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1.
Peiyan Sun Zhenhui Gao Lixin Cao Xinping Wang Qing Zhou Yuhui Zhao Guangmei Li 《中国海洋大学学报(英文版)》2011,10(1):35-41
In recent years, oil spill accidents occur frequently in the marine area of China. Finding out the spilled oil source is a
key step in the relevant investigation. In this paper, a step-by-step fingerprinting identification method was used in a spilled
oil accident in the Bohai Sea in 2002. Advanced chemical fingerprinting and data interpretation techniques were used to characterize
the chemical composition and determine the possible sources of two spilled oil samples. The original gas chromatography -flame
ionization detection (GC-FID) chromatogram of saturated hydrocarbons was compared. The gas chromatography-mass spectrometry
(GC/MS) chromatograms of aromatic hydrocarbons terpane and sterane, n-alkane and poly-aromatic hydrocarbons (PAHs) were analyzed. The correlation analysis on diagnostic ratios was performed with
Student’s t-test. It is found that the oil fingerprinting of the spilled oil (designated as sz1) from the polluted sand beach
was identical with the suspected oil (designated as ky1) from a nearby crude oil refinery factory. They both showed the fingerprinting
character of mixed oil. The oil fingerprinting of the spilled oil (designated as ms1) collected from the port was significantly
different from oil ky1 and oil sz1 and was with a lubricating oil fingerprint character. The identification result not only
gave support for the spilled oil investigation, but also served as an example for studying spilled oil accidents. 相似文献
2.
Photochemical degradation of crude oil in seawater 总被引：2，自引：0，他引：2
1 INTRODUCTION Marine photochemistry is a newly developed subject in marine sciences. Photochemical degrada- tion is important in decomposing and removing various organic contaminants in oceans (Ali et al., 1995a, b; Yang, 2000; Yang and Qi, 2002; 2003). … 相似文献
3.
Accumulation of petroleum hydrocarbons and heavy metals in clams （Ruditapes philippinarum） in Jiaozhou Bay, China 总被引：2，自引：0，他引：2
Accumulation and distributions of aliphatic and polyaromatic hydrocarbons (PAHs) and heavy metals were measured in tissues
of the clam Ruditapes philippinarum collected from 5 sites in Jiaozhou Bay, Qingdao, China. The concentrations of total aliphatic hydrocarbon and PAHs ranged
from 570 to 2 574 ng/gdw (gram dry weight) and from 276 to 939 ng/gdw, in the most and least polluted sites, respectively.
The bio-accumulation of hydrocarbons and PAHs in the clams appeared to be selective. Aliphatic hydrocarbons were predominantly
represented by short chain (<nC23) n-alkanes, suggesting that petroleum hydrocarbons were likely the major contamination source. The selective uptake of 3 and
4 ring PAHs, such as naphthalene, fluorene, phenanthrene, fluoranthene and pyrene, by the clams was probably related to the
physiological and bio-kinetic processes that were energetically favorable for uptake of compounds with fewer rings. Accumulation
of the metals Cd, Cu, Zn, Pb, Cr, Hg, and As in the clam tissues also showed high variability, ranging from 0.043 to 87 μg/gdw.
Among the 7 detected metals, Zn, Cd, Cu, and As had a particularly high potential of accumulation in R. philippinarum. In general, a positive correlation was found between the tissue concentrations and sediment concentrations of hydrocarbons
and of some metals. Our study suggests that moderate contamination with polyaromatic hydrocarbons, and low to moderate contamination
with metals, currently exists for clam R. philippinarum in Jiaozhou Bay, in comparison with other regional studies. A long-term monitoring program is certainly needed for assessment
of the potential ecological influence and toxicity of these contaminants of R. philippinarum in Jiaozhou Bay. 相似文献
4.
Trare amounts of benzene hydrocarbons obtained in Jiaozhou Bay (Qindao) were enriched bysorption on a GDX-102 column and eluted by carbon disulfide. The eluted was concenttaled and then de-temened by capillary column gas cbornatognphy.The contents of virious kinds of benzene hydrocarbons in Jiaozhou Bay coastal water were benzene(22.3-141.6)× 10～(-9)g/L, toluate (15.2-94.0) × 10~(-9) g/L, ethyl benzene(11.8-85.1)×10~(-9) g/L, p -xylene(15.2-78.5) ×10(-9) g/L, m-xylene (10.9-79.4) ×10(-9) g/L, o -xylene (12.4-80.1) x ×10(-9)g/L; iso-propyl(8.4- 73.1) x ×10(-9)g/L, n -propyl (6.9-76.4) ×10(-9) g/L, 1, 3, 5-trimethylbenzene (10.9- 35.9)×10(-9) g/L, 1,2, 4-trimethybenzene (10.0- 38.0)×10(-9) g/L, n - butydriare (8. 1 - 34.6) ×10(-9)g/L. The recovery of benzenehydrocarbons was (85.1 -95.6)%. 相似文献
5.
东营凹陷纯西辉长岩对烃源岩异常生排烃作用研究 总被引：3，自引：0，他引：3
基性岩浆带来大量的热量和地幔物质,并产生极高的压力,加速了周围烃源岩的成熟演化,且促使其排烃,形成放射状排烃格局;辉长岩中的过渡金属由于有机酸的活化、迁移,并最终在周围烃源岩中沉淀、聚集,它们对烃源岩生烃起到显著的催化作用,使其早熟;火山热液中以及辉长岩蚀变产生的CH4和H2对烃源岩生烃起到加氢作用,显著扩大了其生烃量和提高了区域油气丰度。 相似文献
6.
Peat bogs are regarded as one of the faithful archives of atmospheric polycyclic aromatic hydrocarbons(PAHs) deposition, and a large number of studies on PAHs accumulation in peatlands have been reported in Europe and North America. Comparatively little information is available on peat chronological records of atmospheric PAHs flux in China. We investigated the concentrations and historical accumulation rates of PAHs(AR PAHs) through geochemical analysis of three 210Pb-dated ombrotrophic peat cores from Great Hinggan Mountain, northeast China. Eight USEPA priority PAHs were detected and they are naphthalene(Nap), acenaphthylene(Acl), acenaphthene(Ace), fluorence(Flu), phenanthrene(Phe), anthracene(Ant), fluoranthene(Fla) and pyrene(Pyr), respectively. The average total eight PAHs(tPAHs) concentrations are 135.98- 262.43 μg kg-1 and the average AR tPAHs over the last two centuries are 96.45- 135.98 μg m-2 yr-1. The Ace, Acl and Phe account for 30.93- 54.04%, 25.29- 35.81%, and 9.14- 19.84% of the tPAHs, respectively, and have significant positive correlations with the tPAH. As a result, they are regarded as the iconic compounds of PAHs pollution in this area. A ca.200-yr atmospheric PAHs contamination history was reconstructed from the temporal sequences of bothconcentration and AR tPAHs, suggesting the variation of local environmental pollution. The main sources of the PAHs are identified by two isomer ratios as petrogenic origin including oil extraction and refining process as well as their combustions for industrial development. In addition, the contribution of coal combustion for industrial activities and resident heating could not be ignored. But prior to 1860, the undeveloped industry and most of agricultural activities might mainly account for the low level of PAHs, although it could infer a long-range input of atmospheric PAHs from other industrial areas. Therefore, there is a global implication to study longterm PAHs pollution records and all the results will provide practical significance in formulating policies to achieve sustainable and healthy development. 相似文献
7.
根据2009年和2010年的调查资料,对崖城气田附近海域底栖动物污染物含量现状进行分析与评价。结果表明,2009年到2010年该气田附近生物体内污染物含量变化不明显,底栖动物未严重受到重金属和石油烃污染,该区域底栖动物各类群的生物质量状况良好,气田的开发活动对附近海区影响相对较小。 相似文献
8.
【目的】研究南海北部近海区域柱状沉积物多环芳烃组成及分布特征,讨论全新世早期火历史及气候变化。【方法】利用AMS 14C定年技术结合有机地球化学分析手段对全新世早期南海北部近海沉积物柱状样品中多环芳烃(PAHs)分布特征进行研究。【结果】南海北部近海沉积物中16种PAHs总浓度范围为8.58~17.48 ng/g,在约10000 a B.P.的全新世早期呈现先增大后减小波动变化,与TOC变化基本同步。【结论】沉积物中多环芳烃主要来源于南海北部近海陆源区域自然火灾产生的焦炭残渣。PAHs的沉积浓度变化间接指示了全新世早期东亚季风的强度变化。 相似文献
9.
10.
知识型企业中创造型团队的管理 总被引：1，自引：0，他引：1
主要对知识型企业中团队问题进行了研究。从团队领导、团队结构以及团队协作与企业家精神的关系等方面讨论了在知识型企业中建立创造型团队的重要性，并相应提出了人力资源政策建议。 相似文献
11.
Flume experiments and numerical simulation were conducted to characterize the hydrodynamics of a trapezoid artificial reef. Measurements in particle image velocimetry were conducted to observe the formation of upwelling and vortices; and forces for the reef model were measured by load cell. The results of flume experiments agree well with the numerical data. In addition, the flow structure around a reef combining trapezoidal and cubic blocks was simulated numerically under two deployment schemes, showing a more complicated flow structure than that of a stand-alone reef. Relationship between drag coefficient and Reynolds number suggest that the degree of turbulence can be assessed from the value of drag coefficient downstream from the reef. The role of the reef in water flow is to reduce flow velocity and generate turbulence. 相似文献
12.
Based on the principle of turned mass damper(TMD) systems,the conceptual design of semi-submersible platform with a moveable heave-plate(MHS) has been put forward.The heave motion response amplitude operator(RAO) and viscous damping of the MHS platform are calculated by iteration,and the coupling stiffness between the MHS hull and the heave-plate is optimized to decrease the maximum heave motion response of the MHS hull under 10-year survival conditions in the South China Sea.The nu-merical results indicate that the heave motion RAO of the MHS hull can be decreased in the range of predominant wave frequencies,which may provide some reference to the heave motion control of offshore platforms. 相似文献
13.
《山地科学学报》2021,(8)
A tunnel-type anchorage(TTA) is one of the main components in suspension bridges: the bearing mechanism is a key problem. Investigating the deformation characteristics, development law, and failure phenomenon of a TTA under load can provide the theoretical basis for a robust design. Utilizing the TTA of the Jinsha River suspension bridge at Lijiang Shangri-La railway as a prototype, a laboratory model test of the TTA was carried out for three different contact conditions between the anchorage body and the surrounding rock. The stress and deformation distribution law of the anchorage body and its surrounding rock were studied, and the ultimate bearing capacity and failure mode of the TTA were analyzed. The test results show that the compressive stress level is highest at the rear part of the anchorage body. Moving away from the rear portion of the body, the stress decays in a negative exponential function. Based on the load transfer curve, the calculation formula for the shear stress on the contact surface between the anchorage body and the surrounding rock was derived, which shows that the distribution of the shear stress along the axial direction of the anchorage body is not uniform. The distance from the maximum value to the loading surface is approximately 1/3 of the length of the anchorage body, and the stress decreases as the distance from the loading surface increases. Furthermore, the contact condition between the anchorage body and surrounding rock has a great influence on the bearing capacity of the TTA. The increase in the anti-skid tooth ridge and radial anchor bolt can improve the cooperative working capacity of the anchorage body and the surrounding rock, which is approximately 50% higher than that of the flat contact condition. The main function of the anchor bolt is to increase the overall rigidity of the TTA. The contact condition between the anchorage body and the surrounding rock will lead to a change in the failure mode of the TTA. With an increase in the degree of contact, the failure mode will change from shear sliding along the interface to trumpet-shaped inverted cone-shaped failure extending into the surrounding rock. 相似文献
14.
This study aimed to produce a high-quality landslide susceptibility map for Teziutlán municipality, a landslide-prone region in Mexico, which is characterised by a depositional pyroclastic ramp. The heterogeneous quality of available topographic information(i.e. higher resolution digital elevation model only for a sub-region) encouraged to confront modelling results based on two different study area delineations and two raster resolutions. Input data was based on the larger modelling region L15(163 km2) and smaller S(70 km2; located inside L15) with an associated raster cell size of 15 m(region L15 and S15) and 5 m(region S5). The resulting three data sets(L15, S15 and S5) were included into three differently flexible modelling techniques(Generalized Linear Model-GLM, General Additive Model-GAM, Support Vector Machine-SVM) to produce nine landslide susceptibility models. Preceding variable selection was performed heuristically and supported by an exploratory data analysis. The final models were based on the explanatory variables slope angle, slope aspect, lithology, relative slope position, elevation, convergence index, distance to streams, distance to springs and topographic wetness index. The ability of the models to classify independent test data was elaborated using a k-fold cross validation procedure and the AUROC(Area Under the Receiver Operating Characteristic) metric. In general, all produced landslide susceptibility maps depicted the hillslopes of the ravines, which cut the pyroclastic ramp, as prone to landsliding. The modelling results showed that predictive performances(i.e. AUROC values) slightly increased with an increasing flexibility of the applied modelling technique. Thus, SVM performed best, while the GAM outperformed the GLM. This tendency was most distinctive when modelling with the largest landslide sample size(i.e. data set L15; n = 662 landslides). Non-linear classifiers(GAMs, SVMs) performed slightly better when trained on the basis of lower raster resolution(data set S15) compared to the 5 m counterparts(data set S5). Highest predictive performance was obtained for the model based on data set L15 and the SVM classifier(median AUROC: 0.82). However, SVMs also indicated the highest degree of model overfitting. This study indicates that the decision to delineate a study area, the selection of a raster resolution as well as the chosen classification technique can affect varying aspects of subsequent modelling results. The results do not support the assumption that a higher raster resolution(i.e. a more detailed digital representation of the terrain) inevitably leads to better performing or geomorphically more plausible landslide susceptibility maps. 相似文献
15.
The tidal asymmetry-induced siltation below tidal barriers is a worldwide problem that restricts regional socio-economic and environmental development. The hydrodynamic processes of the small mud estuary also feature a high uncertainty after estuary restoration measures. In this study, a hydrodynamic model based on the MIKE21 is used to quantify the responses of tidal asymmetry to a two-phase restoration project in Shuanglong Estuary, Bohai Bay, China. According to the numerical modeling results, the tidal flat removal in the upper estuary(first-phase restoration) induces the flood asymmetry switching to the ebb asymmetry in unrestored reach but enhances flood asymmetry in widening restored reach. Although the tidal asymmetry reverts to flood-dominated pattern after full restoration over the estuary, the imbalance between flood and ebb velocities is relieved. A possible net sediment transport pattern based on a comparison of dominant asymmetric current and actual sediment transport period shows net sediments in the upper estuary and inlet transport seaward and landward, respectively, in the first-phase restoration, whereas landward net sediment transport occurs in the whole estuary under the second-phase restoration scenario. Given these results, we assume that a switch from the flood-dominated estuary to ebb-dominated estuary can be caused by redesigning the cross-sectional profile. The quantitative comparison of Lagrangian residual currents also implies that a channel–shoal structure rather than a flat bathymetry can promote the mass transport. Therefore, reshaping the channel–tidal flat system in restoration projects can prevent the sedimentation of the estuary and improve the water environment. 相似文献
16.
Interception of sulfate deposition from a closed canopy to a forest gap edge canopy in a subalpine dragon spruce plantation 总被引：1，自引：0，他引：1
《山地科学学报》2019,(12)
Reducing the threats of sulfate ion(SO_4~(2-))deposition to terrestrial ecosystems is a great challenge.The canopy interception effect on SO_4~(2-)deposition has been well documented,but the interception efficiency of the gap edge remains unknown.Therefore,a subalpine dragon spruce(Picea asperata) plantation was evaluated in the upper reaches of the Yangtze River.The dynamics of the SO_4~(2-) concentration in the throughfall were investigated from the gap edge to the closed canopy during the rainfall and snowfall periods from August 2015 to July 2016.The annual input of SO_4~(2-) totaled 2.56 kg/ha through rainfall and 0.69 kg/ha through snowfall.The total annual net interception fluxes(NIFs) of SO_4~(2-) at the gap edge and in the closed canopy were 1.48 kg/ha and 0.66 kg/ha,respectively,and the net interception ratios(NIRs) accounted for 45.40% and 20.25%,respectively.The NIF and the NIR of SO_4~(2-) at the gap edge were higher than those in the closed canopy.Therefore,the results suggested that a significant amount of SO_4~(2-) deposition was intercepted by the tree canopy in the subalpine plantation,with more SO_4~(2-) deposition at the gap edge than in the closed canopy,which is beneficial for improving the water quality in the upper reaches of the Yangtze River via forest management. 相似文献
17.
18.
A finite difference model for solving Navier Stokes equations with turbulence taken into account is used to investigate viscous liquid sloshing-wave interaction with baffles in a tank. The volume-of-fluid and virtual boundary force methods are employed to simulate free surface flow interaction with structures. A liquid sloshing experimental apparatus was established to evaluate the accuracy of the proposed model, as well as to study nonlinear sloshing in a prismatic tank with the baffles. Damping effects of sloshing in a rectangular tank with bottom-mounted vertical baffles and vertical baffles touching the free surface are studied numerically and experimentally. Good agreement is obtained between the present numerical results and experimental data. The numerical results match well with the current experimental data for strong nonlinear sloshing with large free surface slopes. The reduction in sloshing-wave elevation and impact pressure induced by the bottom-mounted vertical baffle and the vertical baffle touching the free surface is estimated by varying the external excitation frequency and the location and height of the vertical baffle under horizontal excitation. 相似文献
19.
Liang Qiao Xing-min Meng Guan Chen Yi Zhang Peng Guo Run-qiang Zeng Ya-jun Li 《山地科学学报》2017,14(6):1113-1123
A colluvial landslide in a debris flow valley is a typical phenomena and is easily influenced by rainfall. The direct destructiveness of this kind of landslide is small, however, if failure occurs the resulting blocking of the channel may lead to a series of magnified secondary hazards. For this reason it is important to investigate the potential response of this type of landslide to rainfall. In the present paper, the Goulingping landslide, one of the colluvial landslides in the Goulingping valley in the middle of the Bailong River catchment in Gansu Province, China, was chosen for the study. Electrical Resistivity Tomography (ERT), Terrestrial Laser Scanning (TLS), together with traditional monitoring methods, were used to monitor changes in water content and the deformation of the landslide caused by rainfall. ERT was used to detect changes in soil water content induced by rainfall. The most significant findings were as follows:(1) the water content in the centralupper part (0~41 m) of the landslide was greater than in the central-front part (41~84 m) and (2) there was a relatively high resistivity zone at depth within the sliding zone. The deformation characteristics at the surface of the landslide were monitored by TLS and the results revealed that rainstorms caused three types of deformation and failure: (1) gully erosion at the slope surface; (2) shallow sliding failure; (3) and slope foot erosion. Subsequent monitoring of continuous changes in pore-water pressure, soil pressure and displacement (using traditional methods) indicated that long duration light rainfall (average 2.22 mm/d) caused the entire landslide to enter a state of creeping deformation at the beginning of the rainy season. Shear-induced dilation occurred for the fast sliding (30.09 mm/d) during the critical failure sub-phase (EF). Pore-water pressure in the sliding zone was affected by rainfall. In addition, the sliding L1 parts of the landslide exerted a discontinuous pressure on the L2 part. Through the monitoring and analysis, we conclude that this kind of landslide may have large deformation at the beginning and the late of the rainy season. 相似文献
20.
Mechanisms involved in triggering debris flows within a cohesive gravel soil mass on a slope: a case in SW China 总被引：1，自引：1，他引：0
The triggering mechanisms of debris flows were explored in the field using artificial rainfall experiments in two gullies, Dawazi Gully and Aizi Gully, in Yunnan and Sichuan Provinces, China, respectively. The soils at both sites are bare, loose and cohesive gravel-dominated. The results of a direct shear test, rheological test and back-analysis using soil mass stability calculations indicate that the mechanisms responsible for triggering debris flows involved the decreases in static and dynamic resistance of the soil. The triggering processes can be divided into 7 stages: rainfall infiltration, generation of excess runoff, high pore water pressure, surface erosion, soil creep, soil slipping, debris flow triggering and debris flow increment. In addition, two critical steps are evident: (i) During the process of the soil mass changing from a static to a mobile state, its cohesion decreased sharply (e.g., the cohesion of the soil mass in Dawazi Gully decreased from 0.520 to 0.090 kPa, a decrease of 83%). This would have reduced the soil strength and the kinetic energy during slipping, eventually triggered the debris flow. (ii) When the soil mass began to slip, the velocity and the volume increment of the debris flow fluctuated as a result of the interaction of soil resistance and the sliding force. The displaced soil mass from the source area of the slope resulted in the deposition of a volume of soil more than 7 - 8 times greater than that in the source area. 相似文献