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1.
The low-temperature magnetic hysteresis characteristics of multidomain titanomagnetite were fitted by a mixed coercivity model in which magnetocrystalline-controlled and magnetostriction-controlled domain-wall pinning play an important part. The effective contribution of the former was found to decrease systematically with increasing titanium content for compositions in the range Fe2.48Ti0.52O4Fe2.35Ti0.65O4. In agreement with the model, the observed magnetic remanence transitions and the characteristic peaks on the susceptibility vs. temperature curve became less pronounced as the titanium content increased. The problems in using these features as a means of identifying the carriers of natural remanent magnetization are discussed.  相似文献   

2.
Summary Experiments of heating-cooling cycles in zero magnetic field were performed in order to study self-reversal of NRM in basaltic rocks from Lower Silesia. Complete self-reversal occurred in one sample containing titanomagnetite withT c of 170°C and a small amount of a phase with higher Curie point. During consecutive heat treatments the phenomenon became less conspicuous. In three samples of higher oxidation level, containing several magnetic phases, only partial self-reversal of NRM occurred. For the most oxidized sample no changes of direction of NRM were observed. We suggest that the investigated phenomenon of self-reversal of NRM is due to a negative magnetic interaction between primary titanomagnetite and products of its oxidation. It seems that complete self-reversal can take place in a restricted state of oxidation.  相似文献   

3.
Notes on the variation of magnetization within basalt lava flows and dikes   总被引：2，自引：0，他引：2  
Summary The magnetic properties of basaltic rocks are dominated by the contained primary Fe–Ti oxides. At solidus temperature (1000°C) the composition of these primary oxides is restricted to titanomagnetite (Fe3-xTixO4) and hemoilmenites (Fe2-yTiyO3). The examination of 269 chemical analyses of the primary Fe–Ti oxides in basalts (in sensu lato) gives an average ofx=0.61 (T c=168°C) for the titanomagnetites andy=0.89 (T c=–121°C) for the hemoilmenites. If distinction is made between tholeiites, alkali basalts and andesites, a clear difference for thex-values is observed: the average for tholeiitesx=0.64 (T c=144°C), for alkali basaltsx=0.52 (T c=253°C), for andesitesx=0.38 (T c=341°C).Environment of crystallization and cooling rate are major interrelated factors influencing subsequent changes in the mineralogy of the primary Fe–Ti oxides and resulting magnetic properties. This has been tested by studying the variation of magnetization and some of its parameters in three different basalt rock units: a dike, 180 cm, and two lava flows, 3 m and 33 m thick, respectively. Grain size and oxidation state of the titanomagnetites control the variation of magnetization in these basalt units.  相似文献   

4.
In this paper, we analyze the self-reversal of magnetization in titanomagnetites as a function of the Ti content and the distribution of Fe3+ to Fe2+ ion transitions in sublattices (which is associated with the law of charge conservation). The dependence of the Curie point on the Ti concentration and the temperature dependence of the mean magnetic moment per iron atom at different Ti concentrations and different cation distributions in sublattices are calculated.  相似文献   

5.
Single crystals of approximate composition Fe2.4Ti0.6O4 were prepared from which spherical samples of diameters 1–2 mm were obtained. The measured values of the Königsberger ratio, the ratio of saturation remanence to saturation magnetization and a Lowrie-Fuller test showed that they were multidomain in character. The temperature variation of the coercive force and saturation magnetization was measured between room temperature and the Curie point. The field dependence of intensity of acquired thermoremanent magnetization (TRM) was determined. The predictions of some of the theoretical models for multidomain TRM, which, of necessity, apply to simplifications of real materials (either natural or synthetic), compare favourably with the results of the present study. The validity of the assumptions made in this comparison is discussed.  相似文献   

6.
A suite of synthetic titanomagnetites were prepared with compositions Fe2.6?δTi0.4AlδO4 and Fe2.4?δTi0.6AlδO4 (δ = 0, 0.1, 0.2 in both cases). Ball-milling of the synthesized samples produced material in the magnetic monodomain state as indicated by hysteresis loops and the Lowrie-Fuller test. The coercive force of the specimens depends on the Al concentration and lies in the range 1–2 kOe. The TRM induced in the samples is correspondingly “hard”. The low-field (0–1 Oe) TRM acquisition curve is linear. The higher field TRM-H curve is not in agreement with either monodomain or two-domain theoretical models.  相似文献   

7.
Early in the history of planetary evolution portions of Martian crust became magnetized by dynamo-generated magnetic field. A lateral distribution of the secondary magnetic field generated by crustal remanent sources containing magnetic carriers of certain grain size and mineralogy is able to produce an ambient magnetic field of larger intensity than preexisting dynamo. This ambient field is capable of magnetizing portions of deeper crust that cools through its blocking temperatures in an absence of dynamo. We consider both magnetite (Fe3O4) and hematite (α-Fe2O3) as minerals contributing to the overall magnetization. Analysis of magnetization of magnetic minerals of various grain size and concentration reveals that magnetite grains less than 0.01 mm in size, and hematite grains larger than 0.01 mm in size can become effective magnetic source capable of magnetizing magnetic minerals contained in surrounding volume. Preexisting crustal remanence (for example ∼250 A/m relates to 25% of multi-domain hematite) can trigger a self-magnetizing process that can continue in the absence of magnetic dynamo and continue strengthening and/or weakening magnetic anomalies on Mars. Thickness of the primary magnetic layer and concentration of magnetic carriers allow specification of the temperature gradient required to trigger a self-magnetization process.  相似文献   

8.
Magnetic hydroxyapatite (HAP), which combined superparamagnetic Fe3O4 nanoparticles and HAP, composite materials were prepared by ultrasound method in this paper. It has also been found that these materials have the ability to adsorb phenol in wastewater. The magnetic materials were investigated by scanning electron microscope, X‐ray diffraction (XRD), Fourier transform infrared spectroscopy, thermal gravimetric analysis, vibrating sample magnetometer, and N2 adsorption in order to elucidate the morphology, structure, and other properties. When the prepared magnetic materials were calcined at 200°C, the prepared Fe3O4 was oxidized to Fe2O3, possessing loose‐shaped holes with a high specific area of 325.2 m2/g, a magnetization intensity of 12.5 emu/g, and the N2 adsorption isotherm belongs to porous adsorption type I. Moreover, the magnetic HAP can adsorb 90% phenol in wastewater. This means that it is an excellent recyclable phenol sorbent for sewage treatment. Experiments confirmed that the Freundlich adsorption isotherms model applies to lower phenol concentrations (0–50 mg/L), while for high phenol concentrations (50–500 mg/L) the Langmuir adsorption isotherms model fits. The magnetic sorbents have the capacity to regenerate after reaching adsorption saturation using ethanol as eluant and external magnetic field as separation unit. The efficiency of adsorption was reduced only by 10% over a six time use period.  相似文献   

9.
A study has been made of the magnetic properties of a suite of continental serpentinites from Burro Mountain, California. The chemistry of this set of samples has been previously studied, enabling the magnetic properties to be compared to the chemical changes which occurred during serpentinization. Two distinct magnetic phases have been recognized. The first is extremely stable but does not appear to contribute significantly to the natural remanent magnetization of the most strongly magnetized samples. The second phase is clearly multi-domained magnetite having a well-defined transition in its coercivity near 120°K. However, this second phase is not apparent in either the least serpentinized or the most serpentinized of the samples studied. The magnetic data argue strongly for the existence of two types of serpentinites; the first is magnetized dominantly by a stable component which we suggest may be Ni3Fe, the second is magnetized Fe3O4 with unstable magnetization. There is no clear connection between the appearance of the stable component and the amount of serpentinization.  相似文献   

10.
A suite of synthetic titanomagnetites of composition Fe2.4?δAlδTi0.6O4 and Fe2.6?δAlδTi0.4O4 (δ = 0, 0.1 and 0.2 in both cases) have been prepared by a method of partial self-buffering and pulverized in a ball mill to particle size of about 200–500 Å. Magnetic hysteresis parameters-saturation and remanent magnetizations and coercive force were measured between room temperature and the Curie temperatures and other parameters-X-ray cell edge, initial susceptibility and coercive force of remanence were determined at room temperature. The intrinsic magnetic “hardness” increases with increasing content of Al3+ and Ti4+, both probably corresponding to an increase in the concentration of Fe2+ ions on the tetrahedral sites of the spinel structure. The room-temperature hysteresis properties were compared with those resulting from monodomain models for the work done to magnetically saturate an assemblage of grains and the approach to saturation, and the separate contributions from coexisting anisotropies of cubic and uniaxial symmetries (assumed present) inferred. The cubic anisotropy energy constants so derived are larger than those determined from multidomain single crystals. The derived cubic constants are also larger than the derived uniaxial anisotropy constants. The latter, however, dominate the behaviour (e.g., coercive force) because of the lower symmetry. The materials appear to be entirely in the stable monodomain state at room temperature.  相似文献   

11.
The transformation of acicular γ Fe2O3 particles to α Fe2O3 has been monitored using magnetic properties as a proxy for γ Fe2O3 concentration during the inversion process. The transformation is thermally activated, the height of the barrier opposing inversion being 3.7 eV at atmospheric pressure and 0.5 eV at a pressure of about 100 MPa. The barrier arises from the combination of a term representing the reduction in lattice energy in an inverted region, and the strain energy associated with the interface between the inverted and non-inverted phases. The sensitivity of the inversion process to pressure can be understood in terms of the dependence of these energy terms, and the energy barrier, on interatomic spacing. Extrapolation of these laboratory data to the conditions of the submarine crust at Site 504B of the Deep Sea Drilling Project is consistent with the inferred magnetic mineralogy of the recovered material.  相似文献   

12.
The paper addresses the physical mechanism of the magnetization self-reversal in rocks. The self-reversal is the phenomenon of magnetization of a rock in the direction antiparallel to the magnetizing field. Experimental data on the self-reversal of thermal and thermoremanent magnetizations in natural analogues of hemoilmenites and synthetic hemoilmenites are presented. It is shown that the most probable mechanism of self-reversal is the single-phase Néel mechanism of the N-type. The N-type mechanism underlies the physical mechanism and numerical model of self-reversal developed in the paper. The numerical modeling results are compared with experimental data.  相似文献   

13.
A novel, simple method based on magnetic separation was developed for analytical purposes. In this method, N‐methyl‐D‐glucamine (NMDG) modified magnetic microparticles that were synthesized by using the sol‐gel method were used for the selective extraction and preconcentration of boron from aqueous solutions. This method combines the simplicity and selectivity of solvent extraction with the easy separation of magnetic microparticles from a solution with a magnet without any preliminary filtration step. The structure of the prepared γ‐Fe2O3‐SiO2‐NMDG (magnetic sorbent) composites were characterized by using X‐ray diffraction (XRD), Transmission Electron Microscopy (TEM), and Fourier Transform Infrared Spectroscopy (FTIR). The influence of different parameters on the sorbent capacity, such as the sorption/desorption of boron, magnetic sorbent dosage, pH, equilibrium time, type, and amount of stripping solution, were evaluated by using the magnetic sorbent. Any equilibrium pH greater than 6 can be used for sorption. Desorption from the sorbent was carried out by using 1.0 M HCl. The sorption and desorption efficiency of the γ‐Fe2O3‐SiO2‐NMDG was found as 92.5 ± 0.5% and 99.8 ± 6%, respectively.  相似文献   

14.
The magnetic ground survey of ΔZ across the orebody near Cortegana suggests that the direction of the magnetization of the orebody deviates from the present earth field direction in that area. Magnetic measurements of more than 500 specimens of drilling cores of several vertical and one nearly horizontal drill holes showed that the magnetization of the orebody points essentially to the north in the direction of the inclination of the orebody and the banding of the ore. In the central part of the orebody with an average magnetite content of about 50 vol% the magnetization amounts to 0.35 Gauss, the remanent and induced component having the same order of magnitude. The outer parts of the orebody have a much smaller magnetization according to both the smaller magnetite content and greater inhomogeneity of the remanent magnetization, also partly due to their reversed magnetization which is brought about by the stray field of the central part of the orebody. As all drilling cores have been chemically analyzed with respect to their Fe content a logarithmic relationship could be established between the magnetite content, ranging from 25 to 80 vol%, and the susceptibility.  相似文献   

15.
During revisiting the Upper Pleistocene Pekla loess-soil section located on the Sea of Azov coast of the Taman Peninsula, its lower 6 m were continuously sampled, which led to an increase in the age range from ∼50 to 400 ka. The detailed rock magnetic study of the structure, grain-size, and concentrations of magnetic mineral (natural remanent magnetization (NRM) carrier) in the collected rock samples revealed regular changes in rock magnetic characteristics along the section and their correlation with climatic fluctuations. Magnetite and hematite both deposited during the transport of sedimentary material and formed during pedogenesis, which involved the entire section to a varying extent, represent the main magnetic minerals in the examined rocks. Automorphic paleosoils that were formed during warm and humid periods corresponding to odd stages of the MIS scale are characterized by elevated concentrations of magnetic mineral (NRM, magnetic susceptibility (K lf), saturation isothermal remanent magnetization (SIRM), and anhysteresis (ideal) remanent magnetization (ARM)) parameters and share of superparamagnetic particles (up to 80%, according to elevated values of the frequency-dependent magnetic susceptibility K td) as well as by lowered rigidity parameter (B cr) and grain size (ARM/K parameter). Such changes in the paleosoils may be explained by the occurrence of newly formed fine-grained magnetite particles close in size to its superparamagnetic and single-domain varieties due to the activation of bio/geochemical processes during warm stages. The growth of the above-mentioned rock magnetic parameters in automorphic soils may be considered as serving a quantitative criterion for defining the boundary between warm and cold periods even in poorly developed soils.  相似文献   

16.
Thermally acquired remanent magnetization is important for the estimation of the past magnetic field present at the time of cooling. Rocks that cool slowly commonly contain magnetic grains of millimeter scale. This study investigated 1-mm-sized magnetic minerals of iron, iron–nickel, magnetite, and hematite and concluded that the thermoremanent magnetization (TRM) acquired by these grains did not accurately record the ambient magnetic fields less than 1 μT. Instead, the TRM of these grains fluctuated around a constant value. Consequently, the magnetic grain ability to record the ambient field accurately is reduced. Above the critical field, TRM acquisition is governed by an empirical law and is proportional to saturation magnetization (Ms). The efficiency of TRM is inversely proportional to the mineral's saturation magnetization Ms and is related to the number of domains in the magnetic grains. The absolute field for which we have an onset of TRM sensitivity is inversely proportional to the size of the magnetic grain. These results have implications for previous reports of random directions in meteorites during alternating field demagnetization, or thermal demagnetization of TRM. Extraterrestrial magnetic fields in our solar system are weaker than the geomagnetic field by several orders of magnitude. Extraterrestrial rocks commonly contain large iron-based magnetic minerals as a common part of their composition, and therefore ignoring this behavior of multidomain grains can result in erroneous paleofield estimates.  相似文献   

17.
For remanence-bearing minerals (RBM) such as magnetite-titanomagnetite, susceptibility to induced magnetism (M) measured in alternating fields (H AC ) is field-dependent. However, for fields ≤ 400 A/m, measured in an AC induction coil instrument (at 19,100 Hz), susceptibility k 0 = M/H AC is sufficiently linear to provide a reproducible rock (or mineral) magnetic characteristic and its anisotropy may be related to arrangements of minerals in rock, or for single mineral grains to their crystalline or shape anisotropy. For any remanence-bearing mineral at higher fields k HF (= M/H AC ) is not constant and the term susceptibility is not normally used. This study bridges the responses between traditional low-field susceptibility measurements and those due to high applied fields, for example when studying hysteresis or saturation magnetization of RBM. Where |k HF | is measured in alternating fields that peak significantly above 400 A/m the M(H AC ) relation is forced to follow a hysteresis loop in which |k HF | > k 0 for small |H AC | and where |k HF | decreases to zero for very large fields that achieve saturation magnetization. Hysteresis nonlinearity is due to remanence acquired with one field direction requiring a reverse field for its cancellation. We investigate the transition from initial, traditional “low-field” susceptibility (k 0 ) measurements at 60 A/m, through 24 different fields from 400 A/m to 40,000 A/m (for very high k 0 to 80,000 A/m). This reveals M(H AC ) dependence beyond from conventional k 0 through the range of hysteresis behavior in fields equal to and exceeding that required to achieve saturation magnetization (M S ). We show k HF increases with peak H AC until the peak field is slightly less than saturation magnetization in natural rock samples rich in magnetite (TM0 = Fe3O4) and TM60 (Fe2.4Ti0.6O4). All sample suites predominantly contain multidomain grains with subordinate pseudo-single domain and single-domain grains. k/k 0 increases by ≤ 5% for fields up to 2 kA/m. Above 4 kA/m k/ k 0 increases steeply and peaks, usually between 24 kA/m and 30 kA/m where all grains magnetic moments are activated by H AC since this exceeds the coercive force of most grains. For higher peak H AC , k/k 0 declines sharply as increased H AC values more effectively flip M with each field-direction switch, leading to the low gradient at distal portions of the hysteresis loop. For M0-TM60 bearing rocks, susceptibility peaks for fields ~12 kA/m and for magnetite rich rocks up to 24 kA/m. These values are approximately 10% of saturation magnetizations (M S ) reported for the pure minerals from hysteresis DC field measurements. Both the field at peak k/k 0 and the peak k/k 0 value appear to be controlled by the dominant domain structure; multidomain behavior has larger k/k 0 peaks at lower H AC . Stacked k/k 0 versus H AC curves for each sample suite (n = 12 to n = 39) were successfully characterized at the 95% level by a polynomial fit that requires the cubic form k/k 0 = a + bH + cH 2 + dH 3. Thus, for most M-TM bearing rocks, susceptibility and anisotropy of susceptibility (AMS) measurements made on different instruments would be sufficiently precise for most geological applications, if peak alternating fields are ≤700 A/m.  相似文献   

18.
We investigated the natural remanent magnetization (Jr) of hydrothermally altered basalts from two drill cores KH1 (200 m) and KH3 (400 m) situated at the rim of the Krafla caldera in NE Iceland, where a geothermal field (>150°C) is still active. Low temperature oxidation along with mineral reactions in the chlorite zone (<350°C) is the prevailing cause for the maghemitization and a strong decrease of Jr to occur in our study. Despite a significant decrease of Jr with respect to fresh basalts in surface outcrops of the same area, the stepwise demagnetization analyses of Jr show the presence of a stable magnetic component with the expected inclination of 77° in Iceland. Because the alteration temperature (<350°C) is above the Curie temperatures of most of the original titanomagnetite (40°?C350°C), we suggest that a normal direction of remanence is chemically acquired during the low temperature alteration. We observed only one reliable negative inclination at 293.2 m in the KH3 core, which we rather interpret to be acquired during a geomagnetic excursion with reverse polarity than caused by a self-reversal mechanism.  相似文献   

19.
Synthetic single crystals of titanomagnetite of nominal composition Fe2.4Ti0.6O4 have been oxidized at 1275°C in controlled gas atmospheres, producing multiphase intergrowths to simulate the natural process of deuteric oxidation. The evolution of the intergrowths was monitored using the conventional techniques of petrology: optical and electron microscopy and X-ray and electron microprobe analyses. In addition, the measured magnetic properties — particularly the temperature-dependence of hysteresis properties — provided further information about the composition and concentrations of magnetic phases, and their domain state, as oxidation proceeded. The evolution of a trellis pattern of ilmenite lamellae, characteristic of the “exsolution” stages of deuteric oxidation, was observed in the oxidized crystals. The interlamellar spinel region consisted of two iron-enriched titanomagnetites, one thought to occur along the lamellar boundaries. The magnetic hardness of both phases was found to be greater than the original homogeneous multidomain titanomagnetite crystals, although neither phase achieved monodomain characteristics, and the stability of thermoremanence (TRM) remained quite low (median destructive fields (MDF) of the order of a few thousend A m?1). The lamellae made little contribution to the total remanence. A sharp rise in magnetic hardness, observed during the post-exsolution stages of oxidation, was due to the presence of fine-grain monodomain magnetite, thought to be distributed within the haemoilmenite matrix, but probably not having been formed by lamellar subdivision. The crystals could now carry an intense and stable TRM with MDFs of many tens of thousands of A m?1.  相似文献   

20.
Knowledge of the declination and inclination of the total and induced magnetization vectors is normally required for the interpretation and analysis of magnetic anomalies. A new method of estimating the direction of the total magnetization vector of magnetized rocks from magnetic anomalies is proposed. The unknown declination and inclination (D*T and I*T) can be found by applying a reduction-to-the-pole operator to the measured anomalies for different couples of total magnetization direction parameters (DT and IT) and by observing the variation of the anomaly minimum as a function of both DT and I*T.and D*T are estimated using the maximum of this function. Comparing our method to previous methods, one advantage is that our estimates are not zero-level dependent; furthermore, the method allows inclinations to be well estimated, with the same accuracy as declinations; finally declinations are not underestimated. Our method is applied to a real case and meaningful results are obtained; it is shown that the feasibility of the method is improved by removing the low-frequency components.  相似文献   

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