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1.
Albina I. Kuznetsova Olga V. Zarubina Olga A. Sklyarova 《Geostandards and Geoanalytical Research》2007,31(3):251-259
Reference samples of soils from the Institute of Applied Physics, Irkutsk (RIAP), the Institute of Geochemistry, Irkutsk (IGI) and the United States Geological Survey, Reston (USGS) were analysed with the aim of determining Ag, B, Ge, Mo, Sn, Tl and W abundances by an atomic emission method with air-stabilised D.C. arc excitation. Two series of reference samples of soils and bottom sediments, GSS-1-8 and GSD-1-12 (IGGE), were used to ensure the traceability link for the analytical results. Traceability was also demonstrated through the comparison of measured results by AES and ICP-MS methods. It is shown that the reference samples GSS-1-8 and GSD-1-12 satisfied the "fitness-for-purpose" criterion (uncertainty U of the certified value should be one-third to one-tenth the magnitude of routine laboratory data uncertainty S (S/U > 3-10)) and can be applied for calibrating AES techniques. 相似文献
2.
Analytical data obtained in our two laboratories on three rook samples from the Institute of Geochemistry, Irkutsk, are reported and compared with "established", "certified" and "uncertain" values. Methods used are described briefly and some comments offered on earlier published information. 相似文献
3.
4.
对甘蒙（甘肃-内蒙古）北山地区花牛山、洗肠井、伊哈托里及希热哈达出露的奥陶纪火山岩进行了地球化学研究。结果表明:该区火山岩类型主要为安山玄武岩,以拉斑系列为主。花牛山和洗肠井火山岩的稀土元素配分具有弱的轻稀土亏损-平坦、重稀土略富集的特征,高场强元素比值特征与蛇绿岩（N-MORB）一致,形成环境为洋中脊;伊哈托里和希热哈达火山岩具轻稀土富集,高场强元素Nb、Ta、Ti等亏损的特征,类似于岛弧火山岩,但其ThN/NbN(>>1.00)、Nb/La(<1.00)、Zr/Nb值类似于N-MORB,暗示火山岩遭受了地壳物质的混染作用。伊哈托里和希热哈达火山岩样品w(Zr)>70.00×10-6和Zr/Y>3.00,显示了板内玄武岩的特征。结合区域构造演化分析,认为花牛山和洗肠井火山岩形成于洋中脊环境,而伊哈托里和希热哈达火山岩应属伸展裂解环境的产物。 相似文献
5.
V. I. Vinogradov G. A. Belenitskaya M. I. Bujakaite V. N. Kuleshov M. A. Minaeva B. G. Pokrovskii 《Lithology and Mineral Resources》2006,41(1):85-97
New isotope data on Lower Cambrian rocks of the Irkutsk amphitheater are reported in three communications. The first communication
is devoted to the sulfur isotopic composition, which is most sensitive to ostsedimentary geochemical transformations of sulfate
rocks in saliferous formations. It is shown that δ34S values in Bel’sk and Zhigalovo boreholes are within 22–35‰ The lowest values are close to the sulfur isotopic composition
of a halogenic basin, while the highest values are related to epigenetic sulfate reduction. This process was responsible for
the elimination of 100 m of anhydrites from the Lower Cambrian section. 相似文献
6.
报道的高钾-钾玄质火山岩位于狮泉河镇南东方向约20km处,向东延伸。高钾-钾玄质火山岩Si O2变化于60.35%~68.68%之间,属中酸性岩范畴;具有高的K2O+Na2O含量(8.8%~10.66%),K2O/Na2O值在1.92~2.49之间,Mg O含量较低,介于0.88%~3.47%之间,Al2O3含量为14.02%~14.91%,属于高钾-钾玄质系列。岩石强烈富集大离子亲石元素(LILE)Rb、Ba、Th、U和轻稀土元素(LREE),高场强元素(HFSE)Nb、Ta、Ti具有明显负异常,Cr、Ni、Co相容元素含量低于或接近地壳的平均含量,结合Th/Yb-Ta/Yb、(Th×100)/Zr-(Nb×100)/Zr判别图及La-La/Yb图解,暗示岩浆源区可能为下地壳。在左左乡南东约2km处和狮泉河水泥厂北东约1km处各采集1个高钾-钾玄质火山岩样品,对其中的锆石进行LA-ICP-MS U-Pb同位素测定,得到的206Pb/238U年龄加权平均值分别为22.04±0.42Ma和22.29±0.31Ma,此年龄被解释为狮泉河一带高钾-钾玄质火山岩的喷发时代,即中新世阿启塔期。由此表明,该火山岩是印度板片向北俯冲时在狮泉河一带俯冲板片断离,岩浆发生部分熔融的产物。 相似文献
7.
L.L. PETROV Yu.N. KORNAKOV L.A. PERSIKOVA V.V. MALYKH A.Z. PROKOP'EVA 《Geostandards and Geoanalytical Research》1996,20(1):95-132
The preparation and study of the two rock reference samples, Quartz Diorite SKD-1 and Sviatonossite SSv-1, are described, along with mineralogical and petrographic features. After its homogeneity studies, the two samples were analysed by seventy-five former USSR laboratories in the framework of an interlaboratory analytical program. The two samples have been certified respectively for 41 and 39 major, minor and trace elements; additionally, values are proposed for about 20 trace elements. The compiled data on the two samples are presented as an Appendix. Both the samples, processed in about 280 kg, form now part of the set of eight magmatic rock reference samples prepared by the Institute of Geochemistry in Irkutsk. 相似文献
8.
Many metallic ore deposits of the Late Cretaceous to Early Tertiary periods are distributed in the Gyeongsang Basin. Previous and newly analyzed sulfur isotope data of 309 sulfide samples from 56 ore deposits were reviewed to discuss the genetic characteristics in relation to granitoid rocks. The metallogenic provinces of the Gyeongsang Basin are divided into the Au–Ag(–Cu–Pb–Zn) province in the western basin where the sedimentary rocks of the Shindong and Hayang groups are distributed, Pb–Zn(–Au–Ag–Cu), Cu–Pb–Zn(–Au–Ag), and Fe–W(–Mo) province in the central basin where the volcanic rocks of the Yucheon Group are dominant, and Cu(–Mo–W–Fe) province in the southeastern basin where both sedimentary rocks of the Hayang Group and Tertiary volcanic rocks are present. Average sulfur isotope compositions of the ore deposits show high tendencies ranging from 2.2 to 11.7‰ (average 5.4‰) in the Pb–Zn(–Au–Ag–Cu) province, ?0.7 to 11.5‰ (average 4.6‰) in the Cu–Pb–Zn(–Au–Ag) province, and 3.7 to 11.4‰ (average 7.5‰) in the Fe–W(–Mo) province in relation to magnetite‐series granitoids, whereas they are low in the Au–Ag(–Cu–Pb–Zn) province in relation to ilmenite‐series granitoids, ranging from ?2.9 to 5.7‰ (average 1.7‰). In the Cu(–Mo–W–Fe) province δ34S values are intermediate ranging from 0.3 to 7.7‰ (average 3.6‰) and locally high δ34S values are likely attributable to sulfur derived from the Tertiary volcanic rocks during hydrothermal alteration through faults commonly developed in this region. Magma originated by the partial melting of the 34S‐enriched oceanic plate intruded into the volcanic rocks and formed magnetite‐series granitoids in the central basin, which contributed to high δ34S values of the metallic deposits. Conversely, ilmenite‐series granitoids were formed by assimilation of sedimentary rocks rich in organic sulfur that influenced the low δ34S values of the deposits in the western and southeastern provinces. 相似文献
9.
滇西"三江"地区高镁钾质火山岩地球化学特征及其地质意义 总被引：2，自引：2，他引：0
本文报导了位于金沙江-哀牢山断裂带中段6个暗色超基性-基性火山岩的岩石学特征与稀土微量及Sr-Nd-Pb同位素地球化学数据,并对其成因和起源条件等进行了讨论。研究表明这6个暗色超基性-基性火山岩属于钾质碱性-钙碱性系列,依SiO2含量包括超基性、基性(或中基性)岩类。岩石的Mg#值较高(54.53~79.81),属于高镁火山岩。所有岩石样品具有富集轻稀土和大离子亲石元素,亏损高场强元素的特征。Sr-Nd-Pb同位素显示,源区具有具有较明显的Dupal异常和EMⅡ型富集地幔端元的特征。火山岩的岩石学与地球化学一致表明,本区多数暗色基性火山岩具有原生岩浆性质,其成因与富集地幔的部分熔融有关。源区显著的EMII富集地幔端元可能是扬子古陆和古特提斯洋的双向俯冲及俯冲的下地壳物质和古特提斯洋壳沉积物的再循环的物质记录。这套岩石形成于印度-欧亚大陆碰撞后的剪切和拉张构造环境,软流层地幔的上涌与俯冲的古特提斯洋壳沉积物和扬子古陆壳物质的混合,是诱发源区发生部分熔融的主要原因。金沙江-哀牢山断裂带强烈的剪切和拉张,使这些岩浆直接快速喷发至地表,因此形成具有原生岩浆性质的火山岩。 相似文献
10.
《International Geology Review》2012,54(4):346-350
Industrial development of the Angara region has necessitated geological exploration for available resources. The Angara River flows north from Lake Baikal, intersecting the mountains surrounding it; passes through the 'Irkutsk Amphitheater, ' part of the central Siberian platform; and, near Bratsk, flows across a diabase intrusion, forming the Bratsk rapids (approximately 300 kilometers long). The Angara river basin is underlain by crystalline basement (the Siberian craton) composed of schists, gneisses, marble, and Archean and Proterozoic granites. These rocks dip sharply from the Sayan and Baikal ranges, where they outcrop, toward the Irkutsk Amphitheater, where they reach 3000 meters depth. The craton is covered by sediments ranging in age from Cambrian to Quaternary. Lower Cambrian rocks over 2500 meters thick are overlain by Middle Cambrian strata which are generally eroded. In the Irkutsk coal basin, north of Lake Baikal, Mesozoic rocks 600 meters thick are covered unconformably by Tertiary sediments. Quaternary deposits are known to occur; the Angara River terraces are probably pre-Quaternary. Regional tectonics involved fracturing within the Irkutsk Amphitheature and in the surrounding mountains. Geophysical survey and drilling revealed a wide horizontal protrusion (the 'Angara swell') in the Siberian craton; this protrusion divides the Irkutsk Amphitheater in the Pre-Baikal and Pre-Sayan depressions. Overlying Cambrian sediments are folded in conformity with these basement-complex dislocations. Jurassic deposits, generally horizontal, are disturbed only near the younger uplifts of Sayan and Baikal. The southwestern part of a large trap-rock intrusion crosses the Irkutsk Amphitheater; concordant intrusions, e. g. sills, entered lower Paleozoic sediments along with dikes, during late Permian and, principally, Triassic times. Mineral deposits are rich and varied: Precambrian rocks contain magnetic iron ore (of the Krivoy Rog type); talc; magnesite; pure crystalline limestone; and, possibly, phosphates. Paleozoic rocks contain large marine and lacustrine salt deposits, gypsum, phosphatized shell rock, and, possibly, oil: as well as carbonaceous rocks with lead and zinc minerals. Hydrogen-sulfide -saturated and saline mineral waters as well as subsurface water with high potassium content occur in Cambrian rocks. Siberian trap rocks are rich in magnesium and iron; magnesium-magnetite ores occur in volcanic necks as large veins of pure ore, associated with tuffs and aureoles. Trap rock (diabase) may be used in the new stone-melting industry. Jurassic deposits include saprolitic-bog and humus coals as well as extensive fire-clay and high-quality kaolin deposits. Cambrian fossils include trilobite and brachiopod remains, reefs, and molluscs; fish, insects, ostracods, and numerous fossil plant traces, are representative of the Mesozoic. The Angara River terraces, 25 to 30 meters thick, contain mammal remains, brackish-water molluscs, and, from the Middle Paleolithic, Azilian and Solutrean artifacts. -- D. D. Fisher 相似文献
11.
Gary D. Stice 《Contributions to Mineralogy and Petrology》1968,19(4):343-357
The rocks of the Manu'a Islands are predominantly olivine basalt with lesser amounts of picrite basalt (both ankaramite and oceanite), basalt, hawaiite, olivine gabbro, basaltic lapilli tuff, and ash. Alkali silica ratios obtained from chemical analyses of twenty widely selected samples place the rocks in the alkali basalt suite. All of the samples are also high in titanium. Plots of the chemical analyses, including samples from nearby Tutuila Island, show a progressive enrichment in alkalis. The occurrence of hawaiite and picrite basalt indicates that a primitive alkalic olivine basalt magma was undergoing differentiation. The most important factor in this process was crystal settling, especially of olivine. The dunite xenoliths in the late-stage rocks of Ta'u Island probably came from a residual olivine layer near the bottom of the magma chamber. The magma did not become sufficiently silicic to produce the trachytic end-member of the series, which probably would have contained normative and possibly some modal quartz, as on Tutuila Island. With increasing silica content, iron and titanium generally decrease slightly, whereas alkalis increase.Hawaii Institute of Geophysics Contribution No. 237. 相似文献
12.
We report U-Pb crystallization ages from four metavolcanic rocks and two granitic gneiss samples as well as whole-rock chemical analyses and Sm-Nd isotopic ratios from 25 metaigneous and metasedimentary rocks from the Chopawamsic and Milton terranes, southern Appalachian Orogen. A metarhyolite sample from the Chopawamsic Formation and a metabasalt sample from the Ta River Formation in the Chopawamsic terrane have indistinguishable U-Pb crystallization ages of 471.4+/-1.3 Ma and 470.0+1.3/-1.5 Ma, respectively. A sample from the Prospect granite that intruded metavolcanic rocks of the Ta River Formation yields a younger U-Pb date of 458.0+/-1 Ma. Metarhyolite and granitic gneiss samples from the northern part of the Milton terrane yield U-Pb dates of 458.5+3.8/-1.0 Ma and 450+/-1.8 Ma, respectively. Metavolcanic and metaplutonic rocks from both terranes span a range in major element composition from basalt to rhyolite. Trace element concentrations in these samples show enrichment in large-ion lithophile elements K, Ba, and Rb and depletion in high field strength elements Ti and Nb, similar to those from island arc volcanic rocks. Initial epsilon(Nd) values and T(DM) ages of the metaigneous and metasedimentary samples range from 0.2 to -7.2 and from 1200 to 1700 Ma for the Chopawamsic terrane and from 3.7 to -7.2 and from 850 to 1650 Ma for the Milton terrane. The crystallization ages for the metavolcanic and metaplutonic samples from both terranes indicate that Ordovician magmatism occurred in both. Similar epsilon(Nd) values from representative samples from both terranes suggest that both were generated from an isotopically similar source. Xenocrystic zircons from metavolcanic rocks in the Chopawamsic terrane have predominately Mesoproterozoic (207)Pb/(206)Pb ages (600-1300 Ma), but a single Archean (2.56 Ga) core was also present. The xenocrystic zircons and the generally negative epsilon(Nd) values indicate that both terranes are composed of isotopically evolved continental crust. 相似文献
13.
E. A. Mikheeva E. I. Demonterova A. O. Frolov A. V. Arzhannikova S. G. Arzhannikov T. Yu. Cherkashina A. V. Ivanov 《Stratigraphy and Geological Correlation》2017,25(4):363-384
On the basis of the recently accepted chronostratigraphic chart, Jurassic sedimentation in the Irkutsk coal basin took place over a short time interval (~23 My), from the Pliensbachian (~191 Ma) to the Aalenian (~170 Ma). In this study, we present geochemical and Sm-Nd isotope data for sedimentary rocks of the Prisayan and Kuda formations and those in the upper course of the Angara River, which were deposited over an even shorter time interval (from ~174 to 170 Ma), as indicated by new data on biostratigraphy. Our results suggest that a greater contribution from Transbaikalia compared to that from the Siberian Platform during sediment deposition in the Irkutsk coal basin may reflect the onset of mountain building in Transbaikalia and reorganization of the river drainage network during the Middle Jurassic. 相似文献
14.
马拉苏地区早泥盆世地层为一套滨海—浅海相火山—沉积岩系,对其中的火山岩夹层进行锆石U-Pb同位素定年和岩石地球化学研究,定年结果显示有大量的新太古代和中新元古代锆石,表明该区存在古老的大陆地壳物质。火山岩样品SiO2含量为52.38%~69.6%,Na2O含量为2.80%~4.85%,K2O为0.16%~0.96%,TiO2为0.5%~1.96%,Al2O3为14.62%~18.18%,MgO（1.08%~5.75%）变化范围较大,Mg#值在22.92~38之间,具有高钠、低钾的特征,属于钙碱性、低钾拉斑系列。稀土元素总量∑REE=73×10-6~115×10-6,LREE/HREE值为2.66~3.25,具有明显的Eu负异常（0.83~0.92）。玄武安山岩样品相对富集K、Rb、Ba、Sr等大离子亲石元素,亏损Nb、Ta、Zr、Hf等高场强元素,与典型火山弧玄武岩地球化学特征一致。英安斑岩样品也具有富集大离子亲石元素、亏损Nb、Ta、Ti等高场强元素的特征,反映源区可能有较多壳源物质的加入,其稀土元素配分曲线和微量元素蛛网图与玄武安山岩相似,表明其可能为同源岩浆演化的产物。综合研究认为,这套火山岩具有岛弧火山岩特征,形成于板块俯冲拼贴过程中的岛弧环境。 相似文献
15.
Determination of REE, Y, Nb, Zr, Hf, Ta, Th and U in Geological Reference Materials LSHC-1 and Amf-1 by Solution and Laser Ablation ICP-MS 总被引：1，自引：0，他引：1
Elena V. Smirnova Belinda Flem Elena A. Anchutina Irina N. Mysovskaya Valeriy I. Lozhkin Lev L. Petrov † 《Geostandards and Geoanalytical Research》2010,34(1):49-65
This paper presents data on REE and Y, Nb, Zr, Hf, Ta, Th and U abundances for two candidate reference materials (RMs), spinel lherzolite LSHC-1 and amphibole Amf-1, being currently developed at the Institute of Geochemistry SB RAS, Irkutsk. To determine the contents of these elements inductively coupled plasma-mass spectrometry was applied with: (i) solution nebulisation (solution ICP-MS) and (ii) laser ablation (LA-ICP-MS) of fused glass disks. The precision of results obtained by both techniques was better than 6% RSD for most elements. Accuracy was assessed by using the geochemical RMs JB-2, JGb-1 (GSJ) and MAG-1 (USGS). The trace element results by solution ICP-MS for JGb-1 and JB-2 agree with reference values presented by Imai et al. (1995, this Journal) within 1–10%. Significant differences were found for Nb and Ta determinations. The accuracy of LA-ICP-MS results evaluated by RM MAG-1 was within 4%, except for Eu (about 10%). The analytical results obtained for LSHC-1 and Amf-1 by solution ICP-MS and LA-ICP-MS were in good agreement with each other and with INAA and XRF data presented for the certification of these RMs. They can be considered as the indicative values for assigning certified values to the above-mentioned RMs. 相似文献
16.
Trace element data are reported in 21 lava samples from the Alban Hills, one of the most important volcanic complexes of the
Roman comagmatic region. The samples consist mostly of tephritic leucitites with minor phonolitic tephrites and tephritic
phonolites emplaced during two distinct phases of activity, separated by a caldera collapse.
The ferromagnesian element contents are variable (Ni=93-26 ppm; Co=37-20 ppm; Cr=359-5 ppm; Sc=35-6 ppm) and tend to have
higher values in the post-caldera rocks. Rb, Cs, Th, Sr, and LREE are extremely enriched in all the samples analyzed, with
the pre-caldera rocks displaying a lower content of Rb and Cs and a higher abundance of Th, light REE and La/Yb ratio. Ta
and Hf are not so high and are more enriched in the pre-caldera samples. Sr displays comparable values in the two groups of
rocks.
The trace element variation indicates that the rocks from the Alban Hills represent two distinct series of liquids formed
by crystal/liquid fractionation processes starting from two parental magmas. The genesis of the primary melts is hypothesized
as due to a low degree of partial melting of a mantle peridotite enriched in incompatible elements.
All of the studied samples have distribution patterns of incompatible elements normalized against a hypothetical primordial
mantle composition, which are similar to that displayed by the aeolian calc-alkaline and leucite-tephritic products and distinctively
different from those of typical K-rich volcanics from an intraplate rift environment. This strongly supports the hypothesis
that there is a close genetic connection between Roman magmatism and subductionrelated processes. 相似文献
17.
东天山觉罗塔格带阿奇山南部雅满苏组火山岩的岩石学、锆石LA-ICP-MS U-Pb年代学、全岩地球化学和Sr-Nd同位素分析结果表明阿奇山南部雅满苏组火山岩主要由安山岩、英安岩、流纹岩和相应成分的火山碎屑岩组成,夹少量玄武岩。流纹岩和安山岩中的锆石多呈自形-半自形晶,振荡环带发育,Th/U比值为0.44~1.53,指示岩浆成因。定年结果表明它们形成于早石炭末—晚石炭初(318.6~324.4 Ma)。阿奇山南部雅满苏组火山岩的地球化学特征主要为:酸性火山岩为中钾钙碱性系列,中基性火山岩主要为高钾钙碱性系列;稀土配分模式均呈右倾型,轻重稀土分馏明显(LREE/HREE为2.91~9.92);强烈富集Rb、Ba、K、La、Ce等大离子亲石元素,明显亏损Nb、Ta、P、Ti等高场强元素;(~(87)Sr/~(86)Sr)_i值为0.704 01~0.706 36,ε_(Nd)(t)值主要为4.14~7.21。研究结果表明,中基性火山岩的岩浆源区主要为受俯冲流体交代的亏损地幔楔,而酸性火山岩则源于年轻地壳物质。结合前人研究成果,认为阿奇山南部雅满苏组早石炭世末—晚石炭初火山岩形成于大陆边缘环境,其地球动力学机制与古亚洲洋板块向中天山地块之下的俯冲作用有关。 相似文献
18.
V. I. Vinogradov G. A. Belenitskaya M. I. Bujakaite V. N. Kuleshov M. A. Minaeva B. G. Pokrovskii 《Lithology and Mineral Resources》2006,41(2):165-173
Rb-Sr data were obtained for different Lower Cambrian rocks from boreholes Bel’sk and Zhigalovo drilled in the Irkutsk amphitheater. Shales in the lower part and insoluble residue of marls throughout the entire (up to 2 km thick) sequence define the first transformation stage of silicate rocks dated at 580 Ma with a large uncertainty. Sulfate and carbonate rocks are the main Sr carriers in the Lower Cambrian rocks. Owing to a negligible amount of silicate impurities in them, the input of radiogenic Sr exerted no significant influence on the Rb-Sr isotope system. However, almost all carbonate and sulfate rocks studied are contaminated by radiogenic Sr relative to its initial isotopic composition in the sedimentation basin. Hence, the rocks experienced epigenetic (probably, repeated) recrystallization and one or several stages of dissolution. 相似文献
19.
通过锆石LA-MC-ICP-MS Lu-Hf同位素分析,结合前人地球化学资料对舒家店地区中酸性侵入岩进行了研究.主量、微量元素地球化学特征表明区内侵入岩为准铝质,具有岛弧岩浆岩的特征,区内岩浆的演化可能经历了同化混染与分离结晶（AFC）过程.通过分析,我们认为舒家店地区的早白垩世岩浆活动可能与早白垩世初太平洋板块的斜向俯冲相关,侵入岩的形成演化受到了区域构造应力场的制约.Hf同位素分析及计算结果表明,除两个继承性锆石核外,本区侵入岩锆石的εHf（t）均为负值,橄榄安粗岩系列侵入岩的εHf（t）值为-8.6~-4.1,高钾钙碱性系列εHf（t）值为-13.4~-4.7.与高钾钙碱性系列相比,橄榄安粗岩系列侵入岩的εHf（t）更接近球粒陨石演化线.从εHf（t）值的变化特征来看,两个系列侵入岩均为来源于富集地幔,且在演化过程中混染了地壳物质,而高钾钙碱性系列在这个过程中混入了更多的地壳物质. 相似文献