Stable isotope evidence for the atmospheric origin of CO₂ involved in carbonation of MSWI bottom ash     

C. Flhoc  J.-P. Girard  P. Piantone  F. Bodnan 《Applied Geochemistry》2006,21(12):2037-2048

Stable isotopes were used to constrain the origin of CO₂ involved in the ageing process of municipal solid waste incineration (MSWI) bottom ash under open-air conditions. The δ¹³C and δ¹⁸O values of CaCO₃ occurring in MSWI bottom ash samples of variable age and the δ¹³C of the residual organic matter content were measured, and laboratory assessments made of the isotopic fractionation accompanying CaCO₃ neo-formation during accelerated carbonation experiments of bottom ash or pure lime with atmospheric or industrial CO₂. The results indicate that stable isotopic compositions exhibited by fresh and aged bottom ash samples reflect non-equilibrium processes resembling those described in the carbonation of concrete and mortar. They also lead to conclusions on the prevalent involvement of atmospheric CO₂ in the open-air carbonation of MSWI bottom ash.  相似文献   

2D magnetic resonance tomography applied to karstic conduit imaging   总被引：1，自引：1，他引：1  

J.-F. Girard  M. Boucher  A. Legchenko  J.-M. Baltassat 《Journal of Applied Geophysics》2007,63(3-4):103-116

Karstic conduits play a crucial role for water supply in many parts of the world. However, the imaging of such targets is generally a difficult task for most geophysical methods. Magnetic Resonance Sounding (MRS) is a geophysical method designed for imaging of water bearing structures. Initially, MRS was developed for characterizing horizontally stratified aquifers. However, when applying a 1D MRS measuring setup to the imaging of 2D–3D targets, the size of which may be much smaller than the loop, the accuracy and the lateral resolution may not be sufficient. We have studied the possibility of simultaneously processing several MRS aligned along a profile to perform a Magnetic Resonance Tomography (MRT). This work emphasizes the gain of resolution for 2D–3D imagery of MRT versus the interpolation of 1D inversion results of MRS along the same profile. Numerical modelling results show that the MRT response is sensitive to the size and location of the 2D target in the subsurface. Sensitivity studies reveal that by using the coincident transmitting/receiving (TX/RX) setup and shifting the loop around the anomaly area, the depth, section and position of a single karstic conduit with a size smaller than the MRS loop size can be resolved. The accuracy of the results depends on the noise level and signal level, the latter parameter being linked to the depth and volume of the karstic conduit and the water content in the limestone matrix. It was shown that when applying MRT to the localization of 2D anomalies such as karstic conduits, the inclination of the geomagnetic field, the orientation of the MRT profile and the angle of crossover of the conduit by the MRT profile must be taken into account. Otherwise additional errors in interpretation should be expected. A 2D inversion scheme was developed and tested. Both numerical and experimental results confirm the efficiency of the developed approach.  相似文献   

Short‐term forecasting with a multi‐level spectral primitive equation model part I ‐ model formulation     

Roger Daley  Claude Girard  John Henderson  Ian Simmonds 《大气与海洋》2013,51(2):98-116

A global baroclinic primitive equation model using the spectral technique has been constructed for short‐ and medium‐range numerical weather prediction. The spectral technique, which is a special case of the Galerkin method, employs spherical harmonic basis functions in the evaluation of all horizontal derivatives. The use of a transform technique allows all the horizontal operations to be performed efficiently and allows physical processes to be evaluated in real space. The model employs a semi‐implicit algorithm for time integration and finite differencing in the vertical. Physical processes include orography, moist convection, large scale precipitation and boundary layer processes.  相似文献   

Evaluation of an ensemble of Arctic regional climate models: spatiotemporal fields during the SHEBA year   总被引：1，自引：1，他引：0  

A.?RinkeEmail author  K.?Dethloff  J.?J.?Cassano  J.?H.?Christensen  J.?A.?Curry  P.?Du  E.?Girard  J.-E.?Haugen  D.?Jacob  C.?G.?Jones  M.?K?ltzow  R.?Laprise  A.H.?Lynch  S.?Pfeifer  M.?C.?Serreze  M.?J.?Shaw  M.?Tjernstr?m  K.?Wyser  M.??agar 《Climate Dynamics》2006,26(5):459-472

Simulations of eight different regional climate models (RCMs) have been performed for the period September 1997–September 1998, which coincides with the Surface Heat Budget of the Arctic Ocean (SHEBA) project period. Each of the models employed approximately the same domain covering the western Arctic, the same horizontal resolution of 50 km, and the same boundary forcing. The models differ in their vertical resolution as well as in the treatments of dynamics and physical parameterizations. Both the common features and differences of the simulated spatiotemporal patterns of geopotential, temperature, cloud cover, and long-/shortwave downward radiation between the individual model simulations are investigated. With this work, we quantify the scatter among the models and therefore the magnitude of disagreement and unreliability of current Arctic RCM simulations. Even with the relatively constrained experimental design we notice a considerable scatter among the different RCMs. We found the largest across-model scatter in the 2 m temperature over land, in the surface radiation fluxes, and in the cloud cover which implies a reduced confidence level for these variables. An erratum to this article can be found at  相似文献   

A mass mortality of subtropical intertidal populations of the sea urchin Paracentrotus lividus: analysis of potential links with environmental conditions     

Dominique Girard  Sabrina Clemente  Kilian Toledo-Guedes  Alberto Brito  José Carlos Hernández 《Marine Ecology》2012,33(3):377-385

An outbreak of bald sea urchin disease was detected affecting intertidal populations of the edible temperate species Paracentrotus lividus at its southernmost geographical limit. The mortality event was detected in three sites (Güímar, Palmar and Alcalá) off Tenerife, Canary Islands (Northeastern Atlantic), in October 2003, coinciding with the highest sea surface temperatures (SST) and the lowest wave heights of the year. The prevalence of infection reached 100% but did not affect equally all studied sites or the different size classes. The disease was more prevalent in large sea urchins (>40 mm). The prevalence appeared to be positively correlated with the environmental variable SST and negatively correlated with wave height. In October 2004, only two infected urchins were found (prevalence 1%) at one of the studied sites. However, during 2004 no such extreme values of temperature and wave height were observed. We conclude that high SSTs and low wave heights such as those observed during 2003 are conditions that may trigger outbreaks of urchin disease.  相似文献   

Geodynamic evolution of a forearc rift in the southernmost Mariana Arc     

Julia M. Ribeiro  Robert J. Stern  Fernando Martinez  Osamu Ishizuka  Susan G. Merle  Katherine Kelley  Elizabeth Y. Anthony  Minghua Ren  Yasuhiko Ohara  Mark Reagan  Guillaume Girard  Sherman Bloomer 《Island Arc》2013,22(4):453-476

The southernmost Mariana forearc stretched to accommodate opening of the Mariana Trough backarc basin in late Neogene time, erupting basalts at 3.7–2.7 Ma that are now exposed in the Southeast Mariana Forearc Rift (SEMFR). Today, SEMFR is a broad zone of extension that formed on hydrated, forearc lithosphere and overlies the shallow subducting slab (slab depth ≤ 30–50 km). It comprises NW–SE trending subparallel deeps, 3–16 km wide, that can be traced ≥ ∼30 km from the trench almost to the backarc spreading center, the Malaguana‐Gadao Ridge (MGR). While forearcs are usually underlain by serpentinized harzburgites too cold to melt, SEMFR crust is mostly composed of Pliocene, low‐K basaltic to basaltic andesite lavas that are compositionally similar to arc lavas and backarc basin (BAB) lavas, and thus defines a forearc region that recently witnessed abundant igneous activity in the form of seafloor spreading. SEMFR igneous rocks have low Na₈, Ti₈, and Fe₈, consistent with extensive melting, at ∼23 ± 6.6 km depth and 1239 ± 40°C, by adiabatic decompression of depleted asthenospheric mantle metasomatized by slab‐derived fluids. Stretching of pre‐existing forearc lithosphere allowed BAB‐like mantle to flow along the SEMFR and melt, forming new oceanic crust. Melts interacted with pre‐existing forearc lithosphere during ascent. The SEMFR is no longer magmatically active and post‐magmatic tectonic activity dominates the rift.  相似文献   

Spatial variation of nutrients and primary productivity in the Rufiji Delta mangroves,Tanzania     

A Minu  JF Machiwa  S Pamba 《African Journal of Marine Science》2020,42(2):221-232

Determinations of spatial and temporal variations in organic matter and nutrient dynamics in water and sediments are crucial for understanding changes in aquatic bodies. In this study, we (i) determine the spatial dynamics of dissolved inorganic nutrients, during the transition from the dry to the rainy season, and (ii) provide future productivity predictions for the Rufiji Delta mangroves, Tanzania, based on the input of various nutrients. Water samples were collected from six locations, three times per year between April 2012 and January 2014, and analysed for dissolved nutrients, total organic and inorganic carbon, chlorophyll a, chlorophyll b and total carotenoids. The prediction of future net primary productivity in the Rufiji mangroves was undertaken using the software STELLA. The mean nutrient concentrations were of the order: nitrate > phosphate > ammonium > silica > dissolved organic carbon. The study revealed that high nutrient concentrations occurred in the northern part of the Rufiji Delta as a result of anthropogenic influence in the watershed. Modelling of nutrient inputs into the delta indicated enhanced primary productivity, which is expected to increase the vulnerability of water quality in the near future due to eutrophication.  相似文献   

The influence of long emersion on biota, ammonium fluxes and nitrification in intertidal sediments of Marennes-Oléron Bay, France   总被引：2，自引：0，他引：2  

Laima M  Brossard D  Sauriau PG  Girard M  Richard P  Gouleau D  Joassard L 《Marine environmental research》2002,53(4):381-402

A comparative study between waterlogged and reflooded intertidal sediments was undertaken in March and June 1999 through statistical analysis of selected sediment parameters (biota, salinity, O2, Eh), pool sizes and benthic fluxes of nutrients (NH4+, NO2-, NO3-) and nitrification rates. In March samples, absence of polychaetes and oligochaetes from upper sediment horizons were due to erosional events sweeping away surface sediments. Presence of richer annelid assemblages in June samples indicated more stable hydrodynamic conditions that favoured the development of benthic microalgae biofilms. Dewatering of sediments during a 3-day emersion period promoted a salinity rise on top layers, migration of pore water ions towards the sediment surface, and created sediment fissures that accelerated water exchange on reflooding. Reflooded and waterlogged sediment systems were comparable with respect to the release of NH4+ to overlying water but were different with respect to nitrification rates. Sediment-water NH4+ fluxes were higher (P = 0.011) in March (3.3 mmol m(-2) day(-1) compared to June (1.4 mmol m(-2) day(-1) due to higher macrofauna biomasses and lower benthic microalgae concentrations in March samples. Potential nitrification rates (range from 19 to 60 mmol NO3- (-2) day(-1)) were not statistically different between March and June. A thinner oxic layer in reflooded compared with waterlogged systems reflects a decrease of O2 diffusion into sediment at high salinities which resulted in the fall of the actual nitrification rates (P < 0.05). Our data suggest that long term dessication of intertidal sediments may depress the nitrification process at the ecosystem level.  相似文献   

The Yale/San Juan Southern Proper Motion program     

William F. van Altena  Terrence Girard  Carlos E. López 《Astrophysics and Space Science》1991,177(1-2):59-63

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Resolution of MRS applied to the characterization of hard-rock aquifers   总被引：4，自引：0，他引：4  

Legchenko A  Descloitres M  Bost A  Ruiz L  Reddy M  Girard JF  Sekhar M  Mohan Kumar MS  Braun JJ 《Ground water》2006,44(4):547-554

The performance of the Magnetic Resonance Sounding (MRS) method applied to the investigation of heterogeneous hard-rock aquifers was studied. It was shown using both numerical modeling and field measurements that MRS could be applied to the investigation of the weathered part of hard-rock aquifers when the product of the free water content multiplied by the thickness of the aquifer is >0.2 (for example, 10-m-thick layer with a 2% water content). Using a currently available one-dimensional MRS system, the method allows the characterization of two-dimensional subsurface structures with acceptable accuracy when the size of the subsurface anomaly is equal to or greater than the MRS loop. However, the fractured part of hard-rock aquifers characterized by low effective porosity (<0.5%) cannot be resolved using currently available MRS equipment. It was found that shallow water in the weathered part of the aquifer may screen MRS signals from deeper water-saturated layers, thus further reducing the possibility of investigating deeper fractured aquifers. A field study using the NUMIS(plus) MRS system developed by IRIS Instruments was carried out on an experimental watershed in southern India. A heterogeneous unconfined aquifer in a gneissic formation was successfully localized, and MRS results were confirmed by drilling shortly after the geophysical study. The top of the aquifer revealed by MRS was found to be in a good agreement with observed static water level measurements in boreholes.  相似文献