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1.
北武夷地区高家山矽卡岩型铜钼多金属矿床位于扬子地块与华夏地块碰撞对接带萍乡－广丰深大断裂的南侧,前人获得与成矿有关正长斑岩、花岗斑岩体的K-Ar法同位素年龄为63.6Ma、84.7Ma。本文对与成矿有关的正长斑岩和侵入于正长斑岩、花岗斑岩中的闪长玢岩分别进行了精确的锆石U—Pb定年研究,获得锆石 206Pb/238U年龄分别为232.7±0.6Ma和219.6±1.5Ma,属印支期。通过分析矿石的氧、硫同位素和成矿岩体的地质地球化学特点,认为高家山铜钼矿床与印支期富碱性岩浆活动存在密切的时空和成因联系。因此,成矿岩体年龄间接地反映了本矿床的形成时代为印支期,提供了北武夷地区印支期成矿作用的新信息。 相似文献
2.
1017高地银多金属矿床位于内蒙古自治区东乌珠穆沁旗,矿区大地构造位置处于西伯利亚板块东南缘查干敖包-奥尤特-朝不楞早古生代构造-岩浆岩带东段。银多金属矿体主要赋存于上泥盆统安格尔音乌拉组砂岩和华力西中期二长花岗岩中,矿石工业类型主要为石英脉型和蚀变黑云二长花岗岩型。石英脉型矿石中流体包裹体比较发育,相态组合简单,完全均一温度介于175~225℃区间,属于中低温度,盐度平均值为4.42%~11.46%,属于中低盐度。矿石硫同位素组成相对均一,δ34S值介于3.4‰~8.0‰之间,均值5.35‰,与幔源硫的δ34S值(-3‰~3.0‰)比较,有向沉积硫的明显漂移,表明矿石中硫来源于沉积硫与岩浆硫的混合、平衡作用。矿石硫化物铅同位素比值没有明显的差别,206Pb/204Pb值为18.274 0~18.399 6,207Pb/204Pb值为15.539 9~15.561 6,208Pb/204Pb值为38.036 3~38.177 2,具有Th、Pb微弱亏损特征,指示矿石中硫化物的铅源主要来自于亏损U的上地幔和下地壳相互作用的产物,且成矿流体在上升的过程中又混入了部分富集放射性铀铅的地壳物质。矿石氢氧同位素组成为:δDV-SMOW值介于-103‰~-125‰之间,δ18OV-SMOW值在6.9‰~13.9‰之间,显示成矿流体中的水来源于岩浆水与大气降水的混合水。结合1017高地银多金属矿床的区域成矿地质背景和矿床地球化学特征,认为1017银多金属矿床成矿物质来源于深源岩浆和上地壳的混合,成矿流体主要来自于岩浆期后热液和大气降水,其成因类型可归于中低温度、中低盐度的花岗质岩浆热液型银多金属矿床。 相似文献
3.
大别山双河超高压榴辉岩中变质锆石；离子探针和微区结构研究 总被引：19，自引：6，他引：19
对南大别双河超高压岩板榴辉岩中锆石进行了阴极发光、喇曼光谱、U- Pb和氧同位素离子探针微区分析。发现大部分锆石具有核边结构 ,其核和边有明显不同的 U ,Th,Pb含量、Th/ U比、2 0 6 Pb/ 2 38U年龄和δ1 8O值。锆石边部具有变质锆石的结构和化学特征 ,核部具有岩浆锆石向变质锆石变化的过渡特征。 17个点 U - Pb同位素分析中大多数为不一致年龄 ,由 14个正向不一致点所构成的不一致线与一致曲线的上、下交点年龄分别为 2 4 89± 2 5和 2 4 8± 16 Ma,它们代表了榴辉岩原岩形成时间和前进变质至峰期变质过程中原岩岩浆锆石重结晶和变质增生作用的时间 ,大别山变质锆石的成因是复杂的 ,它既可以是变质新生锆石 ,呈独立的颗粒或原岩岩浆锆石的增生边 ,也可以是由原岩锆石在固相或流体存在下的重结晶作用形成。不同程度的重结晶作用是超高压条件下双河榴辉岩原岩岩浆锆石发生的主要的物理化学变化 ,它导致锆石中 U、Th、Pb和Th/ U比的降低和岩浆振荡环带的消退 相似文献
4.
通过矿物流体包裹体Rb-Sr同位素测年,获得鄂北黑龙潭金矿石英Rb-Sr等时线年龄为132.6±2.7Ma,表明该金矿床形成于早白垩世中期。矿石石英中流体包裹体Sr同位素初始比(~(87)Sr/~(86)Sr)i平均值为0.710798,小于陆源硅酸盐的值(0.720),高于地幔Sr的初始值(0.707),暗示成矿物质来源于壳幔混合。结合各类岩矿石Au丰度变化,S、Pb、H、O等同位素组成,以及稀土和微量元素特征、成矿流体等研究,认为该矿床的形成可能与燕山期持续伸展阶段大规模构造-岩浆活动有关,燕山期中酸性岩浆活动为金矿成矿提供了主要矿源和热源。 相似文献
5.
边家大院银多金属矿床位于大兴安岭成矿带南段,是一个典型的热液脉型银多金属矿床。基于稳定同位素C、H、O、S和放射性Pb同位素的测试和分析,对边家大院银多金属矿床成矿流体及物质来源进行示踪。同位素测试结果表明:成矿流体中水的δD_(水-SMOW)值为-138.5‰~-111.7‰,δ~(18)O_(水-SMOW)值为-8.85‰~9.38‰,表明成矿流体为岩浆水与大气降水的混合物。热液方解石δ~(13)C_(PDB)值为-7.7‰~-2.67‰,δ~(18)O_(SMOW)为-0.41‰~6.03‰,表明热液矿物方解石是2个阶段成矿作用的产物,成矿早阶段流体与岩浆水特征相似,碳主要来源于岩浆,成矿晚阶段流体具有大气降水的特征。边家大院银多金属矿床矿石硫化物δ~(34)S值为0.76‰~4.4‰,显示银铅锌矿体的形成与岩浆作用密切相关,硫主要来自岩浆源。矿石样品~(208)Pb/~(204)Pb值介于38.1~38.634,~(207)Pb/~(204)Pb值介于15.518~15.681,~(206)Pb/~(204)Pb值介于18.155~18.284,表明成矿与岩浆作用关系密切,成矿流体中铅主要来自深源岩浆。成矿作用的发生是在一种总硫浓度比较低的平衡体系中进行的。边家大院银多金属矿床的成因类型属于火山-次火山热液脉状银多金属矿床。 相似文献
6.
7.
湘南宝山铅锌矿床硫、铅、碳、氧同位素特征及成矿物质来源 总被引：3，自引：1，他引：2
宝山铅锌矿床是湘南地区代表性矿床之一。宝山铅锌矿床的成矿作用与156~158 Ma的宝山花岗闪长斑岩密切相关。花岗闪长斑岩主要由古老地壳部分熔融而成。为确定成矿物质来源,文章系统研究了宝山铅锌矿床的硫、铅、碳、氧同位素组成特征。矿床中硫化物黄铁矿、闪锌矿、方铅矿的δ34S值呈狭窄的塔式分布,变化在-2.17‰~6.46‰之间,平均值为3.13‰。δ34S值总体表现为δ34S黄铁矿δ34S闪锌矿δ34S方铅矿,表明硫同位素分馏基本达到了平衡。矿石、花岗闪长斑岩和赋矿地层硫同位素对比研究表明,矿石中的硫主要由岩浆分异演化而来,岩浆中的硫主要来自古老地壳。矿石206Pb/204Pb、207Pb/204Pb和208Pb/204Pb比值分别为18.188~18.844、15.661~15.843和38.562~39.912,赋矿地层206Pb/204Pb、207Pb/204Pb和208Pb/204Pb比值分别为18.268~19.166、15.620~5.721和38.364~39.952。矿石铅同位素组成比地层中的更富放射性成因铅,矿石中部分铅来自宝山花岗闪长质岩浆,在成矿流体运移过程中有部分地层铅参与了成矿,岩浆中的铅主要来自古老地壳。热液方解石的碳、氧同位素组成介于岩浆和赋矿碳酸盐岩的碳、氧同位素之间,主要是由于岩浆流体和碳酸盐岩不同比例的水岩反应所致,测水组有机碳的加入造成了部分热液方解石δ13CPDB值偏低。 相似文献
8.
内蒙古哈达门沟金矿床地质特征及成矿作用探讨 总被引：3，自引：0，他引：3
哈达门沟金矿床地处华北克拉通北缘阴山隆起带南缘乌拉山复背斜南翼,金矿体主要产于新太古界乌拉山群变质岩中,主要矿石类型包括含金石英脉、含金石英-钾长石脉、含金钾化蚀变岩等。成矿流体主要为中低温(160~300℃)、中低盐度(5%~15%NaCleq),气相成分以H2O和CO2为主,液相组分阴离子以Cl-和SO2-4为主,阳离子以Na+、K+和Ca2+为主。矿石δ34S变化于-21.7‰~5.4‰,极差为27.1‰,说明成矿物质来源的复杂性,平均值为-10.6‰,表现出亏损重硫的特点,硫继承了太古代地层中硫的同位素特点,并混有深部含矿流体的硫。矿石铅同位素组成、单阶段模式年龄、Th/U比值、μ值变化范围较大,表现出多源特点,在铅构造模式图上,投点比较分散,表明哈达门沟矿石铅来源的复杂性。氢-氧同位素表明,成矿流体来源于岩浆水和部分变质热液,后期有天水的混入。矿石辉钼矿Re-Os同位素加权平均年龄为386.4±2.7Ma,等时线年龄为386.6±6.1Ma,金钼矿床主要成矿时代为早泥盆世,后期有多期热液活动叠加。矿床形成于弧-陆碰撞后的伸展构造背景。 相似文献
9.
新城金矿是胶东金矿集区招远—莱州成矿带的一个"焦家式"蚀变型金矿床。本文主要通过C、H、O、S、Pb同位素研究,对新城金矿成矿流体、物质来源和成矿作用进行探讨和研究。新城金矿矿石中δD值范围为-116‰~-91‰,δ18O水值范围为3.8‰~7.2‰,表明成矿流体早期来源于岩浆水,成矿晚期混入大气降水。矿石硫化物、郭家岭花岗闪长岩、玲珑花岗岩和胶东群δ34S平均值分为7.9‰、6.5‰、8.5‰和6.2‰,认为矿石硫具有对矿区地层及岩浆岩硫的继承性。硫化物矿石206Pb/204Pb=17.115~17.414,207Pb/204Pb=15.460~15.577,208Pb/204Pb=37.912~38.196,显示铅具有壳幔混合来源的特征。碳、氢、氧、硫、铅同位素反映新城金矿成矿物质和流体主要来源于深部岩浆。 相似文献
10.
《地质与勘探》2015,(1)
新城金矿是胶东金矿集区招远—莱州成矿带的一个"焦家式"蚀变型金矿床。本文主要通过C、H、O、S、Pb同位素研究,对新城金矿成矿流体、物质来源和成矿作用进行探讨和研究。新城金矿矿石中δD值范围为-116‰~-91‰,δ18O水值范围为3.8‰~7.2‰,表明成矿流体早期来源于岩浆水,成矿晚期混入大气降水。矿石硫化物、郭家岭花岗闪长岩、玲珑花岗岩和胶东群δ34S平均值分为7.9‰、6.5‰、8.5‰和6.2‰,认为矿石硫具有对矿区地层及岩浆岩硫的继承性。硫化物矿石206Pb/204Pb=17.115~17.414,207Pb/204Pb=15.460~15.577,208Pb/204Pb=37.912~38.196,显示铅具有壳幔混合来源的特征。碳、氢、氧、硫、铅同位素反映新城金矿成矿物质和流体主要来源于深部岩浆。 相似文献
11.
Ghasem Nabatian Majid Ghaderi Fernando Corfu Franz Neubauer Manfred Bernroider Vsevolod Prokofiev Maryam Honarmand 《Mineralium Deposita》2014,49(2):217-234
Iron oxide–apatite deposits are present in Upper Eocene pyroxene-quartz monzonitic rocks of the Zanjan district, northwestern Iran. Mineralization occurred in five stages: (1) deposition of disseminated magnetite and apatite in the host rock; (2) mineralization of massive and banded magnetite ores in veins and stockwork associated with minor brecciation and calcic alteration of host rocks; (3) deposition of sulfide ores together with potassic alteration; (4) formation of quartz and carbonate veins and sericite, chlorite, epidote, silica, carbonate, and tourmaline alteration; and (5) supergene alteration and weathering. U–Pb dating of monazite inclusions in the apatite indicates an age of 39.99?±?0.24 Ma, which is nearly coeval with the time of emplacement of the host quartz monzonite, supporting the genetic connection. Fluid inclusions in the apatite have homogenization temperatures of about 300 °C and oxygen isotopic compositions of the magnetite support precipitation from magmatic fluids. Late-stage quartz resulted from the introduction of a cooler, less saline, and isotopically depleted fluid. The iron oxide–apatite deposits in the Tarom area of the Zanjan district are typical of a magmatic–hydrothermal origin and are similar to the Kiruna-type deposits with respect to mineral assemblages, fabric and structure of the iron ores, occurrence of the ore bodies, and wall rock alteration. 相似文献
12.
Apatite is a common U- and Th-bearing accessory mineral in igneous and metamorphic rocks, and a minor but widespread detrital component in clastic sedimentary rocks. U–Pb and Th–Pb dating of apatite has potential application in sedimentary provenance studies, as it likely represents first cycle detritus compared to the polycyclic behavior of zircon. However, low U, Th and radiogenic Pb concentrations, elevated common Pb and the lack of a U–Th–Pb apatite standard remain significant challenges in dating apatite by LA-ICPMS, and consequently in developing the chronometer as a provenance tool.This study has determined U–Pb and Th–Pb ages for seven well known apatite occurrences (Durango, Emerald Lake, Kovdor, Mineville, Mud Tank, Otter Lake and Slyudyanka) by LA-ICPMS. Analytical procedures involved rastering a 10 μm spot over a 40 × 40 μm square to a depth of 10 μm using a Geolas 193 nm ArF excimer laser coupled to a Thermo ElementXR single-collector ICPMS. These raster conditions minimized laser-induced inter-element fractionation, which was corrected for using the back-calculated intercept of the time-resolved signal. A Tl–U–Bi–Np tracer solution was aspirated with the sample into the plasma to correct for instrument mass bias. External standards (Ple?ovice and 91500 zircon, NIST SRM 610 and 612 silicate glasses and STDP5 phosphate glass) along with Kovdor apatite were analyzed to monitor U–Pb, Th–Pb, U–Th and Pb–Pb ratiosCommon Pb correction employed the 207Pb method, and also a 208Pb correction method for samples with low Th/U. The 207Pb and 208Pb corrections employed either the initial Pb isotopic composition or the Stacey and Kramers model and propagated conservative uncertainties in the initial Pb isotopic composition. Common Pb correction using the Stacey and Kramers (1975) model employed an initial Pb isotopic composition calculated from either the estimated U–Pb age of the sample or an iterative approach. The age difference between these two methods is typically less than 2%, suggesting that the iterative approach works well for samples where there are no constraints on the initial Pb composition, such as a detrital sample. No 204Pb correction was undertaken because of low 204Pb counts on single collector instruments and 204Pb interference by 204Hg in the argon gas supply.Age calculations employed between 11 and 33 analyses per sample and used a weighted average of the common Pb-corrected ages, a Tera–Wasserburg Concordia intercept age and a Tera–Wasserburg Concordia intercept age anchored through common Pb. The samples in general yield ages consistent (at the 2σ level) with independent estimates of the U–Pb apatite age, which demonstrates the suitability of the analytical protocol employed. Weighted mean age uncertainties are as low as 1–2% for U- and/or Th-rich Palaeozoic–Neoproterozoic samples; the uncertainty on the youngest sample, the Cenozoic (31.44 Ma) Durango apatite, ranges from 3.7–7.6% according to the common Pb correction method employed. The accurate and relatively precise common Pb-corrected ages demonstrate the U–Pb and Th–Pb apatite chronometers are suitable as sedimentary provenance tools. The Kovdor carbonatite apatite is recommended as a potential U–Pb and Th–Pb apatite standard as it yields precise and reproducible 207Pb-corrected, 232Th–208Pb, and common Pb-anchored Tera–Wasserburg Concordia intercept ages. 相似文献
13.
The Uzbek Tian Shan is a prominent metal-rich belt, hosting world-class orogenic Au deposits such as Muruntau. However, its post-collisional history in relation to fluid alteration and mineralisation remains elusive. We present apatite U–Pb dates and rare earth element geochemistry for 44 granitoids, revealing a prolonged history of low-grade metamorphism and associated fluid alteration between ~285 and ~240 Ma. A resulting apatite U–Pb age interpolation map reveals two young anomalies that are interpreted as post-orogenic fluid circulation cells. In addition, the extent of Meso-Cenozoic denudation is presented using apatite fission track (FT) age data. In areas of good data coverage, the combined Apatite U–Pb and FT anomalies reveal a correlation with the locations of orogenic Au mineralisation. Although more data is required to further evaluate such correlation, our study illustrates that integrated multi-method apatite thermochronology and geochemistry may have the potential to become a novel viable tool for mineral exploration. 相似文献
14.
浙东晚中生代玄武岩的锆石SHRIMP U-Pb 年代学及其地质意义 总被引：9，自引：0，他引：9
对浙江东部晚中生代分属上下岩系的8个火山-沉积岩地层的玄武岩样品中的锆石进行了内部结构研究,并用
SHRIMP方法测定了U-Pb年龄。结果显示,下岩系玄武岩中多数锆石给出206Pb/238U年龄为 （120±1） Ma,Th/U比值为
0.65~2.44; 上岩系玄武岩中最年轻锆石的206Pb/238U 年龄为（103±2） Ma,Th/U 范围是0.57~3.03。上下岩系的形成时代的结
果与前人研究的相应地层年代一致,但也存在有明显差别。在测定过程中发现,下岩系玄武岩中锆石年龄分布相对集中,
仅有少量的古老锆石残留,表明在玄武岩形成过程中,只有少量地壳成分混染。上岩系中与玄武岩同时形成的锆石含量较少,
多数是捕获锆石,且年龄分布范围较大,几乎覆盖了华南地块所有岩浆活动时代,这表明在玄武岩形成过程中捕获了陆壳
物质,这种陆壳物质很可能是含有不同时期锆石的碎屑沉积岩/物。 相似文献
15.
辽东五龙地区燕山期侵入岩类同源岩浆演化微量元素、同位素证据与金矿成矿 总被引：11，自引：0，他引：11
辽东五龙地区中生代燕山期侵入岩类在时空上与金矿关系密切。该类侵入岩具有接近的微量元素Th／U、Zr／Hf、Nb／Ta值。随着不同岩石类型中的SiO2、MgO的含量的变化，(^87Sr／^66Sr)i和(^143Nd／^144Nd)i值保持不变，说明岩浆在侵位过程中没有明显受到围岩物质混染，且该类侵入岩有着相同的岩浆源区。Sr、Nd同位素组成表明成岩物质以下地壳为主。三股流花岗岩和矿石有相似的Pb同位家组成，结合含金石英脉(矿体)切穿已固结三股流花岗岩的地质事实，暗示了三股流花岗岩不太可能是直接的矿质提供者，推测成矿物质与成岩物质主体来自深部的同一岩浆源区，金矿成矿是同一岩浆源区岩浆演化不同阶段的产物。 相似文献
16.
Heinz-Günter Stosch Rolf L. Romer Farahnaz Daliran Dieter Rhede 《Mineralium Deposita》2011,46(1):9-21
Iron oxide–apatite (IOA) deposits, often referred to as Kiruna-type iron ore deposits, are known to have formed from the Proterozoic
to the Tertiary. They are commonly associated with calc–alkaline volcanic rocks and regional- to deposit-scale metasomatic
alteration. In the Bafq District in east Central Iran, economic iron oxide–apatite deposits occur within felsic volcanic tuffs
and volcanosedimentary sequences of Early Cambrian age. In order to constrain the age of formation of these ores and their
relationship with the Early Cambrian magmatic event, we have determined the U–Pb apatite age for five occurrences in the Bafq
District. In a 206Pb/238U vs. 207Pb/235U diagram, apatite free of or poor in inclusions of other minerals plots along the Concordia between 539 and 527 Ma with four
out of five samples from one deposit clustering at the upper end of this range. For this deposit, we interpret this cluster
to represent the age of apatite formation, whereas the spread towards younger ages may reflect either minor Pb loss or several
events of IOA formation. Apatite with inclusions of monazite (±xenotime) yields disturbed systems with inclusions having developed
after formation of the iron ore–apatite deposits, possibly as late as 130–140 Ma ago. Obtained apatite ages confirms that
(IOA) and the apatite-rich rocks (apatites) of the Bafq district formed coevally with the Early Cambrian magmatic (-metasomatic)
events. 相似文献
17.
黔东—湘西早古生代岩石圈热状态与高产热率HHPRM型地幔源区 总被引：1，自引：0，他引：1
岩石圈热结构和热状态的研究对于大陆裂解、变质作用及活化构造形成机制等大陆动力学问题的研究十分重要。通过地球化学、构造地质学和综合分析,以贵州省镇远地区金伯利岩-钾镁煌斑岩和黔东—湘西一带的晚元古代地层为例,研究了扬子地块东南缘早古生代岩石圈热结构与热状态。提出高放射性元素产热率的HHPRM型地幔源区,进一步讨论HHPRM型地幔源区形成与演化的大陆动力学机制。认为古富集地幔(HHPRM型地幔源区)是镇远一带的早古生代钾镁煌斑岩-金伯利岩的岩浆源区,镇远地区金伯利岩-钾镁煌斑岩岩浆源区深度(H)在208～244km,形成温度在1547～1403℃间,该温度和深度范围属软流层,具有形成金刚石矿床的地质条件。建议在贵州—湖南—广西三省交界区的金伯利岩和钾镁煌斑岩岩群中应进一步开展金刚石矿床研究与勘查工作。 相似文献
18.
Gregory J. Holk T. Kurtis Kyser Don Chipley Eric E. Hiatt Jim Marlatt 《Journal of Geochemical Exploration》2003,80(2-3):297-320
Lead isotope ratios and associated trace element concentrations (U, Th and Pb) extracted by partial-leaching with 2% nitric acid from Proterozoic sandstones and basement rocks reveal much about the fluid evolution of sedimentary basins hosting unconformity-type uranium deposits. In addition, these techniques have great potential as a guide for exploration of uranium and other types of deposits in basins of any age. Isotope ratios of Pb in Proterozoic sandstones from basins known to contain high-grade uranium deposits are radiogenic at key geological localities and settings distal to known mineralization and particularly in altered zones proximal to mineralization. Sandstones completely cemented by quartz overgrowths typically have non-radiogenic Pb isotope ratios, indicating early closure of porosity and isolation of these rocks from later fluid events. Alternatively, the unconformity served as both a source of uranium and radiogenic Pb as well as an avenue for late-stage (<250–900 Ma) fluid flow. The mafic volcanic units, which are relatively reducing lithologies and therefore have removed uranium from basinal brines, have uranium-supported radiogenic Pb isotope ratios. Comparison of 238U/206Pb and 206Pb/204Pb ratios is useful in determining the timing and nature of U and Pb migration before, during and after mineralization in these basins. This comparison can be used to delineate the presence of radiogenic Pb isotope ratios that are not internally supported by uranium and thorium in rocks, eventually providing the explorationist with geochemical vectors that point toward sites of high potential for economic uranium mineralization. 相似文献
19.
20.
新疆新源县城南石炭纪火山岩岩石学和元素地球化学研究 总被引：14，自引：0，他引：14
新疆新源县南部那拉提山北坡出露的石炭纪火山岩主要由玄武岩、玄武质粗面安山岩、粗面安山岩、安山岩、流纹岩和火山碎屑岩组成。该火山岩中玄武岩属于钙碱性系列,安山质岩石和流纹岩属于高钾钙碱性系列,其中轻稀土轻微富集而重稀土相对亏损,玄武岩富集大离子亲石元素、U、Th和Pb,亏损高场强元素。研究表明,该火山岩岩浆可能是由俯冲板片脱水产生的流体交代地幔楔后,地幔楔发生部分熔融的结果。微量元素模拟计算表明,该玄武岩岩浆可以由石榴石二辉橄榄岩经3％～6％的部分熔融得到;安山质岩浆可由玄武岩岩浆经15％-28％的分离结晶形成。 相似文献