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1.
David F. Boutt 《水文研究》2017,31(7):1479-1497
This study analyzes a long‐term regional compilation of water table response to climate variability based on 124 long‐term groundwater wells distributed across New England, USA, screened in a variety of geologic materials. The New England region of the USA is located in a humid‐temperature climate underlain by low‐storage‐fractured metamorphic and crystalline bedrock dissected by north–south trending valleys filled with glacial and post‐glacial valley fill sediments. Uplands are covered by thin glacial till that comprises more than 60% of the total area. Annual and multi‐annual responses of the water table to climate variability are assessed to understand how local hydraulic properties and hydrogeologic setting (located in recharge/discharge region) of the aquifer influence the hydrologic sensitivity of the aquifer system to climate variability. This study documents that upland aquifer systems dominated by thin deposits of surface till comprise ~70% of the active and dynamic storage of the region. Total aquifer storage changes of +5 to ?7 km3 occur over the region during the study interval. The storage response is dominated by thin and low permeability surficial till aquifer that fills and drains on a multi‐annual basis and serves as the main mechanism to deliver water to valley fill aquifers and underlying bedrock aquifers. Whereas the till aquifer system is traditionally neglected as an important storage reservoir, this study highlights the importance of a process‐based understanding of how different landscape hydrogeologic units contribute to the overall hydrologic response of a region.  相似文献   

2.
Interaction between groundwater and surface water in watersheds has significant impacts on water management and water rights, nutrient loading from aquifers to streams, and in‐stream flow requirements for aquatic species. Of particular importance are the spatial patterns of these interactions. This study explores the spatio‐temporal patterns of groundwater discharge to a river system in a semi‐arid region, with methods applied to the Sprague River Watershed (4100 km2) within the Upper Klamath Basin in Oregon, USA. Patterns of groundwater–surface water interaction are explored throughout the watershed during the 1970–2003 time period using a coupled SWAT‐MODFLOW model tested against streamflow, groundwater level and field‐estimated reach‐specific groundwater discharge rates. Daily time steps and coupling are used, with groundwater discharge rates calculated for each model computational point along the stream. Model results also are averaged by month and by year to determine seasonal and decadal trends in groundwater discharge rates. Results show high spatial variability in groundwater discharge, with several locations showing no groundwater/surface water interaction. Average annual groundwater discharge is 20.5 m3/s, with maximum and minimum rates occurring in September–October and March–April, respectively. Annual average rates increase by approximately 0.02 m3/s per year over the 34‐year period, negligible compared with the average annual rate, although 70% of the stream network experiences an increase in groundwater discharge rate between 1970 and 2003. Results can assist with water management, identifying potential locations of heavy nutrient mass loading from the aquifer to streams and ecological assessment and planning focused on locations of high groundwater discharge. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

3.
A large‐scale groundwater flow and transport model is developed for a deep‐seated (100 to 300 m below ground surface) sedimentary aquifer system. The model is based on a three‐dimensional (3D) hydrostratigraphic model, building on a sequence stratigraphic approach. The flow model is calibrated against observations of hydraulic head and stream discharge while the credibility of the transport model is evaluated against measurements of 39Ar from deep wells using alternative parameterizations of dispersivity and effective porosity. The directly simulated 3D mean age distributions and vertical fluxes are used to visualize the two‐dimensional (2D)/3D age and flux distribution along transects and at the top plane of individual aquifers. The simulation results are used to assess the vulnerability of the aquifer system that generally has been assumed to be protected by thick overlaying clayey units and therefore proposed as future reservoirs for drinking water supply. The results indicate that on a regional scale these deep‐seated aquifers are not as protected from modern surface water contamination as expected because significant leakage to the deeper aquifers occurs. The complex distribution of local and intermediate groundwater flow systems controlled by the distribution of the river network as well as the topographical variation (Tóth 1963) provides the possibility for modern water to be found in even the deepest aquifers.  相似文献   

4.
A large quantity of submarine groundwater discharge (SGD) of about 1000 m3 day?1 m?1 of the 600‐km‐long shoreline of South Atlantic Bight has been estimated by Moore (Global Biogeochemical Cycles, 2010b, 24, GB4005, doi: 10.1029/2009GB003747 ). However, there is great uncertainty in estimating the percentage of net, land‐originated groundwater recharge of SGD. Moreover, most previous studies considered the homogeneous case for the coastal superficial aquifers. Here, we investigated the terrestrial‐originated SGD through a multilayered submarine aquifer system, which comprises two confined aquifers and two semi‐permeable layers. The inland recharge includes a constant part representing the annual average and a periodical part representing its seasonal variation. An analytical solution was derived and used to analyse the distributions of the terrestrial‐originated SGD from the multilayered aquifers along the Winyah Bay transect, South Atlantic Bight. It is found that the width of the zone of SGD from the upper aquifer ranges from ~0.8 to ~8.0 km depending on the leakance of the seabed semi‐permeable layer. A head of the upper aquifer at a coastline 1.0 m higher than the mean sea level will cause a SGD of 1.82– 18.3 m3 day?1 m?1 from that aquifer as the seabed semi‐permeable layer's leakance varies from 0.001 to 0.1 day?1, providing considerable possibility for considerable land‐originated SGD. Seasonal terrestrial‐originated SGD variations predicted by the analytical model provide consistent explanation of the seasonal variation of 226Ra observed by Moore (Journal of Geophysics, 2007, 112, C10013, doi: 10.1029/2007JC004199 ). The contribution of the lower aquifer to SGD is only 1.2–12% of that of the upper aquifer. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

5.
ABSTRACT

The Sebkhet El Behira–Garaat El Majdoul multilayer aquifer system is composed of Mio-Plio-Quaternary and Oligocene groundwater exploited in Sidi Bouzid and Kairouan governorates. Annual withdrawal volumes from El Behira Oligocene groundwater were about 0.37 hm3 in 2005 and 0.36 hm3 in 2008. The present study of the Oligocene reservoir in the Sebkhet El Behira–Garaat El Majdoul basin is based on various data including 2D seismic sections, petroleum wells, field geological cross-sections and geochemical analysis. The gathered data allowed us to establish the tectonic framework and to define its influence on the structure of the aquifers seated in the deep Oligocene sandstone reservoirs. Three Oligocene sub-basin aquifers are defined showing different depth, thickness and petrophysical characteristics: lower salinity (<1.5 g/L) and higher porosity (30%). Two field sections in the northern and in the southern parts of Cherahil anticline exhibit the presence of four to five sandstone levels. The anticlines limit the Sebkhet El Behira–Garaat El Majdoul basin. In addition, the morphostructural configuration controls the piezometry of underground flows in the Oligocene and Mio-Plio-Quaternary unconfined aquifers.
Editor D. Koutsoyiannis; Associate editor M. Besbes  相似文献   

6.
Management of water resources in alluvial aquifers relies mainly on understanding interactions between hydraulically connected streams and aquifers. Numerical models that simulate this interaction often are used as decision support tools for water resource management. However, the accuracy of numerical predictions relies heavily on unknown system parameters (e.g., streambed conductivity and aquifer hydraulic conductivity), which are spatially heterogeneous and difficult to measure directly. This paper employs an ensemble smoother to invert groundwater level measurements to jointly estimate spatially varying streambed and alluvial aquifer hydraulic conductivity along a 35.6‐km segment of the South Platte River in Northeastern Colorado. The accuracy of the inversion procedure is evaluated using a synthetic experiment and historical groundwater level measurements, with the latter constituting the novelty of this study in the inversion and validation of high‐resolution fields of streambed and aquifer conductivities. Results show that the estimated streambed conductivity field and aquifer conductivity field produce an acceptable agreement between observed and simulated groundwater levels and stream flow rates. The estimated parameter fields are also used to simulate the spatially varying flow exchange between the alluvial aquifer and the stream, which exhibits high spatial variability along the river reach with a maximum average monthly aquifer gain of about 2.3 m3/day and a maximum average monthly aquifer loss of 2.8 m3/day, per unit area of streambed (m2). These results demonstrate that data assimilation inversion provides a reliable and computationally affordable tool to estimate the spatial variability of streambed and aquifer conductivities at high resolution in real‐world systems.  相似文献   

7.
Resolution of MRS applied to the characterization of hard-rock aquifers   总被引：4，自引：0，他引：4  
The performance of the Magnetic Resonance Sounding (MRS) method applied to the investigation of heterogeneous hard-rock aquifers was studied. It was shown using both numerical modeling and field measurements that MRS could be applied to the investigation of the weathered part of hard-rock aquifers when the product of the free water content multiplied by the thickness of the aquifer is >0.2 (for example, 10-m-thick layer with a 2% water content). Using a currently available one-dimensional MRS system, the method allows the characterization of two-dimensional subsurface structures with acceptable accuracy when the size of the subsurface anomaly is equal to or greater than the MRS loop. However, the fractured part of hard-rock aquifers characterized by low effective porosity (<0.5%) cannot be resolved using currently available MRS equipment. It was found that shallow water in the weathered part of the aquifer may screen MRS signals from deeper water-saturated layers, thus further reducing the possibility of investigating deeper fractured aquifers. A field study using the NUMIS(plus) MRS system developed by IRIS Instruments was carried out on an experimental watershed in southern India. A heterogeneous unconfined aquifer in a gneissic formation was successfully localized, and MRS results were confirmed by drilling shortly after the geophysical study. The top of the aquifer revealed by MRS was found to be in a good agreement with observed static water level measurements in boreholes.  相似文献   

8.
Streamflow generation in mountain watersheds is strongly influenced by snow accumulation and melt as well as groundwater connectivity. In mountainous regions with limestone and dolomite geology, bedrock formations can host karst aquifers, which play a significant role in snowmelt–discharge dynamics. However, mapping complex karst features and the resulting surface-groundwater exchanges at large scales remains infeasible. In this study, timeseries analysis of continuous discharge and specific conductance measurements were combined with gridded snowmelt predictions to characterize seasonal streamflow response and evaluate dominant watershed controls across 12 monitoring sites in a karstified 554 km2 watershed in northern Utah, USA. Immense surface water hydrologic variability across subcatchments, years and seasons was linked to geologic controls on groundwater dynamics. Unlike many mountain watersheds, the variability between subcatchments could not be well described by typical watershed properties, including elevation or surficial geology. To fill this gap, a conceptual framework was proposed to characterize subsurface controls on snowmelt–discharge dynamics in karst mountain watersheds in terms of conduit flow direction, aquifer storage capacity and connectivity. This framework requires only readily measured surface water and climatic data from nested monitoring sites and was applied to the study watershed to demonstrate its applicability for evaluating dominant controls and climate sensitivity.  相似文献   

9.
This study continues the examination of the influence of groundwater exploitation upon the process of aquifer recharge by flood events. In the course of the developing an earlier hydrological model for the Hazeva Formation aquifer (the Wadi Paran watershed, southern Israel), it became apparent that groundwater extraction influenced absorption capacity of sub‐aquifers and regulated the distribution of percolating surface water between units. The present study lends numerical proof regarding the influence of Hazeva aquifer exploitation upon the regime of runoff and enhancement of transmission losses from flood events in Wadi Paran, and, as a result, upon increased recharge to the aquifer. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

10.
Karst aquifers are well known for their intricate stratigraphy and geologic structures, which make groundwater characterization challenging because flowpaths and recharge sources are complex and difficult to evaluate. Geochemical data, collected from ten closely spaced production wells constructed in two karst aquifers (Bangor Limestone (Mb) and Tuscumbia Limestone/Fort Payne Chert (Mftp)) in Trussville, north‐central Alabama, illustrate two distinctive groundwater end‐members: (1) higher major ion, dissolved inorganic carbon, conductivity, alkalinity concentrations, heavier δ13C ratios (max: −10.2 ± 0.2‰ Vienna Pee Dee Belemnite (PDB)) and lower residence times (mean: 19.5 ± 2 years, n = 2) of groundwater in the Mb aquifer and (2) lower constituent concentrations, lighter δ13C ratios (min: −13.4 ± 0.2‰ PDB) and longer residence times of groundwater (mean: 23.6 ± 2 years, n = 4) in the Mftp aquifer. Summer and fall data and the binary mixing model show aquifer inter‐flow mixing along solution fractures and confirms the distinctive groundwater geochemistry of the two aquifers. Lowering of static water levels over the summer (drawdown from 2 to 5.2 m) leads to more reducing groundwater conditions (lower Eh values) and slightly enriched δ18O and δD ratios during the fall [δ18O: −4.8 ± 0.1 to −5.4 ± 0.1‰ Vienna Standard Mean Oceanic Water (VSMOW), n = 9; δD: −25.4 ± 1 to −27.4 ± 1‰ VSMOW, n = 9] when compared with summer season samples (δ18O: −5.1 ± 0.1 to −5.7 ± 0.1‰ VSMOW, n = 11; δD: −25.0 ± 1 to −30.6 ± 1‰ VSMOW, n = 11). GIS analyses confirm the localized origin of recharge to the investigated aquifers. The combination of GIS, field parameters and geochemistry analyses can be successfully used to identify recharge sources, evaluate groundwater flow and transport pathways and to improve understanding of how groundwater withdrawals impact the sustainability and susceptibility to contamination of karst aquifers. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

11.
Groundwater in the Bengal Basin is badly polluted by arsenic (As) which adversely affects human health. To provide low‐As groundwater for As mitigation, it was sought across 235 km2 of central West Bengal, in the western part of the basin. By drilling 76 boreholes and chemical analysis of 535 water wells, groundwater with <10 µg/L As in shallow aquifers was found under one‐third of a study area. The groundwater is in late Pleistocene palaeo‐interfluvial aquifers of weathered brown sand that are capped by a palaeosol of red clay. The aquifers form two N‐S trending lineaments that are bounded on the east by an As‐polluted deep palaeo‐channel aquifer and separated by a shallower palaeo‐channel aquifer. The depth to the top of the palaeo‐interfluvial aquifers is mostly between 35 and 38 m below ground level (mbgl). The palaeo‐interfluvial aquifers are overlain by shallow palaeo‐channel aquifers of gray sand in which groundwater is usually As‐polluted. The palaeosol now protects the palaeo‐interfluvial aquifers from downward migration of As‐polluted groundwater in overlying shallow palaeo‐channel aquifers. The depth to the palaeo‐interfluvial aquifers of 35 to 38 mbgl makes the cost of their exploitation affordable to most of the rural poor of West Bengal, who can install a well cheaply to depths up to 60 mbgl. The protection against pollution afforded by the palaeosol means that the palaeo‐interfluvial aquifers will provide a long‐term source of low‐As groundwater to mitigate As pollution of groundwater in the shallower, heavily used, palaeo‐channel aquifers. This option for mitigation is cheap to employ and instantly available.  相似文献   

12.
Previous work has shown that streamflow response during baseflow conditions is a function of storage, but also that this functional relationship varies among seasons and catchments. Traditionally, hydrological models incorporate conceptual groundwater models consisting of linear or non‐linear storage–outflow functions. Identification of the right model structure and model parameterization however is challenging. The aim of this paper is to systematically test different model structures in a set of catchments where different aquifer types govern baseflow generation processes. Nine different two‐parameter conceptual groundwater models are applied with multi‐objective calibration to transform two different groundwater recharge series derived from a soil‐atmosphere‐vegetation transfer model into baseflow separated from streamflow data. The relative performance differences of the model structures allow to systematically improve the understanding of baseflow generation processes and to identify most appropriate model structures for different aquifer types. We found more versatile and more aquifer‐specific optimal model structures and elucidate the role of interflow, flow paths, recharge regimes and partially contributing storages. Aquifer‐specific recommendations of storage models were found for fractured and karstic aquifers, whereas large storage capacities blur the identification of superior model structures for complex and porous aquifers. A model performance matrix is presented, which highlights the joint effects of different recharge inputs, calibration criteria, model structures and aquifer types. The matrix is a guidance to improve groundwater model structures towards their representation of the dominant baseflow generation processes of specific aquifer types. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

13.
The coastal confined aquifer in the Gulf of Urabá (Colombia) is an important water source for the banana agro‐industry as well as for urban and rural communities. However, the main processes controlling recharge and mixing in the aquifer are still poorly understood. Hydrochemical analyses and stable isotope monitoring were conducted to (a) determine groundwater recharge origin, mean groundwater age, and the main processes governing groundwater chemistry and the potential mixing of marine water and the influence of diffusive processes from the two surrounding aquitard layers. Hydrochemical data indicate that the main processes affecting the dissolved chemical composition include cation exchange, dissolution of carbonated and CO2, and silicate weathering. δ18O and δ2H compositions combined with 14C data highlight the differences in climatic conditions between the recharge zone and the confined section of the aquifer, which is close to the Atlantic Ocean. Groundwater samples with 14C ages from recent to 28,300 years BP show a depleted isotopic trend ranging from ?6.43‰ to ?9.14‰ in δ18O and from ?43.2‰ to ?65.7‰ in δ2H. The most depleted δ18O and δ2H compositions suggest a cooler recharge climate than the current conditions (corresponding to the last glacial period of the late Pleistocene). Depleted δ13C values in the total dissolved inorganic carbon indicate the existence of organic material oxidation processes within the geologic formation. These results can be used or transferred to enhance groundwater modelling efforts in other confined coastal aquifers of South America where scarcity of long‐term monitoring data limits water resources planification under a changing climate.  相似文献   

14.
Freshwater resources in the arid Arabian Peninsula, especially transboundary aquifers shared by Saudi Arabia, Jordan, and Iraq, are of critical environmental and geopolitical significance. Monthly Gravity Recovery and Climate Experiment (GRACE) satellite‐derived gravity field solutions acquired over the expansive Saq transboundary aquifer system were analysed and spatiotemporally correlated with relevant land surface model outputs, remote sensing observations, and field data to quantify temporal variations in regional water resources and to identify the controlling factors affecting these resources. Our results show substantial GRACE‐derived terrestrial water storage (TWS) and groundwater storage (GWS) depletion rates of ?9.05 ± 0.25 mm/year (?4.84 ± 0.13 km3/year) and ?6.52 ± 0.29 mm/year (?3.49 ± 0.15 km3/year), respectively. The rapid decline is attributed to both climatic and anthropogenic factors; observed TWS depletion is partially related to a decline in regional rainfall, while GWS depletions are highly correlated with increasing groundwater extraction for irrigation and observed water level declines in regional supply wells.  相似文献   

15.
Recent work has suggested that weathering processes occurring in the subsurface produce the majority of silicate weathering products discharged to the world's oceans, thereby exerting a primary control on global temperature via the well‐known positive feedback between silicate weathering and CO2. In addition, chemical and physical weathering processes deep within the critical zone create aquifers and control groundwater chemistry, watershed geometry and regolith formation rates. Despite this, most weathering studies are restricted to the shallow critical zone (e.g. soils, outcrops). Here we investigate the chemical weathering, fracturing and geomorphology of the deep critical zone in the Bisley watershed in the Luquillo Critical Zone Observatory, Puerto Rico, from two boreholes drilled to 37.2 and 27.0 m depth, from which continuous core samples were taken. Corestones exposed aboveground were also sampled. Weathered rinds developed on exposed corestones and along fracture surfaces on subsurface rocks slough off of exposed corestones once rinds attain a thickness up to ~1 cm, preventing the corestones from rounding due to diffusion limitation. Such corestones at the land surface are assumed to be what remains after exhumation of similar, fractured bedrock pieces that were observed in the drilled cores between thick layers of regolith. Some of these subsurface corestones are massive and others are highly fractured, whereas aboveground corestones are generally massive with little to no apparent fracturing. Subsurface corestones are larger and less fractured in the borehole drilled on a road where it crosses a ridge compared with the borehole drilled where the road crosses the stream channel. Both borehole profiles indicate that the weathering zone extends to well below the stream channel in this upland catchment; hence weathering depth is not controlled by the stream level within the catchment and not all of the water in the watershed is discharged to the stream. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

16.
To investigate the origin and behaviour of nitrate in alluvial aquifers adjacent to Nakdong River, Korea, we chose two representative sites (Wolha and Yongdang) having similar land‐use characteristics but different geology. A total of 96 shallow groundwater samples were collected from irrigation and domestic wells tapping alluvial aquifers. About 63% of the samples analysed had nitrate concentrations that exceeded the Korean drinking water limit (44·3 mg l?1 NO3?), and about 35% of the samples had nitrate concentrations that exceeded the Korean groundwater quality standard for agricultural use (88·6 mg l?1 NO3?). Based on nitrogen isotope analysis, two major nitrate sources were identified: synthetic fertilizer (about 4‰ δ15N) applied to farmland, and animal manure and sewage (15–20‰ δ15N) originating from upstream residential areas. Shallow groundwater in the farmland generally had higher nitrate concentrations than those in residential areas, due to the influence of synthetic fertilizer. Nitrate concentrations at both study sites were highest near the water table and then progressively decreased with depth. Nitrate concentrations are also closely related to the geologic characteristics of the aquifer. In Yongdang, denitrification is important in regulating nitrate chemistry because of the availability of organic carbon from a silt layer (about 20 m thick) below a thin, sandy surface aquifer. In Wolha, however, conservative mixing between farmland‐recharged water and water coming from a village is suggested as the dominant process. Mixing ratios estimated based on the nitrate concentrations and the δ15N values indicate that water originating from the village affects the nitrate chemistry of the shallow groundwater underneath the farmland to a large extent. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

17.
This paper presents an analytical model for describing the tidal effects in a two‐dimensional leaky confined aquifer system in an estuarine delta where ocean and river meet. This system has an unconfined aquifer on top and a confined aquifer on the bottom with an aquitard in between the two. The unconfined and confined aquifers interact with each other through leakage. It was assumed that the aquitard storage was negligible and that the leakage was linearly proportional to the head difference between the unconfined and confined aquifers. This model's solution was based on the separation of variables method. Two existing solutions that deal with the head fluctuation in one‐dimensional or two‐dimensional leaky confined aquifers are shown as special cases in the present solution. Based on this new solution, the dynamic effect of the water table's fluctuations can be clearly explored, as well as the influence of leakage on the behaviour of fluctuations in groundwater levels in the leaky aquifer system. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

18.
Aquifers are inherently susceptible to contamination and coastal aquifers in specific are highly vulnerable to sea water intrusion. For efficient planning and management of coastal aquifers in Kayalpattu and Tiruchopuram villages, which extend over 4·05 km2, it is essential to delineate and predict the extent of intrusion into the shallow aquifer. Management of ground water in coastal aquifers is composed of major elements that should be properly evaluated, and special attention is given to the sea water intrusion problem. Different data, like hydro‐geomorphological and depth‐wise iso‐apparent resistivity, are integrated spatially using a geographical information system. The stack‐unit mapping approach is used to delineate the zones with iso‐apparent resistivity of less than 10 Ω m have been found to be increasing in areal extent with reference to depth. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

19.
The identification of groundwater parameters in heterogeneous systems is a major challenge in groundwater modeling. Flexible parameterization methods are needed to assess the complexity of the spatial distributions of these parameters in real aquifers. In this article, we introduce an adaptative parameterization to identify the distribution of hydraulic conductivity within the large‐scale (4400 km2) Upper Rhine aquifer. The method is based on adaptative multiscale triangulation (AMT) coupled with an inverse problem procedure that identifies the parameters' distributions by reducing the error between measured and simulated heads. The AMT method has the advantage of combining both zonation and interpolation approaches. The AMT method uses area‐based interpolation rather than an interpolation based on stochastic features. The method is applied to a standard 2D groundwater model that takes into account the interactions between the aquifer and surface water bodies, groundwater recharge, and pumping wells. The simulation period covers 204 months, from January 1986 to December 2002. Recordings at 109 piezometers are used for model calibration. The simulated heads are globally quite accurate and reproduce the main dynamics of the system. The local hydraulic conductivities resulting from the AMT method agree qualitatively with existing local experimental observations across the Rhine aquifer.  相似文献   

20.
This study explores linkages between the microbial composition and hydrochemical variables of pristine groundwater to identify active redox conditions and processes. Two confined aquifers underlying the city of Qianjiang in the Jianghan Plain in China were selected for this study, having different recharge sources and strong hydrochemical gradients. Typical methods for establishing redox processes according to threshold concentration criteria for geochemical parameters suggest iron or sulphate reduction processes. High‐throughput 16S rRNA sequencing was used to obtain diversity and taxonomic information on microbial communities. Instead of revealing iron‐ and sulphate‐reducing bacteria, salt‐ and alkali‐tolerant bacteria, such as the phylum Firmicutes and the class Gammaproteobacteria, and in particular, the family Bacillaceae, were dominant in the downstream groundwater of the first aquifer that had high ion concentrations caused by the dissolution of calcite and dolomite; meanwhile, the heterotrophic microaerophilic families Comamonadaceae and Rhodocyclaceae prevailed in the upstream groundwater of the first aquifer. Sulphate‐reducing bacteria were extremely abundant in the upstream groundwater of the second aquifer, as the SO42? concentration was especially high. Methanogens and methanotrophs were predominant in the downstream groundwater of the second aquifer even though the concentration of SO42? was much higher than 0.5 mg L?1. The microbial communities, together with the geochemical parameters, indicated that the upstream region of the first aquifer was suboxic, that Fe(III) and Mn(IV) reductions were not the main redox processes in the downstream groundwater of the first aquifer with high Fe and Mn concentrations, and that the redox processes in the upstream and downstream regions of the second confined aquifer were SO42? reduction and methanogenesis, respectively. This study expands understanding of the linkages between microbial communities and hydrogeochemistry in pristine groundwaters and provides more evidence for identifying active redox conditions and processes.  相似文献   

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