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1.
To investigate the factors controlling lead (Pb) concentration and identify the sources of Pb in Yellow Sea sediments along the Korean coast, the concentration of Pb and Pb isotopes in 87 surface and 6 core sediment samples were analyzed. The 1 M HCl leached Pb concentrations had a similar geographic distribution to those of fine-grained sediments, while the distribution of residual Pb concentrations resembled that of coarse-grained sediments. Leached Pb was presumed to be associated with manganese (Mn) oxide and iron (Fe) oxy/hydroxide, while residual Pb was associated with potassium (K)-feldspar, based on good linear relationships between the leached Pb and the Fe/Mn concentrations, and the residual Pb and K concentrations. Based on a ratio–ratio plot with three isotopes (207Pb/206Pb and 208Pb/206Pb) and the geographic location of each sediment, sediments were categorized into two groups of samples as group1 and group2. Group 1 sediments, which were distributed in Gyeonggi Bay and offshore (north of 36.5°N), were determined to be a mixture of anthropogenic and natural Pb originating from the Han River, based on a 208Pb/206Pb against a Cs/Pbleached mixing plot of core and surface sediments. Group 2 sediments, which were distributed in the south of 36.5°N, also showed a two endmembers mixing relationship between materials from the Geum River and offshore materials, which had very different Pb concentrations and isotope ratios. Based on the isotopes and their concentrations in core and surface sediments, this mixing relationship was interpreted as materials from two geographically different origins being mixed, rather than anthropogenic or natural mixing of materials with the same origin. Therefore, the relative percentage of materials supplied from the Geum River was calculated using a two endmembers mixing model and estimated to be as much as about 50% at 35°N. The spatial distribution of materials derived from the Geum River represented that of fine-grained sediments originating from the Geum River. It was concluded that Pb isotopes in sediments could be used as a tracer in studies of the origin of fine-grained sediments along the Korean Yellow Sea coast.  相似文献   

2.
渤海中部沉积物铅来源的同位素示踪   总被引：1，自引：1，他引：0  
本研究对渤海中部表层和柱状沉积物中Pb的含量和同位素进行了分析,研究了其时空分布规律,并探讨了其物质来源。结果表明,表层沉积物中Pb的含量为14.54×10-6~59.42×10-6,其含量在渤海湾近岸、黄河口附近、研究区的东北部较高,而在研究区的中部和渤海湾北部含量较低;Pb同位素207Pb/206Pb的值为0.8341~0.8489,208Pb/206Pb的值为2.0828~2.0980。岩心沉积物中Pb含量、同位素组成与表层沉积物相似,整体上较为稳定,但在1990s以来呈现增大的趋势。渤海中部沉积物中Pb以自然来源为主,黄河沉积物是其主要物质来源,但渤海湾北端则与滦河源物质或沿岸侵蚀相关;人类活动影响主要出现在1990s以后,与中国含Pb矿石的燃烧等工业活动相关,但影响微弱,仅在黄河口西北近岸海域、渤海湾等个别站位得到体现。  相似文献   

3.
We have investigated Pb concentrations and isotopic compositions in settling particles collected by sediment traps experiments over a period of two years, from May 2005 to April 2007, at two depths, 770 and 5100 m, at station KNOT in the Northwestern Pacific Ocean (44°N, 155°E). To the identify provenances of Pb, the samples were separated into two fractions by chemical leaching techniques, with the leachate expected to contain Pb of anthropogenic origin. Isotopic compositions of Pb and concentrations of Pb, Sc, Mn, La, Yb, and Th were measured by quadrupole ICP-MS. The isotope ratios of leachable Pb in settling particles were 207Pb/206Pb = 0.860 ± 0.001; 208Pb/206Pb = 2.116 ± 0.002 (mean ± 95% confidence intervals), which are similar to those of aerosols in China that are greatly affected by pollution from coal combustion. We estimated the mean contribution from anthropogenic Pb sources to the Pb in settling particles, using the conventional binary (anthropogenic and natural Pb) mixing equation for Pb isotopes, as 90% in the upper trap and 78% in the lower trap. Furthermore, we found a significant negative correlation between the isotope ratios of Pb and concentrations of leachable Mn, normalized to those of leachable Pb, suggesting that manganese oxides play an important role in transporting Pb from the upper layers of the ocean to the deeper layers. Our results support the speculation published in a previous study that Pb might be scavenged by Mn oxides in the Northwestern Pacific Ocean.  相似文献   

4.
Submarine canyons represent natural conduits for preferential transport of particulate material, including anthropogenic contaminants, from coastal zones directly to the deep sea. To assess related dispersal of natural and anthropogenic lead (Pb), we analyzed Pb concentrations and stable isotope ratios in surface sediments and sediment trap particulate material from the Portuguese margin Nazaré and Setúbal/Lisbon canyons. Geochemical data are integrated with previously obtained data on near-bottom hydrodynamics and processes and pathways of sediment transport. The two canyon systems are located in close geographic proximity to each other, but represent contrasting settings in terms of sediment input and down-canyon sediment transport processes.Concentration–isotope diagrams and three-isotope plots (206Pb/207Pb vs. 208Pb/206Pb) suggest binary mixing between natural and anthropogenic end members. The inferred isotopic signature of pollutant Pb (206Pb/207Pb=1.143 [1.134–1.149, 95% confidence interval]) is most consistent with industrial Pb; ongoing influence from gasoline Pb additives is at most of minor importance. Two proposed natural end members most likely bracket the isotopic signature of natural Pb. Accordingly, binary mixing calculations indicate that on average 20–45% vs. 35–55% of total Pb is derived from anthropogenic sources in the Nazaré and Setúbal–Lisbon canyon systems, respectively. Enhanced anthropogenic influence in the latter area is consistent with its proximity to heavily populated and industrialized areas and with sediment input from the Tagus and Sado rivers, potential major carriers of pollutant particles. In both canyon systems, the anthropogenic component generally decreases with increasing water depth.Isotopic signatures of sediment trap particulate material are generally consistent with surface sediment data at similar water depth, but show large variability in the upper Nazaré canyon and major deviations from surface sediments in the lower canyon. In the lower canyon, Pb isotopic ratios of sediment trap particulate material mostly reflect low pelagic fluxes from the overlying water column, whereas surface sediment signatures are dominated by episodic down-canyon mass transport events. Such gravity flows appear to incorporate older (pre-industrial) material masking the isotopic signature of pollutant Pb. Large variability in the upper canyon reflects continuous sediment resuspension by bottom currents. Stronger average bottom currents are associated with higher 206Pb/207Pb ratios of sediment trap particulate material and hence decreased influence of pollutant Pb. This may reflect preferential resuspension of natural Pb at the canyon floor and/or additional remobilization of older, less-polluted sediment in adjacent areas such as the canyon walls.  相似文献   

5.
The 210Pb geochronology, heavy metal concentrations (Zn, Cu, and Pb), and stable Pb isotope ratios (206Pb/207Pb) of three sediment cores collected from Jakarta Bay were analyzed to decipher the history of heavy metal contamination in the period 1900–2006. The chemical and isotopic analyses clearly suggest that anthropogenic metal accumulation in the sediments began in the 1920s and increased greatly from the 1970s until the end of the 1990s. From the end of the 1990s to 2006, accumulation rates were constant or decreased for Zn and Pb near the coastal industrialized area. Comparison of economic data and sociological information suggests that the decline in the concentrations of heavy metals could be attributed to the stricter environmental regulations which were enforced at the end of 1990s. However, metal contamination is currently still an important cause of concern in dealing with environmental preservation and protection in Jakarta Bay.  相似文献   

6.
The geographic variation in the isotopic composition of lead in surface waters of the central Pacific provides new evidence of the global anthropogenic perturbation of the element's cycle. Ratios of 206Pb/207Pb decrease from 1.196 in the northern hemisphere (19°N, 158°W) to 1.176 in the southern hemisphere (15°S, 150°W). This decrease parallels the geographic variation in surface concentrations of soluble lead which decrease from 13 ng kg?1 at the northern station to 4 ng kg?1 at the southern station. Both the 206Pb/207Pb and the 206Pb/208Pb ratios of those waters fit between the isotopic ratios of Australian (Broken Hill) and North American (Mississippi Valley) leads which are the predominant sources of leads in anthropogenic emissions to the Pacific Ocean basin.  相似文献   

7.
We deployed hydroponic eelgrass, Zostera marina L., to test its use as a sentinel accumulator and indicator of the source of water-borne lead (Pb) contamination in the marine environment. Eelgrass was deployed unrooted in the water column in the vicinity of the Portsmouth Naval Shipyard, located on Seavey Island in Portsmouth Harbor of New Hampshire and Maine, offshore from seepage sites near the Jamaica Island landfill (JIL). Deployed eelgrass, water samples from seepage sites, and sediment from the deployment sites were analyzed for Pb concentration and stable Pb isotopic composition. Isotopic composition was used to distinguish recent anthropogenic Pb inputs from background Pb in the estuary. Isotope ratios indicated that two groundwater seeps were a source of recent anthropogenic Pb (i.e. industrial Pb from the landfill) to Jamaica Cove. The eelgrass that showed the strongest presence of industrial Pb (having the lowest 206Pb/207Pb) was closest to a high volume seep that drained from the JIL and had a similar isotope signature as well as elevated Pb concentrations. These data confirm a source of water-borne industrial Pb in the estuary and show that eelgrass can function as a sentinel accumulator of Pb from anthropogenic sources.  相似文献   

8.
Abstract

The geochemical characteristics and Pb isotope variations in Fe-Mn deposits collected from the South China Sea (SCS) were studied in this paper. The mineralogical and chemical composition data indicate that the deposits are almost all hydrogenetic in origin. Compared with the Fe-Mn deposits in other oceans, the SCS Fe-Mn deposits have a significantly higher Pb content because of higher material supply in addition to a lower growth rate of the deposits. Pb isotope ratios in the surface of the SCS Fe-Mn deposits are relatively uniform, with a characteristic of relatively lower 206Pb/204Pb ratio. The Pb isotopic compositions of the SCS Fe-Mn deposits are controlled by the Pacific Deep Water and local inputs, which include eolian dust from the Asian continent and weathering products from Taiwan, Luzon and SCS submarine volcanic rocks. The continuously increasing 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb ratios along the transect of nodule D581 over the past 3.5?Ma are affected by the stepwise closure of the Luzon Strait that reduced volcanic material supply and the deep current strengthen at the same time.  相似文献   

9.
The historical trend of pollution sources of Pb in Tokyo Bay, Japan was investigated on the basis of Pb isotope ratios in a sediment core. The isotope ratios of anthropogenic Pb decreased gradually with increasing Pb concentration in the 1900s–1970s, suggesting a combination of Pb sources with various isotope ratios. In contrast, the isotope ratios of anthropogenic Pb in the 1980s–2000s showed no significant trend, and corresponded to the Pb isotope ratios in the three principal rivers flowing into the bay. It is probable that river bottom sediments contaminated with Pb are principal sources of anthropogenic Pb in Tokyo Bay.  相似文献   

10.
新测得 TAG热液区中 6件海底表层热液沉积物样品的铅同位素组成 ,其变化范围不大 ,具有均一性的特征。在 Pb- Pb图解上 ,热液沉积物的铅同位素数据大多落在 MARB的铅同位素组成范围内 ,与大西洋沉积物和 Fe- Mn结核相比明显具较少的放射成因铅 ,反映其上部洋壳岩石为该区热液沉积物的形成提供了铅。对比研究表明 ,因不同地质 -构造环境中的海底热液区为热液沉积物形成提供物源的情况不同 ,是导致有沉积物覆盖洋中脊中热液沉积物的铅同位素组成与无沉积物覆盖洋中脊不同的主要原因。海底扩张中心的扩张速率与热液沉积物的铅同位素组成有一定的对应关系 ,但其并不是热液沉积物铅同位素组成的唯一控制因素  相似文献   

11.
Lead pollution was investigated in environmental matrices and biological indicators collected from two typical subtropical coastal ecosystems in the southeast Gulf of California, Mexico. Lead concentrations and isotopic compositions ((206)Pb/(207)Pb and (208)Pb/(207)Pb) were measured using high resolution inductively-coupled plasma-mass spectrometry (HR-ICP-MS) and thermal ionization mass spectrometry (TIMS), respectively. Lead in surface estuary sediments (10.0-34.2microgg(-1)) and particulate Pb (25.0-128.7microgg(-1), >98% of total Pb) in the water column were significantly higher than levels in natural bedrock soils (15.1+/-8.3microgg(-1)) and river runoff (1.9+/-1.4microgg(-1)). Aquatic plants had Pb concentrations between 2.5 and 7.2microgg(-1), while those in macroalgae ranged from 3 to 5microgg(-1). The ranges of mean Pb concentrations in the aquatic animals studied (ranges in microgg(-1)) were as follows: zooplankton 32+/-3, mussels 2.3-3.9, oysters 1.9-7.9, snail 2.0-7.7, barnacles 0.1-18.5, fish 1.4-8.9, crab 6.3-40.2 and polychaetae 8.5-16.7. Pb values in 20-40% of oyster and fish samples and in all samples of crab exceeded acceptable levels for a food source for human consumption. Pb isotope ratios (206)Pb/(207)Pb, (208)Pb/(207)Pb in biota ranged from 1.188 to 1.206 and 2.448 to 2.470, respectively. A plot of (206)Pb/(207)Pb versus (208)Pb/(207)Pb for the environmental and biological samples collected from two study areas indicates that they contain lead from ores mined in Mexico and used in the past to produce leaded gasoline in use until 1997, natural Pb weathered from the Sierra Madre Occidental mother rock, and the later influence of inputs from a more radiogenic source related to industrial activity in the United States. Statistical software IsoSource results revealed that the Pb contained in environmental matrices and biomonitors is mostly derived from gasoline (20-90%) and US emissions (10-40%).  相似文献   

12.
Si-Fe-Mn-oxyhydroxides dredged at the PACMANUS(Papua New Guinea–Australia–Canada–Manus)hydrothermal field, Eastern Manus Basin, have 87Sr/86Sr=0.708 079–0.708 581; εNd=5.149 833–6.534 826;208Pb/204Pb=38.245–38.440; 207Pb/204Pb=15.503–15.560; 206Pb/204Pb=18.682–18.783. 87Sr/86 Sr isotope ratios are relatively homogeneous and close to the value of the surrounding seawater(0.709 16). The content of Sr in the samples contributed by seawater was estimated to be 76.7%–83.1% of total amount. The mixing temperature of hydrothermal fluids and seawater were ranging from 53.2°C to 72.2°C and the hydrothermal activities were unstable when the samples precipitated. The εNd values of all the samples are positive, which differ from the values of ferromanganese nodules(crusts) with hydrogenic origin. Nd was mainly derived from substrate rocks leached by hydrothermal circulation and preserved the hydrothermal signature. Pb isotopic compositions of most samples show minor variability except Sample #9–2 that has relatively high values of Pb isotopes. The Pb may be derived from the Eastern Manus Basin rocks leached by the hydrothermal fluid. The slightly lower 208Pb/204 Pb and207Pb/204 Pb values of the samples indicated that the hydrothermal circulation in PACMANUS was not entire and sufficient, or that hydrothermal circulation had transient changes in the past. Si-Fe-Mn-oxyhydroxides in the samples preserved the heterogeneities of local rocks.  相似文献   

13.
Arctic sea ice can incorporate sediment and associated chemical species during its formation in shallow shelf environments and can also intercept atmospherically transported material during transit. Release of this material in ice ablation areas (e.g. the Fram Strait) enhances fluxes of both sediments and associated species in such areas. We have used a suite of natural (7Be, 210Pb) and anthropogenic (137Cs, 239Pu, 240Pu) radionuclides in sea ice, sea-ice sediments (SIS), sediment trap material and bottom sediments from the Fram Strait to estimate transit times of sea ice from source to ablation areas, calculate radionuclide fluxes to the Fram Strait and investigate the role of sea-ice entrained sediments in sedimentation processes. Sea ice intercepts and transports the atmospherically supplied radionuclides 7Be and 210Pb, which are carried in the ice and are scavenged by any entrained SIS. All of the 7Be and most of the excess 210Pb measured in SIS collected in the Fram Strait are added to the ice during transit through the Arctic Ocean, and we use these radionuclides as chronometers to calculate ice transit times for individual ice floes. Transit times estimated from the 210Pb inventories in two ice cores are 1–3 years. Values estimated from the 7Be/210Pbexcess activity ratio of SIS are about 3–5 years. Finally, equilibrium values of the activity ratio of 210Pb to its granddaughter 210Po in the ice cores indicate transit times of at least 2 years. These transit times are consistent with back-trajectory analyses of the ice floes. The latter, as well as the clay-mineral assemblage of the SIS (low smectite and high illite content), suggest that the sampled sea-ice floes originated from the eastern Siberian Arctic shelf seas such as the eastern Laptev Sea and the East Siberian Sea. This result is in agreement with the relatively low activities of 239,240Pu and 137Cs and the 240Pu/239Pu atom ratios (∼0.18, equivalent to that in global fallout) in SIS, indicating that prior global atmospheric fallout, rather than nuclear fuel reprocessing facilities, forms the main source of these anthropogenic radionuclides reaching the western Fram Strait at the time of sampling (1999). Transport of radionuclides by sea ice through the Arctic Ocean, either associated with entrained SIS or dissolved in the ice, accounts for a significant flux in ablation areas such as the Fram Strait, up to several times larger than the current atmospheric flux in the area. Calculated fluxes derived from sea-ice melting compare well to fluxes obtained from sediment traps deployed in the Fram Strait and are consistent with inventories in bottom sediments. 240Pu/239Pu atomic ratios lower than 0.18 in bottom sediments from the Fram Strait provide evidence that plutonium from a source other than atmospheric fallout has reached the area. Most likely sources of this Pu include tropospheric fallout from atomic weapons testing of the former Soviet Union prior to 1963 and Pu released from nuclear reprocessing facilities, intercepted and transported by sea ice to the ablation areas. Future work is envisaged to more thoroughly understand the actual mechanisms by which radionuclides are incorporated in sea ice, focusing on the quantification of the efficiency of scavenging by SIS and the effect of melting and refreezing processes over the course of several years during transit.  相似文献   

14.
Origin of sedimentary organic matter in the north-western Adriatic Sea   总被引：1，自引：0，他引：1  
In order to evaluate the origin and the transformation of organic matter on the shallow shelf of the NW Adriatic Sea, organic carbon, total nitrogen and stable isotope ratios of organic carbon were analysed in riverine suspended matter and sediments as well as in marine suspended and sedimentary organic matter, in marine phytoplankton and zooplankton.The deposition of organic matter is influenced by fine sediment concentration. Surface sediments were characterised by highly variable biogeochemical conditions on the sea floor, whereas sub-surface sediments showed a more homogeneous hypoxic/anoxic environment.Low Corg/N ratio and high organic carbon and nitrogen concentrations in riverine suspended organic matter indicate an important contribution of freshwater phytoplankton within rivers, particularly during low flow regimes, which adds to the marine phyto- and zooplankton at shelf locations.In order to evaluate the importance of terrestrial, riverine and marine sources of OM in shelf sediments, a three end-member mixing model was applied to shelf surface sediments using 13C/12C values for organic matter and N/C ratios. The model showed an elevated contribution of terrestrial organic substances at intermediate depths (10–15 m), mostly corresponding to an area of coarser grain-size, whereas the riverine and marine organic fractions were mainly accumulating near the coast and offshore, respectively.  相似文献   

15.
Modern (last 100 yr) accumulation rates of shelf mud deposits in the Yellow and East China Seas were investigated using the distribution of excess 210Pb (210Pbex) in sediment core samples. Compilation and merger of new and previously published data helped clarify sediment accumulation in these seas. The estimated accumulation rates, together with data of suspended sediment concentrations, provided findings on the sediment budget, origin, and transport pathway of the mud deposits. The overall accumulation distribution in the Yellow and East China Sea shelf revealed a general, cross-shelf decreasing trend along the sediment dispersal system away from the rivers, except for the South Sea (SSM) and southeastern Yellow Sea (SEYSM) mud patches found along the Korean coast. Notably, 210Pbex activity profiles within the SSM and the SEYSM yielded a relatively high accumulation rate of 2-5 mm/yr, implying a sedimentation rate of 4-15 × 107 tons per year in this coastal zone. Such an annual accumulation rate is about one order of magnitude greater than the total sediment discharge (6-20 × 106 tons/yr) from Korean rivers, suggesting an additional offshore source. The distribution pattern of the well-defined suspended plume clearly showed the possible transport and exchange of fine-grained sediments between the ECS shelf and the coastal area of Korea, especially during winter. Such a high accumulation in Korean coastal areas is attributable to the sediments supplied from the mud deposit of the ECS (i.e., SWCIM), with origins in Chinese rivers. Therefore, the Korean coastal area may be an important sink for some of Chinese river sediments being transported from the south by the Yellow Sea Warm Current.  相似文献   

16.
Stable isotope ratios (δ13C) of total organic carbon were measured in surface sediments from the continental margins of the northern and western Gulf of Mexico, the north coast of Alaska and the Niger Delta. Gulf of Mexico outer-shelf isotope ratios were in the same range as has been reported for Atlantic coastal shelf sediments, ?21.5 to ?20‰. Off large rivers including the Mississippi, Niger and Atchafalaya (Louisiana), δ13C values increased from terrigenous-influenced (around ?24‰) to typically marine (～?20‰) within a few tens of kilometers from shore. This change was accompanied by a decrease in the amount of woody terrigenous plant remains in the sediment. Alaskan continental margin samples from the cold Beaufort Sea had isotopically more negative carbon (?25.5 to ?22.6‰) than did warmer-water sediments. The data indicate that the bulk of organic carbon in Recent sediments from nearshore to outer continental shelves is marine derived.  相似文献   

17.
We present data on the quality and quantity of particulate organic material deposited to the benthos in the Chukchi Sea. This analysis is undertaken by using 7Be, a short-lived radiotracer, which is associated with particle deposition, the stable carbon isotopic composition of organic material and its C/N ratio in the water column and within the sediments, and the inventories of chlorophyll a present in surface sediments. Using previously published data, we show that sedimentation processes in the regional Bering Strait ecosystem may have shifted in the past decade. Surface sediments collected in 2004 adjacent to the Russian coastline in the Chukchi Sea are less refractory in terms of carbon isotope ratios and C/N ratios than was observed for surface sediments at similar locations in 1995 and 1988. Based upon sediment 7Be and chlorophyll a inventories, short-term sedimentation on the shelf occurs immediately north of Bering Strait, and within and downstream of Barrow and Herald Canyons. Seasonal differences (i.e., ice-covered versus open-water conditions) in the quality of particulate organic carbon reaching the benthos appear to be small in the most productive waters, such as Barrow Canyon. However, in less productive waters, C/N ratios and δ13C values show seasonal variations. Once on the bottom, δ13C values in the organic fractions of the sediments are less negative than observed in settling material in the water column, which is commonly thought to result from biological processing within the sediments.  相似文献   

18.
Distribution of210Pb in sediments on the South Texas Continental Shelf is related to dynamics of the sedimentary transport processes. This radioisotope, whose concentration is time-dependent, defines three depocenters on the shelf. In addition, the variation of210Pb activity at the sediment/water interface delineates areas of terrigenous sedimentation from hemipelagic sedimentation.  相似文献   

19.
Box cores were collected close to river mouths along the eastern Brazilian shelf at water depths of 10–30 m. One core was taken from more than 1000 m depth at the shelf slope. 210Pb and 226Ra activities were measured to establish sediment accumulation rates. Seven of the 10 cores exhibited an exponential decrease with depth of excess 210Pb activities. The sediments from the sheltered Sudeste Channel off Caravelas revealed the highest sediment accumulation rate of 0.81 cm yr−1. The sediments at the shelf slope seaward of the Rio Doce revealed the lowest accumulation rate of 0.13 cm yr−1. Sediment accumulation rates increased towards the Caravelas Bank. Current patterns and the morphology of the seabed favor sediment deposition in this area.  相似文献   

20.
Total suspended matter was collected along the Yangtze River (Changjiang) and in the East China Sea in April to May and in September 2003, respectively, to study origin and fate of particulate organic nitrogen. Concentrations of particulate organic carbon (POC), nitrogen (PN) and hydrolyzable particulate amino acids (PAA; d- and l-enantiomers) were higher in the Yangtze Estuary than in the river and decreased offshore towards the shelf edge. In the coastal area, higher values of PAA were observed in the surface layer than in the bottom water. Stable carbon isotope ratios (δ13C) of POC increased from − 24.4‰ in the river to values around − 21‰ on the East China Sea Shelf. Dominant amino acids were aspartic acid + aspartine (Asx), glutamic acid + glutamine (Glx), glycine, alanine and serine. The proportions of Asx, Glx and isoleucine were higher in the marine than in the riverine samples contrary to the distributions of glycine, alanine, threonine and arginine. The proportions of d-amino acids were highest in the riverine suspended organic matter (6% of PAA) decreasing towards the shelf edge (1.5% of PAA). d-arginine, not reported in natural aquatic samples so far, was the most abundant d-amino acid in the river. The amino acid composition of the particulate organic matter (POM) in the Yangtze River indicates an advanced stage of degradation of POM. Highly degraded organic matter from soils is probably a main source of POM in the Yangtze River, but the relatively high δ13C values and low C/N ratios (7.7 ± 1.6) also indicate contribution from anthropogenic sources. The degraded riverine material was a dominant organic matter source in the estuary, where aquatic primary production had only a small overall contribution. In the East China Sea, gradual settling of riverine organic matter and the addition of fresher phytoplankton impacted the amino acid composition and δ13C values, and on the outer shelf relatively fresh phytoplankton-derived organic matter dominated.  相似文献   

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