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1.
Many studies have been conducted on model transfer in soil–plant systems. However, relatively little information is available on modeling metal transfer in soil–rice system and associated risk assessment in real paddy fields. Based on a random sampling method from Nanxun, Shengzhou and Wenling in Zhejiang province, China, 15 pairs of rice and the corresponding soil samples were respectively collected for analysis of heavy metals and soil pH. The results showed that the accumulation ability of rice for different heavy metals was significantly different (p < 0.05), and was in the order of Cd > Zn > Cu > Ni > Cr > Pb. The relationships of heavy metals in rice with those in soil, along with soil pH, were well described by linear regression models. Except for Pb, the contents of most metals in rice were positively correlated with those of the soil. Soil pH was negatively correlated with the contents of Cd, Zn and Ni in rice, and positively correlated with Pb in rice; however, it had less effect on Cr and Cu. Based on risk reference dose (RfD), the risk assessment data indicated that the rice grown in Zhejiang paddy fields does pose some potential Cd and Cr contamination risk to food safety; rice in Shengzhou posed light Ni risk.  相似文献   

2.
This paper presents the results of laboratory experiments showing the effects of rock fragments contained in three different purple soils of the Sichuan basin of southwest China. The experiments investigated how these rock fragments alter the soil’s physical, chemical, and agronomical characteristics such as infiltration and evaporation. We found that the infiltration rate, whether horizontal or vertical, in the three soils has the following order: gray brown purple soil < reddish brown purple soil < brown purple soil. With increasing rock fragment contents the accumulated infiltration decreases, while the total time decreases first and then increases. The minimum occurs at approximately 10–20% of fragment content by weight. The infiltration rate also changes with the distance. In the 0–5 cm range, the initial infiltration rate increases with increasing rock fragment contents, while in the 5–10 cm range, the slope of infiltration curve increases with increasing rock fragment contents. With increasing distance, the slope gradually decreases and finally reaches a stable value. The presence of rock fragments reduces soil water content, the minimal value appearing when the rock fragments were on top of the soil column (soil + rock sample), decreasing with increasing rock fragments for other samples mixed with fragments. Under the constant 40°C temperature, the accumulated evaporation and evaporation rate are minimal for soils covered by rock fragments, and the accumulated evaporation decreases with increasing rock fragment for other soil samples. However, the evaporation rate increases with increasing rock fragments in the first 4 days and decreases thereafter.  相似文献   

3.
Karst rocky desertification is a process of land degradation involving serious soil erosion, extensive exposure of basement rocks. It leads to drastic decrease in soil productivity and formation of a desert-like landscape. In this regard, changes in climatic conditions are the main origin of the soils degradation. Indeed, soils subjected to successive dry/wet cycling processes caused by climate change develop swelling and shrinkage deformations which can modify their water retention properties, thus inducing the degradation of soil–water capacity. The ecological characteristics of cultivation soils in karst areas, Southwest of China, are extremely easy to be affected by external environmental factors due to its shallow bedding and low vegetation coverage. Based on the analysis of the climate (precipitation) of this region during the past decades, an experimental study has been conducted on a cultivated soil obtained from the typical karst area in southwestern China. Firstly, the soil–water properties have been investigated. The measured soil–water retention curve shows that the air-entry value of the soil is between 50 and 60 kPa, while the residual saturation is about 12%. Based on the experimental results, three identifiable stages of de-saturation have been defined. Secondly, a special apparatus was developed to investigate the volume change behavior of the soil with controlled suction cycles. The vapor equilibrium technique was used for the suction control. The obtained results show that under the effect of dry/wet cycles, (1) the void ratio of the cultivated soil is continuously decreasing, leading to a gradual soil compaction. (2) The permeability decreases, giving rise to a deterioration of water transfer ability as well as a deterioration of soil–water retention capacity. It is then obvious that the long-term dry/wet cycling process caused by the climate change induce a continuously compaction and degradation of the cultivated soil in karst rocky desertification areas.  相似文献   

4.
Major geotechnical problems in construction involving silty–clayey soils are due to their low strength, durability and high compressibility of soft soils, and the swell–shrink nature of the overconsolidated swelling soils. Confronted with these problems, a suitable ground improvement technique is needed, for deep excavations in soft clays, for stability, durability and deformation control. Cement-stabilization is one of the alternatives. An increase in strength and durability, reduction in deformability are the main aims of this method. Conventional cement-stabilization methods are used mainly for surface treatment. However, the use of cement has recently been extended to a greater depth in which cement columns were installed to act as a type of soil reinforcement (deep cement–soil mixing and cement jet grouting). In situ engineering properties of these silty–clayey soils are often variable and difficult to predict. For this reason cement-stabilization methods have a basic target to control the aforementioned engineering properties of these clays so that the properties of a silty–clayey soil become more like the properties of a soft rock such as clayey shale or lightly cemented sandstone. So cement-stabilization of these soils is essential to control their engineering properties and to predict their engineering behaviour for construction. In an effort to predict, classify and study the suitability of silty–clayey soils for cement-stabilization both slaking and unconfined compressive strength tests were carried out on clayey–sand mixtures consisted of two types of clays, kaolin and bentonite. Finally diagrams were prepared to study the variation of slaking and strength due to compaction, curing time and cement percentage and also to predict areas of efficient cement-stabilization.  相似文献   

5.
This study presents the effects of a local nonlinearity in cohesionless soil upon the optimal radius minimizing the bending strains of a vertical, cylindrical fixed-head pile embedded in a layered soil stratum in a soil–pile–structure system where the kinematic interaction dominates. The seismic deformation method (SDM) with discretized numerical models is applied since the SDM is a static numerical method that can easily consider realistic conditions of layered soil strata and the nonlinearity of the soil. In the numerical models, the local nonlinearity of the soil in the vicinity of the pile is represented by subgrade springs having bi-linear skeleton curves with a simple hysteretic loop. Various amplitudes of the lateral displacements of the soil and the lateral forces at the head of the pile are considered as numerical parameters. The results of parametric analyses reveal the presence of an optimal pile radius that locally minimizes the bending strains of the piles under strong nonlinearity of the soil, and the optimal pile radius tends to increase as the degree of nonlinearity increases. Criteria are presented for predicting the increment in the optimal radius of soil–pile–structure systems under strong nonlinearity in the soil.  相似文献   

6.
It is widely recognized that clays and shales can demonstrate membrane properties. When a hydraulic head differential exists across a membrane-functioning clay-rich barrier, some of the solute is rejected by the membrane. This process is known as hyperfiltration. Some shallow geologic environments, including aquitards bounding shallow perched aquifers and unconfined aquifers, some river and stream beds, and some lake bottoms contain clay–soil mixes. Many engineering structures such as landfill liners, mixed soil augered barriers, and retention pond liners also consist of soil–clay mixes. No previous testing has been performed to investigate the likelihood that hyperfiltration may occur in such mixed soils. Therefore, we performed five experiments using different mixes of Na-bentonite and glass beads (100, 50, 25, 12 and 0% clay) to determine if any of these mixes exhibited membrane properties and to investigate what effect clay content had upon the membrane properties of the soil. Each mixture was compacted to 345 kPa and the sample mixtures were 0.58–0.97 mm thick. All the experiments used an approximately 35 ppm Cl− solution under an average 103 kPa hydraulic head. Experimental results show that all the simulated clay–sand mixtures do exhibit measurable membrane properties under these conditions. Values of the calculated reflection coefficient ranged from a low of 0.03 for 12% bentonite to 0.19 for 100% bentonite. Solute rejection ranged from 5.2% for 12% clay to a high of over 30% for the 100% clay. The 100% glass bead sample exhibited no membrane properties.  相似文献   

7.
This study presents a laboratory study of the following two aspects: (1) the influence of sea laver treatment acid on the geoenvironmental properties of Ariake Sea tidal mud, and (2) the natural remediation effect on the sea laver treatment acid contaminated Ariake Sea tidal mud caused by the upward seepage of pore water liquid in the mud. Firstly, the mechanisms of the transport of sea laver treatment acid in the Ariake Sea tidal mud and the generation mechanisms of the upward seepage flow in the Ariake Sea tidal mud are discussed. Secondly, a series of one-dimensional laboratory infiltration tests were carried out to investigate the deterioration of the Ariake Sea tidal mud caused by the sea laver acid treatment practice. Test results reveal that the acid treatment practice caused considerable change in the geochemical properties of the mud in terms of increase in sulfide content and decrease in pH value. After the treatment by the sea laver treatment acid, the sulfide content of the mud even exceeded the safe limit value for the benthos, which represents undesirable living condition for benthos. Thirdly, series of laboratory fresh seawater infiltration tests for the deteriorated Iida site mud were conducted to illustrate this natural remediation efficiency. It is found that with the infiltration of the fresh seawater, the sulfide content of the Iida site mud was considerably reduced and pH value increased to an acceptable range for benthos living in the tidal flat mud. With the increase in the infiltration time and the hydraulic gradient, the remediation efficiency could be increased.  相似文献   

8.
In this study, we tried to model the processes of moisture and heat transfers in the soil–vegetation–atmosphere system in an integrated comprehensive way. The purpose of the study is to simulate profiles of soil water content and temperature at root active zone (i.e., 0–50 cm), taking the root water uptake, soil evaporation, and canopy transpiration into account. The water and heat transfer equations are solved by an iterative Newton–Raphson technique and a finite difference method is used to solve the governing equations. Soil water content and soil temperature dynamics could be simulated rather accurately in a cropped field on Loess Plateau area. The water and heat transfer flux predicted by the classical theory of Philip and de Vries (Tans Am Geophys Union 38:222–232, 1957) slightly overestimated near the surface and underestimated at the deeper depths, as a result of the overestimated soil evaporation at the top soil layer (0–10 cm) and underestimated crop canopy transpiration at the deeper depths (10–50 cm). Water content tended to be underestimated for the entire profile at the soil surface (from 0 to 50 cm). Soil temperatures during the simulated period was slightly overestimated in the nighttimes and underestimated in the daytimes, as a result of the underestimated soil water content at the top soil layer (0–10 cm) and overestimated at the deeper depths (10–50 cm). Soil temperatures tended to be underestimated for the entire profile at the soil surface (from 0 to 50 cm). While the sum of the water and heat regimes yielded a much better match with the soil water content and soil temperature obtained from the field observations. The results obtained show that the model coupled water and heat transfer is able to capture the dynamics of soil water content.  相似文献   

9.
本文通过室内试验验证了深层搅拌桩施工可以引起周围土体的物理,化学及力学性质的变化.其影响机理为高灵敏度粘土的触变性,土体劈裂,化学加固剂的侵入与渗透,胶结作用及固结压密.室内模型试验证明搅拌桩施工可以在周围土体引起约2倍桩径的土性变化领域.在此领域内含水量降低,pH值上升.此领域内先是强度下降,但7天内强度恢复,28天后强度增加3成.  相似文献   

10.
This second paper reports the results of plant growth, plant mortality, plant leaf tissue metal and salt concentrations and leachate quality monitoring from lysimeters in four large field trial treatments established on sulfidic waste rock/soil that was used for haul road construction at a closed gold mine in Australia. The TerraB™, lime and clay treatments allowed good tree growth of four Eucalypt species, compared to the control. There was no statistical difference in tree growth between the TerraB™, lime or clay treatments over the 2 years of monitoring in this paper. However, the growth of one tree species was poor in the TerraB™ treatment. Leaf tissue metal and major ion data are also presented. Leachate pH in the control became increasingly acidic (pH 4.57–3.95). The addition of Ca(OH)2 and biosolids led to an initial increase in leachate pH, compared to the control; however, this has decreased over the duration of the study (pH 5.37–4.89) and may affect the sustainable growth of plants in the future. In the TerraB™ and biosolids treatment leachate pH increased to 6.92 after the first rainfall event and continued to increase over the duration of the study to pH 7.4 after 24 months. After 24 months average heavy metal leachate concentrations (mg/L) in the lysimeters for Al, Cd, Cu, Mn and Zn were, control: 32.55, 5.67, 12.71, 39.29, 121.80, TerraB™: 0.07, 0.02, 0.07, 0.57, 0.23, and lime: 2.19, 1.19, 2.33, 3.6, 28.4. No leachate was available for collection from the clay treatment indicating that this technique was functioning in terms of minimizing the infiltration of water into the mine soil.  相似文献   

11.
A barrier system based on the hydraulic trap design concept for a landfill was proposed. To study the field scenario in which a clay liner is underlain by a granular layer functioning as a secondary leachate drain layer, a laboratory advection–diffusion test was performed to investigate factors controlling the transport of contaminants in a two-layer soil system. The soils used for this study were Ariake clay and, the underlying layer, Shirasu soil from the Kyushu region of Japan. Potassium (K+) was selected as the target chemical species with an initial concentration of 905 mg L−1. The effective diffusion coefficients (D e) of K+ for Ariake clay and Shirasu soil were back-calculated using an available computer program, Pollute V 6.3. Values of D e derived from this experiment are consistent with previously published ones. The Ariake clay has lower D e than the Shirasu soil. The hypothesis that mechanical dispersion can be considered negligible is reasonable based on both the observation that the predicted values well fit the experimental data and the analyses of two dimensionless parameters. Parametric analyses show that transport of K+ through soils is controlled by advection–diffusion rather than diffusion only, whereas at low Darcy velocity (i.e., ≤10−9 m s−1), transport of K+ will be controlled by diffusion. Applications of the test results and parametric analysis results in practical situations were reviewed.  相似文献   

12.
The geochemical study of groundwaters and core sediments from the Old Brahmaputra plain of Bangladesh was conducted to investigate the distribution of arsenic and related trace elements. Groundwaters from tube wells are characterized by pH of 6.4–7.4, dissolved oxygen (DO) of 0.8–1.8 mg/l, Ca contents of 5–50 mg/l, and Fe contents of 0.2–12.9 mg/l. Arsenic concentrations ranged from 8 to 251 μg/l, with an average value of 63 μg/l. A strong positive correlation exists between As and Fe (r 2 = 0.802; p = 0.001) concentrations in groundwater. The stratigraphic sequences in the cores consist of yellowish silty clays at top, passing downward into grayish to yellowish clays and sands. The uppermost 3 m and lower parts (from 13 to 31 m) of the core sediments are oxidized (average oxidation reduction potential (ORP) +170 and +220 mV, respectively), and the ORP values gradually become negative from 3 to 13 m depths (−35 to −180 mV), indicating that anoxic conditions prevail in the shallow aquifers of the Brahmaputra plain. Age determinations suggest that clay horizons at ~10 m depth were deposited at around 2,000 and 5,000 years BP (14C ages) during the transgressive phase of sea-level change. Elevated concentrations of As, Pb, Zn, Cu, Ni, Cr, and V are present in the silts and clays, probably due to adsorption onto clay particles. Significant concentrations of As occur in black peat and peaty sediments at depths between 9 and 13 m. A strong positive correlation between As and Fe was found in the sediments, indicating As may be adsorbed onto Fe oxides in aquifer sediments.  相似文献   

13.
不同水泥土混合桩周围土体的扰动与强度恢复   总被引：1，自引：0，他引：1  
沈水龙  唐翠萍  庞晓明 《岩土力学》2006,27(10):1827-1830
针对由深层搅拌法或高压旋喷法施工的水泥土混合桩周围土体的扰动与强度恢复的问题,采用两种常用的施工法：高压旋喷混合法（简称旋喷法）和水泥浆搅拌混合法（简称湿法）,在日本有明黏土中施工以观测周围土体力学特性的变化。测试结果表明,水泥土混合桩周围土体的扰动程度与其施工方法有关;两种不同施工方法施工后周围土体的当日强度与原状土的强度之比分别是0.42（旋喷法）和0.68（湿法）,施工30 d后,旋喷法有44 %,湿法有40 %的初始强度得到恢复。结果亦表明周围土体模量恢复要慢于强度恢复的速度。  相似文献   

14.
The compressibilities of two synthetic glaucophane samples were measured over the range of 0–10 GPa at ambient temperature in a diamond-anvil cell at the Cornell High-Energy Synchrotron Source (CHESS). The pressure–volume data were fitted to the Birch–Murnaghan equation of state taking care to include only data with a minimum of deviatoric stress. When using a second-order truncation, both samples yielded essentially identical values of the bulk modulus K 0, which had an average value of 91.8 ± 1.3 GPa. Maximum compression was observed approximately along the a* axis as shown by the strain ellipsoid and supported by the a axis showing the highest compressibility. These results agree closely with the earlier study of a natural glaucophane single-crystal by Comodi et al. (Eur J Mineral 3:485–499, 1991), suggesting that the substitution of about 20–30 mol.% of Fe for Mg and Al in the structure may not significantly change its compressibility.  相似文献   

15.
Laboratory cyclic swell–shrink tests were carried out on compacted expansive soil specimens to study in detail the effect of changes in shrinkage pattern on the swell–shrink behaviour of compacted expansive soils. Compacted soil specimens were allowed to swell and either shrank fully or partially shrank to several predetermined heights in each cycle. The tests were carried out at a surcharge pressure of 50 kPa. The test results revealed that shrinkage of compacted saturated soil specimens to predetermined height in each shrinkage cycle provides similar conditions as that of the controlled suction tests with an increasing number of swell–shrink cycles. The water content of soil specimens and hence soil suction was found to remain nearly constant for each pattern of shrinkage. For soil specimens equilibrated to a given swell–shrink pattern, suction at the end of shrinkage cycles was changed from a higher suction to a lower suction, and also from a lower to a higher suction. The experimental results showed that there may be an immediate equilibrium state attained by the soil in terms of swell–shrink potential if suction at the shrinkage cycles was less than the past suction; otherwise, the equilibrium state was accompanied by fatigue of swelling. The volumetric deformation of the soil specimen subjected greater shrinkage was found to be much larger than the corresponding vertical deformation. The compressibility index of microstructure, κm, was determined for several shrinkage patterns. It is shown that κm is heavily influenced by suction at the end of shrinkage cycles.  相似文献   

16.
Recently in China, soil–cement is widely used to improve the soft ground in the highway construction engineering. Literature studies are mainly investigating the mechanical properties of the soil–cement, while its properties of the electrical resistivity are not well addressed. In this paper, the properties of the electrical resistivity of the reconstituted soil-cement and the in situ soil–cement columns are investigated. The test results show that the electrical resistivity of the soil–cement increases with the increase in the cement-mixing ratio and curing time, whereas it decreases with the increase in the water content, degree of saturation and water–cement ratio. A simple equation is proposed to predict the electrical resistivity of soil–cement under the condition of the specified curing time and water–cement ratio. It is found that the electrical resistivity has a good relationship with the unconfined compression strength and blow count of SPT. It is expected that the electrical resistivity method can be widely used for checking/controlling the quality of soil–cement in practice.  相似文献   

17.
Global positioning system (GPS) and satellite-based InSAR (Interferometric Synthetic Aperture Radar) measurements of the subsidence and uplift of a populated area of Sidoarjo, East Java are due to the eruption of the Lusi mud volcano (2006–present). These data are the first direct quantitative measurements of deformation due to the growth of a mud volcano edifice. The GPS data were recorded over periods of a few hours to several months and show that between June 2006 and September 2007, the earth’s surface has been subsiding at rates of 0.1–4 cm/day. Maximum rates of subsidence occurred in an area 300–400 m to the northwest of the main mud volcano vent. Horizontal displacements were 0.03–0.9 cm/day and were also towards this area. In general uplifts of up to 0.09 cm/day were recorded in areas outside of the edifice. Changes in elevation measured using satellite imagery (InSAR technique) provide regional datasets of subsidence and uplift. They confirm that during the first year a roughly circular area was undergoing sag-like subsidence centered to the northwest of the main vent and that uplift was occurring 3–4 months after the initiation of the eruption due to the movement Watukosek fault system. Subsidence occurred due to the weight of mud and man-made dams and the collapse of the overburden due to removal of mud from the subsurface. Assuming constant rates of subsidence of 4 cm/day, then in the centre of the edifice there would be up to 44 m of subsidence in 3 years, and up to 16 m in 10 years. The mud volcano is now in a self-organizing state with new fluid conduits forming as a result of the collapse. An erratum to this article can be found at  相似文献   

18.
This study reports the first field test of a multi-channel, auto-dilution, steady-state, soil–CO2 flux monitoring system being developed to help understand the pathways by which fugitive CO2 from a geologic sequestration site migrates to the surface. The test was conducted from late August through mid-October 2008 at the Zero Emissions Research and Technology project site located in Bozeman, MT. Twenty steady-state and five non-steady-state flux chambers were installed in a 10 × 15 m area, one boundary of which was directly above a shallow (2-m depth) horizontal injection well located 0.5 m below the water table. A total flux of 52 kg CO2 day−1 was injected into the well for 13 days and the efflux from the soil was monitored by the chambers before, during, and for 33 days after the injection. The results showed a rapid increase in soil efflux once injection started, with maximal values reached within 3–7 days in most chambers. Efflux returned to background levels within a similar time period after injection ceased. A radial efflux pattern was observed to at least 2 m from the injection well, and evidence for movement of the CO2 plume during the injection, presumably due to groundwater flow, was seen. The steady-state chambers yielded very stable data, but threefold to fivefold higher fluxes than the non-steady-state chambers. The higher fluxes were attributed to vacuum induced in the steady-state chambers by narrow vent tubes. High winds resulted in significant decreases in measured soil CO2 efflux, presumably by enhancing efflux from soil outside the chambers.  相似文献   

19.
An exploratory study on soil contamination of heavy metals was carried out surrounding Huludao zinc smelter in Liaoning province, China. The distribution of total heavy metals and their chemical speciations were investigated. The correlations between heavy metal speciations and soil pH values in corresponding sites were also analyzed. In general, Cd, Zn, Pb, Cu and As presented a significant contamination in the area near the smelter, comparied with Environmental Quality Standards for Soils in China. The geoaccumulation index showed the degree of contamination: Cd > Zn > Pb > Cu > As. There was no obvious pollution of Cr and Ni in the studied area. The speciation analysis showed that the dominant fraction of Cd and Zn was the acid soluble fraction, and the second was the residual fraction. Pb was mostly associated with the residual fraction, which constituted more than 50% of total concentration in all samples. Cu in residual fraction accounted for a high percentage (40–80%) of total concentration, and the proportion of Cu in the oxidizable fraction is higher than that of other metals. The distribution pattern of Pb and Zn was obviously affected by soil pH. It seemed that Pb and Zn content in acid solution fraction increased with increasing soil pH values, while Cd content in acid soluble fraction accounted for more proportion in neutral and alkaline groups than acidic one. The fraction distribution patterns of Cu in three pH groups were very similar and independent of soil pH values. And the residual fraction of Cu took a predominant part (50%) of the total content.  相似文献   

20.
The compressive and tensile strengths of frozen clay are important parameters for frozen wall design in artificial freezing excavation of tunnels and foundation pits. Up to now, nobody has conducted the compressive and tensile test of frozen clays in Shanghai area. In this paper, the unconfined compressive and tensile tests of frozen clay specimens drilled from the soil horizons 3–5 in Shanghai area were conducted in Zwick-Z020kN High-low Temperature Materials Testing Machine and Frozen Soil Triaxial Testing Machine, the corresponding constitutive equations were suggested; the temperature-unconfined uniaxial compressive strength relation was discussed; the strain rate–unconfined uniaxial compressive strength and strain rate–uniaxial tensile strength relations were studied. The relation between moisture content, dry density and unconfined uniaxial compressive strength was analyzed, too. In addition, the uniaxial compressive elastic modulus of Shanghai frozen clays and its influence factors were discussed. The research work of the current paper is very helpful for the design and theoretical studies of artificial freezing excavation in soft soil areas.  相似文献   

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