid reaction phlogopite+2 diopside + 4 quartz=tremolite+K-feldspar in the calc-schist (combined with the andalusite-sillimanite equilibrium), and phase relations in the granite yield apparently inconsistent results.The implied 6 to 10 km of cover at the time of intrusion may have been provided by subsequently eroded thrust sheets.  相似文献   

13.
The alkalic ultramafic Batbjerg intrusion of East Greenland contains rocks in which nepheline and leucite are important constituents. In addition, there are vermicular, finger print intergrowths of nepheline with potassium feldspar, and patchy to micrographic intergrowths of kalsilite with potassium feldspar. The history of the pseudoleucite problem is reviewed, and it is suggested that the term pseudoleucite be restricted to intergrowths of nepheline with alkali feldspar that appear to be pseudomorphs with the crystal morphology of leucite. It is further suggested that flame-like or feather-like finger print intergrowths of nepheline with alkali feldspar, that are either interstitial to the other minerals of the rock or have grown perpendicularly on relative large and often euhedral nepheline grains are an entirely different problem and are best explained by late-stage magmatic crystallization within the system NaAlSiO4-KAlSiO4-SiO2-H2O.In the Batbjerg intrusion the early crystallization of nepheline was followed by the co-crystallization of nepheline with leucite, or in some cases by nepheline and a silica-rich leucite. Although the magma was essentially dry, as indicated by the dominantly pyroxenitic character of the rocks, water pressure rose toward the late stages of crystallization as indicated by the presence of phlogopite and occasionally both amphibole and zeolite. Shrinkage of the leucite stability field attendant upon this rise in left the liquid that was crystallizing nepheline and leucite stranded on the nepheline-alkali feldspar cotectic. Shrinkage occurred too rapidly for the liquid to remain at the reaction point of the system, and leucite, therefore, was not resorbed. The remaining liquid crystallized rapidly as flames of vermicular intergrowth of nepheline with potassium feldspar (composition Ne 24.0, Ks 45.9, Qz 30.1), a texture that might be attributable to supercooling. Silica-rich leucite compositions (Ks 68.8, Qz 31.2) decomposed to intergrowths of kalsilite with potassium feldspar but reaction kinetics, or possibly variations in throughout the intrusion, prevented the breakdown of leucite.  相似文献   

14.
Iron chlorites with compositions intermediate between the two end-members daphnite (Fe5Al2Si3O10(OH)8) and pseudothuringite (Fe4Al4Si2O10(OH)8) were synthesized from mixtures of reagent chemicals. The polymorph with a 7 Å basal spacing initially crystallized from these mixtures at 300 °C and 2 kb after two weeks. Conversion to a 14 Å chlorite required a further 6 weeks at 550 °C. Shorter conversion times were required at higher water pressures. The products contained up to 20% impurities.The maximum equilibrium decomposition temperature for iron chlorite, approximately 550 °C at 2kb, is at an between assemblages (1) and (2) listed below. Synthetic iron chlorite will break down by various reactions with variable P, T, and fugacity of oxygen. For the composition FeAlSi = 523, the sequence of high temperature breakdown products with increasing traversing the magnetite field for P total = =2kb is: (1) corierite+ fayalite+hercynite; (2) cordierite+fay alite+magnetite; (3) cordierite+magnetite+quartz; (4) magnetite+mullite+quartz. Almandine should replace cordierite in assemblages (1) and (2) but it did not nucleate. The significance of the relationship between iron cordierite and almandine in this system is discussed.At water pressures from 4 to 8.5 kb and at the nickel-bunsite buffer, iron chlorite+quartz break down to iron gedrite+magnetite with temperature 550 to 640 °C along the curve. At temperatures 50 °C greater and along a parallel curve, almandine replaces iron gedrite. For on this buffer curve, almandine is unstable below approximately 4 kb for temperatures to approximately 750 °C.  相似文献   

15.
The Mogan and Fataga formations on the island of Gran Canaria, Canary Islands, represent a sequence of approximately 30 intercalated pyroclastic and lava flows (total volume about 500 km3 dense-rock equivalent) including subalkaline rhyolitic, peralkaline rhyolitic and trachytic pyroclastic flows, nepheline trachyte lavas and a small volume of alkali basaltic lavas and tephra deposits. The eruption of the intermediate to silicic rocks of the Mogan and Fataga formations follows the roughly 4 Ma duration of basaltic shield volcanism. The most common assemblage in the evolved (Mogan and Fataga) rocks is anorthoclase+ edenitic amphibole+ilmenite+magnetite±augite±hypersthene +apatite+pyrrhotite. A few flows also contain plagioclase, biotite, or sphene. Coexisting Fe-Ti oxides yield equilibrium temperatures between 835 and 930° C and log between –11.2 and –12.6. The lowermost pyroclastic flow of the Mogan formation is zoned from a rhyolitic base (848° C) to a basaltic top (931° C). Unit P1 has an oxygen isotope feldspar-magnetite temperature (850° C) very close to its Fe-Ti oxide temperature. One of the youngest Mogan flows is zoned from a comendite (836° C) at the base to a comenditic trachyte (899° C) at the top. The Fataga formation pyroclastic flows show only slight compositional zonation, and one flow has the same Fe-Ti oxide compositions at top and base.Calculations using the reaction 1/3 magnetite+SiO2 (melt)=ferrosilite+1/6 O2 indicate total pressures of 1–4 (±3) kb for six of the Mogan flows and one of the Fataga flows. For four of the pyroclastic flows, equilibria involving tremolite-SiO2-diopside-enstatite-H2O and phlogopite-SiO2-sanidine-enstatite-H2O imply water contents of 0.9 to 2.6 (±0.5) wt% and between 80 and 610 bars, which indicates that magma within the Tejeda reservoir was H2O-undersaturated throughout the entire history of Mogan to Fataga volcanism. The fluorine contents of amphibole, biotite, and apatite, and chlorine contents of apatite reveal thatf HF/ andf HCl/ high compared to most igneous rocks and are consistent with the peralkaline nature of most of the volcanics. Thef HCl estimate for one flow is 10–2 to 10–1 bars andf HF for six of the flows ranges from about 10–1 to 6 bars. Pyrrhotite compositions yield estimates for log between –1 and –3, log between –2 and 1.5, and log between 0.5 and 3, which fall in the range of most intermediate to silicic systems. The lack of a systematic trend with time for magma composition, Fe-Ti oxide temperatures, water contents, phenocryst abundances, and ferromagnesian phase composition indicate that the Tejeda magmatic system was open and kept at nearly the same conditions by the periodic addition of more primitive melts.The intensive thermodynamic parameters estimated from coexisting phenocryst equilibria are used to constrain the eruption dynamics based on solution of the conservation equations for a vapor plus pyroclast mixture. The estimates of magma reservoir temperature, pressure, and water concentration, when combined with a one-dimensional fluid dynamical model of a pyroclastic eruption, imply that the velocities of the ash flows at the vent exit were on the order of 100 to 200 m s–1, and the mass flow rates were about 107 kg s–1 for an assumed vent radius of 10 m.  相似文献   

16.
The core of the El Tormes thermal dome, situated in the central part of one of the main metamorphic belts of the Iberian Peninsula, is formed by garnet-cordierite-biotite-sillimanite pelitic gneisses. These rocks, that very often are cut by minor intrusions of Al-rich S-type granites, are metatexitic gneisses in which there exists garnet showing different stages of resorption and transformation into an aggregate of cordierite±plagioclase±biotite. The garnet, mantled and corroded mainly by cordierite, has never been found to occur in contact with the prismatic sillimanite of the matrix, thus indicating that the continuous reaction Gr+Sill+Q = Cd has taken place. The presence of corroded biotite inside the garnet-rimming cordierite of the aggregates as well as inside the cordierite of the matrix, which usually includes remmants of sillimanite, indicates that the continuous reaction Bi+Sill+Q = Cd+FK+H2O has occurred too. Therefore, a realistic net reaction for these aggretates should be represented by the univariant, at a given , equilibrium: Biotite+Sillimanite+Garnet+Quartz = Cordierite+K-feldspar+H2O (1)The important garnet resorption near the anatectic granitic veins implies that this process is favoured by a decrease in , this factor being otherwise buffered by the reaction (1) assemblage.The most probable P-T path, assuming these conditions, consistent with the AFM projection of the former (inferred) and present assemblages in the aggregates and in the matrix, implies a decrease in P coeval with a decrease in T (Fig. 4, path 2).The most reliable P-T determination for the final stage of garnet breakdown through reaction (1), based on the coexistence of the seven phase assemblage garnet — cordierite — biotite — sillimanite — plagioclase — potash feldspar — quartz plus melt, gives 695° C, 4.3 kbar, = 0.5, The maximum pressure for this process, obtained from the garnet — plagioclase equilibrium, is 6.5±1 kbar at the same temperature.The estimates of the T for the garnet core-garnet included biotite pairs are consistently lower, ca. 550° C, than those obtained for the garnet rim-biotite in aggregates, ca. 645° C, or garnet rim-adjacent cordierite pairs, ca. 695° C.It may, therefore, be supposed that, during their evolution these rocks underwent first an increase in T and then, during the last stages, as garnet and biotite brokedown, a decrease in P and T. This represents an uplift of the core of El Tormes dome under high grade amphibolite to low pressure granulite facies conditions, accompanied by a process of partial melting with local decrase in . It is suggested, from mineral growth-deformation relationships, that this process took place during the late hercynian deformation phases, P-3 or doming stage.  相似文献   

17.
The mineralogy, petrology and geochemistry of the Proterozoic Harney Peak Granite, Black Hills, South Dakota, were examined in view of experimentally determined phase equilibria applicable to granitic systems in order to place constraints on the progenesis of peraluminous leucogranites and commonly associated rare-element pegmatites. The granite was emplaced at 3–4 kbar as multiple sills and dikes into quartz-mica schists at the culmination of a regional high-temperature, low-pressure metamorphic event. Principally along the periphery of the main pluton and in satellite intrusions, the sills segregated into granite-pegmatite couplets. The major minerals include quartz, K-feldspar, sodic plagioclase and muscovite. Biotite-{Mg No. [Molar MgO/(MgO+FeO)]=0.32-0.38} is the predominant ferromagnesian mineral in the granite's core, whereas at the periphery of the main pluton and in the satellite intrusions tourmaline (Mg No.=0.18–0.48) is the dominant ferromagnesian phase. Almandine-spessartine garnet is also found in the outer intrusions. There is virtually a complete overlap in the wide concentration ranges of SiO2, CaO, MgO, FeO, Sr, Zr, W of the biotite- and tourmaline-bearing granite suites with no discernable differentiation trends on Harker diagrams, precluding the derivation of one suite from the other by differentiation following emplacement. This is consistent with the oxygen isotope compositions which are 11.5 ± 0.6 for the biotite granites and 13.2 ± 0.8 for the tourmaline granites, suggesting derivation from different sources. The concentrations of TiO2 and possibly Ba are higher and of MnO and B are lower in the biotite granites. The normative Orthoclase/Albite ratio is extremely variable ranging from 0.26 to 1.65 in the biotite granites to 0.01–1.75 in the tourmaline granites. Very few sample compositions fall near the high-pressure, watersaturated haplogranite minima-eutectic trend, indicating that the granites for the most part are not minimum melts generated under conditions with =1. Instead, most biotite granites are more potassic than the water-saturated minima and eutectics and in analogy with experimentally produced granitic melts, they are best explained by melting at 6 kbar, <1 and temperatures 800°C. Such high temperatures are also indicated by oxygen isotope equilibration among the constituent minerals (Nabelek et al. 1992). Several of the tourmaline granite samples contain virtually no K-feldspar and have oxygen isotope equilibration temperatures 716–775°C. Therefore, they must represent high-temperature accumulations of liquidus minerals crystallized under equilibrium conditions from melts more sodic than the water-saturated haplogranite minima or during fractionation of intruded melts into granite-pegmatite couplets accompanied by volatile-aided differentiation of the alkali elements. The indicated high temperatures, <1, the relatively high TiO2 and Ba concentrations and the relatively low values of the biotite granites suggest that they were generated by high-extent, biotite-dehydration melting of an immature Archean metasedimentary source. The ascent of the hot melts may have triggered low-extent, muscovite-dehydration melting of schists higher in the crust producing the high-B, low-Ti melts comprising the periphery of the main pluton and the satellite intrusions. Alternatively, the different granite types may be the result of melting of a vertical section of the crust in response to the ascent of a thermal pulse, with the low- biotite granites generated at a deeper, hotter region and the high- tourmaline granites at a higher, cooler region of the crust. The low-Ti and high-B concentrations in the high- melts resulted in the crystallization of tourmaline rather than biotite, which promoted the observed differentiation of the melts into the granitic and pegmatitic layers found along the periphery of the main pluton and the satellite intrusions.  相似文献   

18.
Olivinites of the Krestovskaya Intrusion consist of predominant amount of olivine, and minor Ti-magnetite, perovskite, and clinopyroxene (from single grain to a few vol %). Primary crystallized melt inclusions were found and studied in olivine, perovskite, and diopside of the olivinites. Daughter phases in olivine-hosted melt inclusions are monticellite, perovskite, kalsilite, phlogopite, magnetite, apatite, and garnet andradite. Perovskite-hosted melt inclusions contain such daughter phases as kalsilite, pectolite, clinopyroxene, biotite, magnetite, and apatite, while daughter phases in clinopyroxene-hosted melt inclusions are represented by kalsilite, phlogopite, magnetite, and apatite. According to melt inclusion heating experiments, olivine crystallized from above 1230°C to 1180°C. It was followed by perovskite crystallizing at ≥1200°C and clinopyroxene, at 1170°C. According to analysis of quenched glass of the melt inclusions, the chemical composition of melts hosted in the minerals corresponds to the larnite-normative alkali ultramafic (kamafugite) magma significantly enriched in incompatible elements. The high incompatible element concentrations, its distribution, and geochemical indicator ratios evidenced that the magma was derived by the partial melting of garnet-bearing undepleted mantle.  相似文献   

19.
A dacite sample from a nuée ardente deposit at Pitons du Carbet, Martinique, contained cummingtonite, orthopyroxene, quartz, magnetite, and ilmenite as phenocrysts, and thus was suitable for evaluation of the conditions of crystallization of nuée ardente materials according to the method of Ewart et al. (1971). The estimations were obtained with the aid of a Fortran IV program, which permitted the operation of all the arrangements between the available microprobe analyses. The results indicated that the phenocrystic association crystallized at moderate temperatures (ca. 750° C), under high oxygen fugacities (> NNO) and total pressures (2.3–4.5 Kb, with a maximal density of points at about 3.5 Kb), and water pressures approximating total pressures. The groundmass Fe-Ti oxides equilibrated at lower temperatures and under relatively increasing oxygen fugacities, the variation of which is tentatively ascribed to the aerial emplacement of the nuée ardente materials. The phenocryst data imply that in the case studied the high fluid pressures characterizing the nuée ardente eruptions were not acquired at a shallow level because of the deep intratelluric stage of crystallization of these differentiated calcalkalic magmas.  相似文献   

20.
Thermodynamic calculations, modified after Nicholls et al. (1971), which relate the activity of silica in a lava to the temperature and pressure conditions at which the lava could be in equilibrium with a mantle mineral assemblage, have been extended to H2O-bearing magmas by using published experimental data to derive the dependence of on the weight fraction of H2O dissolved in a magma. A petrogenetic grid has been calculated which gives the P-T conditions under which a magma with a given at its liquidus at 1 atm could equilibrate with a mantle mineral assemblage containing olivine (ol) and orthopyroxene (opx) for different amounts of H2O in the magma at its source. This grid is in good agreement with the results of experimental studies as summarized by Green (1971) and Brey and Green (1975). The results show that the pressure at which a given magma composition can equilibrate with ol + opx increases for increasing amounts of H2O dissolved in the magma at depth.In addition, experimental data have been used to calculate the effect of olivine crystallization and removal on the in the residual liquid to assess the effect of low-pressure differentiation on . The results show that if 20 % olivine is added to a basalt magma, its calculated pressure of equilibration with ol+opx increases by 4–5 kbar for a given temperature. The calculated effects of olivine removal and H2O addition on are reasonably consistent with the silicate mixing model of Burnham (1975).Thermodynamic calculations of this type may be useful for assessing the internal consistency of certain experimental data, and in extrapolating the results to other magma compositions. The application of these calculations to determining the possible depth of origin of natural lavas appears to be limited primarily by the difficulty in determining in a lava at its liquidus temperature.  相似文献   

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